CN106070311A - The Herbicidal combinations of a kind of Glufosinate-ammoniumpesticideng and haloxyfop-P-methyl and application thereof - Google Patents
The Herbicidal combinations of a kind of Glufosinate-ammoniumpesticideng and haloxyfop-P-methyl and application thereof Download PDFInfo
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- CN106070311A CN106070311A CN201610459123.0A CN201610459123A CN106070311A CN 106070311 A CN106070311 A CN 106070311A CN 201610459123 A CN201610459123 A CN 201610459123A CN 106070311 A CN106070311 A CN 106070311A
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- glufosinate
- haloxyfop
- herbicidal combinations
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
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- Agronomy & Crop Science (AREA)
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- Health & Medical Sciences (AREA)
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- General Health & Medical Sciences (AREA)
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Abstract
The invention discloses Herbicidal combinations and the application thereof of a kind of Glufosinate-ammoniumpesticideng and haloxyfop-P-methyl, this Herbicidal combinations with glufosinate-ammonium with haloxyfop-P-methyl as principle active component, glufosinate-ammonium is 1:60~60:1 with the mass ratio of haloxyfop-P-methyl.Herbicidal combinations of the present invention can be used for Soybean Field postemergence weed control, has remarkable result especially for preventing and kill off grass family and broad leaved weed in Soybean Field.Herbicidal combinations of the present invention on the premise of improve drug effect, delays Weed Resistance relative to single dose, and herbicidal spectrum is wide, and the lasting period is long, and Semen sojae atricolor and succession crop are all had safety.
Description
Technical field
The invention belongs to technical field of pesticide, especially herbicide field, be specifically related to a kind of Glufosinate-ammoniumpesticideng and fluorine pyrrole first
The binary built Herbicidal combinations of standing grain spirit, this Herbicidal combinations can be applicable to Soybean Field postemergence weed control.
Background technology
Glufosinate-ammonium (Glufosinate-ammonium).Chemical name: 4-[hydroxyl (methyl) phosphono] high third ammonia of-DL-
Acid, has another name called grass fourth phosphine, is the organophosphorus herbicide of a kind of non-selective foliage-spray, and 1979 by Germany Hoechst
(Hoechst) first chemical company synthesizes exploitation.The herbicide effect mechanism of glufosinate-ammonium be absorbed by blade after, have part in
Suction effect, can be by blade base to end-transfer, and to other positions of plant, transfer is less, to the plumelet not being unearthed and seed without
Evil.In plant, disorder is the most i.e. sunk in ammonium metabolism, and strong cytotoxic agent ammonium ion is at plant interior accumulation;
Make dunsiekte and dead.Photosynthesis is the most heavily suppressed simultaneously, in yellow-white after plant chlorosis of being injured, starts after 2~5 days
Withered and yellow die.Lose activity after contact soil, only preferably make stem and leaf spraying after Seedling.Glufosinate-ammonium is mainly used in orchard, vineyard, Ma Ling
Potato field, nursery, forest, pasture, ornamental shrub and the total weed control of no-tillage ground, prevent and kill off annual and perennial grassy weed,
Such as amur foxtail, wild oat, Herba Digitariae, barnyard grass, Herba Setariae Viridis, annual bluegrass, quackgrass, Bermuda grass, bent grass, phragmites communis, fescue grass etc..Also
The broad-leaveds such as Herba chenopodii, Herba Amaranthi tricoloris, knotweed, shepherd's purse, Herba Solani Nigri, Herba stellariae mediae, Herba Portulacae, Herba Galii Teneri, Herba Sonchi Oleracei, creeping thistle, Herba seu Flos Convolvuli arvensis, Herba Taraxaci can be prevented and kill off miscellaneous
Grass, also has certain effect to dried tuber and pteridophyta.
Haloxyfop-P-methyl (Haloxyfop-methyl), chemical name: 2-[4-(3-chloro-5-trifluoromethyl-2-pyridine oxygen
Base) phenoxy group] methyl propionate.
Haloxyfop-P-methyl is selective herbicide after heterocyclic oxy group phenoxy group fatty acid Seedling, fatty acid synthetic inhibitor,
Having Uptake and translocation effect, stem and leaf is quickly absorbed by weeds after processing and is transferred to whole plant, is hydrolyzed into acid, suppression root and stem
Separate living tissue growth, cause death.Horse is prevented and kill off for multiple broad leaf crops such as Semen sojae atricolor, Cotton Gossypii, Semen arachidis hypogaeae, Brassica campestris L, nursery, Caulis et Folium Lini
Annual gramineous weed and the perennial standing grain such as Bermuda grass, Herba Imperatae such as Tang, amur foxtail, Herba Eleusines Indicae, barnyard grass, Herba Setariae Viridis, Semen Euphorbiae
Undergraduate course weeds, invalid to broadleaved herb and dried tuber.
Soybean field herbicide is limited by crop safety at present, and weed control spectrum is the most limited, is used alone a kind of herbicide single dose
Can not control the generation of soybean weeds completely effectively, furthermore some herbicide due to water solublity is big or the field lasting period too
Long, consumption is excessive or the uneven residual hazard all easily caused this season crop or succession crop of dispenser.Inventor is after deliberation
Finding, the synergistic complex of herbicide is to expand weed control spectrum and improve the effective measures of preventive effect, is the most not yet found to have
Close the Herbicidal combinations that glufosinate-ammonium is compounding with haloxyfop-P-methyl.
Summary of the invention
It is an object of the invention to provide the Herbicidal combinations of a kind of Glufosinate-ammoniumpesticideng and haloxyfop-P-methyl.
It is a further object of the present invention to provide the application in Soybean Field weeding of this Herbicidal combinations.
The purpose of the present invention is achieved through the following technical solutions:
A kind of Glufosinate-ammoniumpesticideng and the Herbicidal combinations of haloxyfop-P-methyl, this Herbicidal combinations is with glufosinate-ammonium and haloxyfop-P-methyl
For principle active component, glufosinate-ammonium is 1:60~60:1 with the mass ratio of haloxyfop-P-methyl.Preferably glufosinate-ammonium and haloxyfop-P-methyl
Mass ratio be 1:20~40:1, most preferably 1:30~40:1.In some preferred technical schemes: glufosinate-ammonium and fluorine pyrrole first
Standing grain spirit can 34:1,29:1,59:1,12:1,60:1,50:1,40:1,20:1,10:1,5:1,1:1,1:5,1:10,1:20,
These ratios of 1:30,1:50,1:60 select.
This compound weeding composition can comprise only active component glufosinate-ammonium and haloxyfop-P-methyl, it is possible to when using or prepare
Adding other components in active component, the active ingredient in this Pesticidal combination can be present in compositions with enhancing effective amount
In.
In Herbicidal combinations, glufosinate-ammonium and both haloxyfop-P-methyls weight/mass percentage composition in Herbicidal combinations is
1%~80%, preferred mass percentage composition is 10%~65%.
In the binary built compositions of the glufosinate-ammonium of the present invention and haloxyfop-P-methyl, except glufosinate-ammonium and haloxyfop-P-methyl etc.
Outside effective ingredient, it is also possible to add conventional surfactants, thickening agent, solvent or the solid packing etc. allowed on pesticidal preparations and help
Agent is configured on pesticide any one dosage form allowed.Preferably it is processed into cream, suspending agent, aqueous emulsion, microemulsion, water-dispersible grain
Agent, wettable powder etc..
Herbicidal combinations of the present invention can be applied in Soybean Field postemergence weed control, particularly standing grain in preventing and kill off Soybean Field
In undergraduate course and broad leaved weed, application has remarkable result.
The present invention select can weed control spectrum different, the complementary two kinds of herbicides of glufosinate-ammonium and haloxyfop-P-methyl of pluses and minuses suitably subtract
It is made into mixture after amount to use, had the most both expanded weed control spectrum, hence it is evident that improve herbicidal effect, it also avoid and this season crop is produced
Poisoning and the probability to succession crop generation residual hazard.
The Herbicidal combinations of the present invention has the advantage that
1, activity of weeding is high.The Herbicidal combinations of the present invention can kill weeds by two kinds of different mechanism so that weeds
Resistance produces speed and reduces, and is greatly enhanced the removing activity of herbicide.
2, herbicidal spectrum is wide, and the lasting period is long.After both mixing, it is possible to increase multiple grassy weed and broad leaved weed are prevented
Control.
3, Weed Resistance is delayed.Herbicidal combinations of the present invention passes through binary built, reduces the weeds resistance to medicament, and carries
The preventive effect of high antagonism weeds, thus extend the service life of medicament.
4, safety is high.Owing to its using dosage is under control, making medicament on the premise of improve drug effect, it is to greatly
The safety of bean and succession crop have also been obtained raising.
The Herbicidal combinations of the present invention, is applied to Soybean Field postemergence weed control, and it can prevent and kill off various grass family in Soybean Field
And broad leaved weed, on the premise of improve drug effect, Semen sojae atricolor and succession crop are all had safety.
Therefore, Herbicidal combinations of the present invention can be applied in the herbicide of Soybean Field postemergence weed control in preparation,
Particularly the herbicide of grass family and broad leaved weed is applied for preventing and kill off in Soybean Field in preparation.
Detailed description of the invention
In order to make the purpose of the present invention, technical scheme and advantage clearer, below in conjunction with embodiment, to the present invention
It is further elaborated.Should be appreciated that specific embodiment described herein, only in order to explain the present invention, is not used to limit
Determining the present invention, all simple modifications under the concept thereof of the present invention to preparation method of the present invention broadly fall into the protection model of the present invention
Within enclosing.
In all formula of following example, percentage ratio is mass percent.The processing work of the various preparation of the present composition
Skill is prior art, can be varied from according to different situations.
One, dosage form prepares embodiment
Embodiment 1:35% glufosinate-ammonium haloxyfop-methyl missible oil (34:1)
Glufosinate-ammonium 34%, haloxyfop-P-methyl 1%, alkylphenol polyoxyethylene 4%, phenethyl phenol polyethenoxy ether 15%,
Dimethylbenzene complements to 100%, is configured to, according to conventional formulation method, the cream that weight/mass percentage composition is 35%.
Embodiment 2:30% glufosinate-ammonium haloxyfop-P-methyl suspending agent (29:1)
Glufosinate-ammonium 29%, haloxyfop-P-methyl 1%, methyl naphthalene sulfonate formaldehyde condensate 6%, NPE
3%, aluminium-magnesium silicate 0.5%, ethylene glycol 7%, tributyl phosphate 2%, silicone oil 0.2%, surplus is water, according to conventional preparation side
Method is configured to the suspending agent that weight/mass percentage composition is 30%.
Embodiment 3:60% glufosinate-ammonium haloxyfop-P-methyl water dispersible granules (59:1)
Glufosinate-ammonium 59%, haloxyfop-P-methyl 1%, NNO (sodium methylene bis-naphthalene sulfonate) 5%, ammonium sulfate 3%, polyvinyl alcohol
2%, Kaolin complements to 100%, is configured to, according to conventional formulation method, the water dispersible granules that weight/mass percentage composition is 60%
(WDG)。
Embodiment 4:65% glufosinate-ammonium haloxyfop-P-methyl wettable powder (12:1)
Glufosinate-ammonium 60%, haloxyfop-P-methyl 5%, NNO (sodium methylene bis-naphthalene sulfonate) 6%, sodium lignin sulfonate 4% is high
Ridge soil complements to 100%, is configured to, according to conventional formulation method, the wettable powder (WP) that weight/mass percentage composition is 65%.
Embodiment 5:61% glufosinate-ammonium haloxyfop-methyl missible oil (60:1)
Glufosinate-ammonium 60%, haloxyfop-P-methyl 1%, alkylphenol polyoxyethylene 4%, phenethyl phenol polyethenoxy ether 15%,
Dimethylbenzene complements to 100%, is configured to, according to conventional formulation method, the cream that weight/mass percentage composition is 61%.
Embodiment 6:61% glufosinate-ammonium haloxyfop-methyl missible oil (1:60)
Glufosinate-ammonium 1%, haloxyfop-P-methyl 60%, alkylphenol polyoxyethylene 4%, phenethyl phenol polyethenoxy ether 15%,
Dimethylbenzene complements to 100%, is configured to, according to conventional formulation method, the cream that weight/mass percentage composition is 61%.
Embodiment 7:51% glufosinate-ammonium haloxyfop-P-methyl suspending agent (50:1)
Glufosinate-ammonium 50%, haloxyfop-P-methyl 1%, methyl naphthalene sulfonate formaldehyde condensate 6%, NPE
3%, aluminium-magnesium silicate 0.5%, ethylene glycol 7%, tributyl phosphate 2%, silicone oil 0.2%, surplus is water, according to conventional preparation side
Method is configured to the suspending agent that weight/mass percentage composition is 51%.
Embodiment 8:51% glufosinate-ammonium haloxyfop-P-methyl suspending agent (1:50)
Glufosinate-ammonium 1%, haloxyfop-P-methyl 50%, methyl naphthalene sulfonate formaldehyde condensate 6%, NPE
3%, aluminium-magnesium silicate 0.5%, ethylene glycol 7%, tributyl phosphate 2%, silicone oil 0.2%, surplus is water, according to conventional preparation side
Method is configured to the suspending agent that weight/mass percentage composition is 51%.
Embodiment 9:31% glufosinate-ammonium haloxyfop-P-methyl water dispersible granules (1:30)
Glufosinate-ammonium 1%, haloxyfop-P-methyl 30%, NNO (sodium methylene bis-naphthalene sulfonate) 5%, ammonium sulfate 3%, polyvinyl alcohol
2%, Kaolin complements to 100%, is configured to, according to conventional formulation method, the water dispersible granules that weight/mass percentage composition is 31%.
Embodiment 10:41% glufosinate-ammonium haloxyfop-P-methyl water dispersible granules (40:1)
Glufosinate-ammonium 40%, haloxyfop-P-methyl 1%, NNO (sodium methylene bis-naphthalene sulfonate) 5%, ammonium sulfate 3%, polyvinyl alcohol
2%, Kaolin complements to 100%, is configured to, according to conventional formulation method, the water dispersible granules that weight/mass percentage composition is 41%.
Embodiment 11:42% glufosinate-ammonium haloxyfop-P-methyl wettable powder (20:1)
Glufosinate-ammonium 40%, haloxyfop-P-methyl 2%, NNO (sodium methylene bis-naphthalene sulfonate) 6%, sodium lignin sulfonate 4% is high
Ridge soil complements to 100%, is configured to, according to conventional formulation method, the wettable powder that weight/mass percentage composition is 42%.
Embodiment 12:21% glufosinate-ammonium haloxyfop-P-methyl wettable powder (1:20)
Glufosinate-ammonium 1%, haloxyfop-P-methyl 20%, NNO (sodium methylene bis-naphthalene sulfonate) 6%, sodium lignin sulfonate 4% is high
Ridge soil complements to 100%, is configured to, according to conventional formulation method, the wettable powder that weight/mass percentage composition is 21%.
Embodiment 13:33% glufosinate-ammonium haloxyfop-P-methyl aqueous emulsion (1:10)
Glufosinate-ammonium 3%, haloxyfop-P-methyl 30%, methyl naphthalene sulfonate formaldehyde condensate 6%, NPE
3%, aluminium-magnesium silicate 0.5%, ethylene glycol 7%, tributyl phosphate 2%, solvent naphtha 20%, water complements to 100%, according to routine
Formulation method is configured to the aqueous emulsion that weight/mass percentage composition is 33%.
Embodiment 14:33% glufosinate-ammonium haloxyfop-P-methyl aqueous emulsion (10:1)
Glufosinate-ammonium 30%, haloxyfop-P-methyl 3%, methyl naphthalene sulfonate formaldehyde condensate 6%, NPE
3%, aluminium-magnesium silicate 0.5%, ethylene glycol 7%, tributyl phosphate 2%, solvent naphtha 20%, water complements to 100%, according to routine
Formulation method is configured to the aqueous emulsion that weight/mass percentage composition is 33%.
Embodiment 15:30% glufosinate-ammonium haloxyfop-P-methyl microemulsion (5:1)
Glufosinate-ammonium 25%, haloxyfop-P-methyl 5%, methyl naphthalene sulfonate formaldehyde condensate 6%, NPE
3%, aluminium-magnesium silicate 0.5%, ethylene glycol 7%, tributyl phosphate 2%, water complements to 100%, joins according to conventional formulation method
Make the microemulsion that weight/mass percentage composition is 30%.
Embodiment 16:60% glufosinate-ammonium haloxyfop-P-methyl wettable powder (1:5)
Glufosinate-ammonium 10%, haloxyfop-P-methyl 50%, NNO (sodium methylene bis-naphthalene sulfonate) 6%, sodium lignin sulfonate 4% is high
Ridge soil complements to 100%, is configured to, according to conventional formulation method, the wettable powder that weight/mass percentage composition is 60%.
Embodiment 17:10% glufosinate-ammonium haloxyfop-P-methyl wettable powder (1:1)
Glufosinate-ammonium 5%, haloxyfop-P-methyl 5%, NNO (sodium methylene bis-naphthalene sulfonate) 6%, sodium lignin sulfonate 4%, kaolinite
Soil complements to 100%, is configured to, according to conventional formulation method, the wettable powder that weight/mass percentage composition is 10%.
Two, drug effect checking test
1), toxicity determination test
According to effective ingredient glufosinate-ammonium: haloxyfop-P-methyl quality proportioning is: 34:1,29:1,59:1,12:1,60:1,50:
1,40:1,20:1,10:1,5:1,1:1,1:5,1:10,1:20,1:30,1:50,1:60 test, and measure it to Soybean Field
The co-toxicity coefficient of common weed Bermuda grass.
Test method: be seeded in respectively in the Disposable paper cup of 9cm by the seed of quantitative Bermuda grass, sows 10 in every glass
~15 seeds, cultivate in illumination box, when the 3~6 leaf phase of Bermuda grass, crawler type crops sprayer is sprayed
Process.Continuing in greenhouse after process to cultivate, routine observation respectively processes the preventive effect to weeds, after weighing each process after 30d
Weeds fresh weight, calculates its toxicity regression curve and co-toxicity coefficient.Co-toxicity coefficient is more than 100, shows that two kinds of active substance have increasing
Effect effect, co-toxicity coefficient is more than 120, shows that two kinds of active substance have notable potentiation, and co-toxicity coefficient is less than 100, shows
Two kinds of active substance have antagonism.Measurement result is as shown in table 1.
Table 1 toxicity measurement result
As it can be seen from table 1 glufosinate-ammonium herbicidal effect to Bermuda grass compounding with haloxyfop-P-methyl significantly improves, illustrate two
Person is compounding to have significant synergies to preventing and kill off Bermuda grass.Especially the proportioning of glufosinate-ammonium and haloxyfop-P-methyl at 1:30~
Between 40:1, the co-toxicity coefficient after two kinds of active substance are compounding is optimum, illustrates that the present invention has obvious potentiation.
2), field control effectiveness test.
Reagent agent:
The glufosinate-ammonium of embodiment 1~17 preparation and the re-compounded binary herbicide of haloxyfop-P-methyl different ratio.
Comparison medicament:
30% glufosinate-ammonium AS (commercially available), 10.8% haloxyfop-P-methyl EC (commercially available).
For studying thing: Semen sojae atricolor
Big bean seedlings grow fine, and robust plant, without other pest and disease damages.
Prevent and kill off object:
The weeds such as Herba Eleusines Indicae, amur foxtail, Herba Digitariae, barnyard grass, Herba Setariae Viridis, Semen Euphorbiae, Herba Commelinae, Herba Acalyphae, Bermuda grass.
Test method:
According to the area of experimental plot, the good various medicaments of precise, and after being watered dilution, utilize knapsack sprayer,
Carry out even spraying, the Fan spray head that sprinkler selection herbicide is special.During spraying, it should be noted that uniformly spray application to test little by medicinal liquid
Qu Zhong, accomplishes do not have drain spray, the phenomenon of many sprays.
After test, after medicine, 20d, 40d observe weeds death condition respectively, and compare the activity of weeding of various medicaments.This
Outward, after medicine, the condition of production consumption of every mu of ground effective ingredient (consumption be) of crop is also observed in 1~15d, to investigate
Whether medicament has poisoning to crop.
Embodiments of the invention preparation Herbicidal Testing Trials effect see table 2 (20d after medicine) and table 3 (40d after medicine)
Table 2 field control effectiveness test result (20d after medicine)
Table 3 field control effectiveness test result (40d after medicine)
From table 2 and table 3 it can be seen that glufosinate-ammonium is compounding with haloxyfop-P-methyl has expansion herbicidal spectrum and raising activity of weeding
Effect, and extend the lasting period of medicament.Can effectively prevent and kill off broad leaved weed and grassy weed, its preventive effect is better than single dose
Preventive effect, illustrate that the two compounding preventive effect to broad leaved weed in Soybean Field and grassy weed has significant potentiation.
Table 4 medicament security survey result to crop
Each Semen sojae atricolor processed in community grows fine, and has no any medicine speckle, illustrates that various medicament is the safest to Semen sojae atricolor.
Claims (9)
1. a Glufosinate-ammoniumpesticideng and the Herbicidal combinations of haloxyfop-P-methyl, it is characterised in that this Herbicidal combinations is with glufosinate-ammonium and fluorine
Pyrrole first standing grain spirit is principle active component, and wherein, glufosinate-ammonium is 1:60~60:1 with the mass ratio of haloxyfop-P-methyl.
Herbicidal combinations the most according to claim 1, it is characterised in that glufosinate-ammonium and haloxyfop-methyl in this Herbicidal combinations
The mass ratio of spirit is 1:20~40:1.
Herbicidal combinations the most according to claim 1, it is characterised in that glufosinate-ammonium and amicarbazone in this Herbicidal combinations
Mass ratio be 1:30~40:1.
4. according to the Herbicidal combinations described in claim 1,2 or 3, it is characterised in that glufosinate-ammonium is being removed with both haloxyfop-P-methyls
Weight/mass percentage composition in grass compositions is 1%~80%.
Herbicidal combinations the most according to claim 4, it is characterised in that glufosinate-ammonium and both haloxyfop-P-methyls are in weeding group
Weight/mass percentage composition in compound is 10%~65%.
Herbicidal combinations the most according to claim 1, it is characterised in that this Herbicidal combinations is with glufosinate-ammonium and haloxyfop-methyl
Spirit is configured to any one dosage form for the auxiliary agent allowed on principle active component and pesticide.
Herbicidal combinations the most according to claim 6, it is characterised in that described dosage form be cream, suspending agent, aqueous emulsion,
Microemulsion, water dispersible granules or wettable powder.
8. the application in Soybean Field postemergence weed control of the Herbicidal combinations described in claim 1.
Application the most according to claim 1, it is characterised in that described Herbicidal combinations grass family in preventing and kill off Soybean Field
With the application in broad leaved weed.
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CN107396934A (en) * | 2017-08-04 | 2017-11-28 | 安徽圣丰生化有限公司 | A kind of dispersible oil-suspending agent of Glufosinate-ammoniumpesticideng, fluoroglycofen-ethyl and haloxyfop-r-methyl and preparation method thereof |
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WO2019030097A3 (en) * | 2017-08-09 | 2019-03-21 | Basf Se | Herbicidal mixtures comprising l-glufosinate and their use in soybean cultures |
US11363818B2 (en) | 2017-08-09 | 2022-06-21 | Basf Se | Herbicidal mixtures comprising L-glufosinate and their use in soybean cultures |
US12137689B2 (en) | 2017-08-09 | 2024-11-12 | Basf Se | Herbicidal mixtures comprising L-glufosinate and their use in soybean cultures |
US12144351B2 (en) | 2017-08-09 | 2024-11-19 | Basf Se | Herbicidal mixtures comprising L-glufosinate and their use in corn cultures |
CN113519548A (en) * | 2021-08-18 | 2021-10-22 | 孟州传奇生物科技有限公司 | Herbicide composition and application thereof |
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