CN106007642A - Grade A1 fireproof wall/floor tile and making method thereof - Google Patents
Grade A1 fireproof wall/floor tile and making method thereof Download PDFInfo
- Publication number
- CN106007642A CN106007642A CN201610340624.7A CN201610340624A CN106007642A CN 106007642 A CN106007642 A CN 106007642A CN 201610340624 A CN201610340624 A CN 201610340624A CN 106007642 A CN106007642 A CN 106007642A
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- Prior art keywords
- floor tile
- wall
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- level fire
- grade
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/30—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/60—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
- C04B41/61—Coating or impregnation
- C04B41/70—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Floor Finish (AREA)
- Finishing Walls (AREA)
Abstract
The invention discloses a grade A1 fireproof wall/floor tile and a making method thereof. The wall/floor tile consists of a substrate, an interface layer and a transfer printing layer in sequence from inside to outside, wherein the wall/floor tile substrate is prepared from the following components in parts by mass: 100 parts of magnesium sulfate solution, 110 parts of magnesium oxide, 30-70 parts of quartz sand, 1-3 parts of modifier and 0-2 parts of reinforcing agent. The invention further discloses a making method of the grade A1 fireproof wall/floor tile. The grade A1 fireproof wall/floor tile has a grade A1 fireproofing function, is inflammable at the temperature of 900 DEG C, is free from flame at the temperature of 1,300 DEG C, is over 3 hours in fire-resistant limit, and can protect the main body structures of buildings from being damaged in the case of fire disasters; the production process is simple, the investment is small, and the energy consumption is low; the grade A1 fireproof wall/floor tile is a novel environment-friendly building material which is insusceptible to self-destruction, is convenient for construction and is low in price.
Description
Technical field
The invention belongs to building material field, be specifically related to a kind of A1 level fire wall floor tile and preparation method thereof.
Background technology
At present, China has been construction material manufacturing country maximum in the world and country of consumption.Numerous the building of category
Building in material, Wall or floor tile is liked by people and extensively because of advantages such as its clean, clean and tidy, easy cleanings attractive in appearance
Using, can meet the occasion of naked light especially for kitchen and toilet etc., people especially can be without the least hesitation
Select Wall or floor tile, it is believed that Wall or floor tile is the inorganic fire proof material of standard.Actually this is not so, and test shows, when one
When block standard ceramic tile is placed on naked light barbecue, less than a minutes, ceramic tile will burst in fragment.Study carefully
Its reason is that the heat conductivity of pottery is poor, and during variations in temperature, the surface of brick is heated inequality, everywhere thermal stress
Uneven, under the effect of stress, Wall or floor tile bursts.Thus, when meeting with fire, common wall
Floor tile cannot protect building body.
As far as we know, the most also there is not the specialty fire prevention ceramic tile with A1 level fire protecting performance, one
A little occasions needing to use fire prevention ceramic tiles, such as the tunnel etc. of highway, can only use in a large number fireproof coating or
Or at Wall or floor tile surface-coated fire-retardant paint, not only add cost and the complicated construction technique of tile work.
The most generally there is the problems such as investment of production is big, energy consumption is high in current Wall or floor tile production line.Therefore, exploitation
New Wall or floor tile production technology, it is achieved energy-saving and emission-reduction, environmental protection are the task of top priority of the industry.
Summary of the invention
It is an object of the invention to provide one and can overcome that existing Wall or floor tile fire protecting performance is poor, energy consumption is high lacks
The wall or floor tile of point, a kind of A1 level fire wall floor tile.
The present invention is achieved in that a kind of A1 level fire wall floor tile, it is characterised in that: described Wall or floor tile by
In outwards consist of matrix, boundary layer and transfer printing layer successively, prepare each component of described Wall or floor tile base layer
And mass fraction is:
Baume degrees is the Adlerika 100 parts of 28 degree;
Magnesium oxide: 110 parts;
Quartz sand: 30~70;Part
Modifying agent: 1~3 part;
Reinforcing agent: 0~2 part;
The Baume degrees of described Adlerika is 28 degree;
Described reinforcing agent is the one in glass fibre, asbestos fibre, cellulose fibre, staple fibre or several
Kind;
The particular make-up of described modifying agent and mass ratio be, polyvinyl alcohol: hydrochloric acid: sodium hydroxide: acryloyl
Amine=80:1:1:12.
Further, the raw material of described reinforcing agent uses stalk powder, straw wide material sources, and cost is relatively low,
It is recycled energy-conserving and environment-protective.
Further, described boundary layer is formed by interfacial agents coating, the component of described interfacial agents and quality proportioning
It is respectively, 50% water, 30% water-base resin and 20% titanium dioxide.
Further, the printing decorative pattern that described transfer printing layer includes being transferred by water or the method for thermal transfer is formed.
Another object of the present invention is to, it is provided that the preparation technology of a kind of A1 level fire wall floor tile, its feature exists
In: comprise the following steps:
S1: weigh each component by material mixture ratio and deposit respectively;
S2: by the quartz sand weighed, Adlerika, magnesium oxide, modifying agent and reinforcing agent mix homogeneously system
Obtain idiosome castable;
S3: the idiosome castable in S2 is poured into mould and pours into a mould;
S4: the mould being cast with idiosome castable is placed in room of resting, at ambient temperature shape after natural drying
Become Wall or floor tile idiosome;
S5: in described Wall or floor tile idiosome surface-coated interfacial agents;
S6: transferred by water or the method for thermal transfer is being coated with the Wall or floor tile surface printing decorative pattern of interfacial agents also
Decorative pattern is carried out UV light oil processing, dried acquisition Wall or floor tile finished product.
Further, during described natural drying, temperature control is: 20--30 degree, and the time is at least 5 days.
Further, on the surface of Wall or floor tile obtained or spray one or more layers by the way of direct spraying
F-C paint.
The remarkable advantage of the present invention is:
(1) the A1 level fire wall floor tile of the present invention has A1 level fire protecting performance, during chance fire not
Explosion, 900 DEG C do not burn, 1300 DEG C without flare, fire endurance reaches more than 3 hours.Meet
Substantial amounts of heat energy can be absorbed during fire burning, postpone the rising of ambient temperature.Effectively protect
Protect constructure body structure not to be damaged;
(2) the A1 level fire wall floor tile of the present invention does not the most produce light pollution, and sends out the most easily
It is conigenous quick-fried, safe and convenient to use;
(3) the A1 level fire wall floor tile production technique of the present invention is simple, without large-scale Wall or floor tile
Produce professional equipment, thus, compared with existing Wall or floor tile, effectively achieve energy-saving and emission-reduction,
Product more environmental protection;
(4) the A1 level fire wall floor tile outward appearance of the present invention as existing Wall or floor tile attractive in appearance greatly
Side;
(5) preparation technology determine the A1 level fire wall floor tile of the present invention be unlikely to deform, smooth
Spend, easy construction, the construction time is short, breakage rate is low, unique style, overall no color differnece etc.
Advantage;
In addition the A1 level fire prevention exterior wall dried hanging brick of the present invention is also equipped with excellent heat-insulating property, extremely strong preventing
Collision performance, it is easy to advantages such as promoting the use of.
Accompanying drawing explanation
Fig. 1 is the preparation technology flow chart of the A1 level fire wall floor tile in the embodiment of the present invention 3.
Detailed description of the invention
In order to make the purpose of the present invention, technical scheme and advantage clearer, below in conjunction with accompanying drawing and reality
Execute example, the present invention is further elaborated.Only should be appreciated that specific embodiment described herein
In order to explain the present invention, it is not intended to limit the present invention.
Embodiment 1
The A1 level fire wall floor tile of the present invention consists of matrix, boundary layer and transfer printing layer the most successively,
Each component and the mass fraction thereof of preparing the A1 level fire wall floor tile matrix in the present embodiment be: Baume degrees is 28
The Adlerika of degree: 100 parts, magnesium oxide: 110 parts, quartz sand: 30 parts, modifying agent: 1 part, its
In: modifying agent be vinyl alcohol 160 grams, hydrochloric acid 2 grams, sodium hydroxide 2 grams, acrylamide 24 grams uniformly mixed
Compound;Described boundary layer is formed by interfacial agents coating, and the component of described interfacial agents and quality proportioning are respectively,
50% water, 30% water-base resin and 20% titanium dioxide.
The present embodiment also discloses the preparation technology of this A1 level fire wall floor tile, specifically includes following steps:
S11: weigh each component by material mixture ratio and deposit respectively;
S12: the quartz sand weighed, Adlerika, magnesium oxide and modifying agent mix homogeneously are prepared embryo
Body castable;
S13: the idiosome castable in S12 is poured into mould and pours into a mould;
S14: the mould being cast with idiosome castable is placed in room of resting, at ambient temperature after natural drying
Form Wall or floor tile idiosome;
S15: in described Wall or floor tile idiosome surface-coated interfacial agents;
S16: transferred by water or the method for thermal transfer is being coated with the Wall or floor tile surface printing decorative pattern of interfacial agents
And decorative pattern is carried out UV light oil processing, dried acquisition Wall or floor tile finished product.
In above-mentioned steps S15, the effect in Wall or floor tile idiosome surface-coated interfacial agents is to realize follow-up transfer
Decorative pattern and Wall or floor tile matrix surface between stable adhesive bond;In step s 16 can be according to Wall or floor tile
Different use scenes and the demand of use, select different classes of transfer pattern, the such as lines of imitation wood matter,
Pattern of parian etc..
Embodiment 2
This enforcement is with the difference of above-described embodiment 1, prepares the A1 level fire wall floor tile embryo in the present embodiment
The each component of body and mass fraction thereof be: Baume degrees is 28 degree of Adlerikas: 100 parts, magnesium oxide: 110 parts,
Quartz sand: 50 parts, reinforcing agent: 1 part, modifying agent: 1 part, wherein: modifying agent be vinyl alcohol 160 grams,
Hydrochloric acid 2 grams, sodium hydroxide 2 grams, the homogeneous mixture of acrylamide 24 grams;Reinforcing agent is glass fibre, stone
The mixture of one or more in cotton fiber, cellulose fibre, staple fibre, the most preferably
Using stalk powder as reinforcing agent raw material, straw wide material sources, cost is relatively low, energy-conservation to its recycling
Environmental protection.
The surface printing of the A1 level fire wall floor tile in the present embodiment has decorative pattern.
The present embodiment also discloses the preparation technology of this A1 level fire wall floor tile, specifically includes following steps:
S21: weigh each component by material mixture ratio and deposit respectively;
S22: by the quartz sand weighed, Adlerika, magnesium oxide, modifying agent and reinforcing agent mix homogeneously
Prepare idiosome castable;
S23: the idiosome castable in S22 is poured into mould and pours into a mould;
S24: the mould being cast with idiosome castable is placed in room of resting, at ambient temperature after natural drying
Form Wall or floor tile idiosome;
S25: in described Wall or floor tile idiosome surface-coated interfacial agents;
S26: transferred by water or the method for thermal transfer is being coated with the Wall or floor tile surface printing decorative pattern of interfacial agents
And decorative pattern is carried out UV light oil processing, dried acquisition Wall or floor tile finished product.
Embodiment 3
The present embodiment is with the difference of above-described embodiment 2, prepares the A1 level fire wall floor tile in the present embodiment
The each component of idiosome and mass fraction thereof be: Baume degrees is 28 degree of Adlerikas: 100 parts, magnesium oxide: 110
Part, quartz sand: 70 parts, reinforcing agent: 2 parts, modifying agent: 3 parts, wherein: modifying agent is vinyl alcohol 160
Gram, hydrochloric acid 2 grams, sodium hydroxide 2 grams, the homogeneous mixture of acrylamide 24 grams;Described reinforcing agent is straw
Powder.
The surface printing of the A1 level fire wall floor tile in the present embodiment has decorative pattern, and surface-coated has fluorine carbon
Paint.
The present embodiment also discloses the preparation technology of this A1 level fire wall floor tile, as it is shown in figure 1, specifically include
Following steps:
S31: weigh each component by material mixture ratio and deposit respectively;
S32: by the quartz sand weighed, Adlerika, magnesium oxide, modifying agent and reinforcing agent mix homogeneously
Prepare idiosome castable;
S33: the idiosome castable in S32 is poured into mould and pours into a mould;
S34: the mould being cast with idiosome castable is placed in room of resting, at ambient temperature after natural drying
Form Wall or floor tile idiosome;
S35: in described Wall or floor tile idiosome surface-coated interfacial agents;
S36: transferred by water or the method for thermal transfer is being coated with the Wall or floor tile surface printing decorative pattern of interfacial agents
And decorative pattern is carried out UV light oil processing, dried acquisition Wall or floor tile finished product;
S37: at the surface spraying one layer or many of S36 gained A1 level fire wall floor tile by the way of direct spraying
Layer F-C paint, dried with obtaining fire wall brick product.
Those of ordinary skill in the art is it will be appreciated that embodiment described here is to aid in reader's reason
Solve the present invention principle, it should be understood that protection scope of the present invention be not limited to such special statement and
Embodiment.Those of ordinary skill in the art can make various according to these technology disclosed by the invention enlightenment
Without departing from other various concrete deformation and combination of essence of the present invention, these deformation and combination are still in the present invention
Protection domain in.
Claims (6)
1. an A1 level fire wall floor tile, it is characterised in that: described Wall or floor tile consists of the most successively
Matrix, boundary layer and transfer printing layer, each component and the mass fraction thereof of preparing described Wall or floor tile matrix be:
Baume degrees is the Adlerika 100 parts of 28 degree;
Magnesium oxide: 110 parts;
Quartz sand: 30~70;Part
Modifying agent: 1~3 part;
Reinforcing agent: 0~2 part;
The Baume degrees of described Adlerika is 28 degree;
Described reinforcing agent is one or more in glass fibre, asbestos fibre, cellulose fibre, staple fibre;
The particular make-up of described modifying agent and mass ratio be, polyvinyl alcohol: hydrochloric acid: sodium hydroxide: acrylamide
=80:1:1:12.
A1 level fire wall floor tile the most according to claim 1, it is characterised in that: described reinforcing agent
Raw material uses stalk powder.
A1 level fire wall floor tile the most according to claim 2, it is characterised in that: described boundary layer by
Interfacial agents coating forms, and the component of described interfacial agents and quality proportioning are respectively, 50% water, 30% water-base resin
And 20% titanium dioxide.
A1 level fire wall floor tile the most according to claim 3, it is characterised in that: described transfer printing layer bag
Include transferred by water or thermal transfer method formed printing decorative pattern.
5. the preparation technology of an A1 level fire wall floor tile, it is characterised in that: comprise the following steps:
S1: weigh each component by material mixture ratio and deposit respectively;
S2: the quartz sand weighed, Adlerika, magnesium oxide, modifying agent and reinforcing agent mix homogeneously are prepared embryo
Body castable;
S3: the idiosome castable in S2 is poured into mould and pours into a mould;
S4: the mould being cast with idiosome castable is placed in room of resting, forms wall at ambient temperature after natural drying
Floor tile idiosome;
S5: in described Wall or floor tile idiosome surface-coated interfacial agents;
S6: transferred by water or the method for thermal transfer is being coated with the Wall or floor tile surface printing decorative pattern of interfacial agents and to flower
Stricture of vagina carries out UV light oil processing, dried acquisition Wall or floor tile finished product.
The preparation technology of A1 level fire wall floor tile the most according to claim 5, it is characterised in that: logical
The mode crossing direct spraying on the surface of the A1 level fire wall floor tile obtained or sprays one or more layers F-C paint.
Priority Applications (1)
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CN201610340624.7A CN106007642A (en) | 2016-05-20 | 2016-05-20 | Grade A1 fireproof wall/floor tile and making method thereof |
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CN201610340624.7A CN106007642A (en) | 2016-05-20 | 2016-05-20 | Grade A1 fireproof wall/floor tile and making method thereof |
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Family
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106013678A (en) * | 2016-05-20 | 2016-10-12 | 合沐佳成都新材料有限公司 | A1-level fireproofing wall and floor tile and preparation method thereof |
US12116771B2 (en) | 2020-12-31 | 2024-10-15 | Mitek Holdings, Inc. | Rapid assembly construction modules and methods for use |
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CN1358684A (en) * | 2002-01-10 | 2002-07-17 | 李长科 | Fire-resistant thermo-insulation board |
WO2004061253A2 (en) * | 2002-12-27 | 2004-07-22 | Wallner Christine E | Cementitious veneer and laminate material |
CN101250062A (en) * | 2008-03-12 | 2008-08-27 | 李锦富 | Magnesium cement fireproof board having excellent water-resistance and preparation thereof |
CN102746024A (en) * | 2011-08-08 | 2012-10-24 | 江苏尼高科技有限公司 | Special interface agent for composite foaming cement board, preparation method and external thermal insulation system thereof |
CN105130350A (en) * | 2015-08-13 | 2015-12-09 | 惠州美森板业有限公司 | Novel inorganic decoration base material plate and preparation method thereof |
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2016
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CN1358684A (en) * | 2002-01-10 | 2002-07-17 | 李长科 | Fire-resistant thermo-insulation board |
WO2004061253A2 (en) * | 2002-12-27 | 2004-07-22 | Wallner Christine E | Cementitious veneer and laminate material |
CN101250062A (en) * | 2008-03-12 | 2008-08-27 | 李锦富 | Magnesium cement fireproof board having excellent water-resistance and preparation thereof |
CN102746024A (en) * | 2011-08-08 | 2012-10-24 | 江苏尼高科技有限公司 | Special interface agent for composite foaming cement board, preparation method and external thermal insulation system thereof |
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Title |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106013678A (en) * | 2016-05-20 | 2016-10-12 | 合沐佳成都新材料有限公司 | A1-level fireproofing wall and floor tile and preparation method thereof |
US12116771B2 (en) | 2020-12-31 | 2024-10-15 | Mitek Holdings, Inc. | Rapid assembly construction modules and methods for use |
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CB03 | Change of inventor or designer information | ||
CB03 | Change of inventor or designer information |
Inventor after: Wang Yingxing Inventor after: Fu Jiang Inventor after: Yin Wenbiao Inventor before: Wang Yingxing Inventor before: Fu Jiang Inventor before: He Hui Inventor before: Li Xiaobiao Inventor before: Yin Wenbiao |
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Application publication date: 20161012 |