CN105854912A - BiPO4-WO3 composite photocatalyst and preparation method thereof - Google Patents
BiPO4-WO3 composite photocatalyst and preparation method thereof Download PDFInfo
- Publication number
- CN105854912A CN105854912A CN201610235972.8A CN201610235972A CN105854912A CN 105854912 A CN105854912 A CN 105854912A CN 201610235972 A CN201610235972 A CN 201610235972A CN 105854912 A CN105854912 A CN 105854912A
- Authority
- CN
- China
- Prior art keywords
- mixed solution
- bipo
- hydrothermal reaction
- catalyst
- bismuth nitrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011941 photocatalyst Substances 0.000 title claims abstract description 25
- 239000002131 composite material Substances 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 26
- 238000001027 hydrothermal synthesis Methods 0.000 claims abstract description 24
- 239000011259 mixed solution Substances 0.000 claims abstract description 22
- RXPAJWPEYBDXOG-UHFFFAOYSA-N hydron;methyl 4-methoxypyridine-2-carboxylate;chloride Chemical compound Cl.COC(=O)C1=CC(OC)=CC=N1 RXPAJWPEYBDXOG-UHFFFAOYSA-N 0.000 claims abstract description 19
- XMVONEAAOPAGAO-UHFFFAOYSA-N sodium tungstate Chemical compound [Na+].[Na+].[O-][W]([O-])(=O)=O XMVONEAAOPAGAO-UHFFFAOYSA-N 0.000 claims abstract description 15
- 238000006243 chemical reaction Methods 0.000 claims abstract description 14
- 239000000843 powder Substances 0.000 claims abstract description 14
- 239000011780 sodium chloride Substances 0.000 claims abstract description 13
- 239000000243 solution Substances 0.000 claims abstract description 13
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000008367 deionised water Substances 0.000 claims abstract description 8
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 8
- 229910000403 monosodium phosphate Inorganic materials 0.000 claims abstract description 8
- 235000019799 monosodium phosphate Nutrition 0.000 claims abstract description 8
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 claims abstract description 8
- 238000005406 washing Methods 0.000 claims abstract description 7
- 238000001816 cooling Methods 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims description 15
- 230000004044 response Effects 0.000 claims description 11
- 238000013019 agitation Methods 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 2
- 230000001699 photocatalysis Effects 0.000 abstract description 10
- 238000007146 photocatalysis Methods 0.000 abstract description 6
- 239000000463 material Substances 0.000 abstract description 2
- 238000001035 drying Methods 0.000 abstract 2
- 238000000120 microwave digestion Methods 0.000 abstract 2
- 238000005119 centrifugation Methods 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 description 6
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 5
- 229940043267 rhodamine b Drugs 0.000 description 5
- 230000008901 benefit Effects 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000004065 semiconductor Substances 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- -1 hydroxyl radical free radical Chemical class 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
Abstract
The invention discloses a BiPO4-WO3 composite photocatalyst and a preparation method thereof, and belongs to the technical field of inorganic environment-friendly photocatalysis materials. According to the technical scheme, the preparation method of the BiPO4-WO3 composite photocatalyst comprises the steps that 1, sodium tungstate and sodium chloride are added into deionized water according to the molar ratio of 1:1, the pH value of the mixed solution is adjusted with hydrochloric acid to range from 0.5 to 1 and transferred into a hydrothermal reaction still, the hydrothermal reaction still is placed in a microwave digestion instrument, a microwave reaction is carried out for 10 min to 30 min at the temperature of 180 DEG C, cooling, washing and drying are carried out after the reaction is finished, and WO3 powder is obtained; 2, a bismuth nitrate water solution is prepared, sodium dihydrogen phosphate and the WO3 powder are added to form a mixed solution; 3, the mixed solution obtained in the step 2 is stirred for 1 h at room temperature and then transferred into the hydrothermal reaction still, the hydrothermal reaction still is placed in the microwave digestion instrument, a microwave reaction is carried out for 10 min to 30 min at the temperature of 180 DEG C, centrifugation, washing and drying are carried out after the reaction is finished, and the BiPO4-WO3 composite photocatalyst is prepared. According to the prepared BiPO4-WO3 composite photocatalyst, the utilization rate of sunlight and photocatalytic activity are effectively increased.
Description
Technical field
The invention belongs to inorganic environment-friendly catalysis material technical field, be specifically related to a kind of BiPO4-WO3Composite photo-catalyst and preparation method thereof.
Background technology
In recent years, photocatalysis oxidation technique processes organic pollution owing to possessing that ability is strong, efficiency is high and the advantage such as non-secondary pollution, obtains the widely studied of scholars in Environmental Studies field.Photocatalysis oxidation technique mainly utilizes and produces the hydroxyl radical free radical with high activity and high oxidative, organic pollution carries out oxidation removal, thus reaches the purpose being effectively treated sewage.
In numerous photochemical catalysts, BiPO4As a kind of oxysalt, i.e. receive much concern because of the photocatalysis performance of its brilliance since being found.But, ultraviolet light can only be absorbed owing to its wider band gap magnitude (3.83eV) determines it and cause the utilization rate of light the highest, its light induced electron and hole the most compound, it is greatly reduced photocatalysis efficiency, thus hinders its application industrially.As a kind of important N-shaped visible-light photocatalyst, WO3Due to the energy gap that it is narrower, attract sizable concern.But, the most still there is no pertinent literature about BiPO4-WO3The report of composite photo-catalyst.
Summary of the invention
Present invention solves the technical problem that and there is provided the BiPO that a kind of photo-quantum efficiency is high, solar energy utilization ratio is high and photocatalytic activity is good4-WO3Composite photo-catalyst.
Another technical problem that the present invention solves there is provided the BiPO of a kind of simple and convenient operation4-WO3The preparation method of composite photo-catalyst.
The present invention solves that above-mentioned technical problem adopts the following technical scheme that, a kind of BiPO4-WO3The preparation method of composite photo-catalyst, it is characterized in that comprising the following steps: sodium tungstate and sodium chloride are joined the mixed solution being made into sodium tungstate in deionized water with sodium chloride by (1) in molar ratio for 1:1, after stirring 30min, the pH value with hydrochloric acid regulation mixed solution is 0.5-1, it is transferred to hydrothermal reaction kettle after continuing stirring 30min, then hydrothermal reaction kettle is put in 180 DEG C of microwave reaction 10-30min in microwave dissolver, question response terminate after through cooling down, wash, being dried to obtain WO3Powder；(2) aqueous bismuth nitrate solution is prepared with bismuth nitrate and deionized water for raw material, the WO that addition sodium dihydrogen phosphate and step (1) obtain in aqueous bismuth nitrate solution under agitation3Powder forms mixed solution, and wherein added sodium dihydrogen phosphate is 1:1 with the mol ratio of bismuth nitrate, added WO3Powder is 1-10:1 with the mol ratio of bismuth nitrate；(3) it is transferred to hydrothermal reaction kettle after mixed solution stirring 1h step (2) obtained at ambient temperature, then hydrothermal reaction kettle is put in 180 DEG C of microwave reaction 10-30min in microwave dissolver, question response terminate to be cooled to normal temperature after through being centrifuged, washing, be dried prepare BiPO4-WO3Composite photo-catalyst.
Further preferably, the sodium tungstate of step (1) is 0.05-0.2mol/L with the molar concentration of sodium tungstate in the mixed solution of sodium chloride.
Further preferably, the molar concentration of the aqueous bismuth nitrate solution of step (2) is 0.1-0.5mol/L.
BiPO of the present invention4-WO3Composite photo-catalyst, prepares according to the method described above.
The present invention compared with prior art has the advantages that
1, the present invention is in order to improve BiPO4Spectral response range, by itself and the WO with ideal bandgap3It is combined mutually, utilizes the energy level difference between two kinds of semiconductors that photo-generated carrier can be made to be injected on the energy level of another kind of semiconductor by the energy level of a kind of semiconductive particles, make electric charge efficiently separate, be effectively increased BiPO4Solar energy utilization ratio and photo-quantum efficiency；
2、BiPO4Conduction band potential E of photochemical catalystCB=0.44eV, valence band electromotive force EVB=4.27eV, and WO3Conduction band potential E of photochemical catalystCB=0.41eV, valence band electromotive force EVB=3.18eV, at BiPO4-WO3In composite semiconductor, WO3Conduction band potential more negative, light induced electron is easily from the WO that energy level is low3Conduction band moves to the BiPO that energy level is high4On conduction band, BiPO4Valence band electromotive force corrigendum, photohole is easily from the BiPO that energy level is high4Valence band moves to the WO that energy level is low3In valence band, thus improve the separative efficiency of photogenerated charge, and then improve its photocatalysis performance；
3、WO3Forbidden band is narrower, can effectively expand BiPO4The photochemical catalyst utilization rate to visible ray, and then it is effectively improved utilization rate and the photocatalytic activity of sunshine.
Accompanying drawing explanation
Fig. 1 is under 300W Hg lamp irradiation, the BiPO that the embodiment of the present invention 2 prepares4-WO3Composite photo-catalyst and pure BiPO4Light urges the agent degraded correlation curve figure (operating condition: the amount of catalyst: 0.1g to rhodamine B；The mass concentration of rhodamine B: 5mg/L).
Detailed description of the invention
Being described in further details the foregoing of the present invention by the following examples, but this should not being interpreted as, the scope of the above-mentioned theme of the present invention is only limitted to below example, all technology realized based on foregoing of the present invention belong to the scope of the present invention.
Embodiment 1
(1) sodium tungstate of 0.005 mol and the sodium chloride of 0.005 mol are joined constant volume in deionized water and forms sodium tungstate and the mixed solution of sodium chloride to 100mL, after stirring 30min, the pH value with hydrochloric acid regulation mixed solution is 0.5, it is transferred to hydrothermal reaction kettle after continuing stirring 30min, then hydrothermal reaction kettle is put in 180 DEG C of microwave reaction 10min in microwave dissolver, question response terminate after through cooling down, wash, being dried to obtain WO3Powder；
(2) preparation molar concentration is the aqueous bismuth nitrate solution 100mL of 0.1mol/L, the WO obtained to sodium dihydrogen phosphate and the 0.01mol step (1) of aqueous bismuth nitrate solution addition 0.01mol under agitation3Powder；
(3) it is transferred to hydrothermal reaction kettle after mixed solution stirring 1h step (1) obtained at ambient temperature, then hydrothermal reaction kettle is put in 180 DEG C of microwave reaction 10min in microwave dissolver, question response terminate to be cooled to normal temperature after through being centrifuged, washing, be dried to prepare there is the BiPO of high catalytic activity4-WO3Composite photo-catalyst.
Embodiment 2
(1) sodium tungstate of 0.01mol and the sodium chloride of 0.01mol are joined constant volume in deionized water and forms the mixed solution of sodium tungstate and sodium chloride to 100mL, after stirring 30min, the pH value with hydrochloric acid regulation mixed solution is 0.8, it is transferred to hydrothermal reaction kettle after continuing stirring 30min, then hydrothermal reaction kettle is put in 180 DEG C of microwave reaction 20min in microwave dissolver, question response terminate after through cooling down, wash, being dried to obtain WO3Powder；
(2) preparation molar concentration is the aqueous bismuth nitrate solution 100mL of 0.2mol/L, the WO obtained to sodium dihydrogen phosphate and the 0.1mol step (1) of aqueous bismuth nitrate solution addition 0.02mol under agitation3Powder；
(3) it is transferred to hydrothermal reaction kettle after mixed solution stirring 1h step (2) obtained at ambient temperature, then hydrothermal reaction kettle is put in 180 DEG C of microwave reaction 20min in microwave dissolver, question response terminate to be cooled to normal temperature after through being centrifuged, washing, be dried to prepare there is the BiPO of high catalytic activity4-WO3Composite photo-catalyst.
Fig. 1 is under 300W Hg lamp irradiation, the BiPO that the present embodiment prepares4-WO3Composite photo-catalyst and pure BiPO4Light urges the agent degraded correlation curve figure to rhodamine B, as seen from the figure under the irradiation of simulated visible light, after illumination 4h, pure BiPO4Photochemical catalyst is about 19% to the degradation rate of rhodamine B, and BiPO4-WO3Composite photo-catalyst can reach about 92% to the degradation rate of rhodamine B, shows the photocatalytic activity being remarkably reinforced.
Embodiment 3
(1) sodium tungstate of 0.02mol and the sodium chloride of 0.02mol are joined constant volume in deionized water and forms sodium tungstate and the mixed solution of sodium chloride to 100mL, after stirring 30min, the pH value with hydrochloric acid regulation mixed solution is 1.0, it is transferred to hydrothermal reaction kettle after continuing stirring 30min, then hydrothermal reaction kettle is put in 180 DEG C of microwave reaction 30min in microwave dissolver, question response terminate after through cooling down, wash, being dried to obtain WO3Powder；
(2) preparation molar concentration is the aqueous bismuth nitrate solution 100mL of 0.5mol/L, the WO obtained to sodium dihydrogen phosphate and the 0.5mol step (1) of aqueous bismuth nitrate solution addition 0.05mol under agitation3Powder；
(3) it is transferred to hydrothermal reaction kettle after mixed solution stirring 1h step (2) obtained at ambient temperature, then hydrothermal reaction kettle is put in 180 DEG C of microwave reaction 30min in microwave dissolver, question response terminate to be cooled to normal temperature after through being centrifuged, washing, be dried to prepare there is the BiPO of high catalytic activity4-WO3Composite photo-catalyst.
Embodiment above describes the general principle of the present invention, principal character and advantage; skilled person will appreciate that of the industry; the present invention is not restricted to the described embodiments; the principle that the present invention is simply described described in above-described embodiment and specification; under the scope without departing from the principle of the invention; the present invention also has various changes and modifications, and these changes and improvements each fall within the scope of protection of the invention.
Claims (4)
1. a BiPO4-WO3The preparation method of composite photo-catalyst, it is characterized in that comprising the following steps: sodium tungstate and sodium chloride are joined the mixed solution being made into sodium tungstate in deionized water with sodium chloride by (1) in molar ratio for 1:1, after stirring 30min, the pH value with hydrochloric acid regulation mixed solution is 0.5-1, it is transferred to hydrothermal reaction kettle after continuing stirring 30min, then hydrothermal reaction kettle is put in 180 DEG C of microwave reaction 10-30min in microwave dissolver, question response terminate after through cooling down, wash, being dried to obtain WO3Powder；(2) aqueous bismuth nitrate solution is prepared with bismuth nitrate and deionized water for raw material, the WO that addition sodium dihydrogen phosphate and step (1) obtain in aqueous bismuth nitrate solution under agitation3Powder forms mixed solution, and wherein added sodium dihydrogen phosphate is 1:1 with the mol ratio of bismuth nitrate, added WO3Powder is 1-10:1 with the mol ratio of bismuth nitrate；(3) it is transferred to hydrothermal reaction kettle after mixed solution stirring 1h step (2) obtained at ambient temperature, then hydrothermal reaction kettle is put in 180 DEG C of microwave reaction 10-30min in microwave dissolver, question response terminate to be cooled to normal temperature after through being centrifuged, washing, be dried prepare BiPO4-WO3Composite photo-catalyst.
BiPO the most according to claim 14-WO3The preparation method of composite photo-catalyst, it is characterised in that: the sodium tungstate of step (1) is 0.05-0.2mol/L with the molar concentration of sodium tungstate in the mixed solution of sodium chloride.
BiPO the most according to claim 14-WO3The preparation method of composite photo-catalyst, it is characterised in that: the molar concentration of the aqueous bismuth nitrate solution of step (2) is 0.1-0.5mol/L.
4. a BiPO4-WO3Composite photo-catalyst, it is characterised in that be to prepare according to the method described in any one in claim 1-3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610235972.8A CN105854912A (en) | 2016-04-18 | 2016-04-18 | BiPO4-WO3 composite photocatalyst and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610235972.8A CN105854912A (en) | 2016-04-18 | 2016-04-18 | BiPO4-WO3 composite photocatalyst and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105854912A true CN105854912A (en) | 2016-08-17 |
Family
ID=56632299
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610235972.8A Pending CN105854912A (en) | 2016-04-18 | 2016-04-18 | BiPO4-WO3 composite photocatalyst and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105854912A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106984346A (en) * | 2017-03-30 | 2017-07-28 | 常州大学 | A kind of preparation method of silver orthophosphate compound phosphoric acid bismuth photochemical catalyst |
| CN107597155A (en) * | 2017-09-27 | 2018-01-19 | 大连民族大学 | A kind of one pot process has visible light-responded photochemical catalyst BiPO4/WO3The preparation method of nanometer sheet |
| CN110743584A (en) * | 2019-10-14 | 2020-02-04 | 东北大学秦皇岛分校 | WO (WO)3Preparation and application of modified BiPO4 photocatalyst |
| CN112121830A (en) * | 2020-09-18 | 2020-12-25 | 江苏大学 | Preparation method and application of silver phosphate/tungsten trioxide core-shell nano photocatalytic composite material |
| CN114392734A (en) * | 2021-12-29 | 2022-04-26 | 北京工业大学 | Tungsten oxide composite material and preparation method and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20110130130A (en) * | 2010-05-27 | 2011-12-05 | 금호석유화학 주식회사 | Multi-component metal oxide catalysts containing a bipo4, preparing method thereof and preparing method of 1,3-butadiene using the same |
| CN104128194A (en) * | 2014-07-25 | 2014-11-05 | 浙江工商大学 | p-n-type Bi2O3/BiPO4 heterostructure visible light-response photocatalytic film material and preparation method thereof |
-
2016
- 2016-04-18 CN CN201610235972.8A patent/CN105854912A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20110130130A (en) * | 2010-05-27 | 2011-12-05 | 금호석유화학 주식회사 | Multi-component metal oxide catalysts containing a bipo4, preparing method thereof and preparing method of 1,3-butadiene using the same |
| CN104128194A (en) * | 2014-07-25 | 2014-11-05 | 浙江工商大学 | p-n-type Bi2O3/BiPO4 heterostructure visible light-response photocatalytic film material and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| GUANGFANG LI等: "Microwave synthesis of BiPO4 nanostructures and their morphology-dependent photocatalytic performances", 《JOURNAL OF COLLOID AND INTERFACE SCIENCE》 * |
| 张昭: "WO3/BiVO4复合光催化剂的制备及其可见光光催化性能研究", 《中国优秀硕士学位论文全文数据库（电子期刊）》 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106984346A (en) * | 2017-03-30 | 2017-07-28 | 常州大学 | A kind of preparation method of silver orthophosphate compound phosphoric acid bismuth photochemical catalyst |
| CN107597155A (en) * | 2017-09-27 | 2018-01-19 | 大连民族大学 | A kind of one pot process has visible light-responded photochemical catalyst BiPO4/WO3The preparation method of nanometer sheet |
| CN110743584A (en) * | 2019-10-14 | 2020-02-04 | 东北大学秦皇岛分校 | WO (WO)3Preparation and application of modified BiPO4 photocatalyst |
| CN110743584B (en) * | 2019-10-14 | 2022-03-29 | 东北大学秦皇岛分校 | WO (WO)3Modified BiPO4Preparation method and application of photocatalyst |
| CN112121830A (en) * | 2020-09-18 | 2020-12-25 | 江苏大学 | Preparation method and application of silver phosphate/tungsten trioxide core-shell nano photocatalytic composite material |
| CN114392734A (en) * | 2021-12-29 | 2022-04-26 | 北京工业大学 | Tungsten oxide composite material and preparation method and application thereof |
| CN114392734B (en) * | 2021-12-29 | 2024-01-30 | 北京工业大学 | Tungsten oxide composite material and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105854912A (en) | BiPO4-WO3 composite photocatalyst and preparation method thereof | |
| CN102974373B (en) | Preparation method of visible-light photocatalytic material | |
| CN104128194B (en) | A kind of p-n junction Bi2O3/BiPO4Hetero-junctions visible light responsive photocatalytic thin-film material and preparation method thereof | |
| CN103480353A (en) | Method for synthesis of carbon quantum dot solution by hydrothermal process to prepare composite nano-photocatalyst | |
| CN107081166A (en) | A kind of g C3N4/TiO2Multilevel hierarchy and preparation method thereof | |
| CN103990493A (en) | Visible-light catalyst for degrading rhodamine B in water and application of catalyst | |
| CN106492854A (en) | The composite nano Ag with photocatalysis performance is prepared using two-step method3PO4/TiO2Material and methods and applications | |
| CN102600857A (en) | Preparation method of carbon ball-loaded CuO-BiVO4 heterojunction compound photocatalyst | |
| CN104888858A (en) | Ternary efficient compound visible light photocatalytic material and preparation method thereof | |
| CN105214689A (en) | A kind of TiO 2/ CdS/ Graphene composite photocatalyst material and preparation method thereof | |
| CN104056620A (en) | Visible-light catalyst and preparation method and application thereof | |
| CN105772051B (en) | A kind of Bi2O2CO3-BiFeO3Composite photo-catalyst and preparation method thereof | |
| CN105772018A (en) | Bi2WO6-BiFeO3 compound photocatalyst and preparing method thereof | |
| CN104857995A (en) | PANI (polyaniline)-modified N-doped TiO2 (titanium dioxide) composite photocatalyst adopting nanostructure as well as preparation method and application of photocatalyst | |
| CN105478142A (en) | Indium-sulfide mesoporous hollow microsphere photocatalyst, and preparation method and uses thereof | |
| CN103349982B (en) | Bi2WO6 modified TiO2 nanobelt photocatalyst, preparation method and application thereof | |
| CN104722298A (en) | Method for preparing titania composite nano-gold photocatalyst | |
| CN105195190A (en) | Heterojunction photocatalyst SnS2/g-C3N4 as well as preparation method and application thereof | |
| CN105772045B (en) | A kind of BiPO4‑ZnFe2O4Composite photo-catalyst and preparation method thereof | |
| CN104607214B (en) | A kind of visible light-responded AgBr/TiO2The preparation method of catalyst | |
| CN101972645A (en) | Preparation method of visible light response type semiconductor photocatalyst bismuth vanadate | |
| CN104138763B (en) | Ag3PO4/TiOF2The preparation method of composite photo-catalyst | |
| CN101791562B (en) | Method for preparing ferrum-fluorine-codoped nano-titanium dioxide visible light photocatalyst | |
| CN105797760A (en) | Bi2O2CO3-WO3 composite photocatalyst and preparation method thereof | |
| CN105771953A (en) | Preparation method of zinc titanate and titanium dioxide composite nano material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160817 |