CN105802323A - Ball-point pen and carbon paper diffuse handwriting elimination agent and application method thereof - Google Patents
Ball-point pen and carbon paper diffuse handwriting elimination agent and application method thereof Download PDFInfo
- Publication number
- CN105802323A CN105802323A CN201610303958.7A CN201610303958A CN105802323A CN 105802323 A CN105802323 A CN 105802323A CN 201610303958 A CN201610303958 A CN 201610303958A CN 105802323 A CN105802323 A CN 105802323A
- Authority
- CN
- China
- Prior art keywords
- paper
- carbon paper
- ball
- elimination agent
- handwriting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D9/00—Chemical paint or ink removers
- C09D9/005—Chemical paint or ink removers containing organic solvents
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paper (AREA)
Abstract
The invention discloses a ball-point pen and carbon paper diffuse handwriting elimination agent and an application method thereof. The elimination agent is a paste prepared by taking the mixed liquid of acetone and distilled water in a mass ratio of 1:(3-4) as a solvent and uniformly stirring kieselguhr G and the solvent in a mass ratio of 1:(1-2). A method for eliminating the ball-point pen and carbon paper diffuse handwriting by using the elimination agent comprises the following steps: dipping a brush in the elimination agent and uniformly spreading the elimination agent on the back of the paper of a file with diffuse ball-point pen or carbon paper handwriting; standing for 20-30 seconds; and completely blowing the elimination agent adsorbed with the diffuse ink by a blower. In the elimination agent disclosed by the invention, the kieselguhr G can adsorb the diffuse oily dye on the file with ball-point pen and carbon paper writing, thus an aims of eliminating the diffuse part and making the handwriting clear are achieved without damaging the paper structure and file handwriting; and the elimination agent is of great significance to long-term storage of the file handwriting of ball-point pen or carbon paper.
Description
Technical field
The invention belongs to archives writing resist technology field, be specifically related to a kind of guard method for ball pen and carbon paper writing that diffusion occurs.
Background technology
The writing material such as ball pen and carbon paper broadly falls into not durable writing, and mostly the pigment composition of writing material is oil-soluble dyes, and these dyestuffs can be dissolved in oil.And generally relatively low as the oil of solvent, wax fusing point, slightly meet high temperature, be easily liquefied as liquid; pigment is also taken out of therewith, occurs that oil oozes, thus spreading; As time goes on, the spacing between word and word diminishes, font material stroke None-identified; archives writing thickens unclear; being difficult to recognize, saved these type of archives improperly, if being repaired not in time; it is extremely serious that the writing of these type of archives can spread, and these type of archives even a lot of cause the loss that cannot retrieve because writing cannot read.
Summary of the invention
The technical problem to be solved is in that to provide a kind of when not destroying every mechanical performance and the writing ink of paper, can effectively solve the remover using the files that ball pen and carbon paper are write to occur writing to spread and the method using this remover removal ball pen and carbon paper writing diffusion part.
Solve above-mentioned technical problem be the technical scheme is that this remover be with the mass ratio of acetone and distilled water be 1:3～4 mixed liquor for solvent, kieselguhr G and solvent are stirred the pastel formed for 1:1～2 in mass ratio.
The remover of the present invention preferably with the mass ratio of acetone and distilled water be 1:3.5～3.7 mixed liquor for solvent, the pastel of formation that kieselguhr G and solvent are stirred for 1:1.5 in mass ratio.
The method that remover of the present invention removes ball pen and carbon paper diffusion writing is adopted to be: to dip remover with brush and be spread evenly across ball pen or the back side of paper of carbon paper writing archives that diffusion occurs, after placing 20～30 seconds, with hair-dryer, the remover after having adsorbed the ink of diffusion is purged clean.
The present invention is operated from the back side of paper, kieselguhr G in remover can by unnecessary on the archives using ball pen and carbon paper to write, to go out oiliness dye adsorption gets off, thus reaching to remove diffusion part, make writing purpose clearly, and structure and the archives writing of paper will not be destroyed, efficiently solve the archives writing write with ball pen and carbon paper writing spreads, oil problem, making these type of archives are become easily to identify and identification, the archives writing write for ball pen or carbon paper permanent preserves significant.
Accompanying drawing explanation
The ballpoint pen writing file that Archives Administration of Tu1Shi Shaanxi Province preserves the sixties.
The ballpoint pen writing file that Archives Administration of Tu2Shi Shaanxi Province preserves the eighties.
Detailed description of the invention
Below in conjunction with drawings and Examples, the present invention is described in more detail, but protection scope of the present invention is not limited only to these embodiments.
Embodiment 1
Being as solvent in mass ratio after 1:3.65 mix homogeneously using acetone and distilled water, added in 15g solvent by 10g kieselguhr G, stir formation pastel, and be namely eliminated agent.Dip remover with brush and be spread evenly across the back side of the ballpoint pen writing file that diffusion occurs that Archives Administration of Shaanxi Province preserves the sixties, after placing 20～30 seconds, with hair-dryer, the remover after having adsorbed the ink of diffusion is purged totally.As shown in Figure 1; the right untreated ballpoint pen writing diffusion is serious; if being not added with processing timely protection; what so the spacing between word and word can become is less; font obscures into one and is beyond recognition; and the ballpoint pen writing after the process of the left side becomes apparent from, can be easy to differentiate the content write, the problem illustrating to adopt remover of the present invention can significantly solve ballpoint pen writing diffusion.
Embodiment 2
Being as solvent in mass ratio after 1:4 mix homogeneously using acetone and distilled water, added in 20g solvent by 10g kieselguhr G, stir formation pastel, and be namely eliminated agent.Dip remover with brush and be spread evenly across the back side of the ballpoint pen writing file that diffusion occurs that Archives Administration of Shaanxi Province preserves the eighties, after placing 20～30 seconds, with hair-dryer, the remover after having adsorbed the ink of diffusion is purged totally.As shown in Figure 2; the right untreated ballpoint pen writing diffusion is serious; if being not added with processing timely protection; what so the spacing between word and word can become is less; font obscures into one and is beyond recognition; and the ballpoint pen writing after the process of the left side becomes apparent from, can be easy to differentiate the content write, the problem illustrating to adopt remover of the present invention can significantly solve ballpoint pen writing diffusion.
Embodiment 3
Being as solvent in mass ratio after 1:3 mix homogeneously using acetone and distilled water, added in 10g solvent by 10g kieselguhr G, stir formation pastel, and be namely eliminated agent.Dip remover with brush and be spread evenly across the back side of carbon paper writing file that diffusion occurs, after placing 20～30 seconds, with hair-dryer, the remover after having adsorbed the ink of diffusion is purged totally.
In order to paper be there is no destruction by the paper after proving remover of the present invention process after long-time preservation is placed, inventor makes paper simulation sample and verifies.Make paper simulation sample process: be uniformly applied on paper by ball pen ink, the remover and the method that use embodiment 1 process at the back side of ball pen ink paper, then carry out that ultraviolet lighting is aging respectively, hydrothermal aging and xeothermic aging, test the tensile strength of aging front and back paper, monolayer folding strength and double-deck tearability, specific as follows:
1, the mensuration of tensile strength
Tensile strength refers to when standard test method specifies, born maximum pull before the paper fracture of unit width.Tensile strength is one of important parameter in paper mechanical characteristics, tensile strength is again the most frequently used paper strength index, when measuring, external force is transmitted between fiber by network of fibers, act on the shearing force between fiber and fiber and cause the destruction of fiber combining, when shearing force increases above the shearing strength of fiber combining, fiber combining will rupture.
Pattern is pressed the sufficient amount of paper slip of vertically and horizontally cutting growth 250mm, wide 15 ± 0.1mm, to ensure that vertical and horizontal are respectively arranged with 10 effective data (as from fracture person within chuck 10mm, removed and not remember).Pattern is not allow for any paper defects, and two limits of pattern should be straight, and otch should neatly without any damage.Adopting J-KZ1000 type pendulum tensile test piece machine (the Changjiang river papermaking Instrument Ltd.) tensile strength carrying out pattern by GB GB/T453～2002 to measure (constant speed loading method), test result is in Table 1.
Do not manifest paper before and after table 1 ultraviolet ageing and manifest the measuring mechanical property result of rear paper
Note: in table, experimental data is 10 Validity Test meansigma methodss.
2, the mensuration of folding strength
Folding strength refers to that paper is amenable to the reciprocal folding number of times of 180 degree under some tension.Folding strength is index the sensitiveest for artificial accelerated aging reflection in paper mechanical strength index, and the durability for evaluating paper has relatively restricted publication of international news and commentary entitled and is worth.Folding strength depends primarily on the factors such as the intensity of paper fibre itself, average length and interfibrous adhesion size.After weathering, cellulose body is easier to oxidation and fracture the poor paper of durability so that papery starts hardening embrittlement, shows aging feature.By measuring the change of aging front and back pattern folding strength, it is possible to the durability evaluating paper is strong and weak.The relatively larger then explanation ageing process of folding strength performance indications numerical value is less to its paper fibre destructiveness, and the smaller then explanation ageing process of numerical value is bigger to its paper fibre destructiveness.
Pattern is pressed the sufficient amount of paper slip of vertically and horizontally cutting growth 250mm, wide 15 ± 0.1mm, to ensure that vertical and horizontal are respectively arranged with 10 effective data (as from fracture person within chuck 10mm, removed and not remember).Pattern is not allow for any paper defects, and two limits of pattern should be straight, and otch should neatly without any damage.Adopting MIT135 type computer observing and controlling folding strength instrument (Lan Bo Instrument Ltd.) to carry out the folding test (MIT folding strength instrument method) of sample by GB GB/T2679.5～1995, test result is in Table 2.
Do not manifest paper before and after table 2 hydrothermal aging and manifest the measuring mechanical property result of rear paper
Note: in table, experimental data is 10 Validity Test meansigma methodss.
3, the mensuration of tearability
Tearability refers to work done when tearing paper.In representing the index of mechanical strength of paper, tearability has great importance.The present invention adopts interior method of Tearing to represent, refers to when regulation, the paper cut along otch tear time required power, unit is mN.Owing to fiber being pulled out from sample when paper is torn, or will fiber tear fracture, so the size of tearability depends on the average length of fiber, next to that the interleaving conditions etc. of the orientation of interfibrous adhesion, fiber, the intensity of fiber itself and fiber, tearability increases along with the length of fiber and increases.By measuring the change of the simulation pliable and tough posterior tear degree of sample, it is possible to the resistance to tearing evaluating sample is strong and weak.
Paper is pressed the sufficient amount of paper slip of vertically and horizontally cutting growth 75 ± 2mm, wide 63 ± 0.5mm, to ensure that vertical and horizontal are respectively arranged with 10 effective data (as from fracture person within chuck 10mm, removed and not remember).10 effective tests are done in each direction, if the end of sample tear line and edge of a knife extended line left and right deflection are more than 10mm, should discard and not remember.Adopting SL1000 type computer observing and controlling tearability instrument (Lan Bo Instrument Ltd.) tearability carrying out sample by GB GB/T455～2002 to measure, test result is in Table 3.
The xeothermic aging front and back of table 3 do not manifest paper and manifest the measuring mechanical property result of rear paper
Note: in table, experimental data is 10 Validity Test meansigma methodss.
4, color difference analysis
Common color can use red, green, blue three primary colours light " spelling " in different proportions out.For the ease of measuring color, theoretical it can be seen that the color of any coloured light can represent by tristimulus values according to colorimetry.Tristimulus values can be measured objectively by optics way.To non-luminous body, it is possible to measure its color (also referred to as object color) under certain standard light source is irradiated, be actually the reflection light collecting sample, then measure the stimulus value of these reflection light.Adopting four kinds of unguyed samples in the aging front and back of aging method of X-RiteVS-450 spectrophotometric determination and reinforce the aberration Δ E of sample, taking numerical value 10 groups more stable, then take its meansigma methods, test result is in Table 4.Specify that the more big explanation color change of Δ E value is more big according to GB/T11186-1989, otherwise then illustrate that color change is more little.
The aging front and back of table 4 do not manifest paper and manifest the chromatism test result of rear paper
Note: in table, experimental data is 10 Validity Test meansigma methodss.
The test result of table 1～4 shows, use remover of the present invention by after paper process, after manual simulation ultraviolet ageing, xeothermic aging, hydrothermal aging process, paper be there is no obvious destruction, differing only small with every mechanical performance of untreated paper, and the color of ball pen ink also keeps fine, the ball pen ink before and after processing is after three kinds of aging techniques, the aberration of aging front and back keeps better, and naked eyes are seen and are not substantially any change.As can be seen here, remover of the present invention can when not destroying paper mechanical strength and archives writing, can archives writing that effectively solution ball pen is write and carbon paper writing spreads, oil problem, make to become these type of archives easily to identify and identification, and even across preserving for a long time and placing, the ink color and luster of ball pen and carbon paper writing is affected little by remover of the present invention, and the archives writing write for ball pen or carbon paper permanent preserves significant.
Claims (3)
1. a ball pen and carbon paper diffusion writing remover, it is characterised in that: this remover be with the mass ratio of acetone and distilled water be 1:3～4 mixed liquor for solvent, kieselguhr G and solvent are stirred the pastel formed for 1:1～2 in mass ratio.
2. ball pen according to claim 1 and carbon paper diffusion writing remover, it is characterized in that: this remover be with the mass ratio of acetone and distilled water be 1:3.5～3.7 mixed liquor for solvent, the pastel of formation that kieselguhr G is stirred for 1:1.5 in mass ratio with solvent.
3. the remover that a kind adopts described in claim 1 removes ball pen and the method for carbon paper diffusion writing, it is characterized in that: dip remover with brush and be spread evenly across the back side of paper of ball pen or the carbon paper writing archives that diffusion occurs, after placing 20～30 seconds, with hair-dryer, the remover after having adsorbed the ink of diffusion is purged clean.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610303958.7A CN105802323B (en) | 2016-05-10 | 2016-05-10 | A kind of ball pen and carbon paper diffusion writing remover and its application method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610303958.7A CN105802323B (en) | 2016-05-10 | 2016-05-10 | A kind of ball pen and carbon paper diffusion writing remover and its application method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105802323A true CN105802323A (en) | 2016-07-27 |
| CN105802323B CN105802323B (en) | 2017-10-20 |
Family
ID=56455600
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610303958.7A Active CN105802323B (en) | 2016-05-10 | 2016-05-10 | A kind of ball pen and carbon paper diffusion writing remover and its application method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105802323B (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4299880A (en) * | 1979-11-15 | 1981-11-10 | Minnesota Mining And Manufacturing Company | Demand and timed renewing imaging media |
| CN102251436A (en) * | 2011-06-29 | 2011-11-23 | 陕西师范大学 | Dye-based handwriting protectant for written archives |
| CN104725905A (en) * | 2015-03-30 | 2015-06-24 | 陕西师范大学 | Reinforcement solution and reinforcement method for ball pen and carbon paper handwriting |
| CN104947506A (en) * | 2015-06-18 | 2015-09-30 | 陕西师范大学 | Visualization agent and visualization method of file carbon paper original handwriting |
-
2016
- 2016-05-10 CN CN201610303958.7A patent/CN105802323B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4299880A (en) * | 1979-11-15 | 1981-11-10 | Minnesota Mining And Manufacturing Company | Demand and timed renewing imaging media |
| CN102251436A (en) * | 2011-06-29 | 2011-11-23 | 陕西师范大学 | Dye-based handwriting protectant for written archives |
| CN104725905A (en) * | 2015-03-30 | 2015-06-24 | 陕西师范大学 | Reinforcement solution and reinforcement method for ball pen and carbon paper handwriting |
| CN104947506A (en) * | 2015-06-18 | 2015-09-30 | 陕西师范大学 | Visualization agent and visualization method of file carbon paper original handwriting |
Non-Patent Citations (1)
| Title |
|---|
| 马海鹏: "文献修复中的除污与去渍", 《中国博物馆》 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105802323B (en) | 2017-10-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109738458A (en) | A kind of crizzle detection method | |
| CN106905763B (en) | Pigment type quick-drying neutral ink and ball pen containing same | |
| DE69930627T2 (en) | TWO-TONE INK AND WRITING DEVICE, WHICH CONTAINS THIS | |
| CN105802323A (en) | Ball-point pen and carbon paper diffuse handwriting elimination agent and application method thereof | |
| FR2765898A1 (en) | COLOR LAMINATE PAPER | |
| CN102251436B (en) | Dye-based handwriting protectant for written archives | |
| PurSnAnI et al. | Inking in surgical pathology: does the method matter? A procedural analysis of a spectrum of colours | |
| DE29815121U1 (en) | Coating color and coated paper with a coating formed from the coating color to prevent forms from being counterfeited | |
| CN104947506B (en) | A kind of record carbon-paper original paper writing visualization reagent and process for show | |
| CN104725905B (en) | A kind ofly add solid-liquid and reinforcement means for ballpoint pen and transfer paper writing | |
| JP6571691B2 (en) | Photocrosslinkable writing ink | |
| Bredereck et al. | Fixing of ink dyes as a basis for restoration and preservation techniques in archives | |
| Wu Chiam et al. | Marking the surgical margins of specimens: commercial acrylic pigments are reliable, rapid and safe | |
| CN103102750A (en) | Application of ZB-F600 two-component FEVE water-based fluororesin in repair of silk and paper cultural relic writings and drawings | |
| CN108277517A (en) | The guard method of precision holes and precision face in aluminium and Anodizing Process | |
| CN212400718U (en) | Mark pen with color spreading clamping groove | |
| BR112021011840A2 (en) | NON-NEWTONIAN BALL PEN INK INCLUDING CELLULOSE NANOFIBERS | |
| JP4426564B2 (en) | Water-erasable ink brush composition for calligraphy | |
| CN104693892A (en) | Hidden cultural relic code identification fluid | |
| CN112078268B (en) | Method for restoring original appearance of printing ink polluted paper file | |
| Lindblom | Pens and pencils | |
| Hilal et al. | Study of disappearing ink writings on different types of documents | |
| Dong et al. | Techniques for Filling Losses in Palm Leaf Manuscripts | |
| DE202013102738U1 (en) | Device for repairing wood surfaces | |
| FOTA | ANTOLOGHION, RÂMNIC, 1766. CONSERVATION REPORT. |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |