CN105789052A - Fabrication method of low-temperature poly-silicon thin film transistor and product - Google Patents

Fabrication method of low-temperature poly-silicon thin film transistor and product Download PDF

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Publication number
CN105789052A
CN105789052A CN201510999757.0A CN201510999757A CN105789052A CN 105789052 A CN105789052 A CN 105789052A CN 201510999757 A CN201510999757 A CN 201510999757A CN 105789052 A CN105789052 A CN 105789052A
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layer
transformation
zone
film transistor
low
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CN201510999757.0A
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Inventor
周茂清
段志勇
魏朝刚
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Kunshan Govisionox Optoelectronics Co Ltd
Kunshan Guoxian Photoelectric Co Ltd
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Kunshan Guoxian Photoelectric Co Ltd
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Priority to CN201510999757.0A priority Critical patent/CN105789052A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66227Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
    • H01L29/66409Unipolar field-effect transistors
    • H01L29/66477Unipolar field-effect transistors with an insulated gate, i.e. MISFET
    • H01L29/66742Thin film unipolar transistors
    • H01L29/6675Amorphous silicon or polysilicon transistors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/22Diffusion of impurity materials, e.g. doping materials, electrode materials, into or out of a semiconductor body, or between semiconductor regions; Interactions between two or more impurities; Redistribution of impurities
    • H01L21/223Diffusion of impurity materials, e.g. doping materials, electrode materials, into or out of a semiconductor body, or between semiconductor regions; Interactions between two or more impurities; Redistribution of impurities using diffusion into or out of a solid from or into a gaseous phase
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/324Thermal treatment for modifying the properties of semiconductor bodies, e.g. annealing, sintering
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/78Field effect transistors with field effect produced by an insulated gate
    • H01L29/786Thin film transistors, i.e. transistors with a channel being at least partly a thin film
    • H01L29/78651Silicon transistors
    • H01L29/7866Non-monocrystalline silicon transistors
    • H01L29/78672Polycrystalline or microcrystalline silicon transistor

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Manufacturing & Machinery (AREA)
  • Ceramic Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Recrystallisation Techniques (AREA)
  • Thin Film Transistor (AREA)

Abstract

The invention provides a fabrication method of a low-temperature poly-silicon thin film transistor. The fabrication method comprises the following steps of forming an oxygen heavily doped region on a non-protection region (an insulation conversion region) by an oxygen injection technology after an amorphous silicon layer a-Si is deposited through a photoresist protection pattern region; carrying out an excimer laser annealing (ELA) process to enable non-doped amorphous silicon and oxygen-doped amorphous silicon to respectively form poly-silicon and SiO2; and carrying out GI membrane deposition of a gate dielectric layer, and improving GI step coverage and line width control of P-Si. Since the amorphous silicon layer outside a semiconductor conversion region is removed not by an etching mode, no step is formed at the edge of the poly-silicon semiconductor layer P-Si, the step coverage rate of the high gate dielectric layer GI is effectively improved, and electric leakage is prevented.

Description

The preparation method of a kind of low-temperature polysilicon film transistor and product
Technical field
The invention belongs to organic electroluminescence device technical field, be specifically related to a kind of low temperature polycrystalline silicon thin The manufacture method of film transistor and utilize low-temperature polysilicon film transistor prepared by the method.
Background technology
It is by glass base by low temperature polycrystalline silicon (LTPS) thin film transistor (TFT) (TFT) structure as shown in Figure 1 On plate 1, the non-crystalline silicon (a-Si) of deposition is converted into polysilicon (P-Si) being formed by etching and partly leads Body layer 2, the most thereon cvd silicon oxide (SiO2) as gate dielectric layer 3 (GI), metal gate layers 4(Gate).Due to P-Si marginal existence step after over etching, for ensureing that silicon oxide can cover Step and prevent short circuit electric leakage, frequently with way be to reduce the slope angle of P-Si and increase the thickness of GI. But the mode that P-Si uses quasi-molecule laser annealing (ELA) is formed, often there is projection in its surface, When projection is near marginal position, if GI layer step coverage is deteriorated or Gate etching occurred quarter Shi Ze is susceptible to electric leakage or punctures;On the other hand, reduce the slope angle of P-Si, be unfavorable for the line of figure Wide control, is susceptible to residual.
Summary of the invention
The technical problem to be solved is that in prior art, semiconductor layer surface exists step and causes Gate dielectric layer spreadability is deteriorated and electrical leakage problems occurs, thus provides the system of low-temperature polysilicon film transistor Preparation Method and the low-temperature polysilicon film transistor prepared by this method.The present invention partly leads Body layer edge is formed without step, is effectively improved the step coverage of gate dielectric layer and prevents electric leakage.
For solving above-mentioned technical problem, the present invention is achieved by the following technical solutions:
The preparation method of a kind of low-temperature polysilicon film transistor, comprises the steps:
S1: deposition of amorphous silicon layers on substrate, and amorphous silicon layer is divided into insulation switch region and partly leads Body zone of transformation;
S2: armor coated on described amorphous silicon layer, and etch above the described insulation zone of transformation of removal Protective layer, make described in state insulation zone of transformation and expose, and retain the protective layer above quasiconductor zone of transformation;
S3: inject oxonium ion in insulation zone of transformation;
S4: removed by the protective layer above quasiconductor zone of transformation, uses quasi-molecule laser annealing technique to make The amorphous silicon layer of quasiconductor zone of transformation is converted to polysilicon semiconductor layer, activates insulation zone of transformation note simultaneously The oxonium ion entered, the oxonium ion of described state of activation forms silicon dioxide with the pasc reaction in amorphous silicon layer Sealing coat;
S5, on the basis of step S4, deposit gate dielectric layer, grid layer, intermediate insulating layer and source-drain electrode.
The dosage injecting oxonium ion in described step S3 is more than marginal value, injects oxygen in insulation zone of transformation During ion, the injection direction of oxygen ion beam is perpendicular to the plane at described insulation zone of transformation place.
Described protective layer is photoresist layer.
In described step S2, etching is the photoresist using Exposure mode to remove above described insulation zone of transformation Layer.
Described step S4 is:
Photoresist layer above quasiconductor zone of transformation is carried out ashing process, after then carrying out peeling off cleaning, Quasi-molecule laser annealing technique is used to make the amorphous silicon layer of quasiconductor zone of transformation be converted to polysilicon semiconductor Layer, activates the oxonium ion that insulation zone of transformation injects, the oxonium ion of described state of activation and non-crystalline silicon simultaneously Pasc reaction in Ceng forms silicon dioxide sealing coat;
In described step S5 before deposition gate dielectric layer to polysilicon semiconductor layer and silicon dioxide every The surface of absciss layer uses hydrofluoric acid clean, to reduce the height of its protrusion of surface.
The present invention also provides for a kind of low-temperature polysilicon film transistor prepared by said method.
The technique scheme of the present invention has the advantage that compared to existing technology
The preparation method of the low-temperature polysilicon film transistor that the present invention provides, is at deposition of amorphous silicon layers Protect graphics field by photoresistance after a-Si, note oxygen is used for non-protected area (insulation zone of transformation) Technology forms oxygen heavily doped region, then carries out quasi-molecule laser annealing (ELA) technique, makes unadulterated The non-crystalline silicon of non-crystalline silicon and oxygen doping forms P-Si and SiO2 respectively, carries out GI the most again and sinks film, improves The live width of GI Step Coverage and P-Si controls.Owing to not being employing etching mode removal quasiconductor conversion Amorphous silicon layer beyond district, therefore the edge of polysilicon semiconductor layer P-Si is formed without step, effectively carries The step coverage of high gate dielectric layer GI prevents electric leakage.
Additionally, due to do not use etching mode to remove the amorphous silicon layer beyond quasiconductor zone of transformation, polycrystalline Silicon semiconductor layer P-Si can form the biggest slope angle, improves the live width control of polysilicon semiconductor layer P-Si System, reduces the probability of etching residue.Further, the amorphous silicon layer beyond quasiconductor zone of transformation leads to Crossing and react formation silicon dioxide sealing coat with oxonium ion, silicon dioxide sealing coat is at polysilicon semiconductor layer The surrounding of P-Si forms silicon oxide heat-insulation layer, is conducive to improving the mobility of P-Si when ELA.
Accompanying drawing explanation
In order to make present disclosure be more likely to be clearly understood, below in conjunction with the accompanying drawings, to the present invention It is described in further detail, wherein,
Fig. 1 is the structural representation of the TFT of prior art;
Fig. 2-Fig. 3 is the TFT preparation process schematic diagram of the present invention;
Wherein reference is: 1-substrate, 2-semiconductor layer, 3-gate dielectric layer, 4-grid layer, 5- Protective layer, 21-amorphous silicon layer, 22-silicon dioxide sealing coat, 23-TFT channel region, 24-heavily doped region, 6-intermediate insulating layer, 7-source-drain electrode layer.
Detailed description of the invention
In order to make the purpose of invention, technical scheme and advantage clearer, below in conjunction with accompanying drawing to sending out Bright embodiment is described in further detail.
Invention can be embodied in many different forms, and should not be construed as limited to set forth herein Embodiment.On the contrary, it is provided that these embodiments so that the disclosure will be thorough and complete, and will The design of invention is fully conveyed to those skilled in the art, and invention will only be defined by the appended claims. In the accompanying drawings, for clarity, layer and the size in region and relative size can be exaggerated.It is to be understood that , when element such as layer, region or substrate are referred to as " being formed at " or " being arranged on " another yuan Part " on " time, this element can be arranged directly on another element described, or can also exist Between element.On the contrary, it is referred to as " being formed directly into " or " being set directly at " another element when element Time upper, there is not intermediary element.
As shown in Figures 2 and 3, the invention provides a kind of low-temperature polysilicon film transistor, described Low-temperature polysilicon film transistor preparation method, comprise the steps:
S1: use the method deposition of amorphous silicon layers 21 of chemical gaseous phase deposition on substrate, and by non-crystalline silicon Layer 21 is divided into insulation switch region and quasiconductor zone of transformation;
S2: on described amorphous silicon layer 21 armor coated 5, described protective layer 5 is photoresist layer, And pass through exposure imaging and etch the protective layer 5 removed above described insulation zone of transformation, make described insulation turn Change district to expose, and retain the protective layer above quasiconductor zone of transformation;
S3: to insulation zone of transformation in inject oxonium ion, can use source and drain areas is doped from Sub-injection device, the dosage injecting oxonium ion needs more than marginal value, and typical dosage is 1*1017/cm2; When injecting oxonium ion in insulation zone of transformation, the injection direction of oxygen ion beam is perpendicular to described insulation and converts The plane at place, district.
S4: after being removed by the protective layer above quasiconductor zone of transformation, uses quasi-molecule laser annealing technique The amorphous silicon layer making quasiconductor zone of transformation is converted to polysilicon semiconductor layer 2, due to excimer laser irradiation Non-crystalline silicon can produce high temperature, and typical temperature is more than 1400 DEG C, therefore at quasi-molecule laser annealing The oxonium ion simultaneously making insulation zone of transformation activates and forms silicon dioxide isolation with the pasc reaction in amorphous silicon layer Layer 22;
S5: deposit gate dielectric layer 3, grid layer 4, intermediate insulating layer 6 and on the basis of step S4 Source-drain electrode.
To polysilicon semiconductor layer 2 and silicon dioxide before deposition gate dielectric layer in described step S5 The surface of sealing coat 22 uses hydrofluoric acid clean, and typical concentration is 1wt%, scavenging period 30 seconds, To reduce the height of its protrusion of surface.
Low-temperature polysilicon film transistor preparation method of the present invention also includes step S6 and step S7:
S6: use ion implantation apparatus that polysilicon semiconductor layer 2 is carried out boron ion note after step s 5 Entering, typical implantation dosage is more than 1*1015/cm2To form heavy doping, owing to gate metal is to boron ion Barrier effect, the polysilicon region covered by grid layer 4 forms TFT channel without boron ion implanting District, the polysilicon region not covered by grid layer 4 forms heavily doped region, this district due to boron ion implanting Territory is as source-drain electrode contact area.
S7: deposit intermediate insulating layer 6 on the grid layer 4 that step S5 is formed, and etched by exposure Method formed source-drain electrode contact hole, last sedimentary origin drain metal layer, be etched to define source-drain electrode layer 7.
The structure of the low-temperature polysilicon film transistor that the present invention provides and existing low-temperature polysilicon film The structure of transistor in addition to semiconductor layer difference, remaining each layer, as gate dielectric layer 3, grid layer 4, Intermediate insulating layer 6 and source-drain electrode, and structure is the most identical, does not repeats them here.
The low-temperature polysilicon film transistor that the present invention provides, is not to use etching side due to semiconductor layer Formula removes the amorphous silicon layer beyond quasiconductor zone of transformation, therefore the edge of polysilicon semiconductor layer P-Si without Step is formed, and the step coverage being effectively improved gate dielectric layer GI prevents electric leakage.
Obviously, above-described embodiment is only for clearly demonstrating example, and not to embodiment party The restriction of formula.For those of ordinary skill in the field, the most also may be used To make other changes in different forms.Here without also all of embodiment being given With exhaustive.And the obvious change thus extended out or variation are still in the guarantor of the invention Protect among scope.

Claims (8)

1. the preparation method of a low-temperature polysilicon film transistor, it is characterised in that include walking as follows Rapid:
S1: deposition of amorphous silicon layers (21) on substrate, and amorphous silicon layer (21) is divided into insulation Switch region and quasiconductor zone of transformation;
S2: upper armor coated (5) at described amorphous silicon layer (21), and etch the described insulation of removal Protective layer (5) above zone of transformation, makes described insulation zone of transformation expose, and retains quasiconductor zone of transformation The protective layer of top;
S3: inject oxonium ion in insulation zone of transformation;
S4: removed by the protective layer above quasiconductor zone of transformation, uses quasi-molecule laser annealing technique to make The amorphous silicon layer of quasiconductor zone of transformation is converted to polysilicon semiconductor layer (2), activates insulation simultaneously and converts The oxonium ion that district is injected, the oxonium ion of described state of activation forms dioxy with the pasc reaction in amorphous silicon layer SiClx sealing coat (22);
S5, on the basis of step S4 deposit gate dielectric layer (3), grid layer (4), intermediate insulation Layer (6) and source-drain electrode.
The preparation method of low-temperature polysilicon film transistor the most according to claim 1, its feature It is, described step S3 is injected the dosage of oxonium ion more than marginal value.
The preparation method of low-temperature polysilicon film transistor the most according to claim 2, its feature It is: described step S3 is: when injecting oxonium ion in insulation zone of transformation, the injection side of oxygen ion beam To the plane being perpendicular to described insulation zone of transformation place.
4. according to the preparation method of the low-temperature polysilicon film transistor described in any one of claim 1-3, It is characterized in that: described protective layer (5) is photoresist layer.
The preparation method of low-temperature polysilicon film transistor the most according to claim 4, its feature It is: in described step S2, etching is the photoetching using Exposure mode to remove above described insulation zone of transformation Glue-line.
The preparation method of low-temperature polysilicon film transistor the most according to claim 4, its feature It is: described step S4 is:
Photoresist layer above quasiconductor zone of transformation is carried out ashing process, after then carrying out peeling off cleaning, Quasi-molecule laser annealing technique is used to make the amorphous silicon layer of quasiconductor zone of transformation be converted to polysilicon semiconductor Layer (2), activates the oxonium ion that insulation zone of transformation injects simultaneously, and the oxonium ion of described state of activation is with non- Pasc reaction in crystal silicon layer forms silicon dioxide sealing coat (22).
The preparation method of low-temperature polysilicon film transistor the most according to claim 6, its feature It is: to polysilicon semiconductor layer (2) and two before deposition gate dielectric layer in described step S5 The surface of silicon oxide sealing coat (22) uses hydrofluoric acid clean, to reduce the height of its protrusion of surface.
8. the low-temperature polysilicon film that the method described in an any one of claim 1-6 prepares is brilliant Body pipe.
CN201510999757.0A 2015-12-28 2015-12-28 Fabrication method of low-temperature poly-silicon thin film transistor and product Pending CN105789052A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107068768A (en) * 2017-04-05 2017-08-18 深圳市华星光电技术有限公司 Thin film transistor (TFT) and preparation method thereof, array base palte
CN107833924A (en) * 2017-10-26 2018-03-23 京东方科技集团股份有限公司 Top gate type thin film transistor and preparation method thereof, array base palte, display panel
US10439071B2 (en) 2017-04-05 2019-10-08 Shenzhen China Star Optoelectronics Technology Co., Ltd Thin film transistors and the manufacturing methods thereof, and array substrates

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06338614A (en) * 1993-05-28 1994-12-06 Casio Comput Co Ltd Thin-film transistor and manufacture thereof
CN101067701A (en) * 2006-05-03 2007-11-07 Lg.菲利浦Lcd株式会社 LCD device and its production method

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06338614A (en) * 1993-05-28 1994-12-06 Casio Comput Co Ltd Thin-film transistor and manufacture thereof
CN101067701A (en) * 2006-05-03 2007-11-07 Lg.菲利浦Lcd株式会社 LCD device and its production method

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107068768A (en) * 2017-04-05 2017-08-18 深圳市华星光电技术有限公司 Thin film transistor (TFT) and preparation method thereof, array base palte
WO2018184294A1 (en) * 2017-04-05 2018-10-11 深圳市华星光电技术有限公司 Thin film transistor and manufacturing method thereof, and array substrate
US10439071B2 (en) 2017-04-05 2019-10-08 Shenzhen China Star Optoelectronics Technology Co., Ltd Thin film transistors and the manufacturing methods thereof, and array substrates
CN107833924A (en) * 2017-10-26 2018-03-23 京东方科技集团股份有限公司 Top gate type thin film transistor and preparation method thereof, array base palte, display panel
CN107833924B (en) * 2017-10-26 2020-06-19 京东方科技集团股份有限公司 Top gate type thin film transistor, preparation method thereof, array substrate and display panel

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