CN105368094A - Gamma-chloropropyl trimethoxy siloxane powder modifier - Google Patents
Gamma-chloropropyl trimethoxy siloxane powder modifier Download PDFInfo
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- CN105368094A CN105368094A CN201510861048.6A CN201510861048A CN105368094A CN 105368094 A CN105368094 A CN 105368094A CN 201510861048 A CN201510861048 A CN 201510861048A CN 105368094 A CN105368094 A CN 105368094A
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Abstract
The invention relates to a gamma-chloropropyl trimethoxy siloxane powder modifier which is composed of 3-5 parts of gamma-chloropropyl trimethoxy siloxane, 5-6 parts of aminoethyl propyl aminopropyl methyl methoxyl saline, 5-8 parts of dipropylene glycol monobutyl ether, 3-8 parts of pentaerythritol rosin europium resin, 25-30 parts of cocoanut fatty acid diethanolamide, 5-8 parts of sodium carbonate, 3-5 parts of a sodium acrylate-4-vinyl pyridine copolymer, 5-6 parts of glycerol triacetate, 10-12 parts of di-n-octyltin oxide, 3-5 parts of polyvinyl acetal resin, 25-30 parts of gamma-glycidoxypropyltrimethoxysilane, 3-5 parts of dodecyl dimethyl benzyl ammonium bromide, 20-30 parts of ethanol and 550-600 parts of water. The modifier provided by the invention has the advantages of being easily available in raw materials, low in cost, remarkable in effect and the like.
Description
Technical field
The invention belongs to a kind of functional agent producing non-metallic powder.
Background technology
At present, calcium carbonate is widely used in papermaking, plastics, plastics film, chemical fibre, rubber, tackiness agent, sealing agent, daily-use chemical industry, makeup, building materials, coating, paint, ink, putty, sealing wax, putty, carpet veneer is packed, medicine, food is (as chewing gum, chocolate), in feed, its effect has: increase small product size, reduce costs, improve processing characteristics (as adjusting viscosity, rheological property, curability), improve dimensional stability, reinforcement or half reinforcement, improve printing performance, improve physicals (as thermotolerance, extinction, wear resistance, flame retardant resistance, whiteness, glossiness) etc., for obtaining more superior performance, auxiliary agent is all adopted to carry out activation treatment.
Summary of the invention
The object of the invention is to; A kind of γ-r-chloropropyl trimethoxyl silane powder modifier and preparation method thereof is proposed.
γ of the present invention-r-chloropropyl trimethoxyl silane powder modifier, it is characterized in that: by weight, its formula is by γ-r-chloropropyl trimethoxyl silane 3-5 part, aminoethyl third aminopropyltriethoxy methoxy silane 5-6 part, Dipropylene glycol mono-n-butyl Ether 5-8 part, rosin pentaerythritol ester europium resin 3-8 part, cocoanut fatty acid diethanolamide 25-30 part, sodium carbonate 5-8 part, sodium acrylate-4-vinylpridine multipolymer 3-5 part, Vanay 5-6 part, di-n-octyltin oxide 10--12 part, polyvinyl acetal resin 3-5 part, γ-glycidyl ether oxygen propyl trimethoxy silicane 25-30 part, dodecyl dimethyl benzyl ammonium bromide 3-5 part, ethanol 20-30 part, water 550-600 part forms.
The preparation method of γ of the present invention-r-chloropropyl trimethoxyl silane powder modifier, it is characterized in that: by weight, its formula is by γ-r-chloropropyl trimethoxyl silane 3-5 part, aminoethyl third aminopropyltriethoxy methoxy silane 5-6 part, Dipropylene glycol mono-n-butyl Ether 5-8 part, rosin pentaerythritol ester europium resin 3-8 part, cocoanut fatty acid diethanolamide 25-30 part, sodium carbonate 5-8 part, sodium acrylate-4-vinylpridine multipolymer 3-5 part, Vanay 5-6 part, di-n-octyltin oxide 10--12 part, polyvinyl acetal resin 3-5 part, γ-glycidyl ether oxygen propyl trimethoxy silicane 25-30 part, dodecyl dimethyl benzyl ammonium bromide 3-5 part, ethanol 20-30 part, water 550-600 part forms, first with ethanol by rosin europium resin dissolves, after adding water 550-600 part, add whole raw material and mix, at 85 ~ 95 DEG C, stir 20-30 minute, obtain product.
The present invention compared with prior art its beneficial effect is: have design science reasonable, and technique is simple, safe reliability, is easy to control, easy to operate, is applicable to scale operation, the advantages such as production cost is low.
Embodiment
Below in conjunction with embodiment, the invention will be further described, but embodiments of the present invention are not limited thereto.
All raw materials of the present invention can buy acquisition.
Embodiment 1, the preparation of γ of the present invention-r-chloropropyl trimethoxyl silane powder modifier, it is characterized in that: by weight, its formula is by γ-r-chloropropyl trimethoxyl silane 3-5 part, aminoethyl third aminopropyltriethoxy methoxy silane 5-6 part, Dipropylene glycol mono-n-butyl Ether 5-8 part, rosin pentaerythritol ester europium resin 3-8 part, cocoanut fatty acid diethanolamide 25-30 part, sodium carbonate 5-8 part, sodium acrylate-4-vinylpridine multipolymer 3-5 part, Vanay 5-6 part, di-n-octyltin oxide 10--12 part, polyvinyl acetal resin 3-5 part, γ-glycidyl ether oxygen propyl trimethoxy silicane 25-30 part, dodecyl dimethyl benzyl ammonium bromide 3-5 part, ethanol 20-30 part, water 550-600 part forms, first with ethanol by rosin europium resin dissolves, after adding water 550-600 part, add whole raw material and mix, at 85 ~ 95 DEG C, stir 20-30 minute, obtain product.
Embodiment 2, the preparation of γ of the present invention-r-chloropropyl trimethoxyl silane powder modifier, it is characterized in that: by weight, its formula is by γ-r-chloropropyl trimethoxyl silane 5 parts, aminoethyl third aminopropyltriethoxy methoxy silane 5-6 part, Dipropylene glycol mono-n-butyl Ether 5-8 part, rosin pentaerythritol ester europium resin 3 parts, cocoanut fatty acid diethanolamide 25 parts, 5 parts, sodium carbonate, sodium acrylate-4-vinylpridine multipolymer 3 parts, Vanay 5 parts, dioctyl tin 10 parts, polyvinyl acetal resin 3 parts, glycidyl ether oxygen propyl trimethoxy silicane 25 parts, ethanol 20-30 part, water 550-600 part forms, first with ethanol by rosin europium resin dissolves, after adding water 550-600 part, add whole raw material and mix, at 85 ~ 95 DEG C, stir 20-30 minute, obtain product.
Embodiment 3, the preparation of γ of the present invention-r-chloropropyl trimethoxyl silane powder modifier, it is characterized in that: by weight, its formula is by γ-r-chloropropyl trimethoxyl silane 3 parts, aminoethyl third aminopropyltriethoxy methoxy silane 5-6 part, Dipropylene glycol mono-n-butyl Ether 5-8 part, rosin pentaerythritol ester europium resin 8 parts, cocoanut fatty acid diethanolamide 30 parts, 8 parts, sodium carbonate, sodium acrylate-4-vinylpridine multipolymer 5 parts, Vanay 6 parts, dioctyl tin 12 parts, polyvinyl acetal resin 5 parts, glycidyl ether oxygen propyl trimethoxy silicane 30 parts, dodecyl dimethyl benzyl ammonium bromide 3-5 part, ethanol 20-30 part, water 550-600 part forms, first with ethanol by rosin europium resin dissolves, after adding water 550-600 part, add whole raw material and mix, at 85 ~ 95 DEG C, stir 20-30 minute, obtain product.
Embodiment 4, the preparation of γ of the present invention-r-chloropropyl trimethoxyl silane powder modifier, it is characterized in that: by weight, its formula is by γ-r-chloropropyl trimethoxyl silane 4 parts, aminoethyl third aminopropyltriethoxy methoxy silane 5-6 part, Dipropylene glycol mono-n-butyl Ether 5-8 part, rosin pentaerythritol ester europium resin 3 parts, cocoanut fatty acid diethanolamide 30 parts, 5 parts, sodium carbonate, sodium acrylate-4-vinylpridine multipolymer 5 parts, Vanay 5 parts, dioctyl tin 12 parts, polyvinyl acetal resin 3 parts, glycidyl ether oxygen propyl trimethoxy silicane 25 parts, dodecyl dimethyl benzyl ammonium bromide 3-5 part, ethanol 20-30 part, water 550-600 part forms, first with ethanol by rosin europium resin dissolves, after adding water 550-600 part, add whole raw material and mix, at 85 ~ 95 DEG C, stir 20-30 minute, obtain product.
Product of the present invention, uses through production firm, and produce modified superfine water-ground limestone functional product, reaction effect is fine.
Part material illustrates:
1, described rosin pentaerythritol ester europium resin, the method that can be preferably ZL201410078259.8 by the Chinese patent patent No. obtains.
2, aminoethyl third aminopropyltriethoxy methoxy silane, embodiment Nanjing Xu Yang Chemical Co., Ltd. product, trade(brand)name: precoated sand highly efficient intensifying agent silicon XY-812.
3, γ-glycidyl ether oxygen propyl trimethoxy silicane molecular formula: C
9h
2oO
5si
4, γ-r-chloropropyl trimethoxyl silane, molecular formula: C
6h
15o
3siCl.
Claims (2)
1. γ-r-chloropropyl trimethoxyl silane powder modifier, it is characterized in that: by weight, its formula is by γ-r-chloropropyl trimethoxyl silane 3-5 part, aminoethyl third aminopropyltriethoxy methoxy silane 5-6 part, Dipropylene glycol mono-n-butyl Ether 5-8 part, rosin pentaerythritol ester europium resin 3-8 part, cocoanut fatty acid diethanolamide 25-30 part, sodium carbonate 5-8 part, sodium acrylate-4-vinylpridine multipolymer 3-5 part, Vanay 5-6 part, di-n-octyltin oxide 10--12 part, polyvinyl acetal resin 3-5 part, γ-glycidyl ether oxygen propyl trimethoxy silicane 25-30 part, dodecyl dimethyl benzyl ammonium bromide 3-5 part, ethanol 20-30 part, water 550-600 part forms.
2. the preparation method of γ-r-chloropropyl trimethoxyl silane powder modifier, it is characterized in that: by weight, its formula is by γ-r-chloropropyl trimethoxyl silane 3-5 part, aminoethyl third aminopropyltriethoxy methoxy silane 5-6 part, Dipropylene glycol mono-n-butyl Ether 5-8 part, rosin pentaerythritol ester europium resin 3-8 part, cocoanut fatty acid diethanolamide 25-30 part, sodium carbonate 5-8 part, sodium acrylate-4-vinylpridine multipolymer 3-5 part, Vanay 5-6 part, di-n-octyltin oxide 10--12 part, polyvinyl acetal resin 3-5 part, γ-glycidyl ether oxygen propyl trimethoxy silicane 25-30 part, dodecyl dimethyl benzyl ammonium bromide 3-5 part, ethanol 20-30 part, water 550-600 part forms, first with ethanol by rosin europium resin dissolves, after adding water 550-600 part, add whole raw material and mix, at 85 ~ 95 DEG C, stir 20-30 minute, obtain product.
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| CN201510861048.6A CN105368094A (en) | 2015-11-26 | 2015-11-26 | Gamma-chloropropyl trimethoxy siloxane powder modifier |
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| CN201510861048.6A CN105368094A (en) | 2015-11-26 | 2015-11-26 | Gamma-chloropropyl trimethoxy siloxane powder modifier |
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2015
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| CN102911441A (en) * | 2012-09-18 | 2013-02-06 | 铜陵市铜都特种线缆厂 | High-temperature-resistant moisture-proof mould-proof environment-friendly cable material and preparation method thereof |
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Application publication date: 20160302 |