CN105355962B - Preparation method of winding type laminated battery - Google Patents

Preparation method of winding type laminated battery Download PDF

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Publication number
CN105355962B
CN105355962B CN201510848158.9A CN201510848158A CN105355962B CN 105355962 B CN105355962 B CN 105355962B CN 201510848158 A CN201510848158 A CN 201510848158A CN 105355962 B CN105355962 B CN 105355962B
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barrier film
positive
pole piece
preparation
negative plate
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CN105355962A (en
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王义飞
王晨旭
胡家佳
许涛
王志忠
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Gotion High Tech Co Ltd
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Gotion High Tech Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/04Construction or manufacture in general
    • H01M10/0431Cells with wound or folded electrodes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

The invention provides a preparation method of a winding type laminated battery, which comprises a pole piece preparation process, wherein the pole piece preparation comprises the following steps: after coating, baking, rolling and slitting are finished on the positive and negative current collectors, the positive and negative current collectors are cut regularly according to the design sizes of the positive and negative plates, adhesive tapes or glue are adhered to the edges of the corners of the positive and negative plates, and are bonded and compounded with the diaphragm to form different pole piece-diaphragm complexes, and then the different pole piece-diaphragm complexes are used for preparing the winding type laminated battery. The winding type laminated battery prepared by the invention can solve the problems that the diaphragm and the pole piece are dislocated, the diaphragm is folded, the diaphragm is easy to pierce, the short circuit is easy, the side reaction is easy to generate, the tension of the battery is not easy to control, the performance of the battery is reduced or the battery is safe and the like in the preparation process of the existing laminated battery; the stability and the security of battery can be effectively promoted, the production cost is reduced, and the production efficiency is greatly improved.

Description

A kind of preparation method of takeup type laminated batteries
Technical field
The present invention relates to field of batteries, and in particular to a kind of preparation method of takeup type laminated batteries.
Background technology
The consumption electronic product of modern digital is developing progressively ripe, and component is just being intended to light, thin, short and small target. It is to be growing on and on to its demand and energy-storage battery is the power source of light portable electronic product.In addition, electronic traffic work Tool, decentralized power supply feed system, peak load regulation network, redundant electrical power, green building, portable medical based on solar energy and wind energy The rapid development in the fields such as electronic equipment, Industry Control, Aero-Space, robot, national security, there is an urgent need to more high energy Metric density, more power density, more long circulation life and greater security can charge and discharge energy storage device.Lithium ion battery is due to it Light weight, small volume, higher than energy, self discharge is small, good cycle, pollute small and memory-less effect the features such as, become 21 Century most application prospect one of green secondary cell.
Battery core in the market is typically all winding method, but this lithium battery is due to, high current big with internal resistance Poor performance, temperature are high, the shortcomings of security difference, can not meet the performance requirement of some special occasions, in terms of electrokinetic cell.For Overcome these shortcomings, especially meet the safe handling in terms of electric automobile.Lithium ion battery on traditional structure is in chi After very little amplification, its some internal adverse reaction caused by specific structure is also amplified therewith, and now there is an urgent need to a kind of more excellent The core strueture of change meets the design requirement of high capacity cell, and on this basis, laminated batteries arise at the historic moment.
But the low production efficiency of laminated batteries, pole piece will be punched, section is more, easily pierces through barrier film, easily short circuit, is also easy to produce Side reaction, the tension force of battery are difficult to control, and battery performance reduction or security problems is occurred.
The content of the invention
It is an object of the invention to:A kind of preparation method of takeup type laminated batteries is provided, existing laminated batteries can be improved Misplaced in preparation process septation with pole piece, barrier film fold, easily pierce through barrier film, easily short circuit, be also easy to produce side reaction, battery Tension force is difficult to control, and battery performance reduction or security problems is occurred, can effectively lift the stability and security of battery, especially It is to reduce production cost, increases substantially production efficiency.
For achieving the above object, the present invention provides following technical scheme:
A kind of preparation method of takeup type laminated batteries, including pole piece preparation process, prepared by the pole piece uses following step Suddenly:
Positive and negative collector complete coating, baking, roll-in, cut into bar after, respectively according to positive and negative plate design size Cut out regular, adhesive tape or glue are then stained with the comer edge of positive and negative plate, carries out bonding compound, shape respectively with barrier film Into different pole pieces-barrier film complex, then takeup type laminated battery is prepared with the different pole pieces-barrier film complex again Pond.
Preferably, the specific preparation process of the takeup type laminated batteries is as follows:
It is (1) compound by design spacing and barrier film bonding after the corner for the positive plate cut out being stained with into adhesive tape or glue, Form positive plate-barrier film complex;
It is (2) compound by design spacing and barrier film bonding after the corner for the negative plate cut out being stained with into adhesive tape or glue, Form negative plate-barrier film complex;
(3) positive plate-barrier film complex and negative plate-barrier film complex are prepared in the way of negative pole clad anode Into takeup type laminated batteries battery core, then by forming takeup type laminated batteries after assembling, fluid injection, chemical conversion, partial volume.
Preferably, the positive and negative plate carries out adhesive tape with barrier film on a production line or glue bonding is compound.
Preferably, the adhesive tape/glue main component is rubber or tincture fat high molecular polymer.
Preferably, the positive electrode of the battery is LiFePO4, LiMn2O4, cobalt acid lithium, nickle cobalt lithium manganate or nickel cobalt aluminium One or more in sour lithium material.
Preferably, the negative material of the battery is the one or more in carbons, silicon class, alloy type, lithium titanate material.
Preferably, the barrier film is one kind in polyethylene film, polypropylene screen, ceramic diaphragm.
Preferably, the barrier film is wider 2-6mm than positive and negative plate.
Preferably, the electrolyte in the electrolyte of the battery is organic solvent electrolyte or polymer dielectric.
Preferably, the shell of the battery is made up of aluminum hull, box hat, plastic housing or plastic-aluminum membrane material.
The beneficial effects of the present invention are:Compared with prior art, the takeup type laminated batteries that the present invention is prepared, Reduce lamination it is irregular caused by safety and battery performance difference and the problems such as scrap, improve the qualification rate of laminated batteries, have Beneficial to the production efficiency and product quality for improving laminated batteries, battery production cost is greatly reduced, improves the market of laminated batteries Using with important operation instruction meaning and increase economic benefit effect.
Brief description of the drawings
Fig. 1 is glue hopper controller schematic diagram;
Fig. 2 is positive plate-barrier film complex schematic diagram after adhesion;
Fig. 3 is negative plate-barrier film complex schematic diagram after adhesion;
Fig. 4 prepares schematic diagram for takeup type Z-type laminated batteries;
Fig. 5 prepares schematic diagram for the wound laminated batteries of homonymy homotype electrode slice list membrane coil;
Fig. 6 prepares schematic diagram for the wound laminated batteries of special-shaped alternating electrode piece list membrane coil;
Fig. 7 is that positive and negative electrode composite-type rolling prepares schematic diagram around laminated batteries;
In figure, 1 is positive plate;2 be barrier film;3 be adhesive tape or glue;4 be negative plate.
Embodiment
The present invention is described in further detail below in conjunction with accompanying drawing and example, it is intended to it is easy to the understanding of the present invention, but The invention is not limited in listed embodiment.
Referring to Fig. 1 to Fig. 7, the invention provides a kind of takeup type laminated batteries, including it is positive pole-barrier film complex, negative Pole-barrier film complex, adhesive tape or glue.
The preparation method of described takeup type laminated batteries, includes the preparation process of pole piece, the pole piece prepare use with Lower step:Positive and negative collector complete coating, baking, roll-in, cut into bar after, cut respectively according to positive and negative plate design size Cut out regular, adhesive tape or glue are then stained with the comer edge of positive and negative plate, with barrier film bond compound, formed different Pole piece-barrier film complex, then prepare takeup type laminated batteries with the different pole pieces-barrier film complex again.
The pole piece is cut out size and should be adapted with the size of LITHIUM BATTERY group, then carries out binder adhesive with barrier film, avoids Pole piece misplaces with barrier film, produces fold, occurs so as to avoid the formation of dead band or analysis lithium phenomenon.Fig. 1 controls for glue funnel Device schematic diagram;Fig. 2 is positive plate-barrier film complex schematic diagram after adhesion;Fig. 3 is that negative plate-barrier film after adhesion is compound Body schematic diagram.
Wherein, the positive electrode of the battery is LiFePO4, LiMn2O4, cobalt acid lithium, nickle cobalt lithium manganate or nickel cobalt aluminic acid One or more in lithium material;
The adhesive tape/glue main component is rubber or tincture fat high molecular polymer;
The negative material of the battery is the one or more in carbons, silicon class, alloy type, lithium titanate material;
The barrier film is one kind in polyethylene film, polypropylene screen, ceramic diaphragm;
The barrier film is wider 2-6mm than the positive and negative plate;
Electrolyte in the electrolyte of the battery is organic solvent electrolyte or polymer dielectric;
The shell of the battery is made up of aluminum hull, box hat, plastic housing or plastic-aluminum membrane material.
Embodiment 1
Takeup type laminated batteries shown in Figure 4, coating, baking are completed in positive and negative collector, roll-in, cuts into bar Afterwards, cut out respectively according to positive and negative plate design size it is regular, in the way of similar pole piece is distributed in same barrier film homonymy, i.e., Barrier film side is distributed as positive plate, and opposite side is distributed as negative plate, using the spacing distance marshalling of design, recycles adhesive tape Or itself and barrier film binder adhesive are formed positive and negative plate-barrier film composite integrated, positive and negative electrode are interspersed in through guide plate by glue Between center, carry out the preparation of pole piece of laminated battery, complete the winding of pole group unit, then wrapped up with a barrier film, form winding Formula pole piece of laminated battery.
The barrier film is wider 2-6mm than the positive and negative plate, and the similar pole piece is according to the range distribution of design in barrier film Homonymy, and positive and negative plate should be centered on the barrier film, i.e., the distance maintained like with the side of the barrier film.
The positive and negative plate is distributed in single barrier film both sides, when being bonded it with barrier film using adhesive tape or glue, between pole piece When needing to reserve suitable distance in order to form pole piece of laminated battery, upper and lower layer positive and negative plate is avoided to misplace, so as to influence The welding of later stage positive and negative electrode lug.
The positive and negative plate carries out binder adhesive with corresponding barrier film on a production line, then carries out Z-type lamination behaviour again Make, then by forming takeup type laminated batteries after assembling, fluid injection, chemical conversion, partial volume.
Embodiment 2
Shown in Figure 5, the wound laminated batteries of homonymy special-shaped battery pole piece list membrane coil prepare schematic diagram.In positive and negative collection Fluid complete coating, baking, roll-in, cut into bar after, cut out respectively according to positive and negative plate design size it is regular, according to similar Pole piece is distributed in the mode of same barrier film homonymy, i.e. barrier film side is distributed as positive plate, and opposite side is distributed as negative plate, using setting The spacing distance marshalling of meter, recycle adhesive tape or glue that itself and barrier film binder adhesive, formation positive and negative plate-barrier film is multiple Integration is closed, through core according to alternate mode suitable, counterclockwise, the preparation of pole piece of laminated battery is carried out, completes pole group unit Winding, then wrapped up with a barrier film, form takeup type pole piece of laminated battery.
The barrier film is wider 2-6mm than the positive and negative plate, and the similar pole piece is according to the range distribution of design in barrier film Homonymy, and positive and negative plate should be centered on the barrier film, i.e., the distance maintained like with the side of the barrier film.
The positive and negative plate is distributed in single barrier film both sides, when being bonded it with barrier film using adhesive tape or glue, between pole piece When needing to reserve suitable distance in order to form pole piece of laminated battery, upper and lower layer positive and negative plate is avoided to misplace, so as to influence The welding of later stage positive and negative electrode lug.
The positive and negative plate preferably carries out binder adhesive in different production lines with corresponding barrier film, is then wound again Formula lamination, then by forming takeup type laminated batteries after assembling, fluid injection, chemical conversion, partial volume.
Embodiment 3
Shown in Figure 6, the wound laminated batteries of special-shaped alternating electrode piece list membrane coil prepare schematic diagram.In positive and negative collection Fluid complete coating, baking, roll-in, cut into bar after, cut out respectively according to positive and negative plate design size it is regular, according to abnormal shape Pole piece is alternately distributed in the mode on same barrier film, using the spacing distance marshalling of design, recycles adhesive tape or glue will Itself and barrier film binder adhesive, positive and negative plate-barrier film composite integrated is formed, through core according to same clockwise or counter-clockwise The mode of direction winding, carries out the preparation of pole piece of laminated battery, completes the winding of pole group unit, forms takeup type laminated batteries pole Piece, then by forming takeup type laminated batteries after assembling, fluid injection, chemical conversion, partial volume.
The barrier film is wider 2-6mm than the positive and negative plate, the special-shaped pole piece according to the distance of design be alternately arranged in On barrier film, and positive and negative plate should be centered on the barrier film, i.e., the distance maintained like with the side of the barrier film.
The positive and negative plate is alternately arranged on barrier film, when being bonded it with barrier film using adhesive tape or glue, between pole piece When needing to reserve suitable distance in order to form pole piece of laminated battery, upper and lower layer positive and negative plate is avoided to misplace, so as to influence The welding of later stage positive and negative electrode lug.
The positive and negative plate carries out binder adhesive with barrier film, and distance is left in first negative plate front end with barrier film can be complete Full parcel negative plate edge, when preventing from wind in next step, positive and negative electrode EDGE CONTACT, after avoiding subsequent technique from preparing battery, Generation short circuit;Distance is left in last pole piece end with barrier film can be overlapping with the barrier film wound, so that insulating tape glues Close.
Embodiment 4
Shown in Figure 7, positive and negative electrode composite-type rolling prepares schematic diagram around laminated batteries.Complete to apply in positive and negative collector Cloth, baking, roll-in, cut into bar after, cut out according to positive and negative plate design size regular, be arranged according to special-shaped pole piece respectively Mode on different barrier films, using the spacing distance marshalling of design, recycle adhesive tape or glue that it is gluing viscous with barrier film Close, form positive and negative plate-barrier film composite integrated, through core in the way of same direction suitable or counterclockwise is wound, enter The preparation of row pole piece of laminated battery, the winding of pole group unit is completed, form takeup type pole piece of laminated battery, then by assembling, noting Takeup type laminated batteries are formed after liquid, chemical conversion, partial volume.
The barrier film is wider 2-6mm than the positive and negative plate, the special-shaped pole piece according to the distance of design be alternately arranged in On barrier film, and positive and negative plate should be centered on the barrier film, i.e., the distance maintained like with the side of the barrier film.
The positive and negative plate is alternately arranged on barrier film, when being bonded it with barrier film using adhesive tape or glue, between pole piece When needing to reserve suitable distance in order to form pole piece of laminated battery, upper and lower layer positive and negative plate is avoided to misplace, so as to influence The welding of later stage positive and negative electrode lug.
The positive and negative plate carries out binder adhesive with barrier film, and distance is left in first negative plate front end with barrier film can be complete Full parcel negative plate edge, when preventing from wind in next step, positive and negative electrode EDGE CONTACT, after avoiding subsequent technique from preparing battery, Generation short circuit;Distance is left in last pole piece end with barrier film can be overlapping with the barrier film wound, so that insulating tape glues Close.
In summary, the takeup type laminated batteries that the embodiment of the present invention is provided, the irregular generation of lamination is advantageously reduced Dislocation, easily pierces through barrier film, safety and battery performance difference easily caused by short circuit and the problems such as scrap, improve the conjunction of laminated batteries Lattice rate, improving production efficiency and product quality, battery production cost is greatly reduced.
The foregoing description of the disclosed embodiments, professional and technical personnel in the field are enable to realize or using of the invention real Apply example.A variety of modifications to these embodiments will be apparent for those skilled in the art, in the application In the range of open, drawings and claims, a variety of modifications can be carried out to the building block and/or layout of theme combination layout And improvement.In addition to the variations and modifications carried out to building block and/or layout, to those skilled in the art, other Purposes also will be apparent.Therefore, the embodiment of the present invention is not intended to be limited to the embodiments shown herein, but will Meet the most wide scope consistent with designs disclosed herein feature.

Claims (12)

1. a kind of preparation method of takeup type laminated batteries, it is characterised in that including pole piece preparation process, the pole piece is prepared and adopted Use following steps:
(1) positive and negative collector complete coating, baking, roll-in, cut into bar after, cut respectively according to positive and negative plate design size Cut out it is regular, in the way of similar pole piece is distributed in barrier film homonymy, using the spacing distance marshalling of design, in positive and negative electrode Adhesive tape or glue are stained with the comer edge of piece, respectively with barrier film binder adhesive, forms positive and negative plate-barrier film composite integrated Change, be interspersed in center between positive and negative electrode through guide plate, carry out the preparation of pole piece of laminated battery, complete the winding of pole group unit, shape Into takeup type pole piece of laminated battery,
(2) similar pole piece is according to the range distribution of design in barrier film homonymy, and positive and negative plate should be centered on the barrier film, i.e., The distance equal with the side holding of the barrier film,
(3) positive and negative plate and corresponding barrier film carry out binder adhesive, then carry out Z-type lamination, by assembling, fluid injection, chemical conversion, Takeup type laminated batteries are formed after partial volume.
2. a kind of preparation method of takeup type laminated batteries, it is characterised in that including pole piece preparation process, the pole piece is prepared and adopted Use following steps:
(1) positive and negative collector complete coating, baking, roll-in, cut into bar after, cut respectively according to positive and negative plate design size Cut out it is regular, in the way of similar pole piece is distributed in barrier film homonymy, using the spacing distance marshalling of design, in positive and negative electrode Adhesive tape or glue are stained with the comer edge of piece, respectively with barrier film binder adhesive, forms positive and negative plate-barrier film composite integrated Change, through core according to alternate mode suitable, counterclockwise, carry out the preparation of pole piece of laminated battery, complete the winding of pole group unit, shape Into takeup type pole piece of laminated battery,
(2) similar pole piece is according to the range distribution of design in barrier film homonymy, and positive and negative plate should be centered on the barrier film, i.e., The distance maintained like with the side of the barrier film,
(3) positive and negative plate is distributed in barrier film both sides,
Positive and negative plate carries out binder adhesive with corresponding barrier film, is wound formula lamination, passes through assembling, fluid injection, chemical conversion, partial volume Takeup type laminated batteries are formed afterwards.
3. a kind of preparation method of takeup type laminated batteries, it is characterised in that including pole piece preparation process, the pole piece is prepared and adopted Use following steps:
(1) positive and negative collector complete coating, baking, roll-in, cut into bar after, cut respectively according to positive and negative plate design size Cut out it is regular, in the way of special-shaped pole piece is alternately distributed in same barrier film, using the spacing distance marshalling of design, just, Adhesive tape or glue are stained with the comer edge of negative plate, respectively with barrier film binder adhesive, forms positive and negative plate-barrier film compound one Body, through core in the way of same direction clockwise or counter-clockwise is wound, the preparation of pole piece of laminated battery is carried out, completed The winding of pole group unit, takeup type pole piece of laminated battery is formed,
(2) special-shaped pole piece is alternately arranged on barrier film according to the distance of design, and positive and negative plate should be centered on the barrier film, The distance maintained like with the side of the barrier film,
(3) positive and negative plate carries out binder adhesive with barrier film, is wound formula lamination, passes through shape after assembling, fluid injection, chemical conversion, partial volume Into takeup type laminated batteries.
4. a kind of preparation method of takeup type laminated batteries, it is characterised in that including pole piece preparation process, the pole piece is prepared and adopted Use following steps:
(1) positive and negative collector complete coating, baking, roll-in, cut into bar after, cut respectively according to positive and negative plate design size Cut out it is regular, in the way of special-shaped pole piece is arranged on different barrier films, using the spacing distance marshalling of design, positive and negative Adhesive tape or glue are stained with the comer edge of pole piece, respectively with barrier film binder adhesive, forms positive and negative plate-barrier film composite integrated Change, through core in the way of same direction suitable or counterclockwise is wound, carry out the preparation of pole piece of laminated battery, complete pole group list The winding of member, takeup type pole piece of laminated battery is formed,
(2) special-shaped pole piece is alternately arranged on barrier film according to the distance of design, and positive and negative plate should be centered on the barrier film, The distance maintained like with the side of the barrier film,
(3) positive and negative plate carries out binder adhesive with barrier film, is wound formula lamination, passes through shape after assembling, fluid injection, chemical conversion, partial volume Into takeup type laminated batteries.
5. the preparation method of the takeup type laminated batteries as described in claim 1,2,3 or 4, it is characterised in that the positive and negative electrode Piece carries out adhesive tape with barrier film on a production line or glue bonding is compound.
6. the preparation method of the takeup type laminated batteries as described in claim 1,2,3 or 4, it is characterised in that the adhesive tape/glue Water main component is rubber or tincture fat high molecular polymer.
7. the preparation method of the takeup type laminated batteries as described in claim 1,2,3 or 4, it is characterised in that the battery Positive electrode is the one or more in LiFePO4, LiMn2O4, cobalt acid lithium, nickle cobalt lithium manganate or nickel cobalt aluminic acid lithium material.
8. the preparation method of the takeup type laminated batteries as described in claim 1,2,3 or 4, it is characterised in that the battery Negative material is the one or more in carbons, silicon class, alloy type, lithium titanate material.
9. the preparation method of the takeup type laminated batteries as described in claim 1,2,3 or 4, it is characterised in that the barrier film is One kind in polyethylene film, polypropylene screen, ceramic diaphragm.
10. the preparation method of the takeup type laminated batteries as described in claim 1,2,3 or 4, it is characterised in that the barrier film ratio Wide 2-the 6mm of positive and negative plate.
11. the preparation method of the takeup type laminated batteries as described in claim 1,2,3 or 4, it is characterised in that the battery Electrolyte in electrolyte is organic solvent electrolyte or polymer dielectric.
12. the preparation method of the takeup type laminated batteries as described in claim 1,2,3 or 4, it is characterised in that the battery Shell is aluminum hull, box hat, plastic housing or plastic-aluminum membrane material.
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