CN105176703A - Car shell washing agent - Google Patents

Car shell washing agent Download PDF

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Publication number
CN105176703A
CN105176703A CN201510711947.8A CN201510711947A CN105176703A CN 105176703 A CN105176703 A CN 105176703A CN 201510711947 A CN201510711947 A CN 201510711947A CN 105176703 A CN105176703 A CN 105176703A
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CN
China
Prior art keywords
parts
stearate
water
washing composition
active agent
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Pending
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CN201510711947.8A
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Chinese (zh)
Inventor
梁宗贵
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chengdu Shunfa Disinfectant and Washing Technology Co Ltd
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Chengdu Shunfa Disinfectant and Washing Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Chengdu Shunfa Disinfectant and Washing Technology Co Ltd filed Critical Chengdu Shunfa Disinfectant and Washing Technology Co Ltd
Priority to CN201510711947.8A priority Critical patent/CN105176703A/en
Publication of CN105176703A publication Critical patent/CN105176703A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a car shell washing agent. The car shell washing agent is prepared from, by weight, 2-6 parts of sodium citrate, 2-6 parts of rose essence, 2-6 parts of alkyl ether phosphate, 1-5 parts of butoxyethanol, 0.05-0.1 part of fluorine-containing surfactants, 0.05-0.1 parts of sodium chromate, 0-20 parts of potassium permanganate, 10-15 parts of sodium xylene sulfonate, 0.01-0.05 part of butanol, 1-5 parts of stearate and 50-60 parts of water. The car shell washing agent is convenient to use and store, environmentally friendly, sanitary and suitable for large-scale production and has the advantages of being small in stimulation and free of any harm to the skins.

Description

A kind of automobile case washing composition
Technical field
The present invention relates to a kind of vehicle wash agent, more particularly, the present invention relates to a kind of washing composition being suitable for general-utility car vehicle enclosure.
Background technology
Washing composition is divided into according to mode of appearance: powder washing composition, liquid washing agent, solid detergent;
The main component of washing composition is tensio-active agent, and tensio-active agent is containing hydrophilic group and the two-part organic compound of oleophilic group in molecular structure.Be generally can be decomposed into ion in aqueous according to tensio-active agent, be divided into again two large classes of ionogenic surfactant and nonionic surface active agent.Ionogenic surfactant can be divided into again cats product, anion surfactant and zwitterionics three kinds.In the washing of fabric, only have anion surfactant and nonionic surface active agent, front can be played to fabric decontaminating and effectively act on.Therefore these two kinds of tensio-active agents have just become the main raw of laundry detergent, are well suited for family expenses.Washing composition has good wettability, perviousness, emulsifying property, dispersiveness, lyotropy and the performance such as foaming and froth breaking, so Application Areas is very wide.The places such as such as hotel, hospital, hotel, school, carwash factory.
As automobile washing composition require and clothing, shoes etc. different again.Car wash product is more complex compared to laundry detergent composition, and manufacture craft will bother.Car wash product main component is: surfactant, water glass, phosphoric acid salt, alkaline matter, solvent and friction agent.Wherein, surfactant, also known as tensio-active agent or interfacial agent, is a kind of material that significantly can reduce surface tension of liquid, is indispensable composition in clean-out system.Surfactant in car shampoo mainly contains soft soap and synthesis clean-out system.The chemical name of water glass is water glass.Its Main Function in clean-out system to make the pH value of solution almost remain unchanged.Phosphoric acid salt has tertiary sodium phosphate, Sodium phosphate dibasic and condensed phosphoric acid sodium etc. multiple.Most important with condensed phosphate in cleaning agent formula.The pH value of 1% solution when room temperature of tertiary sodium phosphate is 12.Because its alkalescence is too strong, in clean-out system, amount can not be too many.In formula, it can increase the wetting ability of detergent solution, has certain emulsifying capacity, but its main effect is demineralized water.Be attached to the grease of metallic surface, animal and vegetable oil and the large class of mineral grease two can be divided into substantially.The former is fat, it can be occurred during heating with caustic soda together with saponification send out should, result generation soap and glycerine.These products are all water-soluble, the alkali soap now generated is polar molecule, polar end attract by water, non-polar end attract by oil, therefore solvent surface tension reduce, oil contact completely with solution, solution can penetrate into the inside of oil, grease expands and is wetted by the solution, thus it and intermetallic sticking power are reduced, and finally becomes small particle and disperses in the solution emulsification to occur.Solvent is the main body of surface cleaning agent, and it is together with additives such as tensio-active agents, jointly to dirt react with, reaches the object of cleaning and descaling.Solvent major oil water-based solvent and oil-based solvent two kinds, water-based solvent is water mainly, and oil-based solvent mainly contains gasoline, kerosene, turpentine wet goods.Friction agent increases the material contacting with clean surface, rub, as diatomite etc.The existing washing composition for cleaning automobile, seriously polluted to water source of foam that carwash produces, and washing composition usually to add a large amount of water dilutions after could use, use inconvenience.In washing composition, some composition pungency is strong, large to skin lesion, and soil removability is not all right.
Publication number is CN1339577, publication date is that the Chinese patent literature of 2002.03.13 discloses a kind of detergent for washing car, it is characterized in that: formula constituent is expected by A, B expects, P-hydroxybenzoic acid, essence and deionized water formed, preparation step is poly-is deionized water is heated to 85 degree Celsius, simultaneously, batching in A material and B being expected separately is respectively being heated to fuse respectively in the temperature of 80 degree Celsius, stir, then, first A material is added in deionized water, and uniform stirring is after 5 minutes, again B material is added, continue stirring 10 ~ 15 minutes, finally P-hydroxybenzoic acid and essence added and constantly stir, until Homogeneous phase mixing is cooled to room temperature.Although the detergent for washing car that this invention obtains will facilitate compared with the washing composition of prior art when using, or exist a lot of not enough.Such as, the Sodium dodecylbenzene sulfonate adopted in the middle of A material in the detergent for washing car that this invention obtains, its resistance to hard water is poor, detergency ability can reduce with water hardness, can manage it so remove general soils, but to staying the dirt that on car shell outside surface, permanent accumulation is formed, its soil removability just seems quite low.The pungency of Sodium dodecylbenzene sulfonate is also very large, after washing car, has very strong pungency, damage skin to skin.
Summary of the invention
The present invention is intended to solve the problem that the pungency of above-mentioned detergent for washing car to skin is large, soil removability is low, provides one to skin without any stimulation, and the automobile case washing composition that soil removability is strong.
In order to realize foregoing invention object, the technical solution used in the present invention is as follows:
A kind of automobile case washing composition, is characterized in that: the component comprising following parts by weight:
Trisodium Citrate 2-6 part
Rose compound 2-6 part
Alkyl ether phosphate 2-6 part
Butyl cellosolve 1-5 part
Fluorochemical surfactant 0.05-0.1 part
Sodium chromate 0.05-0.1 part
Potassium pyrophosphate 10-20 part
Sodium xylene sulfonate 10-15 part
Butanols 0.01-0.05 part
Stearate 1-5 part
Water 50-60 part.
Described fluorochemical surfactant is fluorine element tensio-active agent.
Described stearate is calcium stearate, Magnesium Stearate, potassium stearate or sodium stearate.
Trisodium Citrate of the present invention is look crystal or white crystalline powder, and taste is salty, and has refrigerant sense, soluble in water and glycerine, is insoluble in alcohols and other organic solvents, has deliquescence, have efflorescence properties in warm air, and more than 150 DEG C lose crystal water and decompose.
Fluorine element tensio-active agent of the present invention is a kind of non-ionic polymeric type fluorochemical surfactant, this tensio-active agent has very low surface tension, very little smell, very low viscosity, effectively can reduce the interfacial tension between aqueous phase/organic phase, and keep surfactivity in organic phase in polymeric system.
The physical property of described fluorine element tensio-active agent is as follows:
Outward appearance yellow viscous liquid
Proportion 1.170kg/l(9.75lbs./gal)
Flash-point (Setaflash closed-cup) 82 DEG C (180 ℉)
PH value (1% aqueous solution) 4.5
Boiling point 200 DEG C (392 ℉)
Vapour pressure 0.0014psi(0.07mmHg)
Solubleness in water can by any than dispersion
Type non-ionic type
Composition 100% fluoroaliphatic polymeric fat.
The Advantageous Effects that the present invention brings:
One, in the raw material that the present invention is used, fluorine element tensio-active agent is a kind of non-ionic polymeric type fluorochemical surfactant, this tensio-active agent has very low surface tension, very low viscosity, effectively can reduce the interfacial tension between aqueous phase/organic phase, and keep surfactivity in organic phase in polymeric system.Use that pungency is little, to skin fanout free region, and soil removability is strong.
Two, in the raw material that the present invention is used, potassium pyrophosphate solubleness is large, has stronger dissolving power, good to the spot dispersion effect of car case surface.
Three, in the raw material that the present invention is used, butanols is a kind of colourless liquid, has vinosity, and with ethanol, ether and other multiple immiscible organic solvents, solvability is fine, and can effectively dissolve for the greasy dirt being attached to car case surface, soil removability is strong.
Four, the Trisodium Citrate in the raw material that the present invention is used has biological degradability and fabulous solubility property, and solvability raises with water temperature and increases.
Five, easy to use, the environmentally-friendly sanitary of the detergent for vehicle enclosures that obtains of the present invention, be applicable to scale operation.
Embodiment
Embodiment 1
A kind of automobile case washing composition, comprises the component of following parts by weight:
Trisodium Citrate 2 parts
Rose compound 2 parts
Alkyl ether phosphate 2 parts
Butyl cellosolve 1 part
Fluorochemical surfactant 0.05 part
Sodium chromate 0.05 part
Potassium pyrophosphate 10 parts
Sodium xylene sulfonate 10 parts
0.01 part, butanols
Stearate 1 part
50 parts, water.
Described fluorochemical surfactant is fluorine element tensio-active agent.
Described stearate is calcium stearate.
Trisodium Citrate of the present invention is look crystal or white crystalline powder, and taste is salty, and has refrigerant sense, soluble in water and glycerine, is insoluble in alcohols and other organic solvents, has deliquescence, have efflorescence properties in warm air, and more than 150 DEG C lose crystal water and decompose.
Fluorine element tensio-active agent of the present invention is a kind of non-ionic polymeric type fluorochemical surfactant, this tensio-active agent has very low surface tension, very little smell, very low viscosity, effectively can reduce the interfacial tension between aqueous phase/organic phase, and keep surfactivity in organic phase in polymeric system.
The physical property of described fluorine element tensio-active agent is as follows:
Outward appearance yellow viscous liquid
Proportion 1.170kg/l(9.75lbs./gal)
Flash-point (Setaflash closed-cup) 82 DEG C (180 ℉)
PH value (1% aqueous solution) 4.5
Boiling point 200 DEG C (392 ℉)
Vapour pressure 0.0014psi(0.07mmHg)
Solubleness in water can by any than dispersion
Type non-ionic type
Composition 100% fluoroaliphatic polymeric fat.
Embodiment 2
A kind of automobile case washing composition, comprises the component of following parts by weight:
Trisodium Citrate 3 parts
Rose compound 3 parts
Alkyl ether phosphate 3 parts
Butyl cellosolve 2 parts
Fluorochemical surfactant 0.08 part
Sodium chromate 0.08 part
Potassium pyrophosphate 12 parts
Sodium xylene sulfonate 12 parts
0.02 part, butanols
Stearate 2 parts
52 parts, water.
Described fluorochemical surfactant is fluorine element tensio-active agent.
Described stearate is Magnesium Stearate.
Trisodium Citrate of the present invention is look crystal or white crystalline powder, and taste is salty, and has refrigerant sense, soluble in water and glycerine, is insoluble in alcohols and other organic solvents, has deliquescence, have efflorescence properties in warm air, and more than 150 DEG C lose crystal water and decompose.
Fluorine element tensio-active agent of the present invention is a kind of non-ionic polymeric type fluorochemical surfactant, this tensio-active agent has very low surface tension, very little smell, very low viscosity, effectively can reduce the interfacial tension between aqueous phase/organic phase, and keep surfactivity in organic phase in polymeric system.
The physical property of described fluorine element tensio-active agent is as follows:
Outward appearance yellow viscous liquid
Proportion 1.170kg/l(9.75lbs./gal)
Flash-point (Setaflash closed-cup) 82 DEG C (180 ℉)
PH value (1% aqueous solution) 4.5
Boiling point 200 DEG C (392 ℉)
Vapour pressure 0.0014psi(0.07mmHg)
Solubleness in water can by any than dispersion
Type non-ionic type
Composition 100% fluoroaliphatic polymeric fat.
Embodiment 3
A kind of automobile case washing composition, comprises the component of following parts by weight:
Trisodium Citrate 4 parts
Rose compound 4 parts
Alkyl ether phosphate 4 parts
Butyl cellosolve 3 parts
Fluorochemical surfactant 0.06 part
Sodium chromate 0.06 part
Potassium pyrophosphate 17 parts
Sodium xylene sulfonate 13 parts
0.03 part, butanols
Stearate 3 parts
55 parts, water.
Described fluorochemical surfactant is fluorine element tensio-active agent.
Described stearate is potassium stearate.
Trisodium Citrate of the present invention is look crystal or white crystalline powder, and taste is salty, and has refrigerant sense, soluble in water and glycerine, is insoluble in alcohols and other organic solvents, has deliquescence, have efflorescence properties in warm air, and more than 150 DEG C lose crystal water and decompose.
Fluorine element tensio-active agent of the present invention is a kind of non-ionic polymeric type fluorochemical surfactant, this tensio-active agent has very low surface tension, very little smell, very low viscosity, effectively can reduce the interfacial tension between aqueous phase/organic phase, and keep surfactivity in organic phase in polymeric system.
The physical property of described fluorine element tensio-active agent is as follows:
Outward appearance yellow viscous liquid
Proportion 1.170kg/l(9.75lbs./gal)
Flash-point (Setaflash closed-cup) 82 DEG C (180 ℉)
PH value (1% aqueous solution) 4.5
Boiling point 200 DEG C (392 ℉)
Vapour pressure 0.0014psi(0.07mmHg)
Solubleness in water can by any than dispersion
Type non-ionic type
Composition 100% fluoroaliphatic polymeric fat.
Embodiment 4
A kind of automobile case washing composition, comprises the component of following parts by weight:
Trisodium Citrate 5 parts
Rose compound 5 parts
Alkyl ether phosphate 4 parts
Butyl cellosolve 4 parts
Fluorochemical surfactant 0.09 part
Sodium chromate 0.09 part
Potassium pyrophosphate 18 parts
Sodium xylene sulfonate 14 parts
0.04 part, butanols
Stearate 4 parts
58 parts, water.
Described fluorochemical surfactant is fluorine element tensio-active agent.
Described stearate is sodium stearate.
Trisodium Citrate of the present invention is look crystal or white crystalline powder, and taste is salty, and has refrigerant sense, soluble in water and glycerine, is insoluble in alcohols and other organic solvents, has deliquescence, have efflorescence properties in warm air, and more than 150 DEG C lose crystal water and decompose.
Fluorine element tensio-active agent of the present invention is a kind of non-ionic polymeric type fluorochemical surfactant, this tensio-active agent has very low surface tension, very little smell, very low viscosity, effectively can reduce the interfacial tension between aqueous phase/organic phase, and keep surfactivity in organic phase in polymeric system.
The physical property of described fluorine element tensio-active agent is as follows:
Outward appearance yellow viscous liquid
Proportion 1.170kg/l(9.75lbs./gal)
Flash-point (Setaflash closed-cup) 82 DEG C (180 ℉)
PH value (1% aqueous solution) 4.5
Boiling point 200 DEG C (392 ℉)
Vapour pressure 0.0014psi(0.07mmHg)
Solubleness in water can by any than dispersion
Type non-ionic type
Composition 100% fluoroaliphatic polymeric fat.
Embodiment 5
A kind of automobile case washing composition, comprises the component of following parts by weight:
Trisodium Citrate 6 parts
Rose compound 6 parts
Alkyl ether phosphate 6 parts
Butyl cellosolve 5 parts
Fluorochemical surfactant 0.1 part
Sodium chromate 0.1 part
Potassium pyrophosphate 20 parts
Sodium xylene sulfonate 15 parts
0.05 part, butanols
Stearate 5 parts
60 parts, water.
Described fluorochemical surfactant is fluorine element tensio-active agent.
Described stearate is sodium stearate.
Trisodium Citrate of the present invention is look crystal or white crystalline powder, and taste is salty, and has refrigerant sense, soluble in water and glycerine, is insoluble in alcohols and other organic solvents, has deliquescence, have efflorescence properties in warm air, and more than 150 DEG C lose crystal water and decompose.
Fluorine element tensio-active agent of the present invention is a kind of non-ionic polymeric type fluorochemical surfactant, this tensio-active agent has very low surface tension, very little smell, very low viscosity, effectively can reduce the interfacial tension between aqueous phase/organic phase, and keep surfactivity in organic phase in polymeric system.
The physical property of described fluorine element tensio-active agent is as follows:
Outward appearance yellow viscous liquid
Proportion 1.170kg/l(9.75lbs./gal)
Flash-point (Setaflash closed-cup) 82 DEG C (180 ℉)
PH value (1% aqueous solution) 4.5
Boiling point 200 DEG C (392 ℉)
Vapour pressure 0.0014psi(0.07mmHg)
Solubleness in water can by any than dispersion
Type non-ionic type
Composition 100% fluoroaliphatic polymeric fat.

Claims (5)

1. an automobile case washing composition, is characterized in that: the component comprising following parts by weight:
Trisodium Citrate 2-6 part
Rose compound 2-6 part
Alkyl ether phosphate 2-6 part
Butyl cellosolve 1-5 part
Fluorochemical surfactant 0.05-0.1 part
Sodium chromate 0.05-0.1 part
Potassium pyrophosphate 10-20 part
Sodium xylene sulfonate 10-15 part
Butanols 0.01-0.05 part
Stearate 1-5 part
Water 50-60 part.
2. a kind of automobile case washing composition according to claim 1, is characterized in that: described fluorochemical surfactant is fluorine element tensio-active agent.
3. a kind of automobile case washing composition according to claim 1, is characterized in that: described stearate is calcium stearate.
4. a kind of automobile case washing composition according to claim 1, is characterized in that: described stearate is Magnesium Stearate.
5. a kind of automobile case washing composition according to claim 1, is characterized in that: described stearate is potassium stearate.
CN201510711947.8A 2015-10-28 2015-10-28 Car shell washing agent Pending CN105176703A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510711947.8A CN105176703A (en) 2015-10-28 2015-10-28 Car shell washing agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510711947.8A CN105176703A (en) 2015-10-28 2015-10-28 Car shell washing agent

Publications (1)

Publication Number Publication Date
CN105176703A true CN105176703A (en) 2015-12-23

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Family Applications (1)

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CN201510711947.8A Pending CN105176703A (en) 2015-10-28 2015-10-28 Car shell washing agent

Country Status (1)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018112939A1 (en) * 2016-12-23 2018-06-28 王华勤 Antifreeze glass cleaning agent
WO2018112938A1 (en) * 2016-12-23 2018-06-28 王华勤 Multiple-fiber composite cleaning agent

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1970711A (en) * 2006-12-18 2007-05-30 河南理工大学 Automobile case cleaning agent
CN102465061A (en) * 2010-11-10 2012-05-23 罗朝雯 Vehicle shell detergent
CN104371848A (en) * 2014-11-19 2015-02-25 柳州市二和汽车零部件有限公司 Cleaning agent for housing of automobile
CN104745322A (en) * 2013-12-30 2015-07-01 华中科技大学 Phosphorus-free automobile cleaning solution and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1970711A (en) * 2006-12-18 2007-05-30 河南理工大学 Automobile case cleaning agent
CN102465061A (en) * 2010-11-10 2012-05-23 罗朝雯 Vehicle shell detergent
CN104745322A (en) * 2013-12-30 2015-07-01 华中科技大学 Phosphorus-free automobile cleaning solution and preparation method thereof
CN104371848A (en) * 2014-11-19 2015-02-25 柳州市二和汽车零部件有限公司 Cleaning agent for housing of automobile

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018112939A1 (en) * 2016-12-23 2018-06-28 王华勤 Antifreeze glass cleaning agent
WO2018112938A1 (en) * 2016-12-23 2018-06-28 王华勤 Multiple-fiber composite cleaning agent

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Application publication date: 20151223