CN104592809A - High-adhesive force printing ink - Google Patents
High-adhesive force printing ink Download PDFInfo
- Publication number
- CN104592809A CN104592809A CN201510057801.6A CN201510057801A CN104592809A CN 104592809 A CN104592809 A CN 104592809A CN 201510057801 A CN201510057801 A CN 201510057801A CN 104592809 A CN104592809 A CN 104592809A
- Authority
- CN
- China
- Prior art keywords
- parts
- ink
- printing ink
- adhesive force
- polyimide resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to the technical field of printing ink and in particular relates to high-adhesive force printing ink. The high-adhesive force printing ink is prepared from the following raw materials in parts by weight: 15-40 parts of a superfine polyimide resin, 2-6 parts of nano silicon dioxide, 3-7 parts of tert-butylhydroquinone, 4-9 parts of methyl cellulose, 12-19 parts of titanium dioxide, 15-25 parts of ethanol and 10-20 parts of pentaerythritol. The printing ink disclosed by the invention has high adhesive force, does not contain any toxic substance, is environment-friendly to a human body and harmless to the environment, has high wear resistance and fire resistance and can emit ultraviolet rays so as to prevent fading.
Description
Technical field
The present invention relates to technical field of ink, particularly a kind of High-adhesion ink.
Background technology
Ink is the important materials for wrapping material printing, and pattern, the present stock curing ink of literal table are comprised main component and ancillary component by printing by it, and they mix equably and form the gluey fluid of a kind of viscosity through repeat-rolling.Printing-ink is by the pulpous state colloid of colorant, low-melting ink vehicle and the homogenize material such as auxiliary agent and solvent dispersing and mixing.The binder of solvent type ink is made up of solid resin and a large amount of volatile organic solvent.Solid resin is dissolved in after in solvent, is dispersed in by colorant in binder, and ink is printed to printed medium, the rapid volatile dry conjunctiva of solvent.For ink, general expectation uses the aesthetic effect and the permanent printing characteristic kept that can produce on printed medium and show pleasant simultaneously.The example of these printing characteristics comprises press quality, as optical density (OD), colourity etc.; And weather resistance, as water tolerance, fade resistance, persistence, the marker pen of resistance to bronsted lowry acids and bases bronsted lowry smear.
But in prior art, for the ink printed, sticking power is not strong, and pigment easily comes off, the limited material be suitable for.Simultaneously, in order to ensure press quality, a large amount of benzene classes is used when it is prepared, the solvent that the toxicity such as ketone are stronger, such as have the hydrocarbon system solvents such as solvent, dimethylbenzene, the aromatic series series solvents such as ethylbenzene, the ester series solvent type ink such as butylacetate, in Printing ink producing process when solvent treatment not at that time, easily the health of direct labor is damaged, when ink is for printing, the volatilization of ink toxic solvent also can produce certain injury to the health of pressman, and toward the remaining nuisance of contact in dried ink, be difficult to the requirement obtaining environmental protection, also the healthy of printed matter user and contaminate environment in various degree can certainly will be had influence on.
Therefore, under the prerequisite ensureing ink quality, develop and can either prevent public hazards and ensure environmental health, the novel dissolvent type ink that can show again quite high press quality and weather resistance becomes the R&D direction of those skilled in the art.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of High-adhesion ink, and this ink has high adhesive force and persistence, and environmental protection, to human body and environmentally friendly.
For achieving the above object, the present invention adopts following technical scheme:
A kind of High-adhesion ink, be made up of the raw material of following weight part:
Ultra-fine polyimide resin has excellent thermotolerance, wear resistance, melt fluidity are good, there is wetting and adhesive property preferably to other raw material, during solidification, do not produce low molecular weight volatile thing, good with various filler consistency, cohesive strength is high, has good snappiness.
Nano silicon, owing to being nano level, can improve ink adhesion as raw material, as the filler of ink, can also improve wear resistance and the fire performance of ink.
Tertiarybutylhydroquinone has antioxygenation, improves ink stability, and high temperature resistant.
Methylcellulose gum has excellent wettability, dispersiveness, cementability, thickening property, emulsifying property, water-retentivity and film-forming properties, and institute's film forming has excellent toughness, flexibility and transparency.
Preferably, titanium dioxide of the present invention is rutile-type.Rutile type Titanium Dioxide specific refractory power is high, and opacifying power is high, stable, good weatherability.The refractive index of titanium dioxide is 2.7, has stronger reflection potential to ultraviolet, therefore makes the resistance to ultraviolet radiation of ink greatly to strengthen, and is conducive to the persistence improving ink.
Ethanol and tetramethylolmethane are as solvent, substantially nontoxic.
Preferably, High-adhesion ink of the present invention, be made up of the raw material of following weight part:
Beneficial effect of the present invention is:
1, in ink of the present invention not only not containing the toxic chemical substance such as benzene, toluene, environmental protection is to human body and environmentally friendly, and the ink prepared also has high adhesive force, weather resistance, and it is essential also to show goodish printing.
2, in ink of the present invention, the ultra-fine polyimide resin of interpolation and nano silicon also improve wear resistance and the resistivity against fire of ink further.
3, adopt methylcellulose gum dispersion agent of the present invention and ethanol, tetramethylolmethane solvent, the surface tension between raw material can be reduced, improve wettability, make ink have good brightness effect, and make ink have good fluidity.
4, the present invention adds titanium dioxide not only as pigment, simultaneously can uv reflectance, prevents yellowing, variable color and fades.
5, through SGS starting material safety detection, the present invention is nontoxic, not containing heavy metal; Adopt 3 kilograms of pressure by 3M tape sticker at the frosting being printed on ink logo of the present invention, pull stripping by the speed of 30m/s, pattern is without dropping situations.
Embodiment
Below in conjunction with embodiment, the invention will be further described, but the present invention is not limited to these embodiments.
Embodiment 1
A kind of High-adhesion ink, be made up of the raw material of following weight part:
Ethanol and tetramethylolmethane mixing are warming up to 75 DEG C, add methylcellulose gum, ultra-fine polyimide resin and ultra-fine polyimide resin successively and stir, then add nano silicon and titanium dioxide successively, stir, be down to normal temperature, finally continue mechanical stirring 30min, obtain finished product.
Embodiment 2
A kind of High-adhesion ink, be made up of the raw material of following weight part:
Ethanol and tetramethylolmethane mixing are warming up to 80 DEG C, add methylcellulose gum, ultra-fine polyimide resin and ultra-fine polyimide resin successively and stir, then add nano silicon and titanium dioxide successively, stir, be down to normal temperature, finally continue mechanical stirring 40min, obtain finished product.
Embodiment 3
A kind of High-adhesion ink, be made up of the raw material of following weight part:
Ethanol and tetramethylolmethane mixing are warming up to 85 DEG C, add methylcellulose gum, ultra-fine polyimide resin and ultra-fine polyimide resin successively and stir, then add nano silicon and titanium dioxide successively, stir, be down to normal temperature, finally continue mechanical stirring 45min, obtain finished product.
Embodiment 4
A kind of High-adhesion ink, be made up of the raw material of following weight part:
Ethanol and tetramethylolmethane mixing are warming up to 90 DEG C, add methylcellulose gum, ultra-fine polyimide resin and ultra-fine polyimide resin successively and stir, then add nano silicon and titanium dioxide successively, stir, be down to normal temperature, finally continue mechanical stirring 55min, obtain finished product.
Embodiment 5
A kind of High-adhesion ink, be made up of the raw material of following weight part:
Ethanol and tetramethylolmethane mixing are warming up to 85 DEG C, add methylcellulose gum, ultra-fine polyimide resin and ultra-fine polyimide resin successively and stir, then add nano silicon and titanium dioxide successively, stir, be down to normal temperature, finally continue mechanical stirring 60min, obtain finished product.
Claims (3)
1. a High-adhesion ink, is characterized in that, is made up of the raw material of following weight part:
2. High-adhesion ink according to claim 1, is characterized in that, is made up of the raw material of following weight part:
3. High-adhesion ink according to claim 1 and 2, is characterized in that: described titanium dioxide is rutile-type.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510057801.6A CN104592809A (en) | 2015-02-04 | 2015-02-04 | High-adhesive force printing ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510057801.6A CN104592809A (en) | 2015-02-04 | 2015-02-04 | High-adhesive force printing ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104592809A true CN104592809A (en) | 2015-05-06 |
Family
ID=53118886
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510057801.6A Pending CN104592809A (en) | 2015-02-04 | 2015-02-04 | High-adhesive force printing ink |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104592809A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105368134A (en) * | 2015-12-28 | 2016-03-02 | 李栋军 | Letterpress printing ink |
| CN105385231A (en) * | 2015-12-28 | 2016-03-09 | 王璐 | Improved letterpress printing ink |
| CN105419468A (en) * | 2015-12-28 | 2016-03-23 | 王丽萍 | Green and environment-friendly letterpress printing ink |
| CN108003702A (en) * | 2017-12-26 | 2018-05-08 | 湖州品创孵化器有限公司 | A kind of ink adhesive and preparation method thereof |
| CN109337437A (en) * | 2018-10-12 | 2019-02-15 | 楼乐超 | A kind of preparation process of solubility environment-friendly ink |
| CN111441190A (en) * | 2020-04-06 | 2020-07-24 | 浙江一鸣包装印刷有限公司 | Waterproof flame-retardant corrugated carton and production process thereof |
| CN113246626A (en) * | 2021-06-16 | 2021-08-13 | 上海景条印刷有限公司 | Gravure printing process for paper packaging box |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3522270A (en) * | 1966-08-26 | 1970-07-28 | Gen Mills Inc | Polyamide-polyimide resin |
| CN1687259A (en) * | 2005-04-12 | 2005-10-26 | 王崇高 | Dedicated printing ink for electroplating products and preparation method thereof |
| CN101457051A (en) * | 2007-12-14 | 2009-06-17 | 比亚迪股份有限公司 | Printing ink and preparation method thereof |
-
2015
- 2015-02-04 CN CN201510057801.6A patent/CN104592809A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3522270A (en) * | 1966-08-26 | 1970-07-28 | Gen Mills Inc | Polyamide-polyimide resin |
| CN1687259A (en) * | 2005-04-12 | 2005-10-26 | 王崇高 | Dedicated printing ink for electroplating products and preparation method thereof |
| CN101457051A (en) * | 2007-12-14 | 2009-06-17 | 比亚迪股份有限公司 | Printing ink and preparation method thereof |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105368134A (en) * | 2015-12-28 | 2016-03-02 | 李栋军 | Letterpress printing ink |
| CN105385231A (en) * | 2015-12-28 | 2016-03-09 | 王璐 | Improved letterpress printing ink |
| CN105419468A (en) * | 2015-12-28 | 2016-03-23 | 王丽萍 | Green and environment-friendly letterpress printing ink |
| CN108003702A (en) * | 2017-12-26 | 2018-05-08 | 湖州品创孵化器有限公司 | A kind of ink adhesive and preparation method thereof |
| CN109337437A (en) * | 2018-10-12 | 2019-02-15 | 楼乐超 | A kind of preparation process of solubility environment-friendly ink |
| CN111441190A (en) * | 2020-04-06 | 2020-07-24 | 浙江一鸣包装印刷有限公司 | Waterproof flame-retardant corrugated carton and production process thereof |
| CN113246626A (en) * | 2021-06-16 | 2021-08-13 | 上海景条印刷有限公司 | Gravure printing process for paper packaging box |
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| PB01 | Publication | ||
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| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150506 |
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| WD01 | Invention patent application deemed withdrawn after publication |