CN104364364A

CN104364364A - Detergent composition

Info

Publication number: CN104364364A
Application number: CN201380030796.9A
Authority: CN
Inventors: S·G·帕特森; P·F·苏特
Original assignee: Procter and Gamble Ltd
Current assignee: Procter and Gamble Ltd; Procter and Gamble Co
Priority date: 2012-06-11
Filing date: 2013-06-11
Publication date: 2015-02-18
Also published as: EP2674476B1; ES2674940T5; CN111205939A; BR112014030417B1; DK2674476T3; RU2014149582A; ES2674940T3; RU2612142C2; PL2674476T3; IN2014DN10427A; EP2674475A1; BR112014030417A2; BR112014030417A8; TR201809430T4; DK2674476T4; EP2674476B2; MX370587B; PL2674476T5; EP2674476A1; WO2013188331A1

Abstract

Detergent compositions are described having more than one enzyme, in particular having a multi-enzyme co-particle as well as methods of making and using such detergents. The compositions also have low levels of zeolite and phosphate builders and a moisture sink to minimize interaction between enzymes.

Description

Detergent composition

Technical field

The present invention relates to the method for detergent composition and preparation and this type of washing composition of use comprised more than a kind of enzyme.

Background technology

To natural resource, especially the pressure of energy and water increases day by day, and to using the demand of petroleum chemicals to continue to increase.The detergent composition comprising enzyme is known for many years, and especially in few water and/or cold washing, the good opportunity of sending significantly clean, nursing and pure and fresh beneficial effect is provided by washing composition, reduces the needs so depending critically upon petroleum chemistry sill simultaneously.This type of compound method is really with sizable challenge, and described challenge relates to how with cheap way, hides stable product send consistent remarkable cleaning effect by needing several months frame.The area that this problem is warmer is in the world especially serious.

In the open IPCOM000200739D of IP.com, being openly mixed in two or more enzymes intragranular altogether by mixing, being uniformly distributed of enzyme granulate can be improved.Often kind of enzyme will be present in more particles subsequently, to guarantee in washing composition evenly enzyme distribution.Which also reduces the physical isolation of the different enzymes caused due to different particle sizes.But for the detergent composition stored under high temperature and/or super-humid conditions, the interaction that enzyme is total in particle between enzyme can cause enzymic activity to lose, especially when the one in enzyme is proteolytic enzyme.In the detergent composition comprising the strong washing assistant of a small amount of typical case and zeolite and phosphate builders, this problem is especially serious.

Summary of the invention

The present invention relates to detergent composition, described composition comprises (a) multienzyme particle altogether; B zeolite (moisture-free basis) that () is less than 10 % by weight; (c) be less than the phosphoric acid salt (moisture-free basis) of 10 % by weight, wherein said enzyme altogether particle comprises the moisture absorbing component of 10 to 98 % by weight, and described composition also comprises the washing composition moisture absorbing component of 20 to 80 % by weight.

The invention still further relates to the method on process and/or clean surface (preferred fabric surface); said method comprising the steps of: (i) makes described surface contact with the detergent composition described with protecting by claims in aqueous cleaning liquid, (ii) rinsing and/or dry described surface.Preferably, described liquid, aqueous temperature is 5-25 DEG C, and the described liquid, aqueous tensio-active agent preferably comprising 0.1g/L to 3g/L.

Embodiment

definition

As used herein, " detergent composition " refers to consuming product and mechanism's articles for use, includes but not limited to clean and/or treatment compositions (cleaning compositions in particular for clothes washing), dish washing and hard surface cleaning product, other sanitising agent and all for inanimate surfaces nursing and clean cleaning system and fabric conditioner product and the other products that is intended to specially for fabric nursing and maintenance.This type of detergent composition is generally intended to use or consumption with its form of selling.This series products comprises clothes washing and rinsing additive and/or nursing agent, hard surface cleaning and/or treatment agent (comprising floor and detergent for water closet).The present composition is preferably laundry detergent or dishwashing detergent, most preferably laundry detergent.The present composition is generally solid, i.e. particle or powder type, and it optionally can be incorporated into unit dose detergent composition as in tablet or pouch, and described pouch can be single compartment or many compartments.But they can be liquid, gel or paste form.In pouch, the present composition will be present in water-solubility membrane.Under described pouch is many compartments situation, the present composition will be present in one or more compartment.Other composition of not according to the invention can be provided in other compartments one or more in many compartment pouchs.Applicable this series products all can be standard substance, form that is concentrated or even high enrichment, and even arriving this series products can be nonaqueous degree in certain.

As used herein, time in for claim, article such as " one " and " one " are understood to mean one or more claimed or described materials.As used herein, term " comprises ", " comprising " and " containing " be intended to for nonrestrictive.As used herein, term " solid " comprises particle, powder, bar-shaped and tablet form.Except as otherwise noted, otherwise all components or composition levels are all the active substance part about this component or composition, do not comprise the impurity in the commercial source that may be present in these components or composition, such as residual solvent or by product.Except as otherwise noted, otherwise all per-cent and ratio all calculate by weight.Except as otherwise noted, otherwise all per-cent and ratio all calculate based on total composition.

multienzyme is particle altogether

Multienzyme altogether particle comprises at least two kinds of enzymes, or at least three kinds or four kinds or more plant enzyme, be preferably selected from the first washing lipase, clean fiber element enzyme, xyloglucanase enzymes, Perhydrolase, peroxidase, lipoxygenase, laccase, hemicellulase, proteolytic enzyme, nursing cellulase, cellobiose dehydrogenase, zytase, Phospholipid hydrolase, esterase, at, polygalacturonase, mannase, pectate lyase, M-Zyme, reductase enzyme, oxydase, phenol oxidase, ligninase, Starch debranching enzyme, tannase, pentosanase, lichenase, dextranase, arabinofuranosidase/xylosidase, Unidasa, chondroitinase, amylase, and their mixture.Described particle altogether preferably comprises (a) one or more enzymes, and described enzyme is selected from the first washing lipase, clean fiber element enzyme, xyloglucanase enzymes, Perhydrolase, peroxidase, lipoxygenase, laccase and their mixture.In group (a), preferred enzyme is the first washing lipase.In addition; described particle altogether also preferably comprises (b) one or more enzymes, and described enzyme is selected from hemicellulase, proteolytic enzyme, nursing cellulase, cellobiose dehydrogenase, zytase, Phospholipid hydrolase, esterase, at, polygalacturonase, mannonase pectate lyase, M-Zyme, reductase enzyme, oxydase, phenol oxidase, ligninase, Starch debranching enzyme, tannase, pentosanase, lichenase, dextranase, arabinofuranosidase/xylosidase, Unidasa, chondroitinase, amylase and their mixture.Described particle altogether preferably comprises proteolytic enzyme.

Described particle altogether can comprise such as at least two kinds of enzymes, comprises such as: (i) proteolytic enzyme and amylase; (ii) proteolytic enzyme and cellulase; (iii) proteolytic enzyme and the first washing lipase; (iv) cellulase and the first washing lipase; (v) amylase and cellulase; Or (vi) amylase and first washs lipase.Alternatively, described particle altogether can comprise at least three kinds of enzymes, comprises such as (i) proteolytic enzyme, the first washing lipase and cellulase; (ii) proteolytic enzyme, amylase and cellulase; (iii) proteolytic enzyme, amylase and the first washing lipase; (iv) the first washing lipase, amylase and cellulase.Alternatively, described particle altogether can comprise at least four kinds of enzymes, comprises such as (i) proteolytic enzyme, amylase, the first washing lipase and cellulase; (ii) proteolytic enzyme, amylase, the first washing lipase and mannase.

The amount being incorporated into the gross activity zymoprotein in common particle sends the organized enzyme of 0.2 to 1.0 % by weight usually in detergent compositions.

moisture absorbing component

Moisture absorbing component is present in described particle altogether with the amount of 10 to 99 % by weight of common particle.Moisture absorbing materials described herein is preferably interpreted as the material of its anhydrous form, and described material absorbable water becomes hydrate, and when it being positioned in dryer or higher temperatures environment, can be easy to disengage water of hydration.Between anhydrous form and hydrated form, preferably there is at least 0.8g/cm3 for the moisture absorbing materials in the present composition, more preferably at least 1g/cm3, also the density difference of especially at least 1.2g/cm3.Described density difference provides destruction particle: the brilliant bridge mechanism of particle, described brilliant bridge water condensation and being formed when being reduced to the dew point be associated with this powder under powder temperature.When cooling temperature rising after for some time (in temperature cycle), the hydrated material forming brilliant bridge between particle reverts to anhydrous (or low hydration) form.The higher crystalline density be associated with anhydrous (or low hydration) form provides the mechanism destroying these brilliant bridges because crystal volume reduces.This makes one low temperature period adversely and long-term effect pulverized structure, and contributes to good compositions-treated characteristic.

Preferably, based on described particle meter altogether, described moisture absorbing component is with 30,50 or even 60 % by weight of described particle altogether, and the amount of 90 or 95 % by weight exists extremely at the most.The example of suitable moisture absorbing component can absorb moisture.Suitable moisture absorbing component is preferably selected from (a) can the salt of hydration, (b) dry clay, (c) biologic packing material, and (d) their mixture.Can be used as can hydration salt be generally sodium salt, calcium salt, magnesium salts, preferred sodium carbonate salt, sodium chloride salt, sodium citrate salt and sodium sulfate salt and their mixture.Anhydrous sodium carbonate can be preferably.Light sodium carbonate can be preferably.

The example of suitable clay is talcum, calcite, kaolin, rhombspar and wilkinite.Preferred dry clay has 0.1 to 20 % by weight free-water, and more preferably 0.1 to 15, or even 0.1 to 10, or the water content of even 5 % by weight free-waters;

Be suitable for do biologic packing material for any water-soluble or water-insoluble agriculture byproduct.The example of water-insoluble agriculture byproduct is described in WO2007/147698.Preferred biologic packing material has 0.1 to 20 % by weight free-water, and more preferably 0.1 to 15, or even 0.1 to 10 % by weight, or the water content of even 5 % by weight free-waters;

The granularity of preferred described moisture absorbing component, makes the moisture absorbing component particle of at least 90 % by weight have and is less than 700, or be even less than 500 or 300 or 250 microns, or be even less than the diameter of 100 microns.

In described particle altogether, the weight ratio of moisture absorbing component and active enzyme protein is preferably 10:1 or 20:1 or 50:1 or 10:1, extremely at the most 100:1 or 90:1 or 75:1.

enzyme is particle altogether

Be applicable to enzyme herein altogether particle comprise according in following technology any one formed those:

A) spray-dired product, the solution wherein comprising liquid enzymes is atomized to form small droplets in the spray drying tower, and described small droplets along dry between drying tower decrement phase, forms the particulate matter comprising enzyme at them.So can prepare minimum particle (Michael S.Showell (editor); " Powdered detergents; Surfactant Science Series "; 1998; 71st volume; 140-142 page; Marcel Dekker).

B) sandwich-like product, wherein described enzyme is applied as the layer around premolding inert core particle, wherein usually make wherein will comprise the solution atomization of enzyme in the fluidized bed plant of premolding slug particle fluidisation, and the solution comprising enzyme is attached on described slug particle and dry, until leave dry enzyme layer on the surface at described slug particle.If the available slug particle with desired size can be found, then can so obtain the particle with desired size.Such product description is in such as WO 97/23606.

C) absorbent core particle, wherein said enzyme is absorbed on and/or within the surface of described core, instead of coating enzyme is using as the layer around core.These class methods are described in WO 97/39116.

D) to extrude or pelletized products, wherein the paste comprising enzyme is pressed into pellet, or is extruded by microstome under stress and be cut into particle, be then dried.This type of particle sets restriction to the allowable pressure drop of extruding on aperture, so usually have sizable size owing to manufacturing the material (normally having the plate of boring) extruding aperture.And when a use microstome, very high extrusion pressure adds the heat produced in enzyme paste, and this is harmful for enzyme.(Michael S.Showell (editor); " Powdereddetergents; Surfactant Science Series "; 1998; 71st volume; 140-142 page; Marcel Dekker)

E) granulated product or, wherein enzyme powder suspension is in molten wax, and by such as rotating disk atomizer by suspension spray in cooling room, drop quick solidification (Michael S.Showell (editor) wherein; " Powdered detergents; Surfactant ScienceSeries "; 1998; 71st volume; 140-142 page; Marcel Dekker).Products obtained therefrom is that wherein enzyme is evenly distributed in whole inert material instead of concentrates product in its surface.US 4,016,040 and US 4,713,245 also relates to the document of this technique.

F) mixing tank granulation product, wherein adds to the liquid comprising enzyme in the dry powder composite of conventional granulation components.Mix described liquid and powder with suitable ratio, and be inhaled in dry powder due to the moisture of liquid, the component of dry powder will start attachment and cohesion, and will build particle, and formation comprises the particle of enzyme.These class methods are described in US 4, in 106,991 (NOVO NORDISK) and pertinent literature EP 170360 B1, EP 304332 B1, EP 304331, WO 90/09440 and WO 90/09428.Various high-shear mixer can be used as in a specific product of the method for nodulizer wherein, and the particle be made up of enzyme, filler and tackiness agent etc. mixes to make particle strengthening with cellulosic fibre, obtains so-called T-particle.The particle of strengthening is more sane, discharges little enzyme dirt.

The enzyme be preferred in the present composition is total to particle and has core/shell structure.In preferred core/shell embodiment, described core comprises preferably not containing the core of enzyme, and comprises the perisphere of enzyme, and described shell comprises multiple layer, and outermost layer is protective layer.In a preferred embodiment, at least one layer in the core of described core and described shell comprises water-absorbing material.The core of described core preferably accounts for 1% to 60% by the weighing scale of described total particle, and more preferably 3% to 50%, also especially 5% to 40%.The layer comprising water-absorbing material preferably accounts for 0.5% to 40% by the weighing scale of described total particle, and more preferably 1% to 30%, also especially 3% to 20%.Described outermost layer preferably comprises polyvinyl alcohol, more preferably comprises titanium oxide (aesthetic reasons), also especially comprises their combination.Described protective layer preferably accounts for 0.05% to 20% by the weighing scale of described total particle, and more preferably 0.1% to 15%, also especially 1% to 3%.Described enzyme granulate also can comprise promoter material such as antioxidant, dyestuff, activator, solubilizing agent, tackiness agent etc.Enzyme according to this embodiment can be obtained by fluidized-bed layering process, described method and US5, and 324,649, similar described in US 6,602,841 B1 and US2008/0206830A1.

Enzyme according to this embodiment also can be obtained by the combination of method.This fermentoid altogether particle builds around the core that can be free of enzyme or comprise enzyme (preferably comprising water-absorbing material, more preferably sodium sulfate), can adopt multiple method, comprise and use mixing tank nodulizer or forcing machine.Then in fluidized-bed process, process described core, wherein enzyme is sprayed on described core.Then described core coating is preferably comprised water-absorbing material, also more preferably comprise the layer of sodium sulfate, last coated polymer, described polymkeric substance is selected from Vltra tears and/or polyvinyl alcohol and derivative thereof, optionally also comprises other titanium dioxide, polyoxyethylene glycol and/or kaolin or their any mixture.Be suitable for preparing enzyme granulate and be described in US 6,348 for method herein, 442 B2, US 2004/0033927 A1, USP 7,273,736, WO00/01793, US 6,268, in 329 B1 and US2008/0206830A1.Described particle preferably comprises weighing scale about 30% by described particle to about 75%, and the preferably water-absorbing material of about 40 to about 50%, described water-absorbing material is selected from sodium sulfate, Trisodium Citrate and their mixture, preferably sulfuric acid sodium.

Described enzyme altogether particle preferably has about 200 μm to about 1200 μm, more preferably from about 300 μm to about 1000 μm, the also geometry average particle size of especially about 400 μm to about 600 μm.

Except described altogether particle, the present composition comprises the zeolite (moisture-free basis) being less than 10 % by weight, is more preferably less than 7 or 5, or even lower than 3 % by weight zeolite.Zeolite can not be present in detergent composition of the present invention even completely.

Except described altogether particle, the present composition also comprises the phosphoric acid salt (moisture-free basis) being less than 10 % by weight, is more preferably less than 7 or 5, or even lower than 3 % by weight phosphoric acid salt.Phosphoric acid salt can not be present in detergent composition of the present invention even completely.

In addition, composition of the present invention also comprises the washing composition water-retaining agent of 20 to 80 % by weight, preferably the washing composition water-retaining agent of 25 or 30 or 35 or 40 % by weight to 75 % by weight.Suitable washing composition moisture absorbing component can absorb moisture, and be selected from (a) can the vitriol of hydration, (b) dry clay, (c) biologic packing material, and (d) their mixture.Available salt is generally can the sodium sulfate salt of hydration, calcium sulfate salt, magnesium sulfate salt and their mixture.Sodium sulfate is especially preferred, most preferably its anhydrous form.Lightweight salt may also be preferred.

The example of Suitable clays is talcum, calcite, kaolin, rhombspar and wilkinite.Preferred dry clay has 0.1 to 20 % by weight free-water, and more preferably 0.1 to 15, or even 0.1 to 10, or the water content of even 5 % by weight free-waters.

Be suitable for do biologic packing material for any water-soluble or water-insoluble agriculture byproduct.The example of water-insoluble agriculture byproduct is described in WO2007/147698.Preferred biologic packing material has 0.1 to 20 % by weight free-water, and more preferably 0.1 to 15, or even 0.1 to 10 % by weight, or the water content of even 5 % by weight free-waters.

Sodium sulfate is most preferred washing composition moisture absorbing component.

Washing composition moisture absorbing component can dryly add in other detergent builder composition, or via preformed granular as condensation product or blowing powder (particle formed by spray drying process) are incorporated in detergent composition, or can mix via the mixing of these approach.In preferred composition, described washing composition moisture absorbing component is incorporated in detergent composition as dry interpolation grain fraction, described dry interpolation grain fraction comprises at least 80 % by weight, or even at least 90 % by weight, or even at least 95 % by weight washing composition water-retaining agent, in addition be incorporated in detergent composition via blowing powder, described blowing powder packets contains based on described blowing powder meter 15 to 70 % by weight, or the washing composition moisture absorbing component of 20 to 60 % by weight.Usually, when described moisture absorbing component mixes via condensation product particle and/or blowing powder particle, the tensio-active agent of weighing scale at least 10 % by weight that this type of particle will comprise based on described particle.In the especially preferred present composition, described composition comprises the sodium sulfate and blowing powder and/or condensation product doing and add, preferably comprises the blowing powder of sodium sulfate.

According to a preferred aspect of the present invention, described detergent composition also comprises dye transfer inhibitor and/or fabric hueing agent.

promoter material

Detergent composition of the present invention can comprise one or more (washing composition) promoter materials.These such as can strengthen clean-up performance, process substrate to be cleaned, or improve the aesthetic property of composition, the same with the situation of spices, spot grain, tinting material, dyestuff etc.The amount being incorporated into this analog assistant any in any fabric nursing of the present invention and household care products composition is supplementing mentioned any material in mixing above.The exact nature of these annexing ingredients, and their level of mixing by depend on described consuming product physical form and for it by by the essence of clean operation used.Suitable promoter material includes but not limited to tensio-active agent, washing assistant, sequestrant, dye transfer inhibitor, dispersion agent, enzyme and enzyme stabilizers, catalytic material, bleach activator, hydrogen peroxide, hydrogen peroxide cource, preformed peracid, polymeric dispersant, clay soil removal/anti redeposition agent, whitening agent, suds suppressor, dyestuff, dope dye, spices, perfume delivery systems, structure elasticizing agent, fabric softener, carrier, help water solvent, processing aid, solvent and/or pigment.The example of suitable auxiliary agent is described in hereinafter.In addition to the disclosure below, the suitable example of this type of other auxiliary agent and consumption are also present in United States Patent (USP) 5, and 576,282,6,306,812 B1 and 6, in 326,348 B1, described document is incorporated herein by reference.

Fabric hueing agent: composition can comprise fabric hueing agent.Suitable fabric hueing agent comprises dyestuff, dye clay conjugates and pigment.Suitable dyestuff comprises small molecule dyes and polymeric dye.Suitable small molecule dyes comprises and is selected from following small molecule dyes: belong to direct indigo plant, directly red, direct purple, acid blue, Xylene Red, acid violet, alkali blue, alkalescence is purple and alkalescence is red or the dyestuff of the color index of their mixing (C.I.) classification.

On the other hand, suitable small molecule dyes comprises and is selected from following small molecule dyes: color index (Society of Dyers and Colourists, Bradford, UK) number direct purple 9, direct purple 35, direct purple 48, direct purple 51, direct purple 66, direct purple 99, direct blue 1, direct blue 71, direct blue 80, direct blue 279, azogeramine 7, Xylene Red 73, acid red 88, azogeramine 50, acid violet 15, acid violet 17, acid violet 24, acid violet 43, Xylene Red 52, acid violet 49, Blue VRS 5, Blue VRS 7, acid blue 25, acid blue 29, Acid Blue 40, acid blue 45, Acid Blue 75, acid blue 80, acid blue 83, acid blue 90 and Acid blue 113, Acid Black 1, alkaline purple 1, alkaline purple 3, alkalescence purple 4, alkaline purple 10, alkaline purple 35, Basic Blue 3, alkali blue 16, alkali blue 22, alkali blue 47, alkali blue 66, Blue 75, alkali blue 159 and their mixture.On the other hand, suitable small molecule dyes comprises and is selected from following small molecule dyes: color index (Society of Dyers and Colourists, Bradford, UK) number acid violet 17, acid violet 43, Xylene Red 52, Xylene Red 73, acid red 88, azogeramine 50, acid blue 25, acid blue 29, acid blue 45, Acid blue 113, Acid Black 1, direct indigo plant 1, direct indigo plant 71, direct purple 51 and their mixture.On the other hand, suitable small molecule dyes comprises and is selected from following small molecule dyes: color index (Society of Dyers and Colourists, Bradford, UK) number acid violet 17, direct indigo plant 71, direct purple 51, direct indigo plant 1, acid red 88, azogeramine 50, acid blue 29, Acid blue 113 or their mixture.

Suitable polymeric dye comprises and is selected from following polymeric dye: comprise the polymkeric substance of conjugation chromogen (dye-polymer conjugate), polymkeric substance that chromogen copolymerization is incorporated into main polymer chain and their mixture.

In yet another aspect, suitable polymeric dye comprises and is selected from following polymeric dye: with title (Milliken, Spartanburg, South Carolina, USA) fabric-entity tinting material, the dye-polymer conjugate formed by least one reactive dyestuffs sold and be selected from the polymkeric substance comprising following polymkeric substance: hydroxylic moiety, primary amine moiety, secondary amine moieties, thiol moiety and their mixture.On the other hand, suitable polymeric dye comprises and is selected from following polymeric dye: (Milliken, Spartanburg, South Carolina, USA) Violet CT, with the Walocel MT 20.000PV (CMC) of Reactive blue conjugation, reactive violet or active red dye such as with the CMC of C.I. Reactive Blue 19 100 conjugation, by Megazyme, Wicklow, Ireland with ProductName AZO-CM-CELLULOSE, product code S-ACMC sell, oxyalkylated triphenylrnethane polymeric tinting material, oxyalkylated thiophene polymeric colorant and their mixture.

Suitable dye clay conjugates comprises and is selected from following dye clay conjugates: at least one positively charged ion/basic dyestuff and smectic clays and their mixture.In yet another aspect, suitable dye clay conjugates comprises and is selected from following dye clay: a kind of positively charged ion/basic dyestuff, described positively charged ion/basic dyestuff is selected from that C.I. basic yellow 1 to 108, C.I. 2, ba,sic, or,ang,e 21 to 69, C.I. alkali red 1:1 to 118, C.I. alkaline purple 1 to 51, C.I. alkali blue 1 to 164, C.I. alkali green 1 to 14, C.I. alkalescence are brown 1 to 23, CI basic black 1 to 11, and is selected from the clay of montmorillonitic clay, HECTABRITE DP, saponite clay and their mixture.On the other hand, suitable dye clay conjugates comprises and is selected from following dye clay conjugates: montmorillonite alkali blue B7 C.I.42595 conjugate, montmorillonite alkali blue B9 C.I.52015 conjugate, the purple V3 C.I.42555 conjugate of montmorillonite alkalescence, montmorillonite alkali green G1 C.I.42040 conjugate, the red R1 C.I.45160 conjugate of montmorillonite alkalescence, montmorillonite C.I. basic black 2 conjugate, hectorite alkali blue B7 C.I.42595 conjugate, hectorite alkali blue B9 C.I.52015 conjugate, the purple V3 C.I.42555 conjugate of hectorite alkalescence, hectorite alkali green G1 C.I.42040 conjugate, the red R1 C.I.45160 conjugate of hectorite alkalescence, hectorite C.I. basic black 2 conjugate, soap alkali blue B7 C.I.42595 conjugate, soap alkali blue B9 C.I.52015 conjugate, the purple V3 C.I.42555 conjugate of soap alkalescence, soap alkali green G1 C.I.42040 conjugate, the red R1 C.I.45160 conjugate of soap alkalescence, saponite C.I. basic black 2 conjugate and their mixture.

Suitable pigment comprises and is selected from following pigment: flavanthrone, indanthrone, comprise the chlorination indanthrone of 1 to 4 chlorine atom, pyranthrone, dichloro pyranthrone, monobromo dichloro pyranthrone, Dibromo-dichloro pyranthrone, tetrabromo pyranthrone, perylene-3, 4, 9, 10-tetracarboxylic acid diimide, wherein said imide group can be unsubstituted or to be replaced by C1-C3 alkyl or phenyl or heterocyclic group, and wherein said phenyl and heterocyclic group can additionally with the substituting groups not giving solubleness in water, anthrapyrimidine carboxylic acid amide, violanthrone, isoviolanthrone, dioxazine pigment, each molecule can comprise the copper phthalocyanine of 2 chlorine atoms at the most, many chlorine copper phthalocyanine or each molecule comprise many bromines chlorine copper phthalocyanine of 14 bromine atoms at the most, and their mixture.

In yet another aspect, suitable pigment comprises and is selected from following pigment: ultramarine blue (C.I. Pigment blue 29), ultramarine violet (C.I. pigment violet 1 5) and their mixture.

Aforementioned fabric toning agent (any mixture of fabric hueing agent can be used) can be used in combination.Suitable fabric hueing agent can purchased from Aldrich (Milwaukee, Wisconsin, USA); CibaSpecialty Chemicals (Basel, Switzerland); BASF (Ludwigshafen, Germany); Dayglo Color Corporation (Mumbai, India); OrganicDyestuffsCorp. (East Providence, Rhode Island, USA); Dystar (Frankfurt, Germany); Lanxess (Leverkusen, Germany); Megazyme (Wicklow, Ireland); Clariant (Muttenz, Switzerland); Avecia (Manchester, UK) and/or according to comprise herein example preparation.Suitable toning agent is described in greater detail in US 7, in 208,459 B2.

Encapsulation object: described composition can comprise encapsulation object.In one aspect, encapsulation object comprises core, has the shell of internal surface and outside surface, and described shell encapsulates described core.

In of described encapsulation object, described core can comprise and is selected from following material: spices; Whitening agent; Dyestuff; Wormer; Siloxanes; Wax; Flavour agent; VITAMIN; Fabric softener; Skin-care agent, in one aspect, paraffin; Enzyme; Antiseptic-germicide; SYNTHETIC OPTICAL WHITNER; Sensory agent; And their mixture; And described shell can comprise and is selected from following material: polyethylene; Polymeric amide; Polystyrene; Polyisoprene; Polycarbonate; Polyester; Polyacrylic ester; Aminoplastics, described aminoplastics can comprise polyureas, urethane and/or polyureaurethane in one aspect, and described polyureas can comprise polyoxymethylene urea and/or melamino-formaldehyde in one aspect; Polyolefine; Polysaccharide, described polysaccharide can comprise alginate and/or chitosan in one aspect; Gelatin; Lac; Epoxy resin; Vinyl polymer; Water insoluble inorganic substance; Siloxanes; And their mixture.In of described encapsulation object, described core can comprise spices.In of described encapsulation object, described shell can comprise melamino-formaldehyde and/or crosslinked melamino-formaldehyde.

In one aspect, the invention discloses the encapsulation object be applicable to that can comprise core material and shell, described shell is at least in part around described core material.The described encapsulation object of at least 75%, 85% or even 90% can have about 0.2MPa to about 10MPa, about 0.4MPa to about 5MPa, about 0.6MPa to about 3.5MPa, or the rupture strength of even about 0.7MPa to about 3MPa; And 0% to about 30%, 0% to about 20%, or the beneficial agent seepage of even 0% to about 5%.In one aspect, the described encapsulation object of at least 75%, 85% or even 90% can have about 1 micron to about 80 microns, about 5 microns to 60 microns, about 10 microns to about 50 microns, or the granularity of even about 15 microns to about 40 microns.In one aspect, the described encapsulation object of at least 75%, 85% or even 90% can have about 30nm to about 250nm, about 80nm to about 180nm, or the particle wall thickness of even about 100nm to about 160nm.

In an aspect, the core material of described encapsulation object can comprise and is selected from following material: perfume base and/or optional material, described optional material is selected from: vegetables oil (comprising the vegetables oil of pure vegetables oil and/or mixing), comprises Semen Ricini oil, cocounut oil, Oleum Gossypii semen, grapefruit, Semen Brassicae campestris, soybean oil, Semen Maydis oil, plam oil, linseed oil, Thistle oil, sweet oil, peanut oil, Oleum Cocois, palm-kernel oil, Viscotrol C, lemon oil and their mixture; The ester of vegetables oil, ester, comprise Polycizer W 260, dibutyl phthalate, hexanodioic acid benzyl butyl ester, hexanodioic acid octyl group benzyl ester, Tritolyl Phosphate, trioctyl phosphate and their mixture; The hydrocarbon of straight chain or branching, comprises those straight or branched hydrocarbon having boiling point and be greater than about 80 DEG C; Partially hydrogenated terphenyl, bialkyl ortho phthalate, alkyl biphenyl (comprising single isopropyl biphenyl), alkylated naphthalene (comprising dipropyl naphthalene), petroleum spirit (comprising kerosene, mineral oil) and their mixture; Aromatic solvent, comprises benzene, toluene and their mixture; Silicone oil; And their mixture.

In one aspect, the sheating material of described encapsulation object can comprise suitable resin, and described resin comprises the reaction product of aldehyde and amine, and suitable aldehyde comprises formaldehyde.Suitable amine comprises trimeric cyanamide, urea, benzo guanamine, glycoluril and their mixture.Suitable trimeric cyanamide comprises melamine methylol, the melamine methylol that methylates, imino-trimeric cyanamide and their mixture.Suitable urea comprises dimethylolurea, the dimethylolurea that methylates, urea-Resorcinol and their mixture.

In one aspect, suitable formaldehyde scavenger can be used to described encapsulation object, such as, adds in capsule slurries and/or before described encapsulation object is added in consuming product, period or add to afterwards in consuming product.

Suitable capsule can obtain according to the instruction of USPA 2008/0305982 A1 and/or USPA2009/0247449 A1.Alternatively, suitable capsule can purchased from AppletonPapers Inc. (Appleton, Wisconsin USA).

In addition, material for the preparation of aforementioned encapsulation object can purchased from Solutia Inc. (St Louis, Missouri U.S.A.), Cytec Industries (West Paterson, New Jersey U.S.A.), sigma-Aldrich (St.Louis, Missouri U.S.A.), CP Kelco Corp. (San Diego, California, USA); BASF AG (Ludwigshafen, Germany); Rhodia Corp. (Cranbury, New Jersey, USA); Hercules Corp. (Wilmington, Delaware, USA); Agrium Inc. (Calgary, Alberta, Canada), ISP (New Jersey U.S.A.), Akzo Nobel (Chicago, IL, USA); Stroever Shellac Bremen (Bremen, Germany); Dow Chemical Company (Midland, MI, USA); Bayer AG (Leverkusen, Germany); Sigma-Aldrich Corp. (St.Louis, Missouri, USA).

Polymkeric substance: consuming product can comprise one or more polymkeric substance.Example is carboxymethyl cellulose, polyvinylpyrrolidone, PEG, poly-(vinyl alcohol), poly-(vinylpyridine-N-oxide), poly-(vinyl imidazole), polycarboxylate such as polyacrylic ester, toxilic acid/acrylic copolymer and lauryl methacrylate(LMA)/acrylic copolymer.

Described consuming product can comprise one or more amphipathic clean polymkeric substance, such as there is the compound of following formula: two ((C2H5O) (C2H4O) n) (CH3)-N+-CxH2x-N+-(CH3)-bis-((C2H5O) (C2H4O) n), wherein n=20 to 30, and x=3 to 8, or its sulfation or sulfonated variant.

Described consuming product can comprise amphipathic alkoxylate grease cleaning polymkeric substance, and described polymkeric substance has wetting ability and the hydrophobicity of balance, make them from fabric and surface removal fat particles.The specific embodiment of amphipathic oxyalkylated grease cleaning polymkeric substance of the present invention comprises cored structure and is connected to multiple alkoxylate groups of this cored structure.These can comprise oxyalkylated polyalkyleneimine, preferably have interior poly-ethylene oxide block and outer propyleneoxides.

Carboxylate polymer-detergent composition of the present invention also can comprise one or more carboxylate polymer, such as maleate/acrylate random copolymers or polyacrylate homopolymers.In one aspect, described carboxylate polymer is polyacrylate homopolymers, and it has 4,000Da to 9,000Da, or the molecular weight of 6,000Da to 9,000Da.

Detergency polymkeric substance-detergent composition of the present invention also can comprise one or more detergency polymkeric substance, and it has by a structure defined in following structure (I), (II) or (III):

(I)-[(OCHR ¹-CHR ²) _a-O-OC-Ar-CO-] _d

(II)-[(OCHR ³-CHR ⁴) _b-O-OC-sAr-CO-] _e

(III)-[(OCHR ⁵-CHR ⁶) _c-OR ⁷] _f

Wherein:

A, b and c are 1 to 200;

D, e and f are 1 to 50;

Ar is the phenylene of Isosorbide-5-Nitrae-replacement;

SAr is for use SO at 5 ₃1, the 3-phenylene replaced that Me replaces;

Me is Li, K, Mg/2, Ca/2, Al/3, ammonium, an alkylammonium, dialkyl ammonium, trialkyl ammonium or tetra-allkylammonium, and wherein said alkyl group is C ₁-C ₁₈alkyl or C ₂-C ₁₀hydroxyalkyl or their mixture;

R ¹, R ², R ³, R ⁴, R ⁵and R ⁶independently selected from H or C ₁-C ₁₈alkyl or iso-alkyl; And

R ⁷for the C of straight chain or branching ₁-C ₁₈alkyl, or the C of straight chain or branching ₂-C ₃₀thiazolinyl, or the group of naphthene base with 5 to 9 carbon atoms, or C ₈-C ₃₀aromatic yl group, or C ₆-C ₃₀aromatic alkyl group.

Suitable detergency polymkeric substance is polyester detergency polymkeric substance such as Repel-o-tex polymkeric substance, comprises the Repel-o-tex SF supplied by Rhodia, SF-2 and SRP6.Other suitable detergency polymkeric substance comprise Texcare polymkeric substance, comprise the Texcare SRA100 supplied by Clariant, SRA300, SRN100, SRN170, SRN240, SRN300 and SRN325.Other suitable detergency polymkeric substance are Marloquest polymkeric substance, the Marloquest SL such as supplied by Sasol.

Cellulose polymer compound-detergent composition of the present invention also can comprise one or more cellulose polymer compounds, described cellulose polymer compound comprise be selected from alkylcellulose, alkyl alkoxy alkylcellulose, carboxymethyl cellulose, alkyl carboxymethyl cellulose those.In one aspect, described cellulose polymer compound is selected from the group comprising the following: carboxymethyl cellulose, methylcellulose gum, methyl hydroxyethylcellulose, methylcarboxymethyl Mierocrystalline cellulose and their mixture.In one aspect, described carboxymethyl cellulose has the degree of substitution by carboxymethyl of 0.5 to 0.9 and the molecular weight of 100,000Da to 300,000Da.

Enzyme: except being present in the enzyme in common particle, described detergent composition also can comprise one or more additional enzymes, and described additional enzymes provides clean-up performance and/or fabric care benefit.The example of suitable enzyme includes but not limited to hemicellulase, peroxidase, proteolytic enzyme, cellulase, zytase, lipase, Phospholipid hydrolase, esterase, at, polygalacturonase, mannase, pectin lyase, M-Zyme, reductase enzyme, oxydase, phenol oxidase, lipoxygenase, ligninase, Starch debranching enzyme, tannase, pentosanase, Mai Laning enzyme, beta-glucanase, arabinofuranosidase/xylosidase, Unidasa, chondroitinase, laccase and amylase, or their mixture.Typical combination is the enzyme mixture that can comprise proteolytic enzyme and the lipase be such as combined with amylase.When being present in detergent composition of the present invention, aforementioned additional enzymes can by described consuming product weighing scale about 0.00001% to about 2%, about 0.0001% to about 1%, or the zymoprotein of even about 0.001% to about 0.5% content exists.The details hereafter provided relate to enzyme, and described enzyme is suitable for being incorporated in common particle, or is more generally incorporated in detergent composition, instead of mixes via common particle.

In one aspect, preferred enzyme can comprise proteolytic enzyme.Suitable proteolytic enzyme comprises metalloprotease and serine protease, comprises neutrality or alkaline microbial serine protease, as subtilisin (EC 3.4.21.62).Suitable proteolytic enzyme comprise animal, plant or microbial origin those.In one aspect, this type of suitable proteolytic enzyme can be microbial origin.Suitable proteolytic enzyme comprises the mutant of chemistry or gene-modified aforementioned adequate proteins enzyme.In one aspect, suitable proteolytic enzyme can be serine protease, and such as alkaline microbial protease is or/and trypsinase type proteolytic enzyme.Suitable example that is neutral or Sumizyme MP comprises:

(a) subtilisin (EC 3.4.21.62), comprise those that derive from bacillus (Bacillus), such as US 6, 312, 936 B1, US 5, 679, 630, US4, 760, 025, US7, 262, 042 and the bacillus lentus (Bacillus lentus) described in WO09/021867, Alkaliphilic bacillus (B.alkalophilus), subtilis (B.subtilis), bacillus amyloliquefaciens (B.amyloliquefaciens), bacillus pumilus (Bacillus pumilus) and bacillus gibsonii (Bacillus gibsonii).

(b) trypsinase type or Quimotrase type proteolytic enzyme, such as trypsin is such as derived from pig or ox), comprise fusarium (Fusarium) proteolytic enzyme described in WO 89/06270, and the Quimotrase deriving from Cellulomonas (Cellumonas) described in WO 05/052161 and WO 05/052146.

C () metalloprotease, comprises and derives from those of bacillus amyloliquefaciens (Bacillus amyloliquefaciens) described in WO 07/044993A2.

Preferred proteolytic enzyme comprises those that derive from bacillus gibsonii (Bacillus gibsonii) or bacillus lentus (Bacillus Lentus).

The proteolytic enzyme of suitable commercially available acquisition comprises with trade(brand)name with sold by Novozymes A/S (Denmark) those, with trade(brand)name with sold by Genencor International those, with trade(brand)name with sold by Solvay Enzymes those, purchased from Henkel/Kemira those namely BLAP (sequence is shown in US 5,352, in 604 Figure 29, there is following mutation S99D+S101R+S103A+V104I+G159S, hereinafter referred to as BLAP), BLAPR (there is the BLAP of S3T+V4I+V199M+V205I+L217D), BLAP X (there is the BLAP of S3T+V4I+V205I) and BLAP F49 (there is the BLAP of S3T+V4I+A194P+V199M+V205I+L217D)-all derive from Henkel/Kemira; With the KAP (there is the Alkaliphilic bacillus subtilisin of sudden change A230V+S256G+S259N) deriving from Kao.

Suitable α-amylase comprises the amylase being derived from bacterium or fungi.Comprise the mutant (variant) of chemistry or genetic modification.Preferred alkali alpha amylase derives from bacillus (Bacillus) bacterial strain, such as Bacillus licheniformis (Bacillus licheniformis), bacillus amyloliquefaciens (Bacillusamyloliquefaciens), bacstearothermophilus (Bacillus stearothermophilus), subtilis (Bacillus subtilis), or other bacillus such as bacillus NCIB 12289, NCIB 12512, NCIB 12513, DSM 9375 (USP 7, 153, 818), DSM 12368, DSMZ no.12649, KSM AP1378 (WO 97/00324), KSM K36 or KSM K38 (EP 1, 022, 334).Preferred amylase comprises:

(a) WO 94/02597, WO 94/18314, the variant described in WO96/23874 and WO 97/43424, especially relative to the enzyme in WO 96/23874 listed by SEQ ID NO:2, one or more in lower column position have substituent variant: 15,23,105,106,124,128,133,154,156,181,188,190,197,202,208,209,243,264,304,305,391,408 and 444.

B () is described in USP 5,856,164 and WO99/23211, WO 96/23873, WO00/60060 and WO 06/002643 in variant, especially relative to the AA560 enzyme in WO06/002643 listed by SEQ ID No.12, at lower column position, there is one or more substituent variant:

26,30,33,82,37,106,118,128,133,149,150,160,178,182,186,193,203,214,231,256,257,258,269,270,272,283,295,296,298,299,303,304,305,311,314,315,318,319,339,345,361,378,383,419,421,437,441,444,445,446,447,450,461,471,482,484, preferably also comprise the variant of D183* and G184* disappearance.

C () shows the variant of at least 90% identity with the SEQ ID No.4 in WO06/002643, from the wild-type enzyme of bacillus SP722, especially there is in position 183 and 184 variant of disappearance, and the variant described in WO 00/60060, described document is incorporated herein by reference.

D () shows and the wild-type enzyme (US6 from bacillus 707 (Bacillus sp.707), 093, SEQ ID NO:7 in 562) at least 95% identity at least 95% identity, what especially comprise in following sudden change is one or more: those of M202, M208, S255, R172 and/or M261.Preferably, what described amylase comprised in M202L, M202V, M202S, M202T, M202I, M202Q, M202W, S255N and/or R172Q is one or more.Especially preferred be comprise M202L or M202T sudden change those.

The α-amylase of suitable commercially available acquisition comprises with (NovozymesA/S, Bagsvaerd, Denmark), aT 9000 Biozym Biotech TradingGmbH Wehlistrasse 27b A-1200 Wien Austria, with (Genencor International Inc., Palo Alto, California) and (Kao, 14-10Nihonbashi Kayabacho, 1-chome, Chuo-ku Tokyo 103-8210, Japan).In one aspect, suitable amylase comprises with and their mixture.

In one aspect, this fermentoid is optional from lipase, comprises " the first washing lipase ", such as at United States Patent (USP) 6, and those described in 939,702 B1 and U.S. Patent application 2009/0217464.In one aspect, described lipase is the first washing lipase, preferably comprises the wild type lipase variant of the thermophilic hyphomycete of thin cotton like (Thermomyces lanuginosus) of T231R and N233R sudden change.269 seed amino acids (amino acid 23-291) of wild-type sequence to be Swissprot accession number be Swiss-Prot O59952 (deriving from the thermophilic hyphomycete of thin cotton like (Thermomyces lanuginosus) (Humicola lanuginosa (Humicola lanuginosa))).Preferred lipase comprises with trade(brand)name with sell those.

In one aspect, other preferred enzyme comprises the endoglucanase being derived from microorganism, it shows inscribe-β-1,4-dextranase activity (E.C.3.2.1.4), come from the bacterial peptide of bacillus member in comprising, it has and 7, and 141, the sequence of aminoacid sequence SEQ ID NO:2 at least 90%, 94%, 97% and even 99% identity in 403B2), and their mixture.Suitable endoglucanase is with trade(brand)name with (Novozymes A/S (Bagsvaerd, Denmark)) sells.

Other preferred enzyme comprises with trade(brand)name sell pectate lyase and with trade(brand)name the mannase (all deriving from NovozymesA/S (Bagsvaerd, Denmark)) sold, and with trade(brand)name the mannase (Genencor International Inc. (Palo Alto, California)) sold.

SYNTHETIC OPTICAL WHITNER: detergent composition of the present invention can comprise one or more SYNTHETIC OPTICAL WHITNER.The Suitable bleaching agents being different from bleaching catalyst comprises optical white, bleach activator, hydrogen peroxide, hydrogen peroxide cource, premolding peracid and their mixture.In general, when a bleaching agent is used, detergent composition of the present invention can comprise weighing scale about 0.1% by described theme consuming product to about 50%, or the SYNTHETIC OPTICAL WHITNER of even about 0.1% to about 25%.The example of Suitable bleaching agents comprises:

(1) optical white, such as sulfonation phthalocyanine phthalocyanine zinc, aluminum phthalocyanine, xanthene class dyestuff and their mixture;

(2) premolding peracid: suitable premolding peracid includes but not limited to be selected from following compound: percarboxylic acids and salt, percarbonic acid and salt thereof, cross imidic acid and salt, permonosulphuric acid and salt thereof as and their mixture.Suitable percarboxylic acids comprises the hydrophobicity and hydrophilic peracids with formula R-(C=O) O-O-M structure, wherein R is alkyl group, the alkyl of optional branching, when peracid is hydrophobicity, it has 6 to 14 carbon atoms or 8 to 12 carbon atoms, and when peracid is wetting ability, it has and is less than 6 carbon atoms or is even less than 4 carbon atoms; Such as, and M is counter ion, sodium, potassium or hydrogen.Preformed peroxy acid or its salt are preferably peroxycarboxylic acid or its salt, usually have the chemical structure corresponding to following chemical formula:

Wherein: R ¹⁴be selected from alkyl, aralkyl, cycloalkyl, aryl or heterocyclic radical; R ¹⁴group can be straight chain or branching, substituted or unsubstituted; And Y obtains electroneutral any suitable counter ion, and Y is preferably selected from hydrogen, sodium or potassium.R ¹⁴be preferably straight chain or branching, substituted or unsubstituted C _6-14alkyl.When described peracid is hydrophobicity, R ¹⁴preferably there are 6 to 14 carbon atoms, or 8 to 12 carbon atoms, and when described peracid is wetting ability, R ¹⁴preferably have and be less than 6 carbon atoms, or be even less than 4 carbon atoms.Preferably, peroxy acid or its salt are selected from peroxy caproic acid, peroxide enanthic acid, Peroxycaprylic acid, pernoanoic acid, peroxydecanoic, their any salt, or their any combination.Especially preferred peroxy acid is phthalimido peroxoalkanoic acids, ε particularly-phthalimido peroxy caproic acid (PAP).Preferably, described peroxy acid or its salt have 30 DEG C to the fusing point within the scope of 60 DEG C.

Preformed peroxy acid or its salt also can be peroxy sulfonic acid or its salt, usually have the chemical structure corresponding to following chemical formula:

Wherein: R ¹⁵be selected from alkyl, aralkyl, cycloalkyl, aryl or heterocyclic radical; R ¹⁵group can be straight chain or branching, substituted or unsubstituted; And Z obtains electroneutral any suitable counter ion, and Z is preferably selected from hydrogen, sodium or potassium.Preferably, R ¹⁵for straight chain or branching, substituted or unsubstituted C _6-9alkyl.Preferably, this type of bleaching components can 0.01 to 50%, and most preferably the amount of 0.1% to 20% is present in composition of the present invention.

(3) hydrogen peroxide cource, such as inorganic perhydrate salts, comprises the such as sodium salt of following an alkali metal salt: perborate (being generally monohydrate or tetrahydrate), percarbonate, persulphate, superphosphate, persilicate and their mixture.In one aspect of the invention, inorganic perhydrate salts is selected from: peroxyboric acid sodium salt, percarbonic acid sodium salt and their mixture.When utilized, inorganic perhydrate salts exists with the amount of 0.05 % by weight to 40 % by weight or 1 % by weight to 30 % by weight of total fabric and household care product usually, and usually being impregnated in this kind fabric and household care product by coated crystalline solid forms.Suitable coating comprises: inorganic salt such as alkalimetal silicate, carbonate or borate or their mixture, or organic materials such as water-soluble or dispersible polymer, wax, oil or fat soap; With

(4) there is the bleach activator of R-(C=O)-L structure, wherein R is alkyl group, the alkyl of optional branching, when bleach activator is hydrophobicity, it has 6 to 14 carbon atoms or 8 to 12 carbon atoms, and when bleach activator is wetting ability, it has and is less than 6 carbon atoms or is even less than 4 carbon atoms; And L is leavings group.The example of suitable leavings group is phenylformic acid and derivative-especially benzene sulfonate thereof.Suitable bleach activator comprises lauroyl oxygen base benzene sulfonate, decanoyl oxygen base benzene sulfonate, decanoyl aminobenzoic acid or its salt, 3; 5,5-trimethyl acetyl base oxygen base benzene sulfonate, tetra acetyl ethylene diamine (TAED) and nonanoyloxybenzenesulfonate (NOBS).Suitable bleach activator is also disclosed in WO 98/17767.Although any suitable bleach activator can be adopted, in one aspect of the invention, this theme consuming product can comprise NOBS, TAED or their mixture.

When it is present, peracid and/or the content of bleach activator in described consuming product are generally about 0.1 % by weight to about 60 % by weight based on the weighing scale of fabric and household care product, about 0.5 % by weight to about 40 % by weight, or even about 0.6 % by weight to about 10 % by weight.One or more hydrophobic peracids or its precursor can be combined with one or more hydrophilic peracid or its precursor.

Can select the amount of hydrogen peroxide cource and peracid or bleach activator, the mol ratio making available oxygen (from peroxide source) and peracid is 1:1 to 35:1, or even 2:1 to 10:1.

(5) organic bleaching catalyst-detergent composition of the present invention also can comprise one or more can receive the Sauerstoffatom from peroxy acid and/or its salt and the bleaching catalyst described Sauerstoffatom being passed to oxidisable substrate.The bleaching catalyst be suitable for includes but not limited to: imines positively charged ion and polyion; Imines zwitter-ion; The amine of modification; The amine oxide of modification; N-sulphonyl imine; N-phosphonyl imine; N-acyl imine; Thiadiazoles dioxide; Perfluor imines; Cyclic sugar and their mixture, as described in USPA 2007/0173430A1.

In one aspect, described bleaching catalyst has the structure corresponding to following general formula:

Wherein R ¹³be selected from: 2-ethylhexyl, 2-propylheptyl, 2-butyl octyl, 2-pentylnonanyi, 2-hexyl decyl, dodecyl, n-tetradecane base, n-hexadecyl, Octadecane base, different nonyl, isodecyl, isotridecyl and different pentadecyl.

(6) metal matrix bleaching catalyst-described bleaching components can be provided by catalytic metal complexes.The metallic bleaching catalyst of bag of one type is comprise transition-metal cation (the such as copper limiting bleach catalyst activity, iron, titanium, ruthenium, tungsten, molybdenum or manganese positively charged ion), have very low or there is no the auxiliary metal cation (such as zinc or aluminium cations) of bleach catalyst activity, with sequestrant (especially ethylenediamine tetraacetic acid (EDTA) catalyzer and auxiliary metal cation to restriction stability constant, EDTMP and their water-soluble salt) catalyst system.This type of catalyzer is disclosed U.S.4, and 430, in 243.Preferred catalyzer is described in WO09/839406, US6218351 and WO00/012667.Therefore particularly preferably be transition-metal catalyst or part, it is that bridge connects polygamy position N-donor ligand.

If needed, composition herein can use manganic compound to carry out catalysis.This compounds and consumption are well known in the art, and comprise and be such as disclosed in U.S.5,576, the catalyzer based on manganese in 282.

Cobalt bleaching catalyst for this paper is known and is described in such as U.S.5,597,936; U.S.5,595, in 967.This type of cobalt catalyst easily through the preparation of known method, such as US5,597,936 and US 5,595, proposed in 967.

Composition herein also suitably can comprise part such as two piperidone (bispidones) (US 7,501,389) and/or macropolycyclic rigid ligand of transition metal complex-be abbreviated as " MRLs ".As a practical problems, instead of the mode by limiting, the compositions and methods of the invention can be adjusted, to provide the active MRL species of approximately at least one 1/100000000th in aqueous cleaning liquid, and usually will provide about 0.005ppm to about 25ppm in described washing liq, about 0.05ppm to about 10ppm, or the MRL of even about 0.1ppm to about 5ppm.

In transition metal bleach catalyzer of the present invention, suitable transition metal comprises such as manganese, iron and chromium.Suitable MRL comprises 5,12-diethyl-1,5,8,12-tetra-azabicyclo [6.6.2] n-Hexadecane.

Be easy to prepare suitable transition metal M RL, such as U.S.6 by currently known methods, 225,464 and WO 00/32601 in example proposed.

Tensio-active agent: can comprise tensio-active agent or surfactant system according to detergent composition of the present invention, wherein said tensio-active agent can be selected from nonionogenic tenside, anion surfactant, cats product, amphoterics, zwitterionics, semi-polar nonionic surfactants and their mixture.When it is present, the weighing scale that theme consuming product pressed usually by tensio-active agent exists with the content of about 0.1% to about 60%, about 1% to about 50% or even about 5% to about 40%.

Suitable anionic detersive surfactant comprises vitriol and sulfonate detersive surfactant.Suitable sulfonate detersive surfactant comprises alkylbenzene sulfonate, in one aspect, and C _10-13alkylbenzene sulfonate.Suitable alkylbenzene sulfonate (LAS) obtains by making (LAB) sulfonation of the linear alkylbenzene of commercially available acquisition; Suitable LAB comprises rudimentary 2-phenyl LAB, such as with trade(brand)name supplied by Sasol those, or with trade(brand)name by Petresa supplies those, other suitable LAB comprises senior 2-phenyl LAB, such as with trade(brand)name supplied by Sasol those.Suitable anionic detersive surfactant is alkylbenzene sulfonate, and it is obtained by DETAL catalysis process, but other route of synthesis such as HF is also suitable.Suitable sulphate detersive tensio-active agent comprises alkyl-sulphate, in one aspect, and C _8-18alkyl-sulphate, or be mainly C ₁₂alkyl-sulphate.Other suitable sulphate detersive tensio-active agent is alkyl alkoxylated vitriol, in one aspect, and the vitriol of alkyl ethoxylated, in one aspect, C _8-18alkyl alkoxylated vitriol, on the other hand, C _8-18the vitriol of alkyl ethoxylated, usual described alkyl alkoxylated vitriol has 0.5 to 20, or the average degree of alkoxylation of 0.5 to 10, and usual described alkyl alkoxylated vitriol is C _8-18the vitriol of alkyl ethoxylated, it has 0.5 to 10,0.5 to 7, the average degree of ethoxylation of 0.5 to 5 or even 0.5 to 3.Described alkyl-sulphate, alkyl alkoxylated suifate and alkylbenzene sulfonate can be straight chain or branching, substituted or unsubstituted.

Described detersive surfactant can be the detersive surfactant of mid-chain branched, in one aspect, the anionic detersive surfactant of mid-chain branched, in one aspect, the alkyl-sulphate of mid-chain branched and/or the alkylbenzene sulfonate of mid-chain branched, the alkyl-sulphate of such as mid-chain branched.In one aspect, middle side chain is C _1-4alkyl group, is generally methyl and/or ethyl group.

Suitable non-ionic detersive surfactant is selected from: C ₈-C ₁₈alkylethoxylate, such as derives from Shell's nonionogenic tenside; C ₆-C ₁₂the wherein said alcoxylates unit of alkyl phenol alkoxylates can be ethyleneoxy units, propyleneoxy units or their mixture; C ₁₂-C ₁₈alcohol and C ₆-C ₁₂the condenses of alkylphenol and ethylene oxide/propylene oxide block polymer, such as derives from BASF's c ₁₄-C ₂₂the alcohol of mid-chain branched; C ₁₄-C ₂₂the alkyl alkoxylates of mid-chain branched, it has the average degree of alkoxylation of 1 to 30 usually; Alkyl polysaccharide, in one aspect, alkyl glycoside; Polyhydroxy fatty acid amide; Ether capped poly-(alkoxylate) alcohol tensio-active agent; And their mixture.Suitable non-ionic detersive surfactant comprises alkyl polyglucoside and/or alkyl alkoxylated alcohol.In one aspect, non-ionic detersive surfactant comprises alkyl alkoxylated alcohol, in one aspect C _8-18alkyl alkoxylated alcohol, such as C _8-18alkyl ethoxylated alcohol, described alkyl alkoxylated alcohol can have 1 to 50,1 to 30,1 to 20, or the average degree of alkoxylation of 1 to 10.In one aspect, described alkyl alkoxylated alcohol can be C _8-18alkyl ethoxylated alcohol, it can have 1 to 10,1 to 7, the average degree of ethoxylation of more 1 to 5 or 3 to 7.Described alkyl alkoxylated alcohol can be straight chain or branching, and is substituted or unsubstituted.

Suitable cationic detersive surfactants comprises alkyl pyridine compound, alkyl quaternary ammonium compound, quaternary ammonium alkyl compound, alkyl ternary sulfonium compound and their mixture.Suitable cationic detersive surfactants is quaternary ammonium compound expressed by the following formula:

(R)(R ₁)(R ₂)(R ₃)N ⁺X ^-

Wherein, R is straight chain or branching, substituted or unsubstituted C _6-18alkyl or alkenyl part, R ₁and R ₂independently selected from methyl or aminoethyl moiety, R ₃for hydroxyl, methylol or hydroxyethyl moieties, X is for providing electroneutral negatively charged ion, and suitable negatively charged ion comprises: halogenide, such as muriate; Sulfate radical; And sulfonate radical.Suitable cationic detersive surfactants is single C _6-18alkyl list hydroxyethyl dimethyl ammonium chloride.Highly suitable cationic detersive surfactants is single-C _8-10alkyl list-hydroxyethyl is two-methyl chloride quaternary, and single-C _10-12alkyl list-hydroxyethyl is two-methyl chloride quaternary and single-C ₁₀alkyl list-hydroxyethyl is two-methyl chloride quaternary.

Sequestrant: detergent composition herein can comprise sequestrant.Suitable sequestrant comprises copper, iron and/or manganese sequestrant and their mixture.When a chelating agent is used, theme consuming product can comprise by described theme consuming product weighing scale about 0.005% to about 15% or the sequestrant of even about 3.0% to about 10%.The sequestrant be applicable to comprises DTPA (DTPA), HEDP (hydroxyl ethane bisphosphate), DTPMP (diethylene triamine penta(methylene phosphonic acid)), 1, 2-dihydroxy-benzene-3, 5-disulfonate salt hydrate, quadrol, diethylenetriamine, ethylenediamine disuccinic acid (EDDS), N-hydroxyethyl-ethylenediamine nitrilotriacetic (HEDTA), triethylenetetraaminehexaacetic acid (TTHA), N-hydroxyethylamino-diacetic acid (HEIDA), bicine N-(DHEG), ethylenediamine tetrapropionic acid(EDTP) (EDTP) and their derivative.

Dye transfer inhibitor: detergent composition of the present invention also can comprise one or more dye transfer inhibitors.Suitable polymeric dye transfer inhibitor includes but not limited to multipolymer, the polyvinyl of polyvinyl pyrrolidone polymers, polyamine N-oxide pllymers, NVP and N-vinyl imidazole oxazolidone and polyvinyl imidazol or their mixture.When being present in theme consuming product, described dye transfer inhibitor by described consuming product weighing scale can about 0.0001% to about 10%, about 0.01% to about 5% or even about 0.1% to about 3% content exist.

Whitening agent: detergent composition of the present invention also can comprise can by annexing ingredient painted for institute's cleaning article, such as white dyes.

Described composition can comprise the C.I. white dyes 260 of α-crystal type, and it has following structure:

In one aspect, described whitening agent is the whitening agent of cold water solubles, the C.I. white dyes 260 of such as α-crystal type.

In one aspect, described whitening agent is mainly α-crystal type, its refer to usually at least 50 % by weight, at least 75 % by weight, at least 90 % by weight, at least 99 % by weight or even substantially whole C.I. white dyess 260 are α-crystal types.Described whitening agent is generally micronized particle form, and it has 3 microns to 30 microns, 3 microns to 20 microns, or the weight average primary particle sizes of 3 microns to 10 microns.

Described composition can comprise the C.I. white dyes 260 of β-crystal type, and: the C.I. white dyes 260 of (i) α-crystal type can be at least 0.1 with the weight ratio of the C.I. white dyes 260 of (ii) β-crystal type, or at least 0.6.BE680847 relates to the method for the preparation of the C.I. white dyes 260 in α-crystal type.

Suitable fluorescent brightener levels comprise about 0.01 % by weight, about 0.05 % by weight, about 0.1 % by weight or even about 0.2 % by weight lower aq to 0.5 % by weight or even 0.75 % by weight high level.

Silicate-detergent composition of the present invention also can comprise silicate, such as water glass or potassium silicate.Described composition can comprise 0 % by weight to the silicate being less than 10 % by weight, to 9 % by weight, or to 8 % by weight, or to 7 % by weight, or to 6 % by weight, or to 5 % by weight, or to 4 % by weight, or to 3 % by weight, or even to 2 % by weight, and preferably higher than 0 % by weight, or 0.5 % by weight, or even 1 % by weight silicate.Suitable silicate is water glass.

Dispersion agent-detergent composition of the present invention also can comprise dispersion agent.Suitable water soluble organic substance comprises homopolymerization or co-polymeric acids or its salt, and wherein polycarboxylic acid comprises at least two and is separated by and is no more than the carboxyl of two carbon atoms.

Enzyme stabilizers-can by various consistent for the enzyme in described detergent composition.Enzyme used herein can be stablized by the water-soluble source of the calcium existed in final fabric and household care product and/or magnesium ion, and this type of ion is supplied to enzyme by described water-soluble source.When detergent composition comprises proteolytic enzyme, the compound of reversible protease inhibitors as boron compound or such as calcium formiate, sodium formiate and 1,2-propane diol can be added, to improve stability further.

Solvent-suitable solvent comprises water and other solvent such as lipophilic fluid.The example of suitable lipophilic fluid comprises siloxanes, other organosilicon, hydrocarbon, glycol ether, glycerol derivative such as glyceryl ether, perfluorination amine, perfluorination and hydrogen fluorine ether solvents, low volatility non-fluorinated organic solvent, diol solvent, other eco-friendly solvent and their mixture.

prepare the method for described detergent composition

Detergent composition of the present invention is preferably particle form, is optionally incorporated in unit dose detergent composition as above by described particle.

using method

The present invention includes the method on process and/or clean surface (preferred fabric surface), said method comprising the steps of: (i) makes described surface contact with the composition according to any one of claim 1 to 11 in aqueous cleaning liquid, (ii) rinsing and/or dry described surface, described liquid, aqueous temperature is preferably 5 – 25 DEG C, and the described liquid, aqueous tensio-active agent preferably comprising 0.1g/L to 3g/L.

particles Example 1 altogether

Prepare enzyme altogether particle according to the method described in the example 1 of US2008/0206830A1, but described particle comprises described enzyme with the weight ratio in hereafter formulation examples separately.Therefore, described enzyme granulate comprises the core (relative weight ratio is about 6:68:27) with enzyme, sucrose/starch and bitter salt, and the coating (relative weight ratio is about 40:50:10) containing polyvinyl alcohol, titanium dioxide and nonionogenic tenside.Enzyme concn in described particle is about 40g/kg.

formulation examples 1-7

granular laundry cleaning composition is designed for the washing machine of hand washing or top-loaded.

* via the enzyme that the common particle in common Particles Example 1 adds.

example 8-13

Granular laundry cleaning composition is designed for front loaded type automatic washing machine.

Mark: all enzyme content is all expressed as proenzyme material %

* via the enzyme that the common particle in common Particles Example 1 adds.

At 20-90 DEG C, with the concentration of aqueous solution of 7000 to 10000ppm, and the water of 5:1: the ratio of cloth, any one in use above-mentioned composition carrys out laundering of textile fabrics.Typical pH is about 10.Then dry fabric.In one aspect, dryer initiatively dry fabric is used.In one aspect, flatiron initiatively dry fabric is used.On the other hand, only make fabric dry on rope, wherein they are exposed to air and optional sunlight.

for starting material and the explanation of composition example 1 to 20

Alkylbenzene sulfonate, average aliphatic carbon straight chain chain length C ₁₁-C _12.

AE3S is C _12-15alkyl ethoxy (3) vitriol.

AE7 is C _12-15alcohol ethoxylate, average degree of ethoxylation is 7.

AE9 is C _12-13alcohol ethoxylate, average degree of ethoxylation is 9.

HSAS is mid-branched primary alkyl sulphates, and it has the carbon chain lengths of about 16-17

Sequestrant can be diethylene tetramine pentaacetic acid (DTPA), hydroxyl ethane di 2 ethylhexyl phosphonic acid sodium (HEDP) or quadrol-N, N-disuccinic acid sodium (S, S) isomer (EDDS)

celluclean ^tM, with it is all the product of Novozymes, Bagsvaerd, Denmark.

White dyes 1 is white dyes 2 is sulfonation phthalocyanine phthalocyanine zinc

NOBS is nonanoyloxybenzene sulfonate.

TAED is tetra acetyl ethylene diamine.

Washing agent is supplied by Rhodia (Paris, France)

Vinylformic acid/maleic acid molecular weight is 70,000, and propylene acid group: maleate ratio is 70:30.

HSAS is mid-branched alkyl-sulphate, is disclosed in US 6,020,303 and US 6,060, and in 443.

violet CT is supplied by Milliken (Spartanburg, South Carolina, USA)

Random graft copolymer is the polyethylene oxide copolymer of polyvinylacetate grafting, described multipolymer has polyethylene oxide main chain and multiple polyvinyl acetate ester side chain (molecular weight is about 6000, and polyethylene oxide is about 40 to 60 with the weight ratio of polyvinyl acetate).

Dimension disclosed herein is unintelligible for being strictly limited to quoted exact value with value.On the contrary, except as otherwise noted, otherwise each such dimension be intended to represent the value quoted and the scope be functionally equal to around this value.Such as, the dimension being disclosed as " 40mm " is intended to represent " about 40mm ".

Claims

1. a detergent composition, it comprises:

A () multienzyme is particle altogether;

B zeolite (moisture-free basis) that () is less than 10 % by weight;

C phosphoric acid salt (moisture-free basis) that () is less than 10 % by weight, wherein said enzyme altogether particle comprises the moisture absorbing component of 10 to 98 % by weight;

D () and described composition also comprise the washing composition moisture absorbing component of 20 to 80 % by weight.

2. detergent composition according to claim 1, wherein said multienzyme altogether particle comprises (a) one or more enzymes, and described enzyme is selected from the first washing lipase, clean fiber element enzyme, xyloglucanase enzymes, Perhydrolase, peroxidase, lipoxygenase, laccase and their mixture; (b) one or more enzymes, described enzyme is selected from hemicellulase, proteolytic enzyme, nursing cellulase, cellobiose dehydrogenase, zytase, Phospholipid hydrolase, esterase, at, polygalacturonase, mannonase pectate lyase, M-Zyme, reductase enzyme, oxydase, phenol oxidase, ligninase, Starch debranching enzyme, tannase, pentosanase, lichenase dextranase, arabinofuranosidase/xylosidase, Unidasa, chondroitinase, amylase and their mixture.

3., according to detergent composition according to claim 1 or claim 2, wherein said multienzyme altogether particle comprises proteolytic enzyme.

4., according to detergent composition in any one of the preceding claims wherein, wherein said multienzyme altogether particle comprises lipase.

5., according to detergent composition in any one of the preceding claims wherein, wherein said multienzyme altogether particle comprises weight ratio at least 2:5 to 5:2 at the most, the lipase of preferred 2:5 to 1:1 and proteolytic enzyme.

6., according to detergent composition in any one of the preceding claims wherein, wherein said washing composition moisture absorbing component comprises can the salt of hydration, preferably sulfuric acid sodium.

7., according to detergent composition in any one of the preceding claims wherein, it is at least 25 % by weight that described composition comprises content, or even at least 30 % by weight washing composition moisture absorbing component.

8., according to detergent composition in any one of the preceding claims wherein, wherein said moisture absorbing component and described gross activity enzyme are present in described multienzyme altogether in particle with the weight ratio of 4:1 or 6:1 or 8:1 or 10:1 to 100:1 or 60:1 or 40:1 at the most.

9. according to detergent composition in any one of the preceding claims wherein, wherein said multienzyme altogether particle comprises coating, and described coating is selected from titanium dioxide, polyvinyl alcohol, Vltra tears, methylcellulose gum, polycarboxylate, kaolin, polyoxyethylene glycol and their mixture.

10. according to detergent composition in any one of the preceding claims wherein, wherein said moisture absorbing component is selected from: sodium carbonate, preferred anhydrous sodium carbonate, dry clay, preferably comprise 0.1 to 15 % by weight free-water, more preferably the dry clay of 0.1 to 10% free-water; Sodium sulfate, preferred anhydrous sodium sulphate; Sodium-chlor, preferred anhydrous chlorides of rase sodium; Comprise 0 or 0.1 to 15% or 10% free-water biologic packing material and their mixture.

11. according to detergent composition in any one of the preceding claims wherein, and described composition also comprises dye transfer inhibitor.

12. according to detergent composition in any one of the preceding claims wherein, and described composition also comprises fabric coloring dyestuff, such as solvent or dispersed dye, or matching stain or substantive dyestuff or their mixture, and/or pigment or their mixture.

13. according to detergent composition in any one of the preceding claims wherein, described composition comprise in following auxiliary agent one or more:

A () comprises the encapsulation object of spices, described encapsulation object preferably comprises perfume microcapsule;

(b) surfactant system, described surfactant system preferably comprises anion surfactant and the nonionogenic tenside that weight ratio is preferably 20:1 to 1:10 or 1:1;

(c) silicate, described silicate preferably comprises and is selected from following material: water glass, potassium silicate and their mixture;

(d) carboxylate polymer, described carboxylate polymer preferably comprises and is selected from following material: maleate/acrylate random copolymers or polyacrylate homopolymer and their mixture;

(e) detergency polymkeric substance, described detergency polymkeric substance preferably comprises and is selected from following material: terephthalic acid ester copolymer and their mixture;

(f) cellulose polymer compound, described cellulose polymer compound preferably comprises and is selected from following material: alkylcellulose, alkyl alkoxy alkylcellulose, carboxyalkyl cellulose, alkylcarboxyalkyl Mierocrystalline cellulose and their mixture;

(g) sequestrant, described sequestrant preferably comprises and is selected from following material: DTPA (diethylene triaminepentaacetic acid(DTPA)), HEDP (hydroxyl ethane bisphosphate), DTPMP (diethylene triamine penta(methylene phosphonic acid)), ethylenediamine disuccinic acid (EDDS), 1, the derivative of 2-dihydroxy-benzene-3,5-disulfonate salt hydrate, described sequestrant; And

(h) their mixture.

14. according to composition in any one of the preceding claims wherein, described composition also comprises at least 2.5 % by weight, preferably at least 5 % by weight at the most 35 % by weight SPC-D, described SPC-D is optionally coated with protection against the tide, described composition also optionally comprises one or more bleach particles, and described bleach particle is selected from:

A () bleaching catalyst, described bleaching catalyst preferably comprises and is selected from following material: imines positively charged ion, imines polyion; Imines zwitter-ion; The amine of modification; The amine oxide of modification; N-sulphonyl imine; N-phosphonyl imine; N-acyl imine; Thiadiazoles dioxide; Perfluor imines; Cyclic sugar and transition-metal catalyst or form their part or their mixture;

(b) bleach activator, described bleach activator preferably comprises and is selected from following material: dodecane acyloxy benzene sulfonate, decanoyloxybenzenesulphonate, decanoyloxybenzoic acid or its salt, 3,5,5-trimethyl acetyl oxygen base benzene sulfonate, tetra acetyl ethylene diamine (TAED), nonanoly acyloxy benzene sulfonate (NOBS) and their mixture;

(c) metal catalyst;

(d) optical white, preferred Phthalocyanine Zinc and/or aluminum phthalocyanine compound, Food Red, edible bright cherry-red and/or rose bengal; And

(e) their mixture.

The method of 15. 1 kinds of process and/or clean surface, preferred fabric surface, said method comprising the steps of: (i) makes described surface contact with the composition according to any one of claim 1 to 11 in aqueous cleaning liquid, (ii) rinsing and/or dry described surface, described liquid, aqueous temperature is preferably 5-25 DEG C, and the described liquid, aqueous tensio-active agent preferably comprising 0.1g/L to 3g/L.