CN103936126A - Modified carbon black/ferric aluminum polysilicate composite blue algae treating agent and manufacturing method thereof - Google Patents

Modified carbon black/ferric aluminum polysilicate composite blue algae treating agent and manufacturing method thereof Download PDF

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Publication number
CN103936126A
CN103936126A CN201410158521.XA CN201410158521A CN103936126A CN 103936126 A CN103936126 A CN 103936126A CN 201410158521 A CN201410158521 A CN 201410158521A CN 103936126 A CN103936126 A CN 103936126A
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carbon black
minute
modified carbon
treating agent
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CN201410158521.XA
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CN103936126B (en
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章云
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Jixi Yuan Dao agricultural industry Science and Technology Ltd.
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Anhui Zhongri Agriculture Environmental Protection Technology Co Ltd
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Abstract

The invention discloses a modified carbon black/ferric aluminum polysilicate composite blue algae treating agent. The invention is characterized in that the treating agent is prepared from the following raw materials in parts by weight: 28-30 parts of ferric aluminum polysilicate, 18-20 parts of carbon black, 15-18 parts of sodium stearate, 19-21 parts of Cinnamomum camphora fruit, 17-19 parts of fulvic acid, 16-18 parts of aluminum sulfate, 20-22 parts of calcium oxide, 15-17 parts of sodium carbonate, 2-4 parts of malt, 3-5 parts of angelica, 2-4 parts of gromwell and 1-3 parts of picrorhiza rhizome. The treating agent can efficiently kill blue algae in a short time, and is simple and easy to implement.

Description

A kind of modified carbon black/poly aluminium iron silicate compound cyanophyte treatment agent and preparation method thereof
Technical field
The present invention relates to water-treatment technology field, be specifically related to a kind of modified carbon black/poly aluminium iron silicate compound cyanophyte treatment agent and preparation method thereof.
Background technology
In recent years, along with the continuous increase of China's size of population and developing rapidly of industrial and agricultural production, water requirement rapidly increases, and water pollutes more and more serious simultaneously.It is that world today's pollution is the most serious that water pollutes, one of pollution of hazardness maximum, China's quantity of wastewater effluent is large, cause the pollutent in the rivers and lakes water bodys such as Taihu Lake to grow with each passing day, pollution speed has exceeded the detergent power of lake body self, some of them are phosphorous, a large amount of discharges of nitrogenous compound, accelerate rivers and lakes eutrophication process, cause the particularly abnormal breeding growth of blue-green algae of algae, and form one deck blue-greenish colour and to have the offscum of stench taste be wawter bloom at the water surface, discharge stench, water quality is degenerated.Large-scale blue algae bloom, is called as " green tide ", exhausts water oxygen gas and cause the death of fish when serious.More seriously, in blue-green algae, some kind (as Microcystis aeruginosa) also can produce Microcystin (microcystins is called for short MCs), in about 50% green tide, contains a large amount of MCs.MCs, except directly fish, people and animals being produced murder by poisoning, is also the major incentive of liver cancer.
It is a complicated systems engineering that blue-green algae is administered engineering.The main method of taking at present still outside a large amount of manpower and materials of environmental input draw the mode that dirt removal clearly, resettlement contaminating enterprises etc. are transferred the pollution, not contaminated solution root; Aspect interior environmental improvement, method and the treatment agent of biological process (comprising microbial method, animal law, plant method), all kinds of improvement blue-green algaes of chemical method have in succession been there is although domestic, but be still difficult to so far obtain extensively, effectively application, major cause is that existing improvement technology is single, process is complicated, functional not high.
Summary of the invention
Object of the present invention is just to provide a kind of modified carbon black/poly aluminium iron silicate compound cyanophyte treatment agent and preparation method thereof, to overcome the deficiencies in the prior art.
The object of the present invention is achieved like this:
A kind of modified carbon black/poly aluminium iron silicate compound cyanophyte treatment agent, it is characterized in that, made by the raw material of following weight part: poly aluminium iron silicate 28-30, carbon black 18-20, sodium stearate 15-18, fruit of Yellow cinnamon 19-21, fulvic acid 17-19, Tai-Ace S 150 16-18, calcium oxide 20-22, sodium carbonate 15-17, Fructus Hordei Germinatus 2-4, root of Dahurain angelica 3-5, Asian puccoon 2-4, Rhizoma Picrorhizae 1-3.
The preparation method of described a kind of modified carbon black/poly aluminium iron silicate compound cyanophyte treatment agent, is characterized in that comprising the following steps:
(1) Fructus Hordei Germinatus, the root of Dahurain angelica, Asian puccoon, fruit of Yellow cinnamon, Rhizoma Picrorhizae decocted together in water 2-3 hour and filter, getting its filtrate and flood together with carbon black 30 minutes, drying, being ground into powder;
(2) filter residue of step (1) is sent in charring furnace, calcination processing 3-4 hour at 545-650 DEG C, takes out and dries, and is ground into powder;
(3) by sodium stearate and Tai-Ace S 150 mixing 30-40 minute, add calcium oxide mixing 45-50 minute, then add sodium carbonate mixing 50-60 minute;
(4) step (1), (2), (3) reaction mass and other remaining components are mixed to 120-150 minute.
The present invention has following beneficial effect: the present invention adopts herbal medicine to carbon black modified, and raw material sources environmental protection is pollution-free, and the cavernous structure that can not only improve carbon black increases adsorptive power, has improved flocculating and purifying performance; And can within the extremely short time, realize efficiently the killing of blue-green algae, simple.
Embodiment
Described a kind of modified carbon black/poly aluminium iron silicate compound cyanophyte treatment agent, it is characterized in that, made by the raw material of following weight part: poly aluminium iron silicate 29, carbon black 19, sodium stearate 18, fruit of Yellow cinnamon 21, fulvic acid 17, Tai-Ace S 150 16, calcium oxide 20, sodium carbonate 15, Fructus Hordei Germinatus 2, the root of Dahurain angelica 3, Asian puccoon 4, Rhizoma Picrorhizae 1.
Making method comprises the following steps:
(1) Fructus Hordei Germinatus, the root of Dahurain angelica, Asian puccoon, fruit of Yellow cinnamon, Rhizoma Picrorhizae decocted together in water 2-3 hour and filter, getting its filtrate and flood together with carbon black 30 minutes, drying, being ground into powder;
(2) filter residue of step (1) is sent in charring furnace, calcination processing 3-4 hour at 545-650 DEG C, takes out and dries, and is ground into powder;
(3) by sodium stearate and Tai-Ace S 150 mixing 30-40 minute, add calcium oxide mixing 45-50 minute, then add sodium carbonate mixing 50-60 minute;
(4) step (1), (2), (3) reaction mass and other remaining components are mixed to 120-150 minute.
Use blue-green algae treatment agent of the present invention as shown in the table to wastewater suspended substance decontamination effect improving:
Table 1 composite powder blue-green algae treatment agent wastewater suspended substance decontamination effect improving

Claims (2)

1. modified carbon black/poly aluminium iron silicate compound cyanophyte treatment agent, it is characterized in that, made by the raw material of following weight part: poly aluminium iron silicate 28-30, carbon black 18-20, sodium stearate 15-18, fruit of Yellow cinnamon 19-21, fulvic acid 17-19, Tai-Ace S 150 16-18, calcium oxide 20-22, sodium carbonate 15-17, Fructus Hordei Germinatus 2-4, root of Dahurain angelica 3-5, Asian puccoon 2-4, Rhizoma Picrorhizae 1-3.
2. the making method of a kind of modified carbon black/poly aluminium iron silicate compound cyanophyte treatment agent according to claim 1, is characterized in that comprising the following steps:
(1) Fructus Hordei Germinatus, the root of Dahurain angelica, Asian puccoon, fruit of Yellow cinnamon, Rhizoma Picrorhizae decocted together in water 2-3 hour and filter, getting its filtrate and flood together with carbon black 30 minutes, drying, being ground into powder;
(2) filter residue of step (1) is sent in charring furnace, calcination processing 3-4 hour at 545-650 DEG C, takes out and dries, and is ground into powder;
(3) by sodium stearate and Tai-Ace S 150 mixing 30-40 minute, add calcium oxide mixing 45-50 minute, then add sodium carbonate mixing 50-60 minute;
(4) step (1), (2), (3) reaction mass and other remaining components are mixed to 120-150 minute.
CN201410158521.XA 2014-04-18 2014-04-18 Modified carbon black/ferric aluminum polysilicate composite blue algae treating agent and manufacturing method thereof Active CN103936126B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105016437A (en) * 2015-07-22 2015-11-04 合肥一诺生物科技有限公司 Blue algae processing agent with water purification function and preparation method thereof
CN105104452A (en) * 2015-07-22 2015-12-02 合肥一诺生物科技有限公司 High-efficiency cyanobacteria treating agent, and preparation method thereof
WO2023170212A1 (en) 2022-03-09 2023-09-14 Naturalpond B.V. Combination for the inhibition of algae bloom-forming organisms

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1966419A (en) * 2006-11-22 2007-05-23 哈尔滨工业大学 Method for removing pollutant of water with synergistic effect of water treatment agent and microwave
CN101485339A (en) * 2008-08-04 2009-07-22 通州市瑞鑫机械有限公司 Solution for killing blue algae and preparation method thereof
CN101564053A (en) * 2009-04-28 2009-10-28 沈阳鸟王旅游发展有限公司 Algicidal pollution-free fuming agent
CN102948435A (en) * 2011-08-30 2013-03-06 林治 Pure plant Chinese herbal medicine aquaculture algae removal pesticide

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1966419A (en) * 2006-11-22 2007-05-23 哈尔滨工业大学 Method for removing pollutant of water with synergistic effect of water treatment agent and microwave
CN101485339A (en) * 2008-08-04 2009-07-22 通州市瑞鑫机械有限公司 Solution for killing blue algae and preparation method thereof
CN101564053A (en) * 2009-04-28 2009-10-28 沈阳鸟王旅游发展有限公司 Algicidal pollution-free fuming agent
CN102948435A (en) * 2011-08-30 2013-03-06 林治 Pure plant Chinese herbal medicine aquaculture algae removal pesticide

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
张慧弟: "粉煤灰基絮凝剂的制备及含酚废水的处理", 《中国优秀硕士学位论文全文数据库 工程科技I辑》, no. 9, 15 September 2009 (2009-09-15), pages 21 - 25 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105016437A (en) * 2015-07-22 2015-11-04 合肥一诺生物科技有限公司 Blue algae processing agent with water purification function and preparation method thereof
CN105104452A (en) * 2015-07-22 2015-12-02 合肥一诺生物科技有限公司 High-efficiency cyanobacteria treating agent, and preparation method thereof
WO2023170212A1 (en) 2022-03-09 2023-09-14 Naturalpond B.V. Combination for the inhibition of algae bloom-forming organisms
NL2031192B1 (en) * 2022-03-09 2023-09-19 Naturalpond B V Combination for the inhibition of algae bloom-forming organisms

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Address after: 242000 Gao Yang village, Huayang Town, Jixi County, Xuancheng, Anhui (National Grain Reserve Bank)

Patentee after: Jixi Yuan Dao agricultural industry Science and Technology Ltd.

Address before: 241000 international student Park 320, Wuhu economic and Technological Development Zone, Anhui

Patentee before: ANHUI ZHONGRI AGRICULTURE ENVIRONMENTAL TECHNOLOGY CO., LTD.

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