CN103751943A - Fire extinguishing composition containing nitrogenous organic compound - Google Patents
Fire extinguishing composition containing nitrogenous organic compound Download PDFInfo
- Publication number
- CN103751943A CN103751943A CN201410012973.7A CN201410012973A CN103751943A CN 103751943 A CN103751943 A CN 103751943A CN 201410012973 A CN201410012973 A CN 201410012973A CN 103751943 A CN103751943 A CN 103751943A
- Authority
- CN
- China
- Prior art keywords
- fire
- organic compound
- acid
- extinguishing
- hydrazine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- -1 nitrogenous organic compound Chemical class 0.000 title claims abstract description 94
- 239000000203 mixture Substances 0.000 title claims abstract description 15
- 238000002485 combustion reaction Methods 0.000 claims abstract description 9
- 239000002245 particle Substances 0.000 claims abstract description 8
- 239000002131 composite material Substances 0.000 claims description 46
- OAKJQQAXSVQMHS-UHFFFAOYSA-N hydrazine Substances NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 22
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 claims description 14
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 12
- 239000000654 additive Substances 0.000 claims description 12
- 230000000996 additive effect Effects 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 11
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 10
- 235000013877 carbamide Nutrition 0.000 claims description 10
- 239000003063 flame retardant Substances 0.000 claims description 10
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 claims description 8
- PCLIMKBDDGJMGD-UHFFFAOYSA-N N-bromosuccinimide Chemical compound BrN1C(=O)CCC1=O PCLIMKBDDGJMGD-UHFFFAOYSA-N 0.000 claims description 8
- JRNVZBWKYDBUCA-UHFFFAOYSA-N N-chlorosuccinimide Chemical compound ClN1C(=O)CCC1=O JRNVZBWKYDBUCA-UHFFFAOYSA-N 0.000 claims description 8
- IQFYYKKMVGJFEH-XLPZGREQSA-N Thymidine Chemical compound O=C1NC(=O)C(C)=CN1[C@@H]1O[C@H](CO)[C@@H](O)C1 IQFYYKKMVGJFEH-XLPZGREQSA-N 0.000 claims description 8
- 150000001412 amines Chemical class 0.000 claims description 8
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 8
- OVBPIULPVIDEAO-LBPRGKRZSA-N folic acid Chemical compound C=1N=C2NC(N)=NC(=O)C2=NC=1CNC1=CC=C(C(=O)N[C@@H](CCC(O)=O)C(O)=O)C=C1 OVBPIULPVIDEAO-LBPRGKRZSA-N 0.000 claims description 8
- 239000003814 drug Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 claims description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- DMLAVOWQYNRWNQ-UHFFFAOYSA-N azobenzene Chemical compound C1=CC=CC=C1N=NC1=CC=CC=C1 DMLAVOWQYNRWNQ-UHFFFAOYSA-N 0.000 claims description 6
- JFDZBHWFFUWGJE-UHFFFAOYSA-N benzonitrile Chemical compound N#CC1=CC=CC=C1 JFDZBHWFFUWGJE-UHFFFAOYSA-N 0.000 claims description 6
- 239000004202 carbamide Substances 0.000 claims description 6
- BPMFZUMJYQTVII-UHFFFAOYSA-N guanidinoacetic acid Chemical compound NC(=N)NCC(O)=O BPMFZUMJYQTVII-UHFFFAOYSA-N 0.000 claims description 6
- 150000007857 hydrazones Chemical class 0.000 claims description 6
- 150000002923 oximes Chemical class 0.000 claims description 6
- 229920006391 phthalonitrile polymer Polymers 0.000 claims description 6
- GHOKWGTUZJEAQD-ZETCQYMHSA-N (D)-(+)-Pantothenic acid Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCC(O)=O GHOKWGTUZJEAQD-ZETCQYMHSA-N 0.000 claims description 4
- FZENGILVLUJGJX-NSCUHMNNSA-N (E)-acetaldehyde oxime Chemical compound C\C=N\O FZENGILVLUJGJX-NSCUHMNNSA-N 0.000 claims description 4
- IAKHMKGGTNLKSZ-INIZCTEOSA-N (S)-colchicine Chemical compound C1([C@@H](NC(C)=O)CC2)=CC(=O)C(OC)=CC=C1C1=C2C=C(OC)C(OC)=C1OC IAKHMKGGTNLKSZ-INIZCTEOSA-N 0.000 claims description 4
- LTWIBTYLSRDGHP-HCURTGQUSA-N 1,2-bis[(e)-(4-chlorophenyl)methylideneamino]guanidine;hydrochloride Chemical compound [Cl-].C=1C=C(Cl)C=CC=1\C=N\N=C(/N)N\[NH+]=C\C1=CC=C(Cl)C=C1 LTWIBTYLSRDGHP-HCURTGQUSA-N 0.000 claims description 4
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 claims description 4
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 claims description 4
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 claims description 4
- LUBJCRLGQSPQNN-UHFFFAOYSA-N 1-Phenylurea Chemical compound NC(=O)NC1=CC=CC=C1 LUBJCRLGQSPQNN-UHFFFAOYSA-N 0.000 claims description 4
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 claims description 4
- UZJZIZFCQFZDHP-UHFFFAOYSA-N 3-nitrobenzene-1,2-dicarbonitrile Chemical compound [O-][N+](=O)C1=CC=CC(C#N)=C1C#N UZJZIZFCQFZDHP-UHFFFAOYSA-N 0.000 claims description 4
- VHYFNPMBLIVWCW-UHFFFAOYSA-N 4-Dimethylaminopyridine Chemical compound CN(C)C1=CC=NC=C1 VHYFNPMBLIVWCW-UHFFFAOYSA-N 0.000 claims description 4
- ZSTKHSQDNIGFLM-UHFFFAOYSA-N 5-methoxy-N,N-dimethyltryptamine Chemical compound COC1=CC=C2NC=C(CCN(C)C)C2=C1 ZSTKHSQDNIGFLM-UHFFFAOYSA-N 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 4
- 108010011485 Aspartame Proteins 0.000 claims description 4
- DWRXFEITVBNRMK-UHFFFAOYSA-N Beta-D-1-Arabinofuranosylthymine Natural products O=C1NC(=O)C(C)=CN1C1C(O)C(O)C(CO)O1 DWRXFEITVBNRMK-UHFFFAOYSA-N 0.000 claims description 4
- 244000025254 Cannabis sativa Species 0.000 claims description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 4
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 claims description 4
- RPTUSVTUFVMDQK-UHFFFAOYSA-N Hidralazin Chemical compound C1=CC=C2C(NN)=NN=CC2=C1 RPTUSVTUFVMDQK-UHFFFAOYSA-N 0.000 claims description 4
- FFEARJCKVFRZRR-BYPYZUCNSA-N L-methionine Chemical compound CSCC[C@H](N)C(O)=O FFEARJCKVFRZRR-BYPYZUCNSA-N 0.000 claims description 4
- DATAGRPVKZEWHA-YFKPBYRVSA-N N(5)-ethyl-L-glutamine Chemical compound CCNC(=O)CC[C@H]([NH3+])C([O-])=O DATAGRPVKZEWHA-YFKPBYRVSA-N 0.000 claims description 4
- DMULVCHRPCFFGV-UHFFFAOYSA-N N,N-dimethyltryptamine Chemical compound C1=CC=C2C(CCN(C)C)=CNC2=C1 DMULVCHRPCFFGV-UHFFFAOYSA-N 0.000 claims description 4
- OVBPIULPVIDEAO-UHFFFAOYSA-N N-Pteroyl-L-glutaminsaeure Natural products C=1N=C2NC(N)=NC(=O)C2=NC=1CNC1=CC=C(C(=O)NC(CCC(O)=O)C(O)=O)C=C1 OVBPIULPVIDEAO-UHFFFAOYSA-N 0.000 claims description 4
- QIAFMBKCNZACKA-UHFFFAOYSA-N N-benzoylglycine Chemical compound OC(=O)CNC(=O)C1=CC=CC=C1 QIAFMBKCNZACKA-UHFFFAOYSA-N 0.000 claims description 4
- FZERHIULMFGESH-UHFFFAOYSA-N N-phenylacetamide Chemical compound CC(=O)NC1=CC=CC=C1 FZERHIULMFGESH-UHFFFAOYSA-N 0.000 claims description 4
- LCTONWCANYUPML-UHFFFAOYSA-N Pyruvic acid Chemical compound CC(=O)C(O)=O LCTONWCANYUPML-UHFFFAOYSA-N 0.000 claims description 4
- ISAKRJDGNUQOIC-UHFFFAOYSA-N Uracil Chemical compound O=C1C=CNC(=O)N1 ISAKRJDGNUQOIC-UHFFFAOYSA-N 0.000 claims description 4
- DRTQHJPVMGBUCF-XVFCMESISA-N Uridine Chemical compound O[C@@H]1[C@H](O)[C@@H](CO)O[C@H]1N1C(=O)NC(=O)C=C1 DRTQHJPVMGBUCF-XVFCMESISA-N 0.000 claims description 4
- XCCTYIAWTASOJW-XVFCMESISA-N Uridine-5'-Diphosphate Chemical compound O[C@@H]1[C@H](O)[C@@H](COP(O)(=O)OP(O)(O)=O)O[C@H]1N1C(=O)NC(=O)C=C1 XCCTYIAWTASOJW-XVFCMESISA-N 0.000 claims description 4
- DZHMRSPXDUUJER-UHFFFAOYSA-N [amino(hydroxy)methylidene]azanium;dihydrogen phosphate Chemical compound NC(N)=O.OP(O)(O)=O DZHMRSPXDUUJER-UHFFFAOYSA-N 0.000 claims description 4
- YASYVMFAVPKPKE-UHFFFAOYSA-N acephate Chemical compound COP(=O)(SC)NC(C)=O YASYVMFAVPKPKE-UHFFFAOYSA-N 0.000 claims description 4
- HIMXGTXNXJYFGB-UHFFFAOYSA-N alloxan Chemical compound O=C1NC(=O)C(=O)C(=O)N1 HIMXGTXNXJYFGB-UHFFFAOYSA-N 0.000 claims description 4
- BIVUUOPIAYRCAP-UHFFFAOYSA-N aminoazanium;chloride Chemical compound Cl.NN BIVUUOPIAYRCAP-UHFFFAOYSA-N 0.000 claims description 4
- 229960004050 aminobenzoic acid Drugs 0.000 claims description 4
- HAMNKKUPIHEESI-UHFFFAOYSA-N aminoguanidine Chemical compound NNC(N)=N HAMNKKUPIHEESI-UHFFFAOYSA-N 0.000 claims description 4
- RWZYAGGXGHYGMB-UHFFFAOYSA-N anthranilic acid Chemical compound NC1=CC=CC=C1C(O)=O RWZYAGGXGHYGMB-UHFFFAOYSA-N 0.000 claims description 4
- IAOZJIPTCAWIRG-QWRGUYRKSA-N aspartame Chemical compound OC(=O)C[C@H](N)C(=O)N[C@H](C(=O)OC)CC1=CC=CC=C1 IAOZJIPTCAWIRG-QWRGUYRKSA-N 0.000 claims description 4
- 239000000605 aspartame Substances 0.000 claims description 4
- 229960003438 aspartame Drugs 0.000 claims description 4
- 235000010357 aspartame Nutrition 0.000 claims description 4
- QYCSNMDOZNUZIT-UHFFFAOYSA-N benzhydrylidenehydrazine Chemical class C=1C=CC=CC=1C(=NN)C1=CC=CC=C1 QYCSNMDOZNUZIT-UHFFFAOYSA-N 0.000 claims description 4
- MSWZFWKMSRAUBD-UHFFFAOYSA-N beta-D-galactosamine Natural products NC1C(O)OC(CO)C(O)C1O MSWZFWKMSRAUBD-UHFFFAOYSA-N 0.000 claims description 4
- IQFYYKKMVGJFEH-UHFFFAOYSA-N beta-L-thymidine Natural products O=C1NC(=O)C(C)=CN1C1OC(CO)C(O)C1 IQFYYKKMVGJFEH-UHFFFAOYSA-N 0.000 claims description 4
- VTTONGPRPXSUTJ-UHFFFAOYSA-N bufotenin Chemical compound C1=C(O)C=C2C(CCN(C)C)=CNC2=C1 VTTONGPRPXSUTJ-UHFFFAOYSA-N 0.000 claims description 4
- 229960004261 cefotaxime Drugs 0.000 claims description 4
- 239000013078 crystal Substances 0.000 claims description 4
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 4
- VEZUQRBDRNJBJY-UHFFFAOYSA-N cyclohexanone oxime Chemical compound ON=C1CCCCC1 VEZUQRBDRNJBJY-UHFFFAOYSA-N 0.000 claims description 4
- FSEUPUDHEBLWJY-HWKANZROSA-N diacetylmonoxime Chemical compound CC(=O)C(\C)=N\O FSEUPUDHEBLWJY-HWKANZROSA-N 0.000 claims description 4
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 claims description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 4
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 claims description 4
- 229960000304 folic acid Drugs 0.000 claims description 4
- 235000019152 folic acid Nutrition 0.000 claims description 4
- 239000011724 folic acid Substances 0.000 claims description 4
- GPXLRLUVLMHHIK-UHFFFAOYSA-N forchlorfenuron Chemical compound C1=NC(Cl)=CC(NC(=O)NC=2C=CC=CC=2)=C1 GPXLRLUVLMHHIK-UHFFFAOYSA-N 0.000 claims description 4
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 4
- 150000002357 guanidines Chemical class 0.000 claims description 4
- 150000002429 hydrazines Chemical class 0.000 claims description 4
- DMCPFOBLJMLSNX-UHFFFAOYSA-N indole-3-acetonitrile Chemical compound C1=CC=C2C(CC#N)=CNC2=C1 DMCPFOBLJMLSNX-UHFFFAOYSA-N 0.000 claims description 4
- 229940018564 m-phenylenediamine Drugs 0.000 claims description 4
- 229930182817 methionine Natural products 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- YJMNOKOLADGBKA-UHFFFAOYSA-N naphthalene-1-carbonitrile Chemical compound C1=CC=C2C(C#N)=CC=CC2=C1 YJMNOKOLADGBKA-UHFFFAOYSA-N 0.000 claims description 4
- 150000002825 nitriles Chemical class 0.000 claims description 4
- 150000002828 nitro derivatives Chemical class 0.000 claims description 4
- 150000002894 organic compounds Chemical class 0.000 claims description 4
- 229960005206 pyrazinamide Drugs 0.000 claims description 4
- IPEHBUMCGVEMRF-UHFFFAOYSA-N pyrazinecarboxamide Chemical compound NC(=O)C1=CN=CC=N1 IPEHBUMCGVEMRF-UHFFFAOYSA-N 0.000 claims description 4
- 229960005445 robenidine hydrochloride Drugs 0.000 claims description 4
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 claims description 4
- 150000003349 semicarbazides Chemical class 0.000 claims description 4
- QZAYGJVTTNCVMB-UHFFFAOYSA-N serotonin Chemical compound C1=C(O)C=C2C(CCN)=CNC2=C1 QZAYGJVTTNCVMB-UHFFFAOYSA-N 0.000 claims description 4
- 229940104230 thymidine Drugs 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- CXBMCYHAMVGWJQ-CABCVRRESA-N (1,3-dioxo-4,5,6,7-tetrahydroisoindol-2-yl)methyl (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O CXBMCYHAMVGWJQ-CABCVRRESA-N 0.000 claims description 2
- AELCINSCMGFISI-DTWKUNHWSA-N (1R,2S)-tranylcypromine Chemical compound N[C@@H]1C[C@H]1C1=CC=CC=C1 AELCINSCMGFISI-DTWKUNHWSA-N 0.000 claims description 2
- WAKHLWOJMHVUJC-FYWRMAATSA-N (2e)-2-hydroxyimino-1,2-diphenylethanol Chemical compound C=1C=CC=CC=1C(=N/O)\C(O)C1=CC=CC=C1 WAKHLWOJMHVUJC-FYWRMAATSA-N 0.000 claims description 2
- SRADVTGBACJUSV-BYPYZUCNSA-N (2s)-2-(methylideneamino)pentanedioic acid Chemical compound OC(=O)CC[C@H](N=C)C(O)=O SRADVTGBACJUSV-BYPYZUCNSA-N 0.000 claims description 2
- AJYLWDRNNNHBEV-VKHMYHEASA-N (2s)-2-hydrazinylbutanoic acid Chemical compound CC[C@H](NN)C(O)=O AJYLWDRNNNHBEV-VKHMYHEASA-N 0.000 claims description 2
- KYTWXIARANQMCA-PGYIPVOXSA-N (3r,4s,5s,6r,7r,9r,10z,11s,12r,13s,14r)-6-[(2s,3r,4s,6r)-4-(dimethylamino)-3-hydroxy-6-methyloxan-2-yl]oxy-14-ethyl-7,12,13-trihydroxy-10-hydroxyimino-4-[(2r,4r,5s,6s)-5-hydroxy-4-methoxy-4,6-dimethyloxan-2-yl]oxy-3,5,7,9,11,13-hexamethyl-oxacyclotetradec Chemical compound O([C@@H]1[C@@H](C)C(=O)O[C@@H]([C@@]([C@H](O)[C@@H](C)C(=N\O)/[C@H](C)C[C@@](C)(O)[C@H](O[C@H]2[C@@H]([C@H](C[C@@H](C)O2)N(C)C)O)[C@H]1C)(C)O)CC)[C@H]1C[C@@](C)(OC)[C@@H](O)[C@H](C)O1 KYTWXIARANQMCA-PGYIPVOXSA-N 0.000 claims description 2
- ZYMCBJWUWHHVRX-UHFFFAOYSA-N (4-nitrophenyl)-phenylmethanone Chemical compound C1=CC([N+](=O)[O-])=CC=C1C(=O)C1=CC=CC=C1 ZYMCBJWUWHHVRX-UHFFFAOYSA-N 0.000 claims description 2
- IQVNEKKDSLOHHK-FNCQTZNRSA-N (E,E)-hydramethylnon Chemical compound N1CC(C)(C)CNC1=NN=C(/C=C/C=1C=CC(=CC=1)C(F)(F)F)\C=C\C1=CC=C(C(F)(F)F)C=C1 IQVNEKKDSLOHHK-FNCQTZNRSA-N 0.000 claims description 2
- LJHFIVQEAFAURQ-ZPUQHVIOSA-N (NE)-N-[(2E)-2-hydroxyiminoethylidene]hydroxylamine Chemical compound O\N=C\C=N\O LJHFIVQEAFAURQ-ZPUQHVIOSA-N 0.000 claims description 2
- OVXMBIVWNJDDSM-UHFFFAOYSA-N (benzhydrylideneamino) 2,6-bis[(4,6-dimethoxypyrimidin-2-yl)oxy]benzoate Chemical compound COC1=CC(OC)=NC(OC=2C(=C(OC=3N=C(OC)C=C(OC)N=3)C=CC=2)C(=O)ON=C(C=2C=CC=CC=2)C=2C=CC=CC=2)=N1 OVXMBIVWNJDDSM-UHFFFAOYSA-N 0.000 claims description 2
- XLONNWGCEFSFTN-UHFFFAOYSA-N (diaminomethylideneamino)azanium;hydrogen sulfate Chemical compound NC(N)=N[NH3+].OS([O-])(=O)=O XLONNWGCEFSFTN-UHFFFAOYSA-N 0.000 claims description 2
- LPKCJFLRJWWIDI-UHFFFAOYSA-N (diaminomethylideneamino)phosphonic acid Chemical compound NC(N)=NP(O)(O)=O LPKCJFLRJWWIDI-UHFFFAOYSA-N 0.000 claims description 2
- JHNRZXQVBKRYKN-VQHVLOKHSA-N (ne)-n-(1-phenylethylidene)hydroxylamine Chemical compound O\N=C(/C)C1=CC=CC=C1 JHNRZXQVBKRYKN-VQHVLOKHSA-N 0.000 claims description 2
- PTBKFATYSVLSSD-UTCJRWHESA-N (nz)-n-[(5-nitrofuran-2-yl)methylidene]hydroxylamine Chemical compound O\N=C/C1=CC=C([N+]([O-])=O)O1 PTBKFATYSVLSSD-UTCJRWHESA-N 0.000 claims description 2
- DPZSNGJNFHWQDC-ARJAWSKDSA-N (z)-2,3-diaminobut-2-enedinitrile Chemical compound N#CC(/N)=C(/N)C#N DPZSNGJNFHWQDC-ARJAWSKDSA-N 0.000 claims description 2
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 claims description 2
- DIIIISSCIXVANO-UHFFFAOYSA-N 1,2-Dimethylhydrazine Chemical compound CNNC DIIIISSCIXVANO-UHFFFAOYSA-N 0.000 claims description 2
- IWKMQNKKYZERHI-UHFFFAOYSA-N 1,2-bis(2-chlorophenyl)hydrazine Chemical compound ClC1=CC=CC=C1NNC1=CC=CC=C1Cl IWKMQNKKYZERHI-UHFFFAOYSA-N 0.000 claims description 2
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 claims description 2
- UOFGSWVZMUXXIY-UHFFFAOYSA-N 1,5-Diphenyl-3-thiocarbazone Chemical compound C=1C=CC=CC=1N=NC(=S)NNC1=CC=CC=C1 UOFGSWVZMUXXIY-UHFFFAOYSA-N 0.000 claims description 2
- WBQDXWRDENKVSJ-UHFFFAOYSA-N 1-(dichloromethyl)-3-methyl-1-phenylurea Chemical compound CNC(=O)N(C(Cl)Cl)C1=CC=CC=C1 WBQDXWRDENKVSJ-UHFFFAOYSA-N 0.000 claims description 2
- ZFWAHZCOKGWUIT-UHFFFAOYSA-N 1-anilino-3-phenyliminourea Chemical compound C=1C=CC=CC=1N=NC(=O)NNC1=CC=CC=C1 ZFWAHZCOKGWUIT-UHFFFAOYSA-N 0.000 claims description 2
- ZQGAXHXHVKVERC-UHFFFAOYSA-N 1-benzofuran-2-carbonitrile Chemical compound C1=CC=C2OC(C#N)=CC2=C1 ZQGAXHXHVKVERC-UHFFFAOYSA-N 0.000 claims description 2
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- NJPPVKZQTLUDBO-UHFFFAOYSA-N novaluron Chemical compound C1=C(Cl)C(OC(F)(F)C(OC(F)(F)F)F)=CC=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F NJPPVKZQTLUDBO-UHFFFAOYSA-N 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical group CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 2
- 229960003104 ornithine Drugs 0.000 claims description 2
- YBSLUBPQYDULIZ-UHFFFAOYSA-N oxalic acid;urea Chemical compound NC(N)=O.OC(=O)C(O)=O YBSLUBPQYDULIZ-UHFFFAOYSA-N 0.000 claims description 2
- 125000003431 oxalo group Chemical group 0.000 claims description 2
- KHPXUQMNIQBQEV-UHFFFAOYSA-N oxaloacetic acid Chemical compound OC(=O)CC(=O)C(O)=O KHPXUQMNIQBQEV-UHFFFAOYSA-N 0.000 claims description 2
- 125000005646 oximino group Chemical group 0.000 claims description 2
- 125000000636 p-nitrophenyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)[N+]([O-])=O 0.000 claims description 2
- 229940055726 pantothenic acid Drugs 0.000 claims description 2
- 235000019161 pantothenic acid Nutrition 0.000 claims description 2
- 239000011713 pantothenic acid Substances 0.000 claims description 2
- LNHURPJLTHSVMU-UHFFFAOYSA-N para-Benzoquinone dioxime Chemical compound ON=C1C=CC(=NO)C=C1 LNHURPJLTHSVMU-UHFFFAOYSA-N 0.000 claims description 2
- 229920001568 phenolic resin Polymers 0.000 claims description 2
- 239000005011 phenolic resin Substances 0.000 claims description 2
- HKOOXMFOFWEVGF-UHFFFAOYSA-N phenylhydrazine Chemical compound NNC1=CC=CC=C1 HKOOXMFOFWEVGF-UHFFFAOYSA-N 0.000 claims description 2
- 229940067157 phenylhydrazine Drugs 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 239000011574 phosphorus Substances 0.000 claims description 2
- LFSXCDWNBUNEEM-UHFFFAOYSA-N phthalazine Chemical class C1=NN=CC2=CC=CC=C21 LFSXCDWNBUNEEM-UHFFFAOYSA-N 0.000 claims description 2
- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical compound C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 claims description 2
- XQZYPMVTSDWCCE-UHFFFAOYSA-N phthalonitrile Chemical compound N#CC1=CC=CC=C1C#N XQZYPMVTSDWCCE-UHFFFAOYSA-N 0.000 claims description 2
- CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 claims description 2
- 229920000647 polyepoxide Polymers 0.000 claims description 2
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 claims description 2
- 229920006375 polyphtalamide Polymers 0.000 claims description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 2
- 235000019353 potassium silicate Nutrition 0.000 claims description 2
- 235000019260 propionic acid Nutrition 0.000 claims description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- YQUVCSBJEUQKSH-UHFFFAOYSA-N protochatechuic acid Natural products OC(=O)C1=CC=C(O)C(O)=C1 YQUVCSBJEUQKSH-UHFFFAOYSA-N 0.000 claims description 2
- 150000003217 pyrazoles Chemical class 0.000 claims description 2
- 229940107700 pyruvic acid Drugs 0.000 claims description 2
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 2
- XMVJITFPVVRMHC-UHFFFAOYSA-N roxarsone Chemical compound OC1=CC=C([As](O)(O)=O)C=C1[N+]([O-])=O XMVJITFPVVRMHC-UHFFFAOYSA-N 0.000 claims description 2
- 229960003052 roxarsone Drugs 0.000 claims description 2
- 229960002052 salbutamol Drugs 0.000 claims description 2
- 229960000581 salicylamide Drugs 0.000 claims description 2
- 229940043230 sarcosine Drugs 0.000 claims description 2
- IYKVLICPFCEZOF-UHFFFAOYSA-N selenourea Chemical compound NC(N)=[Se] IYKVLICPFCEZOF-UHFFFAOYSA-N 0.000 claims description 2
- 239000004208 shellac Substances 0.000 claims description 2
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 claims description 2
- 229940113147 shellac Drugs 0.000 claims description 2
- 235000013874 shellac Nutrition 0.000 claims description 2
- 229910000077 silane Inorganic materials 0.000 claims description 2
- BEOOHQFXGBMRKU-UHFFFAOYSA-N sodium cyanoborohydride Chemical compound [Na+].[B-]C#N BEOOHQFXGBMRKU-UHFFFAOYSA-N 0.000 claims description 2
- 229940010747 sodium hyaluronate Drugs 0.000 claims description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 2
- YWIVKILSMZOHHF-QJZPQSOGSA-N sodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4r,5s,6r)-3-acetamido-2-[(2s,3s,4r,5r,6r)-6-[(2r,3r,4r,5s,6r)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2- Chemical compound [Na+].CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 YWIVKILSMZOHHF-QJZPQSOGSA-N 0.000 claims description 2
- 229940031352 solanine Drugs 0.000 claims description 2
- ZGVSETXHNHBTRK-OTYSSXIJSA-N solanine Chemical compound O([C@H]1[C@@H](O)[C@@H](CO)O[C@H]([C@@H]1O[C@@H]1[C@@H]([C@H](O)[C@@H](O)[C@H](C)O1)O)O[C@@H]1CC2=CC[C@H]3[C@@H]4C[C@@H]5N6C[C@@H](C)CC[C@@H]6[C@H]([C@@H]5[C@@]4(C)CC[C@@H]3[C@@]2(C)CC1)C)[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O ZGVSETXHNHBTRK-OTYSSXIJSA-N 0.000 claims description 2
- 239000008107 starch Substances 0.000 claims description 2
- 235000019698 starch Nutrition 0.000 claims description 2
- 229960002385 streptomycin sulfate Drugs 0.000 claims description 2
- VNOYUJKHFWYWIR-ITIYDSSPSA-N succinyl-CoA Chemical compound O[C@@H]1[C@H](OP(O)(O)=O)[C@@H](COP(O)(=O)OP(O)(=O)OCC(C)(C)[C@@H](O)C(=O)NCCC(=O)NCCSC(=O)CCC(O)=O)O[C@H]1N1C2=NC=NC(N)=C2N=C1 VNOYUJKHFWYWIR-ITIYDSSPSA-N 0.000 claims description 2
- BRBKOPJOKNSWSG-UHFFFAOYSA-N sulfaguanidine Chemical compound NC(=N)NS(=O)(=O)C1=CC=C(N)C=C1 BRBKOPJOKNSWSG-UHFFFAOYSA-N 0.000 claims description 2
- 229960004257 sulfaguanidine Drugs 0.000 claims description 2
- 229960005404 sulfamethoxazole Drugs 0.000 claims description 2
- 229940124530 sulfonamide Drugs 0.000 claims description 2
- 150000003456 sulfonamides Chemical class 0.000 claims description 2
- JLKIGFTWXXRPMT-UHFFFAOYSA-N sulphamethoxazole Chemical compound O1C(C)=CC(NS(=O)(=O)C=2C=CC(N)=CC=2)=N1 JLKIGFTWXXRPMT-UHFFFAOYSA-N 0.000 claims description 2
- 229960005199 tetramethrin Drugs 0.000 claims description 2
- 229940026510 theanine Drugs 0.000 claims description 2
- 235000019157 thiamine Nutrition 0.000 claims description 2
- 150000003544 thiamines Chemical class 0.000 claims description 2
- OTVAEFIXJLOWRX-NXEZZACHSA-N thiamphenicol Chemical compound CS(=O)(=O)C1=CC=C([C@@H](O)[C@@H](CO)NC(=O)C(Cl)Cl)C=C1 OTVAEFIXJLOWRX-NXEZZACHSA-N 0.000 claims description 2
- 229960003053 thiamphenicol Drugs 0.000 claims description 2
- YUKQRDCYNOVPGJ-UHFFFAOYSA-N thioacetamide Chemical compound CC(N)=S YUKQRDCYNOVPGJ-UHFFFAOYSA-N 0.000 claims description 2
- 108010050939 thrombocytin Proteins 0.000 claims description 2
- OUDSBRTVNLOZBN-UHFFFAOYSA-N tolazamide Chemical compound C1=CC(C)=CC=C1S(=O)(=O)NC(=O)NN1CCCCCC1 OUDSBRTVNLOZBN-UHFFFAOYSA-N 0.000 claims description 2
- 229960002277 tolazamide Drugs 0.000 claims description 2
- DQFPEYARZIQXRM-LTGZKZEYSA-N tralkoxydim Chemical compound C1C(=O)C(C(/CC)=N/OCC)=C(O)CC1C1=C(C)C=C(C)C=C1C DQFPEYARZIQXRM-LTGZKZEYSA-N 0.000 claims description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 2
- UYPYRKYUKCHHIB-UHFFFAOYSA-N trimethylamine N-oxide Chemical compound C[N+](C)(C)[O-] UYPYRKYUKCHHIB-UHFFFAOYSA-N 0.000 claims description 2
- 239000000015 trinitrotoluene Substances 0.000 claims description 2
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 claims description 2
- 229940035893 uracil Drugs 0.000 claims description 2
- DRTQHJPVMGBUCF-UHFFFAOYSA-N uracil arabinoside Natural products OC1C(O)C(CO)OC1N1C(=O)NC(=O)C=C1 DRTQHJPVMGBUCF-UHFFFAOYSA-N 0.000 claims description 2
- 150000003672 ureas Chemical class 0.000 claims description 2
- 229940045145 uridine Drugs 0.000 claims description 2
- WKOLLVMJNQIZCI-UHFFFAOYSA-N vanillic acid Chemical compound COC1=CC(C(O)=O)=CC=C1O WKOLLVMJNQIZCI-UHFFFAOYSA-N 0.000 claims description 2
- TUUBOHWZSQXCSW-UHFFFAOYSA-N vanillic acid Natural products COC1=CC(O)=CC(C(O)=O)=C1 TUUBOHWZSQXCSW-UHFFFAOYSA-N 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- ORZHVTYKPFFVMG-UHFFFAOYSA-N xylenol orange Chemical compound OC(=O)CN(CC(O)=O)CC1=C(O)C(C)=CC(C2(C3=CC=CC=C3S(=O)(=O)O2)C=2C=C(CN(CC(O)=O)CC(O)=O)C(O)=C(C)C=2)=C1 ORZHVTYKPFFVMG-UHFFFAOYSA-N 0.000 claims description 2
- ZAFYATHCZYHLPB-UHFFFAOYSA-N zolpidem Chemical compound N1=C2C=CC(C)=CN2C(CC(=O)N(C)C)=C1C1=CC=C(C)C=C1 ZAFYATHCZYHLPB-UHFFFAOYSA-N 0.000 claims description 2
- 229960001475 zolpidem Drugs 0.000 claims description 2
- 150000003254 radicals Chemical class 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 6
- 239000000126 substance Substances 0.000 abstract description 5
- 230000002195 synergetic effect Effects 0.000 abstract description 2
- 230000005764 inhibitory process Effects 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 description 20
- 239000003795 chemical substances by application Substances 0.000 description 12
- 239000007789 gas Substances 0.000 description 11
- 239000000443 aerosol Substances 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000001816 cooling Methods 0.000 description 4
- 230000007246 mechanism Effects 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 229920004449 Halon® Polymers 0.000 description 2
- 239000004964 aerogel Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- QYNUQALWYRSVHF-OLZOCXBDSA-N (6R)-5,10-methylenetetrahydrofolic acid Chemical compound C([C@H]1CNC=2N=C(NC(=O)C=2N1C1)N)N1C1=CC=C(C(=O)N[C@@H](CCC(O)=O)C(O)=O)C=C1 QYNUQALWYRSVHF-OLZOCXBDSA-N 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- TUJKJAMUKRIRHC-UHFFFAOYSA-N hydroxyl Chemical compound [OH] TUJKJAMUKRIRHC-UHFFFAOYSA-N 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000009740 moulding (composite fabrication) Methods 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000006187 pill Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
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- 238000005507 spraying Methods 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
Landscapes
- Fire-Extinguishing Compositions (AREA)
Abstract
The invention relates to a fire extinguishing composition containing a nitrogenous organic compound. The fire extinguishing composition releases a lot of effective fire extinguishing particles by using heat generated by a pyrotechnic composition in combustion. The fire extinguishing composition containing the nitrogenous organic compound disclosed by the invention reacts at high temperature to generate free radical, and reacts with one or more of necessary free radicals O., OH., and H. for chain combustion reaction through free radical, so that chain combustion reaction is cut off, and meanwhile, the fire extinguishing effect is achieved by physical and chemical inhibition in common. At the same time, the fire extinguishing composition generates a synergistic effect together with the pyrotechnic composition, the fire extinguishing efficiency of the fire extinguishing agent is further improved, and the effective fire extinguishing time is greatly shortened.
Description
Technical field
The invention belongs to aerosol fire-extinguishing technical field, particularly a kind of extinguishment combination with hot gas sol.
Background technology
Since Montreal, CAN pact in 1987 proposes to replace the objectives of halon fire agent to various countries, countries in the world are all in the research of being devoted to new fire-fighting technique, should fire-fighting efficiency high, the fire-fighting technique of environmentally safe be the direction that people make great efforts again.
Gas extinguishing system, powder extinguishing system and water system fire extinguishing system etc. are because the substitute that environmental sound is used as halon fire agent has obtained being widely used.Carbon dioxide, the extinguishing mechanism of the inert gas fire-fighting systems such as IG541 is mainly physics fire extinguishing, the fire smothering by the oxygen concentration of reduction ignition zone, this fire-fighting mode easily threatens to personal safety, powder extinguishing system is that the powder by spraying under gas-pressurized effect contacts with flame, there is physical chemistry inhibitory action and put out a fire, water fog sprinkler is cooling by thin water smoke, suffocating and completely cutting off thermal-radiating triple role is issued to control fire, the object that suppresses fire and stamp out a fire.
But, these fire extinguishing systems all need hig pressure storage, not only volume is large, in storage process, also there is the danger of physical explosion, document " safety analysis of gas extinguishing system " (fire science and technology 200221(5)) analyzed the existing danger of gas extinguishing system, and enumerated the security incident that stored-pressure type gas extinguishing system in use caused.
Existing hot-gas sol fire extinguishing agent mainly contains S type and K type extinguishing chemical, by its characteristic of property of comprehensive analysis, its extinguishing mechanism be hot-gas sol fire extinguishing agent utilize medicament burning occur redox reaction discharge a large amount of gas, active particle, by the chain-breaking reaction of active particle, the covering of a large amount of gases suffocates, and realizes the fire extinguishing object that chemistry combines with physics.Its weak point is that hot-gas sol fire extinguishing agent is when generation combustion reaction discharges hot aerosol, can discharge a large amount of heat, may cause second-time burning, for effectively reducing device and aerocolloidal temperature, avoid occurring spot fire, need to increase cooling system, although the material that cools of existing condensed aerosol fire extinguishing device can reduce the temperature of product, also greatly weakened the extinguishing property of product simultaneously, in order to make up the loss on the extinguishing property that cooling system brings, a lot of products or reduced extinguishing grade, continue to strengthen the quality of actual extinguishing chemical, small product size is increased, service efficiency declines, this causes apparatus structure complicated heavy, technological process complexity, cost is high, and spout temperature is higher, easily fire extinguishing personnel are damaged.
Summary of the invention
For the inherent shortcoming in the present situation of existing extinguishing device, particularly GAFES, the object of the present invention is to provide one safer, more efficient fire-extinguishing composite.
The technical solution used in the present invention is:
A fire-extinguishing composite that contains nitrogenous class organic compound, is characterized in that: described fire-extinguishing composite contains nitrogenous class organic compound; Described fire-extinguishing composite utilizes the burning of firework medicament to discharge a large amount of effective fire extinguishing particles.
Further, quality percentage composition >=35% of nitrogenous class organic compound in described fire-extinguishing composite.
Further, described nitrogenous class organic compound comprises one or more in nitro compound, amine, amide-type, (idol) diazonium compounds, (different) nitrile, isocyanide ester class, guanidine class, ureas, hydrazine class, hydrazone class, oximes.
Further, described nitro compound comprises: furazolidone, 2,4,6-tri-(trinitro-methyl)-1,3,5-triazine, 2,4-DNP, 3-[(4-nitrobenzophenone) carbamyl amino] propionic acid, Nilvadipine, aulin, 5-Nitro-2-propoxyaniline, trinitrotoluene, meta nitro aniline, trishydroxymethylnitromethane, hexanitroethane, p-nitrophenol, Clonazepam, roxarsone, nitroguanidine, nitrosobenzene.
Further, described aminated compounds comprises: dinitrophenol sodium, nitrosamine, carbodiimides, N, N-dimethyl-5-methoxytryptamine, 5-methoxyl group dimethyltryptamine, dimethyltryptamine, psilosin, bufotenine, thrombocytin, 5-hydroxyryptophan, parnitene, methylphenidate, salbutamol, Thiamphenicol, chapter amine hydrochlorate, folic acid, 5,10-CH2-THFA, N-chlorosuccinimide, N-bromo-succinimide, polyvinylpyrrolidone, the acid of card English, solanine, o-phenylenediamine, TMAO, galactosamine, Glucosamine, N-acetyl-glucosamine, HYG, streptomycin sulfate, Sodium Hyaluronate, N-formylmethionine, methionine, cystine, homocysteine, GABA, N-acetylglutamat, Aspartame, ornithine, methionine, pyruvic acid, KG, oxaloacetic acid, succinyl-coenzyme A, fumaric acid, PEP, ketogenic amino acid, argininosuccinic acid, N-phosphinothricin acetyl base-L-Aspartic acid, β-methylamino-ALANINE, pyrrolysine, citrulling, left-handed bran amic acid, betaine, selenocystein, first selenium propylhomoserin, sarcosine, amine methylene glutamic acid, theanine, cucurbitin, Iibotenicacid, glutamic acid-1-semialdehyde, Asymmetric Dimethylarginine, methyl red, methyl blue, crystal violet, Flutamide, 4-aminobphenyl, 4-ASA, 4,4'-diaminodiphenyl ether, diethylamino (2-hydroxybenzoyl) hexyl-benzoate, xylene blue, fast green FCF, sulfamethoxazole, crystal violet, Chlorambucil, catecholamine, Ortho-Aminophenol, PAP, diphenylamines, Dequalinium Chloride, p-aminobenzoic acid, atoxylic acid, ortho-aminobenzoic acid, gavaculine, p-aminobenzoic acid, benzidine, o-phenylenediamine, m-phenylene diamine (MPD), p-phenylenediamine (PPD), Isosorbide-5-Nitrae-diazabicylo [2.2.2] octane, DMAP, trishydroxymethylaminomethane, melamine, ethylenediamine tetra-acetic acid, xylenol orange, nitrolim, para-totuidine, thiamines, cytimidine, glyphosate, grass ammonium phosphine, Amitraz, pyrazoles, benzimidazole, acephatemet, asccharin, 4-chloroaniline, 4,4'-MDA, 3,3-dichloro-benzidine, dimethoxy benzidine.
Further, described amide-type organic compound comprises: orthene, Ah method's methyl Thiofentanyl, antifebrin, acetamide, zolpidem, chitin, colchicine, folic acid, 5, 10-methylene tetrahydrofolate, orthene, uracil, uridine, uridine diphosphate (UDP), 5-bromo-2-deoxyuridine, thymidine, thymidine, alloxan, caprolactam, ground that sulphur, hydroxyindole, Pyrazinamide, sulfonamide, acetazolamide, honey element, polyphthalamide, poly, N-chlorosuccinimide, N-bromo-succinimide, phthalimide, buspirone hydrochloride, tetramethrin, acrylamide, oxamid, antifebrin, N, N', N''-triethylene thiophosphoramide, Aspartame, to acetamido phenol, salicylamide, niacinamide, Pyrazinamide, endoxan, thioacetamide, pipering, hippuric acid, pantothenic acid.
Further, described (idol) diazonium class organic compound comprises: 1-((p-nitrophenyl) azo)-beta naphthal, azodiisobutyronitrile, azobenzene, azidamfenicol, 4-aminoazabenzol, azodiisobutyronitrile, benzenediazonium chloride, diazoaminobenzene, azobenzene, p hydroxyazobenzene, butter yellow, P-aminoazobenzene, azodicarbonamide, tonyred, 2,2'-dichlorohydrazobenzene, 4,4 ˊ-dihydroxy azobenzene, azo dicyclohexyl formonitrile HCN, ABVN.
Further, described (different) nitrile organic compound comprises: isonitrile, 2,3-bis-is chloro-5,6-dicyan 1,4-benzoquinone, dicyandiamide, cyanamide, sodium cyanoborohydride, hexachlorocyclotriph,sphazene, 1-naphthonitrile, 3-indoles formonitrile HCN, pyrrole-2-carbonitriles, 5-nitrothiophene-2-formonitrile HCN, benzofuran-2-formonitrile HCN, 3-amino-5-chloropyrazine-2-formonitrile HCN, 3-indole acetonitrile, 4-biphenyl acetonitrile, salt acid amide nitrile, methylene aminoacetonitriles, 1,2,4,5-benzene tetramethyl nitrile, RH-7592, 2-4-hydroxy-benzonitrile, para-Phthalonitrile, phthalonitrile, isophthalodinitrile, 4-nitrophthalonitrile, 3-nitrophthalonitrile, pchlorobenzotrifluoride, tetrachloro-p-phenylene's dimethoxy nitrile, tetrachloro phthalonitrile, termil, 3-nitrophthalonitrile, 4-acetyl bromide cyanophenyl, 2-amino-5-methyl cyanophenyl, 3,4,5,6-tetrafluoro phthalic nitrile, 2,3,5,6-tetrafluoro para-Phthalonitrile, the iodo-4-decoyl of 3,5-bis-oxygen cyanophenyl, benzyl allyl dintrile, o-chloro benzonitrile, cis-two (benzonitrile) platinous chloride, diaminomaleonitrile, rich horse dintrile, AMBN, 2,3-dichlorobenzonitrile, 2,6-dichlorobenzonitrile.
Further, described guanidine class organic compound comprises: guanidine, guanidine nitrate, guanidine carbonate, moroxydine, glycocyamine, guanidine thiocyanate, nitrosoguanidine, 12 guanidines, robenidine hydrochloride, biguanide, dicyandiamide, sulphaguanidine, phenylacetic acid guanidine, aminoguanidine, acetyl guanidine, phosphoguanidine, guanoclor, guanidine sulfate, methyl guanamines, sulfuric acid aminoguanidine, hydroxyguanidine sulfate, 1-methyl-3-nitro guanidine, aminoguanidine nitrate, robenidine hydrochloride, glucocyamine, diphenylguanidine, guanidines carbonate, dodine, buformin, aminoguanidinium salts hydrochlorate, vinyl guanamines.
Further, described ureas organic compound comprises: urea, ethylene thiourea, dichlorophenyl dimethyl urea, urea ethane, Acetohexamide, chlorpropamide, orinase, tolazamide, carbutamide, Glimepiride, hydantoins, benzene thiocarbamide, CPPU, urea phosphate, semicarbazides, propyl group urea, benzylurea, ureasulfuric acid, sulfonylureas, forchlorfenuron, tert-butylalcohol, ethylene urea, acetylurea, urea oxalate, MU, glycoluril, cyclohexyl urea, selenourea, phenylurea, urea phosphate, sulfuric acid hydroxyl urea, ureaformaldehyde, cyano group acetyl ethyl carbamide, Rimon, cyanogen acetylurea, imidazolidinyl urea, methyl-nitroso-urea, Cucurbituril.
Further, described hydrazine class organic compound comprises: 1, 2-hydrazo-benzene, indazole, semicarbazides, phthalazines, hydrolazine, luminol, hydrazine sulfate, phenylhydrazine, isoniazid, dimethylhydrazine, benzyl hydrazine, benzoyl hydrazine, grass amine hydrazides, 4 hydroxybutyric acid hydrazine, Laur hydrazine, hydroxyacyl hydroxyacyl hydrazine, formic acid hydrazine, hydrazine bromide, hydrazine hydrochloride, hydrazine Huang, malonyl hydrazine, phenylhydrazide, succinyl hydrazine, formylhydrazine, hydralazine, Nifurzide, 2-Thiophene Carboxylic Acid hydrazine, thiocarbohydrazide, oxalyl two hydrazines, hydrazine perchlorate, phenylacetyl hydrazine, maleic acid hydrazide, two hydrazine hydrochlorides, salicylyl hydrazine, neohydrazid, carbazic acid methyl esters, vanillic acid hydrazine.
Further, described hydrazone class organic compound comprises: phenylhydrazone, metaflumizone, dithizone, salicylide hydrazone, diphenyl carbazone, acetone phenylhydrazone, benzil hydrazone, Benzophenonehydrazones, hydramethylnon, salicylide carbonyl hydrazone, Benzophenonehydrazones, diflufenzopyr, acetophenone tosylhydrazone, bisoxalydihydrazone, 2-methyl-4-dibenzyl aminobenzaldehyde-1,1-diphenyl hydrazone, methyl-GAG, ferimzone, cyclohexanone-2,4-dinitrophenylhydrazone, pyridine-2-formaldehyde 2-quinoline hydrazone.
Further, described oximes organic compound comprises: acetaldoxime, sheet brain ketoxime, acetoxime, cyclohexanone oxime, benzamidoxime, erythromycin oxime, dimethylglyoxime, salicyloyl amidoxime, benzoin oxime, biacetyl monoxime, nifuroxime, Chinese cassia tree aldoxime, tralkoxydim, glyoxime, oxime bacterium ester, acetophenone oxime, 9-Fluorenone oxime, cefotaxime acetic acid, n-Heptaldehyde oxime, fluorine is carried oxime ammonia, fat dimoxystrobin, pyroracemic aldehyde-1-oxime, pyribenzoxim, diacetyl monoxime, cyclohexanone isoxime, cefotaxime ethyl ester, benzene first hydroximic acid, parabenzoquinone dioxime, acetohydroxamic acid, methyl tri acetylacetonate oximino silane.
Further, described fire-extinguishing composite also comprises auxiliary extinguish material.
Further, described auxiliary extinguish material comprises: bromide fire retardant, chlorine-based flame retardant, organic phosphorus flame retardant, phosphorus-halogenated flame retardant, nitrogenated flame retardant and phosphorus-nitrogenated flame retardant, inorganic combustion inhibitor or its any combination.
Further, described fire-extinguishing composite also comprises additive, and the content of additive is 0.1-10%.
Further, described additive is stearate, graphite, or waterglass, phenolic resins, shellac, starch, dextrin, one or more in rubber, epoxy resin, acetal glue, hydroxypropyl methylcellulose.Except above-mentioned, enumerate material, other the organic or inorganic materials that can realize above-mentioned functions all can be used as the additive substitute in fire-extinguishing composite of the present invention.
Further, in described fire-extinguishing composite, each component and quality percentage composition thereof are:
Nitrogenous class organic compound 35%～96%
Auxiliary extinguish material 3%～60%
Additive 1%～10%
Further, in described fire-extinguishing composite, each component and quality percentage composition thereof are:
Nitrogenous class organic compound 50%～90%
Auxiliary extinguish material 5%～45%
Additive 3%～8%
The suppression mechanism of fire-extinguishing composite of the present invention is as follows:
During use, take pyrotechnics class medicament as heating power source and power source, by lighting pyrotechnics class medicament burning liberated heat, making to contain nitrogenous class organic compound at high temperature reacts, produce alkyl (or aryl) free radical, acyl group free radical and carbonyl radical, N, hydroxyl radical free radicals etc. are fire extinguishing particle effectively, these particles of effectively putting out a fire react necessary O with looping combustion, OH, one or more in H free radical are reacted, thereby cut off looping combustion reaction, meanwhile, produce synergistic function with firework medicament, further improved the fire extinguishing effectiveness of extinguishing chemical, greatly shortened effective attack time.
Compared with existing hot-gas sol fire extinguishing agent, fire-extinguishing composite of the present invention has the following advantages:
1, at high temperature reacting containing nitrogen compound in fire-extinguishing composite of the present invention, produce a large amount of nanoscales effectively put out a fire particle and multiple free radical, by cutting off combustion reaction chain, product together with hot aerosol propellant is brought into play fire extinguishing function jointly, further improve the fire extinguishing effectiveness of extinguishing chemical, shortened effective attack time.
2, fire-extinguishing composite of the present invention utilizes the heat that aerogel generating agent burning produces, heat absorption reacts rapidly, absorbed the heat that firework medicament burning discharges, reduced the temperature of extinguishing device spout, security is better, can not damage fire extinguishing personnel, also avoid the generation of spot fire.
3, adopt the aerosol fire-extinguishing device of fire-extinguishing composite of the present invention without increasing complex structure, the cooling system that volume is larger, therefore has the features such as structure is light, and technological process is simple, good economy performance.
The specific embodiment
Be below the specific embodiment of content of the present invention, for setting forth present specification, want the technical scheme of technical solution problem, contribute to those skilled in the art to understand content of the present invention, but the realization of technical solution of the present invention is not limited to these embodiment.
By outer fire-extinguishing composite of the present invention doping, make water as solvent, sieve after granulation, additional releasing agent, sieves after mixing, and it is spherical can adopting the technological formings such as pill, mold pressing, extruding, sheet, strip, bulk, cellular.
By above-mentioned fire-extinguishing composite, in the following manner and experimental result can show that the usefulness of fire-extinguishing composite of the present invention is obviously better than existing extinguishing medium beyond all doubtly, and attack time also greatly shorten.
Composition adopts following proportioning to test, and its concrete result of the test is:
Embodiment
Embodiment 1-100 gets respectively nitrogenous class organic compound of containing of certain mass percent in proportion, the auxiliary extinguish material of certain mass percent, the additive of certain mass percent, make water as solvent, use after 20 object sieve granulations, the dolomol of additional certain mass percent is as releasing agent, mix rear mistake 15 mesh sieve, beat sheet, get 50g and add in the extinguishing device that 50g K type aerogel generating agent is housed, fire extinguishing effect in Table 1 to table 20.
Comparative example 1:
Use the extinguishing device sample of 50gK salt type aerosol extinguishing agent, according to the experiment of put out a fire of fire extinguishing experimental model, the effect of putting out a fire in Table.
Comparative example 2:
Use the extinguishing device sample of 50g S type aerosol extinguishing agent, according to the experiment of put out a fire of fire extinguishing experimental model, the effect of putting out a fire in Table.
Fire extinguishing experimental model: food tray fire fire extinguishing experiment
By above-mentioned fire-extinguishing composite formula, according to the 6.3.2.1 in GA86-2009< Simple fire extinguisher > standard, it is 25m that experimental technique is implemented area
2, 93# gasoline 8B fire extinguishing experiment, every group of formula is carried out three experiments, record fire extinguishing effect and attack time.Experimental result sees the following form.
The various component comparison of ingredients of table 1 and the contrast of fire extinguishing experimental result
The various component comparison of ingredients of table 2 and the contrast of fire extinguishing experimental result
The various component comparison of ingredients of table 3 and the contrast of fire extinguishing experimental result
The various component comparison of ingredients of table 4 and the contrast of fire extinguishing experimental result
The various component comparison of ingredients of table 5 and the contrast of fire extinguishing experimental result
The various component comparison of ingredients of table 6 and the contrast of fire extinguishing experimental result
The various component comparison of ingredients of table 7 and the contrast of fire extinguishing experimental result
The various component comparison of ingredients of table 8 and the contrast of fire extinguishing experimental result
The various component comparison of ingredients of table 9 and the contrast of fire extinguishing experimental result
The various component comparison of ingredients of table 10 and the contrast of fire extinguishing experimental result
The various component comparison of ingredients of table 11 and the contrast of fire extinguishing experimental result
The various component comparison of ingredients of table 12 and the contrast of fire extinguishing experimental result
The various component comparison of ingredients of table 13 and the contrast of fire extinguishing experimental result
The various component comparison of ingredients of table 14 and the contrast of fire extinguishing experimental result
The various component comparison of ingredients of table 15 and the contrast of fire extinguishing experimental result
The various component comparison of ingredients of table 16 and the contrast of fire extinguishing experimental result
The various component comparison of ingredients of table 17 and the contrast of fire extinguishing experimental result
The various component comparison of ingredients of table 18 and the contrast of fire extinguishing experimental result
The various component comparison of ingredients of table 19 and the contrast of fire extinguishing experimental result
The various component comparison of ingredients of table 20 and the contrast of fire extinguishing experimental result
Above-described embodiment is only the explanation to preferred version of the present invention, does not limit the present invention.As long as the variation to above-described embodiment, modification all should fall in the application's the scope of claims request protection within the scope of connotation of the present invention.
Claims (19)
1. a fire-extinguishing composite that contains nitrogenous class organic compound, is characterized in that: described fire-extinguishing composite contains nitrogenous class organic compound; Described fire-extinguishing composite utilizes the burning of firework medicament to discharge a large amount of effective fire extinguishing particles.
2. the fire-extinguishing composite that contains nitrogenous class organic compound according to claim 1, is characterized in that: quality percentage composition >=35% of nitrogenous class organic compound in described fire-extinguishing composite.
3. the fire-extinguishing composite that contains nitrogenous class organic compound according to claim 1 and 2, it is characterized in that, described nitrogenous class organic compound comprises one or more in nitro compound, amine, amide-type, (idol) diazonium compounds, (different) nitrile, isocyanide ester class, guanidine class, ureas, hydrazine class, hydrazone class, oximes.
4. the fire-extinguishing composite that contains nitrogenous class organic compound according to claim 3, it is characterized in that, described nitro compound comprises: furazolidone, 2,4,6-tri-(trinitro-methyl)-1,3,5-triazine, 2,4-DNP, 3-[(4-nitrobenzophenone) carbamyl amino] propionic acid, Nilvadipine, aulin, 5-Nitro-2-propoxyaniline, trinitrotoluene, meta nitro aniline, trishydroxymethylnitromethane, hexanitroethane, p-nitrophenol, Clonazepam, roxarsone, nitroguanidine, nitrosobenzene.
5. the fire-extinguishing composite that contains nitrogenous class organic compound according to claim 3, is characterized in that described aminated compounds comprises: dinitrophenol sodium, nitrosamine, carbodiimides, N, N-dimethyl-5-methoxytryptamine, 5-methoxyl group dimethyltryptamine, dimethyltryptamine, psilosin, bufotenine, thrombocytin, 5-hydroxyryptophan, parnitene, methylphenidate, salbutamol, Thiamphenicol, chapter amine hydrochlorate, folic acid, 5,10-CH2-THFA, N-chlorosuccinimide, N-bromo-succinimide, polyvinylpyrrolidone, the acid of card English, solanine, o-phenylenediamine, TMAO, galactosamine, Glucosamine, N-acetyl-glucosamine, HYG, streptomycin sulfate, Sodium Hyaluronate, N-formylmethionine, methionine, cystine, homocysteine, GABA, N-acetylglutamat, Aspartame, ornithine, methionine, pyruvic acid, KG, oxaloacetic acid, succinyl-coenzyme A, fumaric acid, PEP, ketogenic amino acid, argininosuccinic acid, N-phosphinothricin acetyl base-L-Aspartic acid, β-methylamino-ALANINE, pyrrolysine, citrulling, left-handed bran amic acid, betaine, selenocystein, first selenium propylhomoserin, sarcosine, amine methylene glutamic acid, theanine, cucurbitin, Iibotenicacid, glutamic acid-1-semialdehyde, Asymmetric Dimethylarginine, methyl red, methyl blue, crystal violet, Flutamide, 4-aminobphenyl, 4-ASA, 4,4'-diaminodiphenyl ether, diethylamino (2-hydroxybenzoyl) hexyl-benzoate, xylene blue, fast green FCF, sulfamethoxazole, crystal violet, Chlorambucil, catecholamine, Ortho-Aminophenol, PAP, diphenylamines, Dequalinium Chloride, p-aminobenzoic acid, atoxylic acid, ortho-aminobenzoic acid, gavaculine, p-aminobenzoic acid, benzidine, o-phenylenediamine, m-phenylene diamine (MPD), p-phenylenediamine (PPD), Isosorbide-5-Nitrae-diazabicylo [2.2.2] octane, DMAP, trishydroxymethylaminomethane, melamine, ethylenediamine tetra-acetic acid, xylenol orange, nitrolim, para-totuidine, thiamines, cytimidine, glyphosate, grass ammonium phosphine, Amitraz, pyrazoles, benzimidazole, acephatemet, asccharin, 4-chloroaniline, 4,4'-MDA, 3,3-dichloro-benzidine, dimethoxy benzidine.
6. the fire-extinguishing composite that contains nitrogenous class organic compound according to claim 3, is characterized in that described amide-type organic compound comprises: orthene, Ah method's methyl Thiofentanyl, antifebrin, acetamide, zolpidem, chitin, colchicine, folic acid, 5,10-CH2-THFA, orthene, uracil, uridine, uridine diphosphate (UDP), 5-bromo-2-deoxyuridine, thymidine, thymidine, alloxan, caprolactam, ground that sulphur, hydroxyindole, Pyrazinamide, sulfonamide, acetazolamide, honey element, polyphthalamide, poly, N-chlorosuccinimide, N-bromo-succinimide, phthalimide, buspirone hydrochloride, tetramethrin, acrylamide, oxamid, antifebrin, N, N', N''-triethylene thiophosphoramide, Aspartame, to acetamido phenol, salicylamide, niacinamide, Pyrazinamide, endoxan, thioacetamide, pipering, hippuric acid, pantothenic acid.
7. the fire-extinguishing composite that contains nitrogenous class organic compound according to claim 3, it is characterized in that described (idol) diazonium class organic compound comprises: 1-((p-nitrophenyl) azo)-beta naphthal, azodiisobutyronitrile, azobenzene, azidamfenicol, 4-aminoazabenzol, azodiisobutyronitrile, benzenediazonium chloride, diazoaminobenzene, azobenzene, p hydroxyazobenzene, butter yellow, P-aminoazobenzene, azodicarbonamide, tonyred, 2, 2'-dichlorohydrazobenzene, 4, 4 ˊ-dihydroxy azobenzene, azo dicyclohexyl formonitrile HCN, ABVN.
8. the fire-extinguishing composite that contains nitrogenous class organic compound according to claim 3, is characterized in that described (different) nitrile organic compound comprises: isonitrile, 2,3-bis-is chloro-5,6-dicyan 1,4-benzoquinone, dicyandiamide, cyanamide, sodium cyanoborohydride, hexachlorocyclotriph,sphazene, 1-naphthonitrile, 3-indoles formonitrile HCN, pyrrole-2-carbonitriles, 5-nitrothiophene-2-formonitrile HCN, benzofuran-2-formonitrile HCN, 3-amino-5-chloropyrazine-2-formonitrile HCN, 3-indole acetonitrile, 4-biphenyl acetonitrile, salt acid amide nitrile, methylene aminoacetonitriles, 1,2,4,5-benzene tetramethyl nitrile, RH-7592, 2-4-hydroxy-benzonitrile, para-Phthalonitrile, phthalonitrile, isophthalodinitrile, 4-nitrophthalonitrile, 3-nitrophthalonitrile, pchlorobenzotrifluoride, tetrachloro-p-phenylene's dimethoxy nitrile, tetrachloro phthalonitrile, termil, 3-nitrophthalonitrile, 4-acetyl bromide cyanophenyl, 2-amino-5-methyl cyanophenyl, 3,4,5,6-tetrafluoro phthalic nitrile, 2,3,5,6-tetrafluoro para-Phthalonitrile, the iodo-4-decoyl of 3,5-bis-oxygen cyanophenyl, benzyl allyl dintrile, o-chloro benzonitrile, cis-two (benzonitrile) platinous chloride, diaminomaleonitrile, rich horse dintrile, AMBN, 2,3-dichlorobenzonitrile, 2,6-dichlorobenzonitrile.
9. the fire-extinguishing composite that contains nitrogenous class organic compound according to claim 3, it is characterized in that described guanidine class organic compound comprises: guanidine, guanidine nitrate, guanidine carbonate, moroxydine, glycocyamine, guanidine thiocyanate, nitrosoguanidine, 12 guanidines, robenidine hydrochloride, biguanide, dicyandiamide, sulphaguanidine, phenylacetic acid guanidine, aminoguanidine, acetyl guanidine, phosphoguanidine, guanoclor, guanidine sulfate, methyl guanamines, sulfuric acid aminoguanidine, hydroxyguanidine sulfate, 1-methyl-3-nitro guanidine, aminoguanidine nitrate, robenidine hydrochloride, glucocyamine, diphenylguanidine, guanidines carbonate, dodine, buformin, aminoguanidinium salts hydrochlorate, vinyl guanamines.
10. the fire-extinguishing composite that contains nitrogenous class organic compound according to claim 3, it is characterized in that described ureas organic compound comprises: urea, ethylene thiourea, dichlorophenyl dimethyl urea, urea ethane, Acetohexamide, chlorpropamide, orinase, tolazamide, carbutamide, Glimepiride, hydantoins, benzene thiocarbamide, CPPU, urea phosphate, semicarbazides, propyl group urea, benzylurea, ureasulfuric acid, sulfonylureas, forchlorfenuron, tert-butylalcohol, ethylene urea, acetylurea, urea oxalate, MU, glycoluril, cyclohexyl urea, selenourea, phenylurea, urea phosphate, sulfuric acid hydroxyl urea, ureaformaldehyde, cyano group acetyl ethyl carbamide, Rimon, cyanogen acetylurea, imidazolidinyl urea, methyl-nitroso-urea, Cucurbituril.
11. fire-extinguishing composites that contain nitrogenous class organic compound according to claim 3, it is characterized in that described hydrazine class organic compound comprises: 1, 2-hydrazo-benzene, indazole, semicarbazides, phthalazines, hydrolazine, luminol, hydrazine sulfate, phenylhydrazine, isoniazid, dimethylhydrazine, benzyl hydrazine, benzoyl hydrazine, grass amine hydrazides, 4 hydroxybutyric acid hydrazine, Laur hydrazine, hydroxyacyl hydroxyacyl hydrazine, formic acid hydrazine, hydrazine bromide, hydrazine hydrochloride, hydrazine Huang, malonyl hydrazine, phenylhydrazide, succinyl hydrazine, formylhydrazine, hydralazine, Nifurzide, 2-Thiophene Carboxylic Acid hydrazine, thiocarbohydrazide, oxalyl two hydrazines, hydrazine perchlorate, phenylacetyl hydrazine, maleic acid hydrazide, two hydrazine hydrochlorides, salicylyl hydrazine, neohydrazid, carbazic acid methyl esters, vanillic acid hydrazine.
12. fire-extinguishing composites that contain nitrogenous class organic compound according to claim 3, it is characterized in that described hydrazone class organic compound comprises: phenylhydrazone, metaflumizone, dithizone, salicylide hydrazone, diphenyl carbazone, acetone phenylhydrazone, benzil hydrazone, Benzophenonehydrazones, hydramethylnon, salicylide carbonyl hydrazone, Benzophenonehydrazones, diflufenzopyr, acetophenone tosylhydrazone, bisoxalydihydrazone, 2-methyl-4-dibenzyl aminobenzaldehyde-1,1-diphenyl hydrazone, methyl-GAG, ferimzone, cyclohexanone-2,4-dinitrophenylhydrazone, pyridine-2-formaldehyde 2-quinoline hydrazone.
13. fire-extinguishing composites that contain nitrogenous class organic compound according to claim 3, it is characterized in that described oximes organic compound comprises: acetaldoxime, sheet brain ketoxime, acetoxime, cyclohexanone oxime, benzamidoxime, erythromycin oxime, dimethylglyoxime, salicyloyl amidoxime, benzoin oxime, biacetyl monoxime, nifuroxime, Chinese cassia tree aldoxime, tralkoxydim, glyoxime, oxime bacterium ester, acetophenone oxime, 9-Fluorenone oxime, cefotaxime acetic acid, n-Heptaldehyde oxime, fluorine is carried oxime ammonia, fat dimoxystrobin, pyroracemic aldehyde-1-oxime, pyribenzoxim, diacetyl monoxime, cyclohexanone isoxime, cefotaxime ethyl ester, benzene first hydroximic acid, parabenzoquinone dioxime, acetohydroxamic acid, methyl tri acetylacetonate oximino silane.
14. according to the fire-extinguishing composite that contains nitrogenous class organic compound described in any one in claim 4～13, it is characterized in that: described fire-extinguishing composite also comprises auxiliary extinguish material.
15. fire-extinguishing composites that contain nitrogenous class organic compound according to claim 14, it is characterized in that: described auxiliary extinguish material comprises: bromide fire retardant, chlorine-based flame retardant, organic phosphorus flame retardant, phosphorus-halogenated flame retardant, nitrogenated flame retardant and phosphorus-nitrogenated flame retardant, inorganic combustion inhibitor or its any combination.
16. fire-extinguishing composites that contain nitrogenous class organic compound according to claim 14, is characterized in that: described fire-extinguishing composite also comprises additive, the content of additive is 0.1-10%.
17. fire-extinguishing composites that contain nitrogenous class organic compound according to claim 16, it is characterized in that: described additive is stearate, graphite, or waterglass, phenolic resins, shellac, starch, dextrin, one or more in rubber, epoxy resin, acetal glue, hydroxypropyl methylcellulose.
18. fire-extinguishing composites that contain nitrogenous class organic compound according to claim 17, is characterized in that in described fire-extinguishing composite that each component and quality percentage composition thereof are:
Nitrogenous class organic compound 35%～96%
Auxiliary extinguish material 3%～60%
Additive 1%～10%.
19. fire-extinguishing composites that contain nitrogenous class organic compound according to claim 18, is characterized in that in described fire-extinguishing composite that each component and quality percentage composition thereof are:
Nitrogenous class organic compound 50%～90%
Auxiliary extinguish material 5%～45%
Additive 3%～8%.
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