CN103734182B - A kind of Fungicidal insecticidal composition containing mancozeb - Google Patents
A kind of Fungicidal insecticidal composition containing mancozeb Download PDFInfo
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- CN103734182B CN103734182B CN201310746441.1A CN201310746441A CN103734182B CN 103734182 B CN103734182 B CN 103734182B CN 201310746441 A CN201310746441 A CN 201310746441A CN 103734182 B CN103734182 B CN 103734182B
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- mancozeb
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- 239000000203 mixture Substances 0.000 title claims abstract description 40
- 239000005802 Mancozeb Substances 0.000 title claims abstract description 33
- 230000000749 insecticidal effect Effects 0.000 title claims abstract description 17
- 230000000855 fungicidal effect Effects 0.000 title claims abstract description 10
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 13
- 239000000839 emulsion Substances 0.000 claims abstract description 13
- PPCUNNLZTNMXFO-ACCUITESSA-N Imicyafos Chemical group CCCSP(=O)(OCC)N1CCN(CC)\C1=N/C#N PPCUNNLZTNMXFO-ACCUITESSA-N 0.000 claims abstract description 12
- 239000000843 powder Substances 0.000 claims abstract description 12
- 239000004480 active ingredient Substances 0.000 claims abstract description 10
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- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 4
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- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
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- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
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- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
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- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
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- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
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- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 2
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- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 1
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- 244000241257 Cucumis melo Species 0.000 description 1
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- PPCUNNLZTNMXFO-UHFFFAOYSA-N [1-[ethoxy(propylsulfanyl)phosphoryl]-3-ethylimidazolidin-2-ylidene]cyanamide Chemical compound CCCSP(=O)(OCC)N1CCN(CC)C1=NC#N PPCUNNLZTNMXFO-UHFFFAOYSA-N 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of Fungicidal insecticidal composition containing mancozeb, its active ingredient is Imicyafos and mancozeb two yuan of mixtures, and the ratio of weight and number of two kinds of active ingredients is 1 ~ 50: 1 ~ 50, and preferred weight portion rate is 3 ~ 25: 5 ~ 25; The parts by weight content that in insecticidal and bactericidal composition, active ingredient is total is 1% ~ 80%, preferred weight number content is 5% ~ 35%, all the other are allow in agricultural chemicals to use and acceptable auxiliary element, wetting powder, suspending agent, microemulsion, aqueous emulsion and water dispersible granules can be prepared into by known method, Fungicidal insecticidal composition of the present invention be mainly used in preventing and treating grain, cotton, oil, really, vegetables, flowers the damage by disease and insect of crop.
Description
Technical field
The present invention relates to technical field of pesticide combination, being specifically related to a kind of is the composite insecticidal and bactericidal composition of active ingredient two yuan containing agricultural chemicals Imicyafos and mancozeb.
Background technology
Imicyafos (AKD-3088) is a kind of cyanamide heterocyclic organic matter, it is combined by the sub-imidazolidine of cyano group of asymmetric organic phosphor and nicotinic insecticide, can be used for the crops such as radish, carrot, strawberry, eggplant, tomato, cucumber, muskmelon, watermelon, sweet potato and potato, its chemical structural formula is:
Mancozeb is a kind of excellent protective fungicide, belongs to low-toxin farm chemicals.Because its bactericidal range extensively, not easily produces resistance, control efficiency is obviously better than other same series bactericidal agents, manganese, zinc microelement have significantly short strong, production-increasing function, to preventing and treating the Be very effective such as pear scab, alternaria leaf spot of apple, vegetable category epidemic disease, downy mildew, field crop rust to crop.
The insecticide that Long-Time Service is single or bactericide, insect or germ are easy to develop immunity to drugs, and pesticide dosage is increased, and cause the adverse consequencess such as high poison, consumption are large, residual many, drug effect is poor, and effect field are more single.The different mechanism of action and without the insecticide of cross resistance and bactericide rational mixture by a certain percentage, crop disease prevention effect can be improved, reduce dosage, residual few, reduce environmental pollution, effectively the pesticide resistance of reduction crop.
Summary of the invention
According to the deficiencies in the prior art; the present invention proposes a kind of Fungicidal insecticidal composition containing mancozeb, said composition contains A, B two kinds of effective active components, and component A selects novel pesticide Imicyafos; B is selected from mancozeb; it is wide that the present composition has effect field, can desinsection again can sterilization, and consumption is few; preventive effect is high; residual few, the lasting period is long, is conducive to environmental protection.
The present invention be a kind of with novel pesticide Imicyafos and mancozeb for active ingredient carries out the insecticidal and bactericidal composition preparation of two yuan of mixtures, wherein in insecticidal and bactericidal composition of the present invention, the ratio of weight and number of active ingredient novel pesticide Imicyafos and mancozeb is 1 ~ 50: 50 ~ 1, on the basis of test recipe screening targetedly, the ratio of weight and number of active ingredient novel pesticide Imicyafos and mancozeb can be preferably 3 ~ 25: 25 ~ 5.
The formulations of pesticide that the preparation method of agricultural insecticide bactericidal composition field of pesticide preparation of the present invention can be prepared into are wetting powder, suspending agent, microemulsion, aqueous emulsion and water dispersible granules, in preparation, active ingredient gross weight accounts for the portion rate of gross weight in preparation is 1% ~ 80%, on the basis of test recipe screening targetedly, in preparation, active ingredient gross weight accounts for the portion rate of gross weight in preparation is 3% ~ 35%, and all the other are usual auxiliaries in agricultural chemicals.
When above-described Pesticidal combination is microemulsion, in preparation, the ratio of weight and number of each component is:
The concrete production stage of this microemulsion is: former medicine imicyafos, mancozeb cosolvent are dissolved completely, then adds other compositions such as emulsifier, antifreezing agent stabilizing agent, and Homogeneous phase mixing, finally adds water, can be made into microemulsion after fully stirring.
When above-described Pesticidal combination is wetting powder, in preparation, the ratio of weight and number of each component is:
The concrete procedure of processing of this Pesticidal combination wetting powder is: by above-mentioned formula by active principle A and active principle B and the mixing of dispersant, wetting agent and filler, uniform stirring in stirred tank, mixing after airslide disintegrating mill, namely can be made into the wetting powder of the present composition.
When above-described Pesticidal combination is suspending agent, in preparation, the ratio of weight and number of each component is:
The concrete production stage of this suspending agent is for first to mix other auxiliary agents, mix through high speed shear, add active principle A and active principle B, abrading-ball 2 ~ 3 hours in ball crusher, make a diameter all at below 5mm, the aqueous suspension formulations of obtained Pesticidal combination of the present invention.
When above-described Pesticidal combination is aqueous emulsion, in preparation, the ratio of weight and number of each component is:
The concrete production stage of this aqueous emulsion is: first former medicine active principle A and active principle B, solvent and emulsifier, cosolvent are added together, and makes to be dissolved into uniform oil phase; By part water, antifreeze, other the insecticides adjuvant such as antimicrobial mixes uniformly aqueous phase; While high-speed stirred, oil phase is added aqueous phase in a kettle., slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water, shear about half an hour, form the aqueous emulsion of oil-in-water type.The i.e. aqueous emulsion of obtained Pesticidal combination of the present invention.
When above-described Pesticidal combination is water dispersible granules, in preparation, the ratio of weight and number of each component is:
The concrete procedure of processing of this Pesticidal combination water dispersible granules is: active principle A, active principle B and dispersant, wetting agent, disintegrant and filler are mixed by above-mentioned formula, pulverize with micro jet, through mediating, then add in fluidized-bed granulation dryer and carry out through sample analysis after granulation, drying, screening, be i.e. the water dispersible granules of obtained Pesticidal combination of the present invention.
Described emulsifier is selected from least one in calcium dodecyl benzene sulfonate and aliphatic acid polyethenoxy ether, alkylphenol polyoxyethylene sulfosuccinate, styrylphenol polyoxyethylene ether, polyoxyethylene nonylphenol ether, castor oil polyoxyethylene ether, aliphatic acid polyethenoxy base ester, polyoxyethylene aliphatic alcohol ether.
Described solvent is at least one in dimethylbenzene or biodiesel, toluene, diesel oil, methyl alcohol, ethanol, n-butanol, isopropyl alcohol, turpentine oil, solvent naphtha, dimethyl formamide, dimethyl sulfoxide (DMSO), water equal solvent.
Described dispersant is selected from least one in polycarboxylate, lignosulfonates, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, fatty acid glyceride APEO.
Described wetting agent is selected from lauryl sodium sulfate, calcium dodecyl benzene sulfonate, at least one pulled open in powder copper rosinate X., wetting and penetrating agent F, alkylnaphthalene sulfonate, polyoxyethylene tri-styryl phosphenylic acid salt, spaonin powder, silkworm excrement, soapberry powder.
Described disintegrant is selected from least one in bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, sodium bicarbonate.
Described thickener is selected from least one in xanthans, CMC, hydroxyethylcellulose, methylcellulose, Magnesiumaluminumsilicate, polyvinyl alcohol.
Described stabilizing agent is selected from least one in sodium citrate, resorcinol.
Described antifreezing agent is selected from least one in ethylene glycol, propane diols, glycerine.
Described defoamer is selected from silicone oil, silicone compound, C
10-20saturated fat acid compounds, C
8-10at least one in aliphatic alcohols compound.
Described filler is selected from least one in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate.
Agricultural insecticide bactericidal composition of the present invention to grain, cotton, oil, really, vegetables, flowers multiple fungal disease all there is favorable effect, especially the powdery mildew on the cereal such as wheat, fruit and vegetables, downy mildew, rust, tikka class disease, scab, rot etc. are caused by germ, had the control of the disease of certain resistance to have excellent preventive effect to ergosterol class synthetic inhibitor class agricultural chemicals.Pesticidal combination of the present invention can prevent and treat nematoda, etc. the various insects such as sufficient class, coleoptera class pest, Lepidoptera class pest, gastropod, orthoptera pest, plant parasitic acarid class, Thysanoptera, Diptera pest, Hymenoptera insect, hidden wing order insect, Anoplura insect, Isoptera insect, Hemipteran pest, damp insects, centipede insects, thousand-legger class.Especially to destroying the insect of agriculture horticultural crop and trees etc. in soil, destroying the insect of the seed of agriculture horticultural crop and trees, such as nematoda, etc. sufficient class, coleoptera class pest, Lepidoptera class pest, gastropod, orthoptera pest, plant parasitic acarid class, Hemipteran pest preventive effect remarkable.
The above nematode pests comprises the pratylenchus classes such as pratylenchus, pseudo-Pratylenchidae, Lu Si Pratylenchidae, disability Pratylenchidae, the Cyst nematode such as soybean cyst nematode Heterodera glycines, globodera rostochiensis class, the root-knot nematode such as peanut root-knot nematode, Meloidogyne incognita class, the Aphelenchoidea classes such as aphelenchoides besseyi, leaf bud nematode, species of Tylenchorhynchus Nematodes class, loop wire insects, needlework insects, long capsule nematoda, burr nematoda, nematode on strawberry, pine wood nematode.All favorable effect is had in addition to insects such as aphid, leafhopper, plant hopper, chrysomelid, wireworm, cutworm, diamond-back moth, imported cabbageworm, rice thripses.
In addition, insecticidal and bactericidal composition of the present invention compares similar medicament also other obvious advantages a lot, the first, compare single dose sphere of action wider, can desinsection again can diseases prevention; The second, greatly delay the drug-fast generation of crop, decreased agricultural chemicals Reusability number of times, reduce Pesticide use amount, reduce agricultural cost; 3rd, the residual quantity of this insecticidal and bactericidal composition is lower, more friendly to environment; There is general fresh-keeping production-increasing function to crops in the application of last this insecticidal and bactericidal composition, the increasing both production and income of agricultural region is significant.
Embodiment:
In order to make object of the present invention, technical scheme and advantage clearly understand, the following specific embodiment of the present invention is described, but the present invention is only limitted to absolutely not these examples.The method that the present invention adopts indoor bioassay and field trial to combine, if no special instructions, the ratio (comprising percentage) below mentioned is all ratio of weight and number.
Embodiment 1: by imicyafos10 part, mancozeb 15 parts, lignosulfonates 9 parts, lauryl sodium sulfate 11 parts and the mixing of 65 parts, diatomite, uniform stirring in stirred tank, mixing after airslide disintegrating mill, i.e. the wetting powder of obtained Pesticidal combination of the present invention.
Embodiment 2: by imicyafos5 part, mancozeb 22 parts, alkylphenol polyoxyethylene 8 parts, oxygen ethene triphenylethylene phosphenylic acid salt 14 parts and bentonite 51 parts mixing, uniform stirring in stirred tank, mixing after airslide disintegrating mill, i.e. the wetting powder of obtained Pesticidal combination of the present invention.
Embodiment 3: by imicyafos3 part, mancozeb 25 parts, dispersant 10 parts, wetting agent 12 parts and filler 50 parts mixing, uniform stirring in stirred tank, is mixing after airslide disintegrating mill, the i.e. wetting powder of obtained Pesticidal combination of the present invention.
Embodiment 4: by alkylphenol polyoxyethylene 8 parts, glycerine 2 parts, CMC 4 parts, silicone oil 1 part, the mixing of 60 parts, water, mix through high speed shear, add imicyafos20 part, mancozeb 5 parts successively, abrading-ball 2 ~ 3 hours in ball crusher, make a diameter all at below 5mm, the aqueous suspension formulations of obtained Pesticidal combination of the present invention.
Embodiment 5: by dispersant 10 parts, antifreezing agent 2 parts, thickener 3 parts, defoamer 1 part, the mixing of 66 parts, water, mix through high speed shear, add imicyafos8 part, mancozeb 10 parts successively, abrading-ball 2 ~ 3 hours in ball crusher, make a diameter all at below 5mm, the aqueous suspension formulations of obtained Pesticidal combination of the present invention.
Embodiment 6: by dispersant 8 parts, antifreezing agent 2 parts, thickener 4 parts, defoamer 1 part, the mixing of 60 parts, water, mix through high speed shear, add imicyafos5 part, mancozeb 20 parts successively, abrading-ball 2 ~ 3 hours in ball crusher, make a diameter all at below 5mm, the aqueous suspension formulations of obtained Pesticidal combination of the present invention.
Embodiment 7: imicyafos10 part, mancozeb 25 parts, 12 parts, turpentine oil, castor oil polyoxyethylene ether 5 parts, resorcinol 6 parts are mixed, is dissolved into uniform oil phase; Part water, propane diols 2 parts, silicone compound 1 part are mixed uniformly aqueous phase; While high-speed stirred, oil phase is added aqueous phase in a kettle., add polyvinyl alcohol 4 parts, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water and supply 100 parts, shear about half an hour, form the aqueous emulsion of oil-in-water type.The i.e. aqueous emulsion of obtained Pesticidal combination of the present invention.
Embodiment 8: imicyafos25 part, mancozeb 10 parts, solvent 20 parts, emulsifier 8 parts, stabilizing agent 12 parts are mixed, is dissolved into uniform oil phase; Part water, antifreezing agent 1 part, defoamer 2 parts are mixed uniformly aqueous phase; While high-speed stirred, oil phase is added aqueous phase in a kettle., add thickener 3 parts, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water and supply 100 parts, shear about half an hour, form the aqueous emulsion of oil-in-water type.The i.e. aqueous emulsion of obtained Pesticidal combination of the present invention.
Embodiment 9: imicyafos15 part, mancozeb 8 parts, solvent 18 parts, emulsifier 10 parts, stabilizing agent 8 parts are mixed, is dissolved into uniform oil phase; Part water, antifreezing agent 1 part, defoamer 2 parts are mixed uniformly aqueous phase; While high-speed stirred, oil phase is added aqueous phase in a kettle., add thickener 3 parts, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water and supply 100 parts, shear about half an hour, form the aqueous emulsion of oil-in-water type.The i.e. aqueous emulsion of obtained Pesticidal combination of the present invention.
Embodiment 10: imicyafos25 part, mancozeb 10 parts, aliphatic amine polyoxyethylene ether 10 parts, alkylnaphthalene sulfonate 10 parts, 5 parts, aluminium chloride and bentonite 40 parts are mixed, pulverize with micro jet, through mediating, then add in fluidized-bed granulation dryer and carry out through sample analysis after granulation, drying, screening, be i.e. the water dispersible granules of obtained Pesticidal combination of the present invention.
Embodiment 11: imicyafos10 part, mancozeb 20 parts, dispersant 12 parts, wetting agent 10 parts, disintegrant 5 parts and filler 43 parts are mixed, pulverize with micro jet, through mediating, then add in fluidized-bed granulation dryer and carry out through sample analysis after granulation, drying, screening, be i.e. the water dispersible granules of obtained Pesticidal combination of the present invention.
Embodiment 12: imicyafos10 part, mancozeb 18 parts, dispersant 10 parts, wetting agent 12 parts, disintegrant 3 parts and filler 47 parts are mixed, pulverize with micro jet, through mediating, then add in fluidized-bed granulation dryer and carry out through sample analysis after granulation, drying, screening, be i.e. the water dispersible granules of obtained Pesticidal combination of the present invention.
Embodiment 13: former medicine imicyafos15 part, mancozeb 15 parts are dissolved completely with cosolvent, add other compositions such as aliphatic acid polyethenoxy base ester 10 parts, ethylene glycol 2 parts, sodium citrate 4 parts, resorcinol 4 parts again, Homogeneous phase mixing, finally add water, after fully stirring, can microemulsion be made into.
Embodiment 14: former medicine imicyafos13 part, mancozeb 18 parts are dissolved completely with cosolvent, then add other compositions such as emulsifier 11 parts, antifreezing agent 2 parts, stabilizing agent 7 parts, Homogeneous phase mixing, finally adds water, can be made into microemulsion after fully stirring.
Embodiment 15: former medicine imicyafos8 part, mancozeb 22 parts are dissolved completely with cosolvent, then add other compositions such as emulsifier 9 parts, antifreezing agent 2 parts, stabilizing agent 11 parts, Homogeneous phase mixing, finally adds water, can be made into microemulsion after fully stirring.
Field experiment: to the control of Cucumber Pests And Diseases.
(1) investigation method
Field trial is all located at the cucumber ground in Li Tai township, Yangling district of Shaanxi Province, and in custard squash booth, 5 points are investigated in every community, often some investigation 2 strains, and record occurring degree by staging, grade scale is as follows:
0 grade: without scab;
1 grade: lesion area accounts for less than 5% of whole leaf area;
3 grades: lesion area accounts for whole leaf area 6% ~ 10%;
5 grades: lesion area accounts for 11% ~ 25% of whole leaf area;
7 grades: lesion area accounts for 26% ~ 50% of whole leaf area;
9 grades: lesion area accounts for more than 50% of whole leaf area.
(2) control time and number of times
Test is investigated 3 times altogether, i.e. disease index investigation before medicine, preventive effect investigation in 7 days after the 1st medicine, 7 days and preventive effect investigation in 15 days after 2 medicines.
(3) drug effect computational methods
Sick leaf rate (%)=sick number of sheets/investigate the total number of sheets × 100
Disease index=∑ (the sick number of sheets × relative level numerical value at different levels)/(investigating the total number of sheets × 9) × 100
Control efficiency (%)=(before 1-(blank district medicine after disease index × treatment region medicine disease index)/(after blank district medicine before disease index × treatment region medicine disease index)) × 100
(4) poisoning investigation method
Whether after dispenser, continuous 7d estimates medicament has poisoning to crop.
(5) result of the test and analysis
The effect of powdery mildew of cucumber prevented and treated by table 1 respectively process
As can be seen from Table 1, the ratio of weight and number of 30%imicyafos mancozeb be 10: 20 mixture combination to prevent and treat the effect of powdery mildew of cucumber very remarkable, Be very effective is better than single dose, and its quick-acting and lasting effect are all relatively good, especially outstanding with lasting effect.Complex preparation control efficiency under the consumption of high concentration is significantly better than the effect under low concentration consumption.After the 1st medicine, after 7 days, the 2nd time medicine, the best control efficiency of 7 days reaches 89.77% and 92.23% respectively, and after the 2nd medicine, 15 days best preventive effects reach 91.23%.And 15 days best preventive effects are 79.21% after single dose 25% mancozeb SC the 2nd medicine, the Be very effective of complex preparation is better than single dose.According to field range estimation, substantially there is no insect pest with the cucumber of 30%imicyafos mancozeb, and growth fraction is more vigorous, and the cucumber of 25% mancozeb single dose occurs that insect pest is more, than with the insect pest plant of complex preparation much about about 15%.
In addition within the scope of test dose, plant growth is normal, and the poisoning phenomenon to cucumber does not all appear in each treatment agent, illustrates that it is safe to cucumber.
Claims (1)
1. containing the Fungicidal insecticidal composition of mancozeb, it is characterized in that: this Fungicidal insecticidal composition is that all the other components are usual auxiliaries in agricultural chemicals with A Imicyafos and B mancozeb for the composite composite preparation of active ingredient two yuan,
A Imicyafos，
In this Fungicidal insecticidal composition, the ratio of weight and number of effective constituents A and B is 10: 20, in this Fungicidal insecticidal composition, effective constituents A and B gross weight account for the portion rate of gross weight in preparation is 5% ~ 35%, and the preparation formulation that insecticidal and bactericidal composition can be mixed with is wetting powder, suspending agent, microemulsion, aqueous emulsion and water dispersible granules.
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