CN103666384A - Nontoxic odorless cold accumulation agent and preparation method thereof - Google Patents

Nontoxic odorless cold accumulation agent and preparation method thereof Download PDF

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Publication number
CN103666384A
CN103666384A CN201310685654.8A CN201310685654A CN103666384A CN 103666384 A CN103666384 A CN 103666384A CN 201310685654 A CN201310685654 A CN 201310685654A CN 103666384 A CN103666384 A CN 103666384A
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Prior art keywords
polyvinyl alcohol
cold storage
borax
storage agent
water
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Pending
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CN201310685654.8A
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Chinese (zh)
Inventor
包伟强
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Suzhou Antek Industrial Co Ltd
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Suzhou Antek Industrial Co Ltd
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Priority to CN201310685654.8A priority Critical patent/CN103666384A/en
Publication of CN103666384A publication Critical patent/CN103666384A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/14Thermal energy storage

Abstract

The invention discloses a nontoxic odorless cold accumulation agent and a preparation method thereof. The cold accumulation agent comprises polyvinyl alcohol, dipotassium phosphate, hydroxyethyl cellulose sodium, borax, lauryl sodium sulfate and water. The preparation method comprises the following steps: (A) preparing raw materials according to a ratio; (B) adding the polyvinyl alcohol into the water under the ice-bath condition, and fully stirring; (C) slowly dropwise adding the dipotassium phosphate and hydroxyethyl cellulose sodium into a solution obtained from the step (B) at the room temperature; (D) heating the solution obtained from the step (C) to 40-50 DEG C, slowly adding the lauryl sodium sulfate and borax in a high-speed stirring state, uniformly stirring at the room temperature, and naturally cooling to obtain the cold accumulation agent. The preparation method is simple, low in cost and more favorable for large-scale production; the cold accumulation agent is nontoxic, odorless and reusable; the phase-change latent heat is 260-320 KJ/Kg and the phase-change temperature is -10 DEG C to 4 DEG C.

Description

A kind of nonpoisonous and tasteless cold storage agent and preparation method thereof
technical field:
The present invention relates to Cool Storage Technology field, be specifically related to a kind of nonpoisonous and tasteless cold storage agent and preparation method thereof.
background technology:
Cool Storage Technology is to utilize the effective means such as various physics, chemistry, machinery that cold is stored in cold storage agent, the process again cold of storage being discharged while needing.By this technology, produced and can efficiently be stored cold, this material that meets again various physics, chemistry requirement is referred to as cold storage agent.
Cool storage material is the key of Cool Storage Technology, though ice is the Nature, bestows a kind of Natural Cold Energy Storage agent to the mankind, although it has much valuable character, but still can not meet the increasing requirement of people.The problems such as existing cold storage agent ubiquity cold storage capacity is not enough, and Discharging time is shorter, and complicated process of preparation and use cost are higher.
summary of the invention:
The present invention seeks to, overcome the deficiency that above-mentioned prior art exists, a kind of nonpoisonous and tasteless cold storage agent and preparation method thereof is provided.
To achieve these goals, technical scheme of the present invention is as follows:
A cold storage agent, according to weight percent meter, comprises polyvinyl alcohol 15-20%, dipotassium hydrogen phosphate 1-3%, sodium hydroxyethyl cellulose 0.5-1.3%, borax 0.2-1.2%, sodium lauryl sulphate 2-6%, and surplus is water.
Described cold storage agent, according to weight percent meter, comprises polyvinyl alcohol 15%, dipotassium hydrogen phosphate 3%, sodium hydroxyethyl cellulose 0.5%, borax 0.2%, sodium lauryl sulphate 6%, water 75.3%.
Described cold storage agent, according to weight percent meter, comprises polyvinyl alcohol 20%, dipotassium hydrogen phosphate 1%, sodium hydroxyethyl cellulose 1.3%, borax 1.2%, sodium lauryl sulphate 2%, water 74.5%.
The preparation method of described cold storage agent, comprises following step:
(A) according to required ratio, be ready to polyvinyl alcohol, dipotassium hydrogen phosphate, sodium hydroxyethyl cellulose, borax, sodium lauryl sulphate and water standby;
(B) under condition of ice bath, polyvinyl alcohol is added to the water and is fully stirred, obtain polyvinyl alcohol water solution;
(C) at ambient temperature, in the polyvinyl alcohol water solution obtaining in step (B), slowly drip dipotassium hydrogen phosphate and sodium hydroxyethyl cellulose, stir rear standby;
(D) solution obtaining in step (C) is heated to 40-50 ℃, under high-speed stirring state, slowly adds sodium lauryl sulphate and borax, stir at ambient temperature, after naturally cooling, obtain described cold storage agent, after packing, obtain cold storage agent finished product.
Beneficial effect of the present invention is as follows:
1) preparation method of the present invention is simple, has reduced cost, more contributes to scale operation;
2) cold storage agent of the present invention is nontoxic, tasteless, reusable;
3) found through experiments, the latent heat of phase change of cold storage agent of the present invention is 260-320KJ/Kg, and transformation temperature is-10-4 ℃.
embodiment:
For technique means, creation characteristic that the present invention is realized, reach object and effect is easy to understand, below in conjunction with specific embodiment, further set forth the present invention.
Embodiment 1:
In the present embodiment, a kind of cold storage agent, according to weight percent meter, comprises polyvinyl alcohol 15%, dipotassium hydrogen phosphate 3%, sodium hydroxyethyl cellulose 0.5%, borax 0.2%, sodium lauryl sulphate 6%, water 75.3%.
The preparation method of described cold storage agent, is characterized in that, comprises following step:
(A) according to required ratio, be ready to polyvinyl alcohol, dipotassium hydrogen phosphate, sodium hydroxyethyl cellulose, borax, sodium lauryl sulphate and water standby;
(B) under condition of ice bath, polyvinyl alcohol is added to the water and is fully stirred, obtain polyvinyl alcohol water solution;
(C) at ambient temperature, in the polyvinyl alcohol water solution obtaining in step (B), slowly drip dipotassium hydrogen phosphate and sodium hydroxyethyl cellulose, stir rear standby;
(D) solution obtaining in step (C) is heated to 50 ℃, under high-speed stirring state, slowly adds sodium lauryl sulphate and borax, stir at ambient temperature, after naturally cooling, obtain described cold storage agent, after packing, obtain cold storage agent finished product.
1) preparation method of the present invention is simple, has reduced cost, more contributes to scale operation;
2) this cold storage agent is nontoxic, tasteless, reusable;
3) found through experiments, the latent heat of phase change of the present embodiment is 270KJ/Kg, and transformation temperature is-8 ℃.
Embodiment 2:
In this enforcement, a kind of cold storage agent, according to weight percent meter, comprises polyvinyl alcohol 20%, dipotassium hydrogen phosphate 1%, sodium hydroxyethyl cellulose 1.3%, borax 1.2%, sodium lauryl sulphate 2%, water 74.5%.
The preparation method of described cold storage agent, comprises following step:
(A) according to required ratio, be ready to polyvinyl alcohol, dipotassium hydrogen phosphate, sodium hydroxyethyl cellulose, borax, sodium lauryl sulphate and water standby;
(B) under condition of ice bath, polyvinyl alcohol is added to the water and is fully stirred, obtain polyvinyl alcohol water solution;
(C) at ambient temperature, in the polyvinyl alcohol water solution obtaining in step (B), slowly drip dipotassium hydrogen phosphate and sodium hydroxyethyl cellulose, stir rear standby;
(D) solution obtaining in step (C) is heated to 40 ℃, under high-speed stirring state, slowly adds sodium lauryl sulphate and borax, stir at ambient temperature, after naturally cooling, obtain described cold storage agent, after packing, obtain cold storage agent finished product.
1) preparation method of the present invention is simple, has reduced cost, more contributes to scale operation;
2) this cold storage agent is nontoxic, tasteless, reusable;
3) found through experiments, latent heat of phase change of the present invention is 300KJ/Kg, and transformation temperature is 0 ℃.
More than show and described ultimate principle of the present invention and principal character and advantage of the present invention.The technician of the industry should understand; the present invention is not restricted to the described embodiments; that in above-described embodiment and specification sheets, describes just illustrates principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.The claimed scope of the present invention is defined by appending claims and equivalent thereof
Figure 800625DEST_PATH_IMAGE001
Figure 780082DEST_PATH_IMAGE001
.

Claims (4)

1. a cold storage agent, is characterized in that, according to weight percent meter, comprises polyvinyl alcohol 15-20%, dipotassium hydrogen phosphate 1-3%, sodium hydroxyethyl cellulose 0.5-1.3%, borax 0.2-1.2%, sodium lauryl sulphate 2-6%, and surplus is water.
2. cold storage agent according to claim 1, is characterized in that, according to weight percent meter, comprises polyvinyl alcohol 15%, dipotassium hydrogen phosphate 3%, sodium hydroxyethyl cellulose 0.5%, borax 0.2%, sodium lauryl sulphate 6%, water 75.3%.
3. cold storage agent according to claim 1, is characterized in that, according to weight percent meter, comprises polyvinyl alcohol 20%, dipotassium hydrogen phosphate 1%, sodium hydroxyethyl cellulose 1.3%, borax 1.2%, sodium lauryl sulphate 2%, water 74.5%.
4. the preparation method of cold storage agent according to claim 1, is characterized in that, comprises following step:
(A) according to required ratio, be ready to polyvinyl alcohol, dipotassium hydrogen phosphate, sodium hydroxyethyl cellulose, borax, sodium lauryl sulphate and water standby;
(B) under condition of ice bath, polyvinyl alcohol is added to the water and is fully stirred, obtain polyvinyl alcohol water solution;
(C) at ambient temperature, in the polyvinyl alcohol water solution obtaining in step (B), slowly drip dipotassium hydrogen phosphate and sodium hydroxyethyl cellulose, stir rear standby;
(D) solution obtaining in step (C) is heated to 40-50 ℃, under high-speed stirring state, slowly adds sodium lauryl sulphate and borax, stir at ambient temperature, after naturally cooling, obtain described cold storage agent, after packing, obtain cold storage agent finished product.
CN201310685654.8A 2013-12-16 2013-12-16 Nontoxic odorless cold accumulation agent and preparation method thereof Pending CN103666384A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN201310685654.8A CN103666384A (en) 2013-12-16 2013-12-16 Nontoxic odorless cold accumulation agent and preparation method thereof

Publications (1)

Publication Number Publication Date
CN103666384A true CN103666384A (en) 2014-03-26

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104896822A (en) * 2015-06-30 2015-09-09 黄琳 Low-temperature chemical ice bag and preparation method thereof
CN106916570A (en) * 2015-12-24 2017-07-04 上海邦中高分子材料有限公司 A kind of combined phase-change energy storage material of high quality and at a reasonable price
CN107216861A (en) * 2017-07-25 2017-09-29 合肥嘉仕诚能源科技有限公司 A kind of compound agent for storage of coldness
CN108276967A (en) * 2018-01-31 2018-07-13 安徽工业大学 A kind of anti-leak cold-storage material and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1063302A (en) * 1992-01-16 1992-08-05 黑龙江商学院附属制冷设备厂 Cold storage agent and preparation method
CN102942905A (en) * 2012-11-20 2013-02-27 上海创始实业(集团)有限公司 Low temperature phase change cool storage agent and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1063302A (en) * 1992-01-16 1992-08-05 黑龙江商学院附属制冷设备厂 Cold storage agent and preparation method
CN102942905A (en) * 2012-11-20 2013-02-27 上海创始实业(集团)有限公司 Low temperature phase change cool storage agent and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104896822A (en) * 2015-06-30 2015-09-09 黄琳 Low-temperature chemical ice bag and preparation method thereof
CN106916570A (en) * 2015-12-24 2017-07-04 上海邦中高分子材料有限公司 A kind of combined phase-change energy storage material of high quality and at a reasonable price
CN107216861A (en) * 2017-07-25 2017-09-29 合肥嘉仕诚能源科技有限公司 A kind of compound agent for storage of coldness
CN108276967A (en) * 2018-01-31 2018-07-13 安徽工业大学 A kind of anti-leak cold-storage material and preparation method thereof

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