CN103254710A - Scraping water-in-water multi-color paint and preparation method thereof - Google Patents
Scraping water-in-water multi-color paint and preparation method thereof Download PDFInfo
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- CN103254710A CN103254710A CN2013101247083A CN201310124708A CN103254710A CN 103254710 A CN103254710 A CN 103254710A CN 2013101247083 A CN2013101247083 A CN 2013101247083A CN 201310124708 A CN201310124708 A CN 201310124708A CN 103254710 A CN103254710 A CN 103254710A
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Abstract
The invention especially relates to a scraping water-in-water multi-color paint and a preparation method thereof, which belongs to the field of building and ornament materials. The scraping water-in-water multi-color paint comprises a base paint and a continuous-phase emulsion paint and is prepared by subjecting the base paint to toning and multi-color particle granulation and mixing obtained multi-color particles with the continuous-phase emulsion paint according to a ratio of 5: 4. According to the invention, a pre-dissolved thickening agent is used to increase the viscosity of the dispersed aqueous multi-color particles, adjust a ratio of protective colloid and a gel reactant, enhance stability of the surface layer of the aqueous multi-color particles and increase viscosity of a finished paint; mechanical stability of the aqueous multi-color particles of the multi-color paint during construction of the finished paint is improved, scraping construction of the multi-color paint is realized, the degree of restriction by a variety of construction conditions is substantially reduced, operation is easy and convenient, requirements on operation capability of constructors are low, consistency of a finished paint film obtained after construction can be well guaranteed, and considerable defects of a traditional multi-color paint which can only be sprayed are overcome.
Description
Technical field
The present invention discloses a kind of architectural decoration material field, particularly a kind of crowd of preparation method who scrapes type water bag water multicolor finish.
Background technology
Water bag water multicolor finish is very popular product innovation type in the building coating industry in recent years, and product is theoretical basis with physicochemical colloid technology and process for treating surface; Liquid aqueous resin refinement is rolled into the multiple gluey hydrate colour particle that varies in size, varies in color, and even stable suspension disperses to be in the special external phase aqueous emulsion paint, through a construction molding, and the effect of decorative patterns of the artificial granite stone material of finished product can reach the degree of mixing the spurious with the genuine; Product is form of construction work with the spraying, substitutes stone material and be widely used in decoration of exterior wall in recent years, but have environmental protection and energy saving, easy construction, durable in use, reprocess characteristics easily, development prospect is very wide; Since water bag aqueous systems store, stable bad in transportation and the construction, after when practical application, being difficult to guarantee to construct, the consistence of paint film effect, this is the major cause that limits product is promoted on a large scale.
Summary of the invention
The objective of the invention is to adjust the proportioning of protective colloid and gel reaction agent by using pre-molten thickening material to improve the viscosity of disperseing the aqueous colorful particle, strengthen aqueous colorful particle top layer stability, improve the viscosity of finished product lacquer; Improve multi-color lacquer aqueous colorful particle in the mechanical stability of finished product lacquer construction, multi-color lacquer can be criticized scrape construction; The paint film effect is subjected to the defective of construction environment restriction and consistence difference when improving water bag water multicolor finish spraying application, scrapes type water bag water multicolor finish for related a kind of batch.
For realizing that the technical scheme that purpose of the present invention adopts is:. scrape type water bag water multicolor finish for a kind of batch, it is characterized in that: comprise base paint and external phase emulsion coatings, the color particle that described base paint obtains after toning and the granulation of color grain and external phase emulsion coatings form according to the mixed of 5:4; Wherein:
The component of described base paint weight part:
Deionized water 25-30 part
Natvosol 0.5-1 part
Ammonium salt dispersion agent 0.5-1 part
Negatively charged ion wetting agent 0.2-0.5 part
Defoamer 0.2-0.5 part
Sanitas 0.2-0.5 part
Water-washed kaoline 8-10 part
Rutile titanium white powder 1-3 part
1250 order talcum powder 4-6 parts
PH conditioning agent 0.1-0.5 part
Ethylene glycol 0.2-0.5 part
Film coalescence aid 1-3 part
Pure acrylate elastic emulsion 25-30 part
Gel reaction agent 0.1-0.3 part
Complex protection colloidal solution A 10-15 part
Pre-molten thickening material 10-15 part;
The component of described external phase emulsion coatings weight part:
Deionized water 25-30 part
Organosilicon crylic acid latex 55-60 part
Sanitas 0.2-0.5 part
Mould inhibitor 0.5-1.0 part
Ethylene glycol 2-4 part
Film coalescence aid 3-5 part
Defoamer 0.5-1 part
PH conditioning agent 0.5-1 part
Pre-molten thickening material 10-12 part.
The described a kind of crowd of preparation method who scrapes type water bag water multicolor finish may further comprise the steps composition:
A. under whipped state, Natvosol is slowly added in the deionized water, observed into translucent viscous fluid in high speed dispersion 10-15 minute;
B. add ammonium salt dispersion agent, negatively charged ion wetting agent, defoamer and sanitas, and add water-washed kaoline, rutile titanium white powder and 1250 order talcum powder, high speed dispersion 20-30 minute to fineness≤60 μ m;
C. adding PH conditioning agent, ethylene glycol, film coalescence aid and pure acrylate elastic emulsion under the middling speed whipped state successively stirs, and slowly adding the gel reaction agent stirred 10 minutes, the gel reaction agent is fully mixed with each component, slowly add complex protection colloidal solution A and stir, use pre-molten thickening material to adjust viscosity and be 140KU-145KU;
D. base paint is mixed colours as required;
The various colored paints that E. will mix up look use churned mechanically method to carry out granulation with after complex protection colloidal solution B mixes according to the ratio of 1:1;
F. under whipped state, organosilicon crylic acid latex is slowly poured in the deionized water, slowly added organosilicon crylic acid latex, sanitas, mould inhibitor, ethylene glycol, film coalescence aid, defoamer, PH conditioning agent and pre-molten thickening material successively and mix;
G. under whipped state, according to the ratio of 4:5 the external phase emulsion is added in the color particle, transfer to after viscosity is 100-105KU with pre-molten thickening material, i.e. packing.
Described complex protection colloidal solution A is the aqueous solution of 8% protection glue.
Described complex protection colloidal solution B is the aqueous solution of 8% protection glue and 3% gel reaction agent.
The present invention has following advantage:
The present invention improves the viscosity of disperseing the aqueous colorful particle by using pre-molten thickening material, adjusts the proportioning of protective colloid and gel reaction agent, strengthens aqueous colorful particle top layer stability, improves the viscosity of finished product lacquer; Improve multi-color lacquer aqueous colorful particle in the mechanical stability of finished product lacquer construction, multi-color lacquer can be criticized scrape construction, reduce the degree that is not subjected to various limitation of construction greatly, operational capability to the workmen requires also more simple and convenient, and the consistence of the back finished product paint film that can well guarantee to construct, solved traditional multi-color lacquer can only the many defectives of spraying application.
Embodiment
The present invention will be described in detail below in conjunction with specific embodiment.
Illustrated embodiments of the present invention:
Scrape type water bag water multicolor finish, it is characterized in that for a kind of batch: comprise base paint and external phase emulsion coatings, the color particle that described base paint obtains after toning and the granulation of color grain and external phase emulsion coatings form according to the mixed of 5:4; Wherein:
The component of described base paint weight part:
28.0 parts of deionized waters
0.8 part of Natvosol
0.6 part of ammonium salt dispersion agent
0.2 part of negatively charged ion wetting agent
0.3 part of defoamer
0.2 part of sanitas
9 parts of water-washed kaolines
2 parts in rutile titanium white powder
5 parts of 1250 order talcum powder
0.15 part of PH conditioning agent
0.2 part of ethylene glycol
1.4 parts of film coalescence aid
28.0 parts of pure acrylate elastic emulsions
0.1 part of gel reaction agent
12 parts of complex protection colloidal solution A
12.0 parts of pre-molten thickening materials;
The component of described external phase emulsion coatings weight part:
25.25 parts of deionized waters
57.5 parts of organosilicon crylic acid latexs
0.25 part of sanitas
0.5 part of mould inhibitor
2.5 parts of ethylene glycol
3.0 parts of film coalescence aid
0.50 part of defoamer
0.50 part of PH conditioning agent
10.30 parts of pre-molten thickening materials.
The described a kind of crowd of preparation method who scrapes type water bag water multicolor finish may further comprise the steps composition:
A. under whipped state, Natvosol is slowly added in the deionized water, observed into translucent viscous fluid in high speed dispersion 10-15 minute;
B. add ammonium salt dispersion agent, negatively charged ion wetting agent, defoamer and sanitas, and add water-washed kaoline, rutile titanium white powder and 1250 order talcum powder, high speed dispersion 20-30 minute to fineness≤60 μ m;
C. adding PH conditioning agent, ethylene glycol, film coalescence aid and pure acrylate elastic emulsion under the middling speed whipped state successively stirs, and slowly adding the gel reaction agent stirred 10 minutes, the gel reaction agent is fully mixed with each component, slowly add complex protection colloidal solution A and stir, use pre-molten thickening material to adjust viscosity and be 140KU-145KU;
D. base paint is mixed colours as required;
The various colored paints that E. will mix up look use churned mechanically method to carry out granulation with after complex protection colloidal solution B mixes according to the ratio of 1:1;
F. under whipped state, organosilicon crylic acid latex is slowly poured in the deionized water, slowly added organosilicon crylic acid latex, sanitas, mould inhibitor, ethylene glycol, film coalescence aid, defoamer, PH conditioning agent and pre-molten thickening material successively and mix;
G. under whipped state, according to the ratio of 4:5 the external phase emulsion is added in the color particle, transfer to after viscosity is 100-105KU with pre-molten thickening material, i.e. packing.
Claims (4)
1. scrape type water bag water multicolor finish for one kind batch, it is characterized in that: comprise base paint and external phase emulsion coatings, the color particle that described base paint obtains after toning and the granulation of color grain and external phase emulsion coatings form according to the mixed of 5:4; Wherein:
The component of described base paint weight part:
Deionized water 25-30 part
Natvosol 0.5-1 part
Ammonium salt dispersion agent 0.5-1 part
Negatively charged ion wetting agent 0.2-0.5 part
Defoamer 0.2-0.5 part
Sanitas 0.2-0.5 part
Water-washed kaoline 8-10 part
Rutile titanium white powder 1-3 part
1250 order talcum powder 4-6 parts
PH conditioning agent 0.1-0.5 part
Ethylene glycol 0.2-0.5 part
Film coalescence aid 1-3 part
Pure acrylate elastic emulsion 25-30 part
Gel reaction agent 0.1-0.3 part
Complex protection colloidal solution A 10-15 part
Pre-molten thickening material 10-15 part;
The component of described external phase emulsion coatings weight part:
Deionized water 25-30 part
Organosilicon crylic acid latex 55-60 part
Sanitas 0.2-0.5 part
Mould inhibitor 0.5-1.0 part
Ethylene glycol 2-4 part
Film coalescence aid 3-5 part
Defoamer 0.5-1 part
PH conditioning agent 0.5-1 part
Pre-molten thickening material 10-12 part.
2. above-mentioned crowd of preparation method who scrapes type water bag water multicolor finish, it is characterized in that: described this method may further comprise the steps composition:
A. under whipped state, Natvosol is slowly added in the deionized water, disperse to observe in 10-15 minute translucent viscous fluid;
B. add ammonium salt dispersion agent, negatively charged ion wetting agent, defoamer and sanitas, and add water-washed kaoline, rutile titanium white powder and 1250 order talcum powder, high speed dispersion 20-30 minute to fineness≤60 μ m;
C. adding PH conditioning agent, ethylene glycol, film coalescence aid and pure acrylate elastic emulsion under whipped state successively stirs, and slowly adding the gel reaction agent stirred 10 minutes, the gel reaction agent is fully mixed with each component, slowly add complex protection colloidal solution A and stir, use pre-molten thickening material to adjust viscosity and be 140KU-145KU;
D. base paint is mixed colours as required;
The various colored paints that E. will mix up look use churned mechanically method to carry out granulation with after complex protection colloidal solution B mixes according to the ratio of 1:1;
F. under whipped state, organosilicon crylic acid latex is slowly poured in the deionized water, slowly added organosilicon crylic acid latex, sanitas, mould inhibitor, ethylene glycol, film coalescence aid, defoamer, PH conditioning agent and pre-molten thickening material successively and mix;
G. under whipped state, according to the ratio of 4:5 the external phase emulsion is added in the color particle, transfer to after viscosity is 100-105KU with pre-molten thickening material, i.e. packing.
3. a kind of crowd of preparation method who scrapes type water bag water multicolor finish according to claim 2 is characterized in that: described complex protection colloidal solution A is the aqueous solution of 8% protection glue.
4. a kind of crowd of preparation method who scrapes type water bag water multicolor finish according to claim 2 is characterized in that: described complex protection colloidal solution B is the aqueous solution of 8% protection glue and 3% gel reaction agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310124708.3A CN103254710B (en) | 2013-04-11 | 2013-04-11 | A kind of batch of scratch-type water-in-water multicolor coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310124708.3A CN103254710B (en) | 2013-04-11 | 2013-04-11 | A kind of batch of scratch-type water-in-water multicolor coating and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
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| CN103254710A true CN103254710A (en) | 2013-08-21 |
| CN103254710B CN103254710B (en) | 2016-12-28 |
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| CN201310124708.3A Active CN103254710B (en) | 2013-04-11 | 2013-04-11 | A kind of batch of scratch-type water-in-water multicolor coating and preparation method thereof |
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Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103952051A (en) * | 2014-05-22 | 2014-07-30 | 富思特新材料科技发展股份有限公司 | Internally-crosslinked multicolor paint and preparation method thereof |
| CN104194456A (en) * | 2014-08-29 | 2014-12-10 | 亚士漆(上海)有限公司 | Water-in-water colorful reflective insulating stone-like coating and preparation method thereof |
| CN104194457A (en) * | 2014-08-29 | 2014-12-10 | 亚士漆(上海)有限公司 | Toning base paint for sand-wall multicolor coating, and sand-wall multicolor coating and preparation method thereof |
| CN104293055A (en) * | 2014-09-30 | 2015-01-21 | 陈潮汉 | Aqueous brushing type colorful paint and preparation method thereof |
| CN104725944A (en) * | 2013-12-18 | 2015-06-24 | 浙江曼得丽涂料有限公司 | Aqueous rock color paint and preparation method thereof |
| CN104761967A (en) * | 2015-03-10 | 2015-07-08 | 安徽省贝安居建筑节能材料科技有限公司 | W/W sand brick-containing rock coating |
| CN106147476A (en) * | 2015-04-13 | 2016-11-23 | 富阳科信经济信息咨询有限公司 | A kind of production technology of water type multicolor paint for water drum |
| CN106752482A (en) * | 2015-11-25 | 2017-05-31 | 铂恩塞尔新材料（上海）股份有限公司 | A kind of water burnt-in sand multicolor finish and preparation method thereof |
| CN106833298A (en) * | 2016-12-30 | 2017-06-13 | 大厂金隅涂料有限责任公司 | A kind of artificial granite paint |
| CN107434938A (en) * | 2016-05-25 | 2017-12-05 | 上海三银涂料科技股份有限公司 | Colour aqueous colorful building coating of colloid resist blocking and that and preparation method thereof |
| CN108485437A (en) * | 2018-04-25 | 2018-09-04 | 廊坊旭博涂立德新型材料科技有限公司 | A kind of colorful paint formula |
| CN109665750A (en) * | 2018-12-27 | 2019-04-23 | 亚士漆(上海)有限公司 | Water-in-water multicolor coating and preparation method thereof, construction method and application |
| CN110540783A (en) * | 2019-08-28 | 2019-12-06 | 北京莱恩斯新材料科技有限公司 | Matte water-in-water base paint, preparation method and matte water-in-water coating |
| CN111826040A (en) * | 2020-07-02 | 2020-10-27 | 广东嘉宝莉科技材料有限公司 | Water-in-water multicolor paint with strong layering sense and capable of being coated in batches and preparation method thereof |
| CN111892876A (en) * | 2020-08-11 | 2020-11-06 | 河北品致涂料有限公司 | Batch-scraping type multicolor paint and construction process thereof |
| CN112300650A (en) * | 2020-11-18 | 2021-02-02 | 福州居家逸涂料科技有限公司 | Scraping type stone-like paint and application thereof |
| CN113583528A (en) * | 2021-08-02 | 2021-11-02 | 佛山市顺德区佳涂乐恒融建筑装饰有限公司 | Batch-scraping type multicolor paint and construction process thereof |
| CN113667367A (en) * | 2021-09-02 | 2021-11-19 | 浙江曼得丽涂料有限公司 | Water-based interior wall soft sand coating and preparation method thereof |
| CN115477862A (en) * | 2021-05-31 | 2022-12-16 | 立邦涂料（中国）有限公司 | Inorganic water-in-water multicolor interior wall coating and preparation method thereof |
| CN115926559A (en) * | 2022-11-10 | 2023-04-07 | 浙江添艺新材料有限公司 | Anti-aging batch-scraping type colorful stone-like paint and preparation method thereof |
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Cited By (26)
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| CN104725944A (en) * | 2013-12-18 | 2015-06-24 | 浙江曼得丽涂料有限公司 | Aqueous rock color paint and preparation method thereof |
| CN103952051B (en) * | 2014-05-22 | 2016-08-31 | 富思特新材料科技发展股份有限公司 | Interior crosslinking multicolor finish and preparation method thereof |
| CN103952051A (en) * | 2014-05-22 | 2014-07-30 | 富思特新材料科技发展股份有限公司 | Internally-crosslinked multicolor paint and preparation method thereof |
| CN104194456A (en) * | 2014-08-29 | 2014-12-10 | 亚士漆(上海)有限公司 | Water-in-water colorful reflective insulating stone-like coating and preparation method thereof |
| CN104194457A (en) * | 2014-08-29 | 2014-12-10 | 亚士漆(上海)有限公司 | Toning base paint for sand-wall multicolor coating, and sand-wall multicolor coating and preparation method thereof |
| CN104194457B (en) * | 2014-08-29 | 2017-06-20 | 亚士创能科技(上海)股份有限公司 | Sand wall-like multicolor finish and preparation method thereof |
| CN104293055B (en) * | 2014-09-30 | 2017-11-14 | 江门市万兴佳化工有限公司 | A kind of water-based brush-on-type multicolor finish and preparation method thereof |
| CN104293055A (en) * | 2014-09-30 | 2015-01-21 | 陈潮汉 | Aqueous brushing type colorful paint and preparation method thereof |
| CN104761967A (en) * | 2015-03-10 | 2015-07-08 | 安徽省贝安居建筑节能材料科技有限公司 | W/W sand brick-containing rock coating |
| CN106147476A (en) * | 2015-04-13 | 2016-11-23 | 富阳科信经济信息咨询有限公司 | A kind of production technology of water type multicolor paint for water drum |
| CN106752482A (en) * | 2015-11-25 | 2017-05-31 | 铂恩塞尔新材料（上海）股份有限公司 | A kind of water burnt-in sand multicolor finish and preparation method thereof |
| CN107434938A (en) * | 2016-05-25 | 2017-12-05 | 上海三银涂料科技股份有限公司 | Colour aqueous colorful building coating of colloid resist blocking and that and preparation method thereof |
| CN106833298B (en) * | 2016-12-30 | 2019-02-22 | 大厂金隅涂料有限责任公司 | A kind of artificial granite paint |
| CN106833298A (en) * | 2016-12-30 | 2017-06-13 | 大厂金隅涂料有限责任公司 | A kind of artificial granite paint |
| CN108485437A (en) * | 2018-04-25 | 2018-09-04 | 廊坊旭博涂立德新型材料科技有限公司 | A kind of colorful paint formula |
| CN109665750A (en) * | 2018-12-27 | 2019-04-23 | 亚士漆(上海)有限公司 | Water-in-water multicolor coating and preparation method thereof, construction method and application |
| CN110540783B (en) * | 2019-08-28 | 2021-04-20 | 北京莱恩斯新材料科技有限公司 | Matte water-in-water base paint, preparation method and matte water-in-water coating |
| CN110540783A (en) * | 2019-08-28 | 2019-12-06 | 北京莱恩斯新材料科技有限公司 | Matte water-in-water base paint, preparation method and matte water-in-water coating |
| CN111826040A (en) * | 2020-07-02 | 2020-10-27 | 广东嘉宝莉科技材料有限公司 | Water-in-water multicolor paint with strong layering sense and capable of being coated in batches and preparation method thereof |
| CN111892876A (en) * | 2020-08-11 | 2020-11-06 | 河北品致涂料有限公司 | Batch-scraping type multicolor paint and construction process thereof |
| CN112300650A (en) * | 2020-11-18 | 2021-02-02 | 福州居家逸涂料科技有限公司 | Scraping type stone-like paint and application thereof |
| CN115477862A (en) * | 2021-05-31 | 2022-12-16 | 立邦涂料（中国）有限公司 | Inorganic water-in-water multicolor interior wall coating and preparation method thereof |
| CN115477862B (en) * | 2021-05-31 | 2023-09-05 | 立邦涂料（中国）有限公司 | Inorganic water-in-water multicolor interior wall coating and preparation method thereof |
| CN113583528A (en) * | 2021-08-02 | 2021-11-02 | 佛山市顺德区佳涂乐恒融建筑装饰有限公司 | Batch-scraping type multicolor paint and construction process thereof |
| CN113667367A (en) * | 2021-09-02 | 2021-11-19 | 浙江曼得丽涂料有限公司 | Water-based interior wall soft sand coating and preparation method thereof |
| CN115926559A (en) * | 2022-11-10 | 2023-04-07 | 浙江添艺新材料有限公司 | Anti-aging batch-scraping type colorful stone-like paint and preparation method thereof |
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|---|---|
| CN103254710B (en) | 2016-12-28 |
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