CN103131110A - Inflaming retarding poly carbonate(PC)/poly styrene (PS) mixed alloy materials and manufacture method and purpose thereof - Google Patents
Inflaming retarding poly carbonate(PC)/poly styrene (PS) mixed alloy materials and manufacture method and purpose thereof Download PDFInfo
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Abstract
The invention belongs to the technical field of high polymer materials and relates to inflaming retarding poly carbonate(PC)/poly styrene (PS) mixed alloy materials and a manufacture method and a purpose of the inflaming retarding PC/PS mixed alloy materials. The inflaming retarding PC/PS mixed alloy materials comprise, by weight, 70 parts to 80 parts of PS, 10 parts to 20 parts of PC, 5 parts to 15 parts of glass fibers, 3 parts to 6 parts of red phosphorus, 0.2 part to 0.5 part of a lubricating agent, 0.2 part to 0.5 part of an anti-oxygen agent and 0.5 part to 1.5 parts of assistant agents. The inflaming retarding PC/PS plastic alloy replaces a gypsum plate or a wood plate for manufacturing a ceiling board. One one hand, energy is saved, the aim of replacing wood by plastic is achieved and the superior inflaming retarding performance can guarantee the safety performance of the plastic, on the other hand, the glass fibers are included by the particle material set, whole strength of the materials is greatly enhanced and highly impact-resistant styrene has good toughness so that the alloy has good toughness and strength at the same time.
Description
Technical field
The invention belongs to technical field of polymer materials, relate to a kind of fire retardation PC/PS (polycarbonate/polystyrene) blend alloy material and its production and use.
Background technology
Along with the progress of society, the development of science and technology, people's life are more and more convenient, and people are to inherently safe and also more and more higher to the environmental concern degree simultaneously.At the modern house repairs profession, top ceiling is the part that people attach great importance to always, is the live important guarantees of comfort level of people.
Top ceiling is mainly with plasterboard at present, plank, and glued board, aluminum-pinch are main raw, its material mostly is inflammable material and can produces a large amount of smog and drip phenomenon in combustion processes.Top ceiling is in people's life staying idle at home, personnel safety to be threatened the best part, causes fire uncontrollable because top ceiling is fire-retardant in fire, causes a large amount of people life property loss' example of common occurrence.Its top ceiling exists inflammable potential safety hazard always.Simultaneously country advocates " to mould Dai Gang, to mould Dai Mu ", and invent a kind of novel flame-retardant high-strength top ceiling materials and necessitate, and this kind material must satisfy high strength, high tenacity, corrosion-resistant, and can apply the requirements such as good flame resistance.
Summary of the invention
The object of the invention is to for the defective of prior art and a kind of flame retardant resistance PC/PS blend alloy material and its production and use is provided.
For achieving the above object, the present invention is by the following technical solutions:
A kind of PC/PS blend alloy material, this material is made by the component that comprises following weight part:
Polystyrene 70-80 part,
Polycarbonate (PC) 10-20 part,
Glass fibre 5-15 part,
Red phosphorus 3-6 part,
Lubricant 0.2-0.5 part,
Oxidation inhibitor 0.2-0.5 part,
Auxiliary agent 0.5-1.5 part.
Described polystyrene is high-impact polystyrene.
Described glass fiber diameter is 6-18 μ m, preferred 8-12 μ m.
Described red phosphorus is red phosphorus 440T (main component is phosphorus).
Described lubricant is selected from one or more in stearyl alcohol, silicone, paraffin or Zinic stearas.
Described oxidation inhibitor is selected from antioxidant 1010 (four [β-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic ester] pentaerythritol ester), one or more in antioxidant 1076 (β-positive octadecanol ester of (3,5-di-tert-butyl-hydroxy phenyl) propionic acid) or irgasfos 168 (three [2.4-di-tert-butyl-phenyl] phosphorous acid ester).
Described auxiliary agent is selected from one or more in thermo-stabilizer, processing stabilizers, filler, softening agent, nucleator or coupling agent.
Described thermo-stabilizer is SP-1934, is mainly calcium zinc stabilizer (selling manufacturer is: sharp trade Co., Ltd is risen in the Guangzhou).
Described processing stabilizers is elected PPA-3520 as, and main component is the fluoro containing polymers polymkeric substance (production firm: the Jilin good plastic cement of dragon company limited) of high molecular.
Described filler is selected from calcium carbonate or talcum powder.
Described softening agent is dioctyl phthalate (DOP) (DOP).
Described nucleator is saturated carboxylic acid sodium salt (NaV101).
Described coupling agent is phthalate ester coupling agent, preferred three iso stearate isopropyl titanates (NDZ-132).
A kind of above-mentioned PC/PS blend alloy material preparation method, the method comprises the following steps:
(1) take each component raw material by said ratio;
(2) with above-mentioned raw materials through high mixer high speed mixing, then pour compound into screw extrusion press, can obtain product through the pelletizing of screw extrusion press tie rod.
In described step (1), the high mixer rotating speed is 800-1000rpm, and mixing temperature is 30-60 ℃, and mixing time is 5-15 minute.
Described screw extrusion press is single screw extrusion machine or twin screw extruder.
The extrusion temperature of described step (2) is 220-260 ℃.
A kind of above-mentioned fire retardation PC/PS blend alloy material is as the purposes of water top ceiling material.
The present invention has following beneficial effect:
The present invention replaces plasterboard or plank to make top ceiling with fire retardation PC/PS polyblend, on the one hand can save energy, realize guaranteeing its safety performance with the purpose of moulding Dai Mu its good flame retardant properties simultaneously.On the other hand, contain glass fibre in this granular component, strengthened greatly the bulk strength of material, the high impact styrene ability has good toughness, makes this alloy have simultaneously good toughness and intensity.
Embodiment
The present invention is described in detail below in conjunction with specific embodiment.
Embodiment 1
(1) prepare raw material according to following component and content: 70 parts of high-impact polystyrenes, 20 parts of polycarbonate, 10 parts, glass fibre, 5 parts, red phosphorus, 0.5 part of silicone, 0.5 part of antioxidant 1010,0.5 part of filler-calcium carbonate;
(2) controlling high mixer speed is 800-1000rmp, and temperature is 30 ℃, mixes 15 minutes, and above-mentioned raw materials through high mixer high speed mixing, controlling temperature at 220-240 ℃, can be obtained product with mixture through the pelletizing of screw extrusion press tie rod.
Embodiment 2
(1) prepare raw material according to following component and content: 80 parts of high-impact polystyrenes, 10 parts of polycarbonate, 10 parts, glass fibre, 3 parts, red phosphorus, 0.2 part of silicone, 0.5 part of antioxidant 1010,1 part of filler talcum powder;
(2) controlling high mixer speed is 800-1000rmp, and temperature is 60 ℃, mixes 5 minutes, and above-mentioned raw materials through high mixer high speed mixing, controlling temperature at 240-260 ℃, can be obtained product with mixture through the pelletizing of screw extrusion press tie rod.
Embodiment 3
(1) prepare raw material according to following component and content: 75 parts of high-impact polystyrenes, 10 parts of polycarbonate, 15 parts, glass fibre, 6 parts, red phosphorus, 0.2 part of silicone, 0.2 part of antioxidant 1010, processing aid PPA-35200.5 part, 0.3 part of nucleator;
(2) controlling high mixer speed is 800-1000rmp, and temperature is 60 ℃, mixes 10 minutes, and above-mentioned raw materials through high mixer high speed mixing, controlling temperature at 240-260 ℃, can be obtained product with mixture through the pelletizing of screw extrusion press tie rod.Its performance is referring to table 1.
Embodiment 4
(1) prepare raw material according to following component and content: 80 parts of high-impact polystyrenes, polycarbonate 20,5 parts, glass fibre, 4 parts, red phosphorus, 0.5 part of silicone, 0.5 part of antioxidant 1010,0.5 part of processing aid PPA-3520,0.5 part of thermo-stabilizer SP-1934;
(2) controlling high mixer speed is 800-1000rmp, and temperature is 60 ℃, mixes 5 minutes, and above-mentioned raw materials through high mixer high speed mixing, controlling temperature at 240-260 ℃, can be obtained product with mixture through the pelletizing of screw extrusion press tie rod.
Embodiment 5
(1) prepare raw material according to following component and content: 75 parts of high-impact polystyrenes, 10 parts of polycarbonate, 15 parts, glass fibre, 4 parts, red phosphorus, 0.5 part of silicone, 0.2 part of antioxidant 1010,0.5 part of processing aid PPA-3520,1 part of talcum powder;
(2) controlling high mixer speed is 800-1000rmp, and temperature is 50 ℃, mixes 10 minutes, and above-mentioned raw materials through high mixer high speed mixing, controlling temperature at 240-260 ℃, can be obtained product with mixture through the pelletizing of screw extrusion press tie rod.
Embodiment 6
(1) prepare raw material according to following component and content: 80 parts of high-impact polystyrenes, 15 parts of polycarbonate, 5 parts, glass fibre, 4 parts, red phosphorus, 0.2 part of Zinic stearas, 0.3 part of irgasfos 168,0.5 part of processing aid PPA-3520,1 part of filler-calcium carbonate;
(2) controlling high mixer speed is 800-1000rmp, and temperature is 40 ℃, mixes 15 minutes, and above-mentioned raw materials through high mixer high speed mixing, controlling temperature at 230-260 ℃, can be obtained product with mixture through the pelletizing of screw extrusion press tie rod.
Embodiment 7
(1) prepare raw material according to following component and content: 80 parts of high-impact polystyrenes, 10 parts of polycarbonate, 15 parts, glass fibre, 4 parts, red phosphorus, 0.2 part, paraffin, 0.5 part of antioxidant 1076,0.5 part of plasticizer DOP, 0.5 part of processing aid PPA-3520;
(2) controlling high mixer speed is 800-1000rmp, and temperature is 40 ℃, mixes 15 minutes, and above-mentioned raw materials through high mixer high speed mixing, controlling temperature at 240-260 ℃, can be obtained product with mixture through the pelletizing of screw extrusion press tie rod.
Embodiment 8
(1) prepare raw material according to following component and content: 80 parts of high-impact polystyrenes, 10 parts of polycarbonate, 10 parts, glass fibre, 6 parts, red phosphorus, 0.5 part of silicone, 0.5 part of antioxidant 1010, processing aid PPA-35200.5 part, plasticizer DOP is part O.5;
(2) controlling high mixer speed is 800-1000rmp, and temperature is 80 ℃, mixes 8 minutes, and above-mentioned raw materials through high mixer high speed mixing, controlling temperature at 240-260 ℃, can be obtained product with mixture through the pelletizing of screw extrusion press tie rod.
Embodiment 9
(1) prepare raw material according to following component and content: 70 parts of high-impact polystyrenes, 20 parts of polycarbonate, 15 parts, glass fibre, 3 parts, red phosphorus, 0.5 part of silicone, 0.5 part of irgasfos 168,0.5 part processing aid PPA-3520,0.5 part of phthalate ester coupling agent NDZ-132;
(2) controlling high mixer speed is 800-1000rmp, and temperature is 30 ℃, mixes 15 minutes, and above-mentioned raw materials through high mixer high speed mixing, controlling temperature at 240-260 ℃, can be obtained product with mixture through the pelletizing of screw extrusion press tie rod.
Embodiment 10
(1) prepare raw material according to following component and content: 70 parts of high-impact polystyrenes, 20 parts of polycarbonate, 15 parts, glass fibre, 3 parts, red phosphorus, 0.5 part of stearyl alcohol, 0.5 part of irgasfos 168,1 part of processing aid PPA-3520, phthalate ester coupling agent NDZ-1320.5 part;
(2) controlling high mixer speed is 800-1000rmp, and temperature is 30 ℃, mixes 15 minutes, and above-mentioned raw materials through high mixer high speed mixing, controlling temperature at 240-260 ℃, can be obtained product with mixture through the pelletizing of screw extrusion press tie rod.
Physicochemical property:
Table 1
Test data in table 1 is the physical and chemical parameter of embodiment 3, the product that makes of embodiment 3 as can be drawn from Table 1, and its performance is enough to the top ceiling service requirements, and its good flame retardant resistance guarantees to use safety simultaneously, and save energy realizes to mould the purpose of Dai Mu.Polyblend has fabulous erosion resistance, contains glass fibre in this granular component simultaneously, has strengthened greatly the bulk strength of material.
The above-mentioned description to embodiment is can understand and apply the invention for ease of those skilled in the art.The person skilled in the art obviously can easily make various modifications to these embodiment, and in the General Principle of this explanation is applied to other embodiment and needn't pass through performing creative labour.Therefore, the invention is not restricted to the embodiment here, those skilled in the art are according to announcement of the present invention, and not breaking away from the improvement that category of the present invention makes and revise all should be within protection scope of the present invention.
Claims (10)
1. polycarbonate/polystyrene blend alloy material, it is characterized in that: this material is made by the component that comprises following weight part:
Polystyrene 70-80 part,
Polycarbonate 10-20 part,
Glass fibre 5-15 part,
Red phosphorus 3-6 part,
Lubricant 0.2-0.5 part,
Oxidation inhibitor 0.2-0.5 part,
Auxiliary agent 0.5-1.5 part.
2. polycarbonate according to claim 1/polystyrene blend alloy material, it is characterized in that: described polystyrene is high-impact polystyrene;
Or described glass fiber diameter is 6-18 μ m, preferred 8-12 μ m;
Or described red phosphorus is red phosphorus 440T.
3. polycarbonate according to claim 1/polystyrene blend alloy material, it is characterized in that: described lubricant is selected from one or more in stearyl alcohol, silicone, paraffin or Zinic stearas;
Or described oxidation inhibitor is selected from antioxidant 1010 (four [β-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic ester] pentaerythritol ester), one or more in antioxidant 1076 (β-positive octadecanol ester of (3,5-di-tert-butyl-hydroxy phenyl) propionic acid) or irgasfos 168 (three [2.4-di-tert-butyl-phenyl] phosphorous acid ester).
4. polycarbonate according to claim 1/polystyrene blend alloy material, it is characterized in that: described auxiliary agent is selected from one or more in thermo-stabilizer, processing stabilizers, filler, softening agent, nucleator or coupling agent.
5. polycarbonate according to claim 4/polystyrene blend alloy material, it is characterized in that: described thermo-stabilizer is SP-1934;
Or described processing stabilizers is PPA-3520;
Or described filler is selected from calcium carbonate or talcum powder.
6. polycarbonate according to claim 4/polystyrene blend alloy material, it is characterized in that: described softening agent is dioctyl phthalate (DOP).
7. polycarbonate according to claim 4/polystyrene blend alloy material, it is characterized in that: described nucleator is the saturated carboxylic acid sodium salt;
Or described coupling agent is phthalate ester coupling agent, preferred three iso stearate isopropyl titanates.
8. arbitrary described polycarbonate/polystyrene blend alloy material preparation method in a claims 1-7, it is characterized in that: the method comprises the following steps:
(1) take each component raw material by proportioning claimed in claim 1;
(2) with above-mentioned raw materials through high mixer high speed mixing, then pour compound into screw extrusion press, can obtain product through the pelletizing of screw extrusion press tie rod.
9. preparation method according to claim 8 is characterized in that: in described step (2), the high mixer rotating speed is 800-1000rpm, and mixing temperature is 30-60 ℃, and mixing time is 5-15 minute;
Or described screw extrusion press is single screw extrusion machine or twin screw extruder;
Or the extrusion temperature of described step (2) is 220-260 ℃.
In a claims 1-7 arbitrary described polycarbonate/polystyrene blend alloy material as the purposes of water top ceiling material.
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| Application Number | Priority Date | Filing Date | Title |
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| CN2011103883544A CN103131110A (en) | 2011-11-29 | 2011-11-29 | Inflaming retarding poly carbonate(PC)/poly styrene (PS) mixed alloy materials and manufacture method and purpose thereof |
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| CN2011103883544A CN103131110A (en) | 2011-11-29 | 2011-11-29 | Inflaming retarding poly carbonate(PC)/poly styrene (PS) mixed alloy materials and manufacture method and purpose thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103965558A (en) * | 2014-04-11 | 2014-08-06 | 苏州市依星橡塑有限公司 | Preparation technology of oxidation resisting plastic film |
| CN104961989A (en) * | 2015-07-30 | 2015-10-07 | 苏州荣昌复合材料有限公司 | Polystyrene modified plastic and preparation method thereof |
| CN106947174A (en) * | 2017-03-31 | 2017-07-14 | 东莞市美饰家窗帘制品有限公司 | A kind of louver lamina composite and its method for preparing the louver lamina |
| CN107216559A (en) * | 2017-07-21 | 2017-09-29 | 安徽江淮汽车集团股份有限公司 | A kind of PS PC composites and preparation method thereof |
| CN108752775A (en) * | 2018-06-20 | 2018-11-06 | 安徽江淮汽车集团股份有限公司 | A kind of flame-retarded heat-conducting recycling PS composite material and preparation methods |
| CN112358702A (en) * | 2018-04-29 | 2021-02-12 | 徐菡 | Antibacterial flame-retardant HIPS composite material |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101508835A (en) * | 2009-03-12 | 2009-08-19 | 华南理工大学 | Halogen-free flame-proof static resistant polycarbonate composition and method for producing the same |
| CN102070853A (en) * | 2011-01-05 | 2011-05-25 | 广州市波斯塑胶颜料有限公司 | Foamed polystyrene curtain plate sheet and manufacturing method thereof |
-
2011
- 2011-11-29 CN CN2011103883544A patent/CN103131110A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101508835A (en) * | 2009-03-12 | 2009-08-19 | 华南理工大学 | Halogen-free flame-proof static resistant polycarbonate composition and method for producing the same |
| CN102070853A (en) * | 2011-01-05 | 2011-05-25 | 广州市波斯塑胶颜料有限公司 | Foamed polystyrene curtain plate sheet and manufacturing method thereof |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103965558A (en) * | 2014-04-11 | 2014-08-06 | 苏州市依星橡塑有限公司 | Preparation technology of oxidation resisting plastic film |
| CN104961989A (en) * | 2015-07-30 | 2015-10-07 | 苏州荣昌复合材料有限公司 | Polystyrene modified plastic and preparation method thereof |
| CN106947174A (en) * | 2017-03-31 | 2017-07-14 | 东莞市美饰家窗帘制品有限公司 | A kind of louver lamina composite and its method for preparing the louver lamina |
| CN107216559A (en) * | 2017-07-21 | 2017-09-29 | 安徽江淮汽车集团股份有限公司 | A kind of PS PC composites and preparation method thereof |
| CN112358702A (en) * | 2018-04-29 | 2021-02-12 | 徐菡 | Antibacterial flame-retardant HIPS composite material |
| CN108752775A (en) * | 2018-06-20 | 2018-11-06 | 安徽江淮汽车集团股份有限公司 | A kind of flame-retarded heat-conducting recycling PS composite material and preparation methods |
| CN108752775B (en) * | 2018-06-20 | 2019-12-31 | 安徽江淮汽车集团股份有限公司 | Flame-retardant heat-conducting recycled PS composite material and preparation method thereof |
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Application publication date: 20130605 |