CN102977443A - Carbon fiber rigid cable engineering pipe - Google Patents

Carbon fiber rigid cable engineering pipe Download PDF

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CN102977443A
CN102977443A CN2012104531123A CN201210453112A CN102977443A CN 102977443 A CN102977443 A CN 102977443A CN 2012104531123 A CN2012104531123 A CN 2012104531123A CN 201210453112 A CN201210453112 A CN 201210453112A CN 102977443 A CN102977443 A CN 102977443A
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carbon fiber
rigid cable
coupling agent
pipe
cable engineering
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CN102977443B (en
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彭国宾
刘江
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CHENGDU INFOEASY TECHNOLOGY CORP.
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CHENGDU INFOEASY TECHNOLOGY Co Ltd
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Abstract

The invention discloses a carbon fiber rigid cable engineering pipe. The carbon fiber rigid cable engineering pipe is, by weight, prepared from the following components: 80-100 parts of high-density polyethylene(HDPE), 8-12 parts of T800 carbon fiber, 15-30 parts of Hydrous magnesium oxysulfate whisker, 1-2 parts of coupling agent of organic titanate, 0.8-1 part of polyethylene (PE) wax, and 4-5 parts of color concentrate. The carbon fiber rigid cable engineering pipe is a tubular product provided with special properties. The HDPE is used as the main material and the carbon fiber rigid cable engineering pipe is formed after the blending modification of the HDPE with the carbon fiber and the like. The carbon fiber rigid cable engineering pipe has the properties of high strength, high tenacity, good corrosion resistant property, small friction factor, high Vicat degree, good heat radiation property, voltage resistance and the like, and meanwhile has the advantages of being high in insulation resistance, high in fire resistance, long in service life (more than 60 years), white ant proof, large in applicable differential temperature, not prone to deformation, simple in construction, small in maintenance rate, low in comprehensive cost, and the like. The carbon fiber rigid cable engineering pipe is an ideal substitute product of a cast-iron pipe, a polyvinyl chloride (PVC) pipe, a cement pipe and the like. The carbon fiber rigid cable engineering pipe is suitable for the outer sleeve protections of optical cables and cables, and is widely used in the field of communications, electric power, urban construction, industrial and civil buildings, and the expanding and rechannelling of the radio and television network.

Description

A kind of carbon fibre rigid cable engineering pipe
Technical field
The invention belongs to the material technology field; be specifically related to a kind of carbon fibre rigid cable engineering pipe and preparation method thereof; this product is mainly used in optical cable, cable, cable jacket protection, is widely used in the electrical network enlargings and transformation field such as communication, electric power, urban construction, municipal administration, industrial civil building, road and bridge.
Background technology
As everyone knows, the cable work pipe that uses in the market, mostly adopt CPVC, VPVC and Glass Steel Tube, the defectives such as CPVC pipe rigidity is low, the flexible distortion of insufficient strength, heat-drawn wire are low have had a strong impact on the expansion of its range of application, and the Glass Steel Tube conduit volume is large, material is heavy, be not easy to install and use, because pipeline is crisp hard, the work-ing life of breaking easily is short again; And above-mentioned pipeline when wearing cable and the cable contact surface large, friction resistance is large, cable skin damages easily, its insulating property are poor, radiating effect is poor, has been not suitable with the mat formation demand of industry development of cable.
Summary of the invention
In view of above-mentioned weak point, the object of the present invention is to provide a kind of carbon fibre rigid cable engineering pipe and preparation method thereof, this carbon fibre rigid cable engineering pipe not only its tensile strength, shock strength and flexural strength strengthens greatly, and also greatly increase work-ing life.
In order to achieve the above object, we at first are studied prescription and the preparation technology of carbon fibre rigid cable engineering pipe:
Because high density polyethylene(HDPE) has the advantages such as good impact resistance, good, the anti-anti-environmental stress cracking of winter hardiness is good, chemical stability is splendid, oil-proofness good, electrical insulating property is good, still with the major ingredient of high density polyethylene(HDPE) as this prescription.
Because alkali magnesium sulfate crystal whisker is a kind of inorganic enhancing toughening material, have intensity height, proportion little, to characteristics such as the polar solvent affinity are strong, can be used for the reinforced plastics mechanical property.In order further to increase the rigidity of cable work pipe, we select alkali magnesium sulfate crystal whisker to be used as the firm masterbatch that increases of the present invention's prescription.
In whole prescription and preparation technology thereof, alkali magnesium sulfate crystal whisker need to be used with coupling agent, and adopt alkali magnesium sulfate crystal whisker to cooperate the test that high density polyethylene(HDPE) is strengthened its mechanical property to show with coupling agent, the consumption of coupling agent and effect are not to be proportional relation, amount too much then the coupling agent surplus make on the contrary degradation, be embodied in indexs such as in plastics, making stretchings, shock resistance and descend, if measure very little, then because cladding not exclusively, effect is not remarkable.Select titanate coupling agent among the present invention, because the titanate coupling agent consumption is few, bring into play due effect for making it, it is disperseed in alkali magnesium sulfate crystal whisker equably, otherwise, do not reach coupling effect, we have just taked following technique: first titanate coupling agent is put into toluene solvant and soak, the toluene consumption just covers titanate coupling agent with the toluene liquid level and is as the criterion; And then alkali magnesium sulfate crystal whisker and the titanate coupling agent that soaks toluene mixed, then with heating or decompression method is removed toluene solvant, the alkali magnesium sulfate crystal whisker that obtains mixing and the mixture of titanate coupling agent.
Although having, its tensile strength of matrix material, shock strength and the flexural strength of high density polyethylene(HDPE) being carried out making after the modification by alkali magnesium sulfate crystal whisker and titanate coupling agent significantly improved, but because alkali magnesium sulfate crystal whisker itself is exactly the high strength hard brittle material, it still has following problem: the matrix material that makes, fragility is large, ageing resistance is poor, and the matrix material heat dispersion is not good etc.
We are by further research experiment, finding to add the T800 carbon fiber can effectively address the above problem, and the adding of T800 carbon fiber does not affect the aggregated structure of original matrix material, it mainly is distributed in the amorphous component of high density polyethylene(HDPE), similar to carbon black-filled crystalline polymer, when T800 carbon fiber add-on when shared mass percent is 5-12% in whole prescription, can obviously prolong the ageing-resistant time (the ageing-resistant time increases more than 20%), and can allow the mechanical property of matrix material strengthen more than 10%.And the adding carbon fibre, its thermal conduction characteristic of carbon fibre can make whole matrix material heat dispersion more excellent.
Can find out from above-mentioned prescription apolegamy, carry out a large amount of creative works by the contriver, obtain in following mass percent scope, having the carbon fibre rigid cable engineering pipe prescription of better effects:
A kind of carbon fibre rigid cable engineering pipe, count by weight ratio this project pipe and made by following composition:
High density polyethylene(HDPE): 80-100 part
T800 carbon fiber: 8-12 part
Alkali magnesium sulfate crystal whisker: 15-30 part
Titanate coupling agent: 1-2 part
PE wax: 0.8-1 part
Colour batch: 4-5 part.
Further, by mass percentage, carbon fibre rigid cable engineering pipe is made by following composition: 100 parts of high density polyethylene(HDPE)s, 10 parts on T800 carbon fiber, 20 parts of alkali magnesium sulfate crystal whiskers, 1 part of titanate coupling agent, 0.8 part in PE wax, 4 parts of colour batches.
The preparation method of described carbon fibre rigid cable engineering pipe includes following steps:
(1) processing of alkali magnesium sulfate crystal whisker: titanate coupling agent is put into toluene solvant soak, the toluene consumption just covers titanate coupling agent with the toluene liquid level and is as the criterion; And then alkali magnesium sulfate crystal whisker and the titanate coupling agent that soaks toluene mixed, then with heating or decompression method is removed toluene solvant, the mixture that gets alkali magnesium sulfate crystal whisker and titanate coupling agent is for subsequent use.
(2) mixture of the alkali magnesium sulfate crystal whisker of high density polyethylene(HDPE), T800 carbon fiber, step (1) gained and titanate coupling agent and PE wax and colour batch are mixed mixed, add single screw extrusion machine, at 180-200 ℃ of plasticizing forming, the pipe of extrusion moulding, enter in the forming mould of rotation through longitudinal stretching, then pass through vacuum forming, the cross directional stretch moulding namely gets carbon fibre rigid cable engineering pipe, its longitudinal stretching is than being 1.3-1.7, and cross directional stretch is than being 1.5-2.0.
Beneficial effect of the present invention is: the present invention is take HDPE as main raw material, the tubing that interpolation carbon fibre etc. have property through blending and modifying.Have the performances such as high strength, high tenacity, corrosion resistance and good, frictional coefficient are little, Wei Kadugao, perfect heat-dissipating, reactance voltage; have simultaneously insulation resistance height, flame retardant resistance height, long service life (more than 60 years), termite-proof, to adapt to the temperature difference large; not yielding, construction is simple; the maintenance rate is few; the low various features that waits of comprehensive cost; the desirable regeneration products such as cast iron pipe, pvc pipe and cement pipe; be applicable to optical cable, cable jacket protection; be widely used in communication, electric power, urban construction, industrial civil building, Broadcasting Cable Network enlarging and the field of changing its course.
Embodiment
Embodiment 1
The prescription of carbon fibre rigid cable engineering pipe (by weight ratio meter):
100 parts of high density polyethylene(HDPE)s, 10 parts on T800 carbon fiber, 20 parts of alkali magnesium sulfate crystal whiskers, 1 part of titanate coupling agent, 0.8 part in PE wax, 4 parts of colour batches.
The preparation method of carbon fibre rigid cable engineering pipe:
(1) processing of alkali magnesium sulfate crystal whisker: titanate coupling agent is put into toluene solvant soak, the toluene consumption just covers titanate coupling agent with the toluene liquid level and is as the criterion; And then alkali magnesium sulfate crystal whisker and the titanate coupling agent that soaks toluene mixed, then with heating or decompression method is removed toluene solvant, the mixture that gets alkali magnesium sulfate crystal whisker and titanate coupling agent is for subsequent use.
(2) mixture of the alkali magnesium sulfate crystal whisker of high density polyethylene(HDPE), T800 carbon fiber, step (1) gained and titanate coupling agent and PE wax and colour batch are mixed mixed, add single screw extrusion machine, at 180-200 ℃ of plasticizing forming, the pipe of extrusion moulding, enter in the forming mould of rotation through longitudinal stretching, then pass through vacuum forming, the cross directional stretch moulding namely gets carbon fibre rigid cable engineering pipe, its longitudinal stretching is than being 1.3-1.7, and cross directional stretch is than being 1.5-2.0.
Embodiment 2
The prescription of carbon fibre rigid cable engineering pipe (by weight ratio meter):
80 parts of high density polyethylene(HDPE)s, 8 parts on T800 carbon fiber, 15 parts of alkali magnesium sulfate crystal whiskers, 1 part of titanate coupling agent, 0.8 part in PE wax, 4 parts of colour batches.The preparation method of carbon fibre rigid cable engineering pipe is with embodiment 1.
Embodiment 3
The prescription of carbon fibre rigid cable engineering pipe (by weight ratio meter):
100 parts of high density polyethylene(HDPE)s, 10 parts on T800 carbon fiber, 30 parts of alkali magnesium sulfate crystal whiskers, 2 parts of titanate coupling agents, 1 part in PE wax, 5 parts of colour batches.
The preparation method of carbon fibre rigid cable engineering pipe is with embodiment 1.
The carbon fibre rigid cable engineering pipe of embodiment 1 gained has been carried out benchmark test such as table 1.
Table 1 is the Performance Detection table of embodiment 1 product.
Figure 2012104531123100002DEST_PATH_IMAGE002
Same, embodiment 2 and 3 has also been done corresponding evaluation test, the evaluation test result of test-results and embodiment 1 is without significant difference, so do not do deposited stating at this.

Claims (4)

1. carbon fibre rigid cable engineering pipe is characterized in that: meter by weight ratio, and this project pipe is made by following composition:
High density polyethylene(HDPE): 80-100 part
T800 carbon fiber: 8-12 part
Alkali magnesium sulfate crystal whisker: 15-30 part
Titanate coupling agent: 1-2 part
PE wax: 0.8-1 part
Colour batch: 4-5 part.
2. carbon fibre rigid cable engineering pipe according to claim 1 is counted by weight ratio, and this project pipe is made by following composition: 100 parts of high density polyethylene(HDPE)s, 10 parts on T800 carbon fiber, 20 parts of alkali magnesium sulfate crystal whiskers, 1 part of titanate coupling agent, 0.8 part in PE wax, 4 parts of colour batches.
3. carbon fibre rigid cable engineering pipe according to claim 1 and 2, it is characterized in that: described titanate coupling agent is monoalkoxy type or corrdination type titanate coupling agent.
4. prepare a kind of method of carbon fibre rigid cable engineering pipe as claimed in claim 1 or 2, it is characterized in that the method includes following steps:
(1) processing of alkali magnesium sulfate crystal whisker: titanate coupling agent is put into toluene solvant soak, the toluene consumption just covers titanate coupling agent with the toluene liquid level and is as the criterion; And then alkali magnesium sulfate crystal whisker and the titanate coupling agent that soaks toluene mixed, then with heating or decompression method is removed toluene solvant, the mixture that gets alkali magnesium sulfate crystal whisker and titanate coupling agent is for subsequent use;
(2) mixture of the alkali magnesium sulfate crystal whisker of high density polyethylene(HDPE), T800 carbon fiber, step (1) gained and titanate coupling agent and PE wax and colour batch are mixed mixed, add single screw extrusion machine, at 180-200 ℃ of plasticizing forming, the pipe of extrusion moulding, enter in the forming mould of rotation through longitudinal stretching, then pass through vacuum forming, the cross directional stretch moulding namely gets carbon fibre rigid cable engineering pipe, its longitudinal stretching is than being 1.3-1.7, and cross directional stretch is than being 1.5-2.0.
CN201210453112.3A 2012-11-13 2012-11-13 Carbon fiber rigid cable engineering pipe Active CN102977443B (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105754261A (en) * 2016-05-19 2016-07-13 合肥庭索环保材料有限公司 Carbon fiber high-strength cable material
CN111098557A (en) * 2019-12-30 2020-05-05 安徽徽一通讯科技有限公司 High-strength flame-retardant silicon core pipe and preparation method thereof
CN111320801A (en) * 2020-04-24 2020-06-23 吉林美高管道系统有限公司 Crosslinked polyethylene heat-conducting pipe and preparation method thereof
CN111440371A (en) * 2020-03-24 2020-07-24 杭州联通管业有限公司 Anti-freezing polyethylene power tube and preparation method thereof
CN115651295A (en) * 2022-10-14 2023-01-31 安徽杰蓝特新材料有限公司 Stretch-proofing PE gas pipe
CN116333404A (en) * 2023-04-03 2023-06-27 广东新力通实业有限公司 High-strength anti-collision HDPE cable protection pipe and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1763129A (en) * 2004-10-20 2006-04-26 大连圣迈化学有限公司 Thermoplastic halogen-free few-smoke flame-proof cable sheath material and machining process
CN1787120A (en) * 2004-12-06 2006-06-14 大连圣迈化学有限公司 Thermoplastic non-halogen low fume fire resistant cable isolation material and processing tech. thereof
CN101440180A (en) * 2008-12-26 2009-05-27 哈尔滨理工大学 Polyolefin based non-linear dielectric material
CN101463159A (en) * 2009-01-12 2009-06-24 李立才 Method for producing DTX carbon fibre cable protecting and leading pipes
CN101497727A (en) * 2009-03-04 2009-08-05 南亚塑胶工业股份有限公司 PVC resin composition and product thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1763129A (en) * 2004-10-20 2006-04-26 大连圣迈化学有限公司 Thermoplastic halogen-free few-smoke flame-proof cable sheath material and machining process
CN1787120A (en) * 2004-12-06 2006-06-14 大连圣迈化学有限公司 Thermoplastic non-halogen low fume fire resistant cable isolation material and processing tech. thereof
CN101440180A (en) * 2008-12-26 2009-05-27 哈尔滨理工大学 Polyolefin based non-linear dielectric material
CN101463159A (en) * 2009-01-12 2009-06-24 李立才 Method for producing DTX carbon fibre cable protecting and leading pipes
CN101497727A (en) * 2009-03-04 2009-08-05 南亚塑胶工业股份有限公司 PVC resin composition and product thereof

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105754261A (en) * 2016-05-19 2016-07-13 合肥庭索环保材料有限公司 Carbon fiber high-strength cable material
CN111098557A (en) * 2019-12-30 2020-05-05 安徽徽一通讯科技有限公司 High-strength flame-retardant silicon core pipe and preparation method thereof
CN111098557B (en) * 2019-12-30 2020-12-01 安徽徽一通讯科技有限公司 High-strength flame-retardant silicon core pipe and preparation method thereof
CN111440371A (en) * 2020-03-24 2020-07-24 杭州联通管业有限公司 Anti-freezing polyethylene power tube and preparation method thereof
CN111320801A (en) * 2020-04-24 2020-06-23 吉林美高管道系统有限公司 Crosslinked polyethylene heat-conducting pipe and preparation method thereof
CN115651295A (en) * 2022-10-14 2023-01-31 安徽杰蓝特新材料有限公司 Stretch-proofing PE gas pipe
CN115651295B (en) * 2022-10-14 2024-02-02 安徽杰蓝特新材料有限公司 Stretch-proofing PE gas pipe
CN116333404A (en) * 2023-04-03 2023-06-27 广东新力通实业有限公司 High-strength anti-collision HDPE cable protection pipe and preparation method thereof
CN116333404B (en) * 2023-04-03 2024-01-26 广东新力通实业有限公司 High-strength anti-collision HDPE cable protection pipe and preparation method thereof

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Address after: 611430, No. 359, Hing Yuen Road, A District, Xinjin County Industrial Park, Sichuan, Chengdu

Patentee after: CHENGDU INFOEASY TECHNOLOGY CORP.

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Patentee before: Chengdu Infoeasy Technology Co., Ltd.

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