CN102940585B - Healthy shampoo taking natural source raw materials as main component - Google Patents
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Abstract
The invention relates to a healthy shampoo taking natural source raw materials as main component. The healthy shampoo is characterized by comprising the natural source raw materials containing soft water which account for 95 percent or more of total weight of the shampoo, and ethoxylation components are avoided. In addition, the components of the shampoo have the following characteristics that 1, the selected surfactant is moderate and does not contain sulfate; 2, the selected conditioner does not contain organosilicone; 3, the selected preservative does not contain a formaldehyde release body and enhanceparaben; and 4, the odorant is not artificially synthesized. The shampoo is excellent in hair and scalp conditioning property, natural in components, moderate and healthy and is not accumulated after being used for a long time.
Description
Technical field
The present invention relates to a kind of shampoo, be specifically related to a kind of healthy hair-washing composition of natural origin raw material as master of take.
Background technology
Domestic market hair shampoo article is numerous hundreds of, and this wherein adopts the raw material of chemosynthesis mostly, and some raw material of selecting may exist potential safety hazard to health because of impure composition, and life-time service security risk is larger.Such as, formaldehyde releaser class, parabens antiseptic it is reported human body is existed to carcinogenic risk; Compound essence, pigment etc. easily cause human body skin allergy; That containing the raw material of ethylene oxide structure, can bring trace into easily makes the carcinogenic diox of people; Also some raw material may be inevitably with the impurity component being detrimental to health, as acrylamide monomer, monoxone, formaldehyde, methanol, nitrosamine, phenol etc. in the process of its chemosynthesis.In addition, this type of hair shampoo article after repeatedly using for a long time, its form in the conditioner such as some polymer, silicone oil be easy to produce accumulation on hair, make that hair is impaired, dry, scalp is itched.For these problems, in the market in the urgent need to human-body safety, non-stimulated, do not accumulate and the natural health shampoo of excellent performance.
The upsurge of meanwhile, having risen " back to nature " in world wide in recent years.The products such as " organic ", " green ", " natural ", " without adding " emerge in succession, chase trend and direction that natural, healthy cosmetics have become daily use chemicals industry.Although authentications natural, organic cosmetics also do not have unified standard in the world at present, but the numerous internationally renowned brands through Third Party Authentication obtain favorable comment and approval widely already, as Related products such as Origins, PATYKA, L ' Oreal, BCOMBIO, GAMARDE.
With natural material development cosmetics, in China, have the history of several thousand, according to < < China, noting at all times > > carries, as far back as abundant business period, people just bring into use Cymbidium floribundum lindl floral leaf to smash juice, to make " lipoid facing ".The ancient books and records that successive dynasties are recorded natural hair-blackening hair caring are a lot, as the < < Sheng Nong's herbal classic > > of Qin Han, the < < Qianjin Yao Fang > > of the Tang Dynasty, the < < Taiping Royal Prescriptions > > of the Song dynasty, < < Compendium of Materia Medica > > of the < < Imperial drug institution side > > in the Yuan Dynasty and the Ming Dynasty etc., relate to content very abundant, theoretical penetrating.Therefore, natural, the organic cosmetics of domestic research and development and hair shampoo article have advantageous superiority.
Yet, the what is called " natural shampoo " of declaring in industry at present, by adding the mode of the composition of the natural or natural origin such as a small amount of plant, Chinese medicine, mineral, realize often, its main body composition remains chemosynthesis raw material, fails fundamentally to solve the safety issue of product.
Summary of the invention
Natural safe, non-stimulated and without the market demand of hair washing product of accumulation for meeting, the invention provides a shampoo formula, it is characterized in that, the all components of described shampoo is not all containing ethoxylation composition, the 95wt% of described shampoo and above composition are natural origin raw material, described natural origin raw material obtains through physics and/or physico-chemical process, and direct or composition group all comes from the raw material of plant, mineral or animal.In addition the surfactant that, described shampoo is selected is containing sulfate not all; The conditioner that described shampoo is selected is not all containing silicone ingredients; The antiseptic that described shampoo is selected is not all containing formaldehyde releaser and parabens; The odorant that described shampoo is selected is not all containing chemosynthesis essence.Preferably, the characteristic component content of described shampoo is as follows: the surfactant that (a) accounts for the not containing sulfate of shampoo gross weight 5 to 50%; (b) account for shampoo gross weight 1 to 10% not containing the conditioner of silicone ingredients; (c) account for shampoo gross weight 0.01 to 2% not containing the antiseptic of formaldehyde releaser and parabens; (d) account for shampoo gross weight 0.01 to 1% not containing the odorant of chemosynthesis.
Because 95wt% and the above composition of shampoo of the present invention is natural origin composition, for example, and containing the various harmful components of the safety problem that may cause having one's hair wash:, formaldehyde, diox, acrylamide monomer, monoxone, methanol, nitrosamine, phenol etc., therefore overcome in prior art due to the harm to health that exists these chemical substances to cause, and owing to not containing organosilicon base polymer, can not cause the accumulation of this type of material on hair because of this shampoo of life-time service, and then avoided the hair causing because of a kind of hair washing product of life-time service to become dry, impaired, the scalp problem such as itch.
One preferred embodiment in, selected table surface-active agent accounts for the 5wt% to 50wt% of described shampoo gross weight.Surface-active contents, not only can be in order to be effective within the scope of this, i.e. the clean appropriateness to hair, and there is not a production technology difficult problem.
Preferably, described surfactant selects one or more in the group that free amino acid surfactant, betaines surfactant, imidazolines surfactant, alkyl polyglucoside and derivatives class surfactant thereof form.These surfactants all do not comprise sulfate, thus the damage to hair of having avoided sulfate to bring.Wherein amino acid surfactant can be obtained by the amino acids material of natural generation, and for example cocos nucifera oil acyl glutamate, Glu prepares from fatty acid and the glutamate, Glu condensation of natural origin; Betaines surfactant is the composition group of alkyl betaine especially---and alkyl and glycine are natural origin raw material; Alkyl polyglucoside and derivatives class surfactant thereof can be prepared alkyl polyglucoside by glucose and fatty alcohol reaction, then make alkyl androstanediol ester with organic acid reaction again.Picture amino acid surfactant, alkyl polyglucoside and these surfactants of derivatives class surfactant thereof are owing to deriving from natural materials, nontoxic, biodegradable, compatibility is good, gentle, zest is low, can significantly reduce formula system zest, therefore little to the stimulation of hair and scalp, can soft clean hair and scalp on various dirts, and can not damage hair and scalp.
Described amino acid surfactant can be selected from sodium salt, potassium salt or the triethanolamine salt of N-acylamino acid; the carbon number 8-18 of the alkyl group of this surfactant wherein; amino acid group is glycine or glutamic acid or alanine or taurine or collagen amino acid or canaline, is preferably one or more in cocos nucifera oil acyl (or lauroyl) glutamate, Glu, cocos nucifera oil acyl (or lauroyl) alanine salt, cocos nucifera oil acyl (or lauroyl) taurate, cocos nucifera oil acyl (or lauroyl) collagen amino acid salt.Described betaines surfactant is selected from mountain Yu base betanin, coco betaine, lauryl betaine.Described imidazolines surfactant is selected from acetate type imidazoline surfactant and/or sulfonate type imidazoline surfactant and/or phosphate type imidazoline surfactant, preferred acetate type imidazoline surfactant, more preferably cocoyl both sexes acetate, lauryl both sexes acetate.The alkyl group carbon number of described alkyl polyglucoside and derivatives class surfactant thereof is 8-16, select at least one in the group that free alkyl polyglucoside, alkyl polyglucoside sulfosuccinate, alkyl glucose amide, alkyl polyglucoside citrate, alkyl polyglucoside tartrate and alkyl polyglucoside acetate form, be preferably C
12-16alkyl polyglucoside, alkyl polyglucoside citrate.
One preferred embodiment in, described conditioner accounts for the 1wt% to 10wt% of described shampoo gross weight.Conditioner in this content range can make this shampoo in hair washing, reach the optimum efficiency of hair care, if lower than 1wt%, may make hair wash rear uninteresting, easy damaged; If higher than 10wt%, may bring the problems such as greasy feeling, difficult flushing.
Preferably, described conditioner comprises natural origin conditioner and cationic polymer, wherein said natural origin conditioner selects in the group that free protein, polysaccharide, fatty alcohol, oils and fats, vitamin form one or more, described cationic polymer to select in the group that free modified cellulose, modified starch, polyquaternary amine salt form one or more.These conditioners all do not contain silicone ingredients, thereby have avoided silicone ingredients to be accumulated in hair surface along with hair washing increased frequency.
Wherein, described natural origin conditioner, is preferably collagen protein, lactalbumin, hydrolyzed vegetable protein, hydrolyzed silk protein, chitin, cellulose, guar gum, cetearyl alcohol, olein or vitamin B5; Described cationic polymer is preferably alkylcellulose, hydroxy alkyl cellulose, cation guar gum, Polyquaternium-10.As outstanding hair conditioner, protein and hydrolyzed protein can effectively be attached to hair surface or infiltrate hair inside, and excellent smooth feeling and powerful moisture retention are provided, and can not produce life-time service accumulative effect simultaneously, make hair more healthy.In addition, easy to use in formula, can be compatible with various surfactants.Appropriate vitamin A can suppress scalp head fat and produce, and reaches the oily effect of control; Vitamin B group, as vitamin B1, vitamin B2, vitamin B5, vitamin B6, vitamin B12 and folic acid etc., can improve scalp blood circulation, suppress the infringement of hair, pre-Anti-hair loss or hair restoration etc.; Effect is moistened in the correct initiation of vitamin E, prevents that hair is dried and embrittlement.H vitamin can promote natural on-off cycles of hair growth, improves withered, fragile hair quality.Polysaccharide can significantly improve the wet Comb rationality of hair when hair washing, promotes shampoo rheological property, and wherein cellulose, as chitin, guar gum etc., can obtain by modes such as grinding, steaming and decoctings from animal, plant or mineral and their tissue.Described fatty alcohol comprises C
10, C
12, C
16, C
18, C
22deng fatty alcohol, preferred cetearyl alcohol, these fatty alcohol can react acquisition by fat saponification.Described oils and fats can effectively nourish scalp and hair-care, improves shampoo result of use, is preferably natural Oleum Cocois, shea butter, glyceride etc.
Another preferred embodiment in, described in shampoo of the present invention, antiseptic accounts for the 0.01wt% to 2wt% of described shampoo gross weight.Due to the composition that in shampoo of the present invention, composition more than 95wt% is natural origin, if there is no antiseptic, easily fermentation is rotten.Antiseptic within a certain period of time character, the composition of (in the shelf-life) assurance shampoo does not change.The present invention, containing " formaldehyde releaser and parabens " antiseptic, does not select other relatively mild antiseptic, is exemplified below.
Described antiseptic further comprises collaborative anticorrosion synergist polyquaternary ammonium salt-37 and/or polyquaternary ammonium salt-7.Described antiseptic is the antiseptic that does not contain formaldehyde releaser and parabens, thereby has avoided the harm of this type of material to health.
One preferred embodiment in, described odorant accounts for the 0.01wt% to 1wt% of described shampoo gross weight.The concentration of odorant has determined the abnormal smells from the patient of shampoo, and the fragrance of appropriateness can allow user feel joyful, and overrich runs counter to desire, and crosses the light effect that do not have.
Described odorant selects free natural essential oil, spice, have at least one in the group that the animal or plant extract of fragrance characteristic forms, the stimulation injury of having avoided compound essence to bring human body.Such as extracting citrus quintessence oil from Fructus Citri Sarcodactylis, Fructus Citri Limoniae etc., also have cypress, Herba Rosmarini Officinalis etc. quintessence oil.
In a further preferred embodiment, shampoo of the present invention further comprises 0.01 to 2% other composition that accounts for shampoo gross weight, is selected from one or more in wetting agent, chelating agen, acidity regulator, antioxidant, solubilizing agent, functional additive.
Shampoo of the present invention is except mentioned component, and surplus water is supplemented to 100%.
The outward appearance of shampoo of the present invention can opaque shape, also can become transparence, different depending on formulation selection raw material.
Accompanying drawing explanation
With reference to the specific embodiment and the accompanying drawing that form the application's part, can understand more fully the present invention.
Fig. 1 is the shampoo of preparation according to the embodiment of the present invention and the result figure of two kinds of current commercially available shampoo cumulant comparisons.
The specific embodiment
The following term using in this description has implication hereinafter described.Except as otherwise noted, all scientific and technical terminologies used herein have the implication identical with the common understanding of those of ordinary skills.
" natural " of indication of the present invention refers to the shampoo of the natural origin raw material that contains higher proportion (95% above weight ratio), and real pure natural shampoo is non-existent." natural origin raw material " refer to directly from or its form group and all come from plant, mineral or animal, especially plant or mineral.
Each chief component composition of shampoo of the present invention is below described one by one.
1, the surfactant of containing sulfate not
Described surfactant has natural origin attribute, is selected from one or more in amino acid surfactant, betaines surfactant, imidazolines surfactant, alkyl polyglucoside and derivatives class surfactant thereof.
Amino acid surfactant is the amide that amino acid whose amino and fatty acid condensation form, and it is nontoxic, biodegradable, compatibility good, gentle, zest is low, can significantly reduce formula system zest.For amino acid surfactant of the present invention (by active matter 100wt% calculating) account for shampoo gross weight 2 to 20wt%; The carbon number of the alkyl group of selected amino acid surfactant is 8-18, and amino acid group is glycine or glutamic acid or alanine or taurine or collagen amino acid or canaline, and cation is sodium salt, potassium salt or triethanolamine salt; Be preferably one or more in cocos nucifera oil acyl (or lauroyl) glutamate, Glu, cocos nucifera oil acyl (or lauroyl) alanine salt, cocos nucifera oil acyl (or lauroyl) taurate, cocos nucifera oil acyl (or lauroyl) collagen amino acid salt.
For betaines surfactant of the present invention (calculating by active matter 100%), account for 2 to 20% of shampoo gross weight, its hydrophobic group can be cocoyl, lauryl, myristyl, palmityl, counter ion is sodium, potassium or triethanolamine, preferably coco betaine, mountain Yu base betanin, lauryl betaine.
For imidazolines surfactant of the present invention (pressing active matter 100wt% calculates), account for 1 to 10% of shampoo gross weight, its hydrophobic group can be cocoyl, lauryl, myristyl, palmityl, counter ion is sodium, potassium or triethanolamine, acetate type imidazoline surfactant and/or sulfonate type imidazoline surfactant and/or phosphate type imidazoline surfactant be can be selected from, lauryl both sexes sodium acetate, cocoyl both sexes sodium acetate, palmityl both sexes sodium acetate are preferably.
Alkyl polyglucoside and derivatives class surfactant thereof, belong to non-ionic surface active agent, and safety, gentle, detergency is good, and compatibility is good, easily biological-degradable.For alkyl polyglucoside of the present invention and derivatives class (pressing active matter 100% calculates) thereof, account for 0 to 10% of shampoo gross weight, be selected from C
8-16alkyl polyglucoside, alkyl polyglucoside sulfosuccinate, alkyl glucose amide, alkyl polyglucoside citrate, alkyl polyglucoside tartrate, alkyl polyglucoside acetate, be preferably C
12-16alkyl polyglucoside and derivant thereof.
2, the conditioner that does not contain silicone ingredients
Described conditioner comprises natural origin conditioner and cationic polymer, wherein said natural origin conditioner selects free protein, polysaccharide, fatty alcohol, oils and fats, in the group that vitamin forms one or more, be preferably collagen protein, lactalbumin, hydrolyzed vegetable protein, hydrolyzed silk protein, chitin, cellulose, guar gum, cetearyl alcohol, olein, vitamin B5, described cationic polymer selects free modified cellulose, modified starch, in the group that polyquaternary amine salt forms one or more, be preferably alkylcellulose, hydroxy alkyl cellulose, cation guar gum, Polyquaternium-10.
As outstanding hair conditioner, the natural origin conditioners such as protein and hydrolyzed protein, vitamin, polysaccharide can effectively be attached to hair surface or infiltrate hair inside, excellent smooth feeling and powerful moisture retention are provided, can produce life-time service accumulative effect, make hair more healthy simultaneously.In addition, easy to use in formula, can be compatible with various surfactants.Aliphatic alcohols, natural oil lipid can deeply be permeated hair, and the degree of depth is nourished.Applicable cationic polymer of the present invention, as quaternized oligofructose, cationic cellulose, Polyquaternium-10, quaternized Cassia bean gum etc., continues to use, and hair can not produce because of bring coarse, dry and astringent of accumulation or the sensation of hardening.
3, antiseptic
Selected antiseptic is not containing formaldehyde releaser and parabens, optional, adds collaborative anticorrosion synergist polyquaternary ammonium salt-37 and/or polyquaternary ammonium salt-7 in described antiseptic.
4, odorant
Described odorant is selected from natural essential oil and/or natural perfume material and/or has the natural extract of fragrance characteristic.
other composition
Other composition, for known or be effective to the additional optional composition in hair care product, comprises wetting agent, chelating agen, pH adjusting agent, antioxidant, solubilizing agent, functional additive etc., and addition is according to the operative norm of product and function and determine.
In shampoo of the present invention, except the above composition, surplus water is supplemented to 100%.
The outward appearance of shampoo of the present invention can opaque shape, also can become transparence, different depending on formulation selection raw material.
using method
The shampoo the present invention relates to, is used in the mode clean and conditioning hair of routine, reusable as required, to reach clean, conditioning effect.
The gentle safety of shampoo of the present invention, had both been applicable to adult, was also suitable for child and used.
Preparation method: shampoo of the present invention, by any known or other equipment that is effectively suitable for the production of shampoo, to prepare, the method for preparing shampoo of the present invention comprises conventional preparation and hybrid technology.
Although aforementioned embodiments of the present invention has been described with reference to above-mentioned each embodiment, the present invention is not limited to these embodiments and can various form implements.It will be understood by those skilled in the art that in description, illustrate, do not changing under the condition of technical spirit of the present invention or basic feature, the present invention can embodied in other realize technique effect of the present invention.Therefore, should understand these embodiments be interpreted as in every respect illustrative, should with restriction mode not consider.Scope of the present invention should be limited by claims.
Claims (3)
1. a shampoo, is characterized in that,
The all components of described shampoo is not all containing ethoxylation composition;
Described shampoo 95wt% and above composition are natural origin raw material, and described natural origin raw material is to obtain through physics and/or physico-chemical process, and direct or composition group all comes from the raw material of plant, mineral or animal;
The surfactant that described shampoo is selected is containing sulfate not all, the conditioner that described shampoo is selected is not all containing silicone ingredients, the antiseptic that described shampoo is selected is not all containing formaldehyde releaser and parabens, and the odorant that described shampoo is selected is not all containing chemosynthesis essence;
The characteristic component content of described shampoo is as follows:
(a) account for the surfactant of the not containing sulfate of shampoo gross weight 5 to 50%, the surfactant of described not containing sulfate is amino acid surfactant, betaines surfactant, imidazolines surfactant and alkyl polyglucoside class surfactant;
Wherein, described amino acid surfactant is selected from one or more in cocos nucifera oil acyl glutamate, Glu, lauroyl glutamate, cocos nucifera oil acyl alanine salt, lauroyl alanine salt, accounts for the 2-20wt% of shampoo gross weight; Described betaines surfactant is selected from coco betaine, mountain Yu base betanin, lauryl betaine, accounts for the 2-20wt% of shampoo gross weight; Described imidazolines surfactant is selected from lauryl both sexes sodium acetate, cocoyl both sexes sodium acetate, palmityl both sexes sodium acetate, accounts for the 1-10wt% of shampoo gross weight; Described alkyl polyglucoside class surfactant is selected from C12-16 alkyl polyglucoside, accounts for the 0-10wt% of shampoo gross weight;
(b) account for shampoo gross weight 1 to 10% not containing the conditioner of silicone ingredients, described is not natural origin conditioner and cationic polymer containing the conditioner of silicone ingredients;
Wherein, described natural origin conditioner selects one or more in the group of free protein, composition; Described cationic polymer is selected from Polyquaternium-10;
(c) account for shampoo gross weight 0.01 to 2% not containing the antiseptic of formaldehyde releaser and parabens;
(d) account for shampoo gross weight 0.01 to 1% not containing the odorant of chemosynthesis essence.
2. shampoo as claimed in claim 1, is characterized in that,
Described odorant is selected from the animals and plants extract with fragrance characteristic.
3. shampoo as claimed in claim 1, is characterized in that,
Optionally add 0.01 to 2% other composition that accounts for shampoo gross weight, described other composition comprises one or more in wetting agent, chelating agen, acidity regulator, antioxidant, solubilizing agent, functional additive.
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| CN102940585B true CN102940585B (en) | 2014-08-27 |
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Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
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| JP5752220B2 (en) * | 2013-12-16 | 2015-07-22 | 花王株式会社 | Bactericidal detergent composition for hard surfaces |
| CN105232410B (en) * | 2015-11-19 | 2018-03-02 | 北京章光101科技股份有限公司 | Hair washing product of oil-control anticreep and preparation method thereof |
| CN107875064A (en) * | 2017-12-04 | 2018-04-06 | 珠海伊斯佳科技股份有限公司 | A kind of scalp care compositions |
| CN108283583A (en) * | 2018-03-27 | 2018-07-17 | 广州禾力生物科技有限公司 | A kind of no silicoamino-acid shampoo and preparation method thereof |
| CN108578321A (en) * | 2018-06-15 | 2018-09-28 | 黄森 | A kind of shampoo and preparation method thereof with bacteriostasis |
| MX2022011787A (en) * | 2020-03-27 | 2023-07-13 | Unilever Ip Holdings B V | Compositions comprising naturally derived preservatives. |
| CN113136040B (en) * | 2021-05-08 | 2022-07-19 | 中国科学院华南植物园 | Cationic starch gel and preparation method and application thereof |
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| CN1274277A (en) * | 1997-09-05 | 2000-11-22 | 普罗克特和甘保尔公司 | Cleansing and conditioning products for skin or hair with improved deposition of conditioning ingredients |
| CN102552056A (en) * | 2012-03-05 | 2012-07-11 | 纳爱斯集团有限公司 | Shampoo composition |
| CN102716044A (en) * | 2012-07-03 | 2012-10-10 | 澳宝化妆品（惠州）有限公司 | Low-stimulation hair-cleaning compound |
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| CN1274277A (en) * | 1997-09-05 | 2000-11-22 | 普罗克特和甘保尔公司 | Cleansing and conditioning products for skin or hair with improved deposition of conditioning ingredients |
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| CN102716044A (en) * | 2012-07-03 | 2012-10-10 | 澳宝化妆品（惠州）有限公司 | Low-stimulation hair-cleaning compound |
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