CN102416187A - Photocatalyst air purifying liquid and preparation method thereof - Google Patents
Photocatalyst air purifying liquid and preparation method thereof Download PDFInfo
- Publication number
- CN102416187A CN102416187A CN2011103248518A CN201110324851A CN102416187A CN 102416187 A CN102416187 A CN 102416187A CN 2011103248518 A CN2011103248518 A CN 2011103248518A CN 201110324851 A CN201110324851 A CN 201110324851A CN 102416187 A CN102416187 A CN 102416187A
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- CN
- China
- Prior art keywords
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- photocatalyst air
- air purifying
- purifying liquid
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000007788 liquid Substances 0.000 title claims abstract description 29
- 239000011941 photocatalyst Substances 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 11
- 239000006185 dispersion Substances 0.000 claims abstract description 11
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 11
- 239000005543 nano-size silicon particle Substances 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 8
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 5
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 5
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 5
- 239000002245 particle Substances 0.000 claims abstract description 4
- 239000012153 distilled water Substances 0.000 claims abstract description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 22
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 15
- 230000001804 emulsifying effect Effects 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 6
- 229910052710 silicon Inorganic materials 0.000 claims description 6
- 239000010703 silicon Substances 0.000 claims description 6
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 abstract description 12
- 238000002156 mixing Methods 0.000 abstract description 9
- 230000000694 effects Effects 0.000 abstract description 6
- 230000009931 harmful effect Effects 0.000 abstract description 6
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 abstract description 6
- 239000012459 cleaning agent Substances 0.000 abstract description 3
- 230000001954 sterilising effect Effects 0.000 abstract description 3
- 230000003115 biocidal effect Effects 0.000 abstract description 2
- 238000000354 decomposition reaction Methods 0.000 abstract description 2
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 238000004887 air purification Methods 0.000 abstract 2
- 229920000877 Melamine resin Polymers 0.000 abstract 1
- 238000004945 emulsification Methods 0.000 abstract 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 239000002904 solvent Substances 0.000 description 8
- 239000004408 titanium dioxide Substances 0.000 description 8
- 230000000844 anti-bacterial effect Effects 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 230000005284 excitation Effects 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 231100000957 no side effect Toxicity 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
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- Catalysts (AREA)
Abstract
The invention provides a photocatalyst air purification liquid and a preparation method thereof, belonging to the technical field of preparation of cleaning agents and being prepared by mixing the following raw materials in parts by weight: nano titanium dioxide: 4-6 parts of nano silicon dioxide: 1-3 parts, melamine or sodium sulfate: 3-10 parts of polyethylene glycol: 15-25 parts of water: 50-70 parts of nano titanium dioxide with the particle size of 5-10 nanometers, and distilled water, wherein the raw materials are uniformly mixed according to a proportion and are subjected to emulsification and dispersion treatment to prepare the photocatalyst air purification liquid. Compared with the prior art, the photocatalyst air purifying liquid and the preparation method thereof have the characteristics of reasonable raw material compatibility, low preparation cost, convenient use, good cleaning effect and the like, the air cleaning agent can be sprayed in a room or smeared on furniture, can be naturally volatilized without leaving traces, and can excite the nano titanium dioxide to generate the effects of sterilization, antibiosis and harmful gas decomposition only by weak ultraviolet irradiation.
Description
Technical field
The present invention relates to a kind of cleaning agent, specifically a kind ofly can be sprayed in the room or spread upon on the furniture, room air or furniture are carried out photocatalyst air purifying liquid of antibacterial, sterilization, cleaning and preparation method thereof.
Background technology
Research shows: nano titanium oxide, particle diameter have very strong adsorptivity between 5-25 nanometers, and it can be adsorbed onto its surface with harmful gass such as airborne benzene, formaldehyde, under the irradiation of uviol lamp, with its decomposition.
Summary of the invention
Technical assignment of the present invention is the deficiency to prior art; Provide a kind of and can be sprayed in the room or the volatilization of giving free rein to of the furniture surface in room, only need faint ultraviolet radiation just can excitation nano titanium dioxide generation cleaning, photocatalyst air purifying liquid of antibacterial, resolving harmful gas effect and preparation method thereof.
The technical solution adopted for the present invention to solve the technical problems is:
Photocatalyst air purifying liquid is that the raw materials mix by following parts by weight forms:
Nano titanium oxide: 4-6 part,
Nano silicon: 1-3 part,
Tripolycyanamide or sodium sulfate: 3-10 parts,
Polyethylene Glycol: 15-25 parts,
Water: 50-70 parts.
Also be added with silicon third in the above-mentioned mixed material: 2-4 part.
Also be added with acetic acid in the above-mentioned mixed material: 5-15 part.
The particle diameter of above-mentioned nano titanium oxide is between 5-10 nanometers.
Said water is distilled water, and the temperature of water is between 50-90 ℃.
The manufacture method of said photocatalyst air purifying liquid is that above-mentioned raw materials is mixed in proportion, and promptly can be made into said photocatalyst air purifying liquid through the emulsifying dispersion treatment.
Photocatalyst air purifying liquid of the present invention and preparation method thereof compared with prior art, the beneficial effect that is produced is:
1) the present invention has that material combination is reasonable, preparation cost is low; Characteristics such as easy to use, cleaning effect is good; Owing to adopted nano titanium oxide to make raw material, therefore, only need faint ultraviolet radiation just can excitation nano titanium dioxide generation antibacterial, the effect of resolving harmful gas.
2) the present invention can be sprayed in the room or spreads upon above the furniture, can volatilize naturally and leave no trace, only need faint ultraviolet radiation just can excitation nano titanium dioxide generation antibacterial, the effect of antibiotic, resolving harmful gas.And to the environment non-secondary pollution, to human non-toxic, have no side effect.
3) sterilizing rate of the present invention reaches more than 95%, and the harmful gas removing rate reaches more than 85%.
The specific embodiment
Explanation at length below below in conjunction with embodiment photocatalyst air purifying liquid of the present invention and preparation method thereof being done.
Embodiment 1:
Titanium dioxide with 5-10 nanometers: 5 parts, nano silicon: 2 parts, tripolycyanamide: 3 parts, 20 parts of Polyethylene Glycol, water: 70 parts of mix homogeneously, promptly can be made into said air cleaning liquid through the emulsifying dispersion treatment, can be used as eliminating smell agent and use.
Embodiment 2:
Titanium dioxide with 5-10 nanometers: 4 parts, nano silicon: 3 parts, sodium sulfate: 10 parts, 15 parts of Polyethylene Glycol, water: 68 parts of mix homogeneously, promptly can be made into said air cleaning liquid through the emulsifying dispersion treatment, can be used as eliminating smell agent and use.
Embodiment 3:
Titanium dioxide with 5-10 nanometers: 6 parts, nano silicon: 1 part, tripolycyanamide: 10 parts, 25 parts of Polyethylene Glycol, water: 58 parts of mix homogeneously, promptly can be made into said air cleaning liquid through the emulsifying dispersion treatment, can be used as eliminating smell agent and use.
Embodiment 4:
Titanium dioxide with 5-10 nanometers: 5 parts, nano silicon: 2 parts, sodium sulfate: 3 parts, Polyethylene Glycol: 25 parts, 65 parts of mix homogeneously of water, promptly can be made into said air cleaning liquid through the emulsifying dispersion treatment, can be used as eliminating smell agent and use.
Embodiment 5:
With the third 3 parts of mixing of 2 parts of 5 parts of titanium dioxide, the nano silicons of 5-10 nanometers, silicon as solute; 55 parts of mixing of water of 10 parts of 10 parts of tripolycyanamide, 15 parts of Polyethylene Glycol, acetic acid and 70 ℃ are as solvent, even with above-mentioned solute and solvent, promptly can be made into said air cleaning liquid through the emulsifying dispersion treatment, can be used as air purifying preparation and use.
Embodiment 6:
With the third 2 parts of mixing of 3 parts of 4 parts of titanium dioxide, the nano silicons of 5-10 nanometers, silicon as solute; 53 parts of mixing of water of 15 parts of 3 parts of tripolycyanamide, 20 parts of Polyethylene Glycol, acetic acid and 50 ℃ are as solvent, even with above-mentioned solute and solvent, promptly can be made into said air cleaning liquid through the emulsifying dispersion treatment, can be used as air purifying preparation and use.
Embodiment 7:
With the third 4 parts of mixing of 1 part of 6 parts of titanium dioxide, the nano silicon of 5-10 nanometers, silicon as solute; 54 parts of mixing of water of 25 parts of 10 parts of tripolycyanamide, Polyethylene Glycol and 90 ℃ are as solvent, even with above-mentioned solute and solvent, promptly can be made into said air cleaning liquid through the emulsifying dispersion treatment, can be used as the deacration cleanser and use.
Embodiment 8:
With the third 3 parts of mixing of 2 parts of 4 parts of titanium dioxide, the nano silicons of 5-10 nanometers, silicon as solute; With 5 parts of acetic acid, Polyethylene Glycol: 66 parts of mixing of water of 20 parts and 70 ℃ are as solvent, and above-mentioned solute and solvent is even, promptly can be made into said air cleaning liquid through the emulsifying dispersion treatment, can be used as the deacration cleanser and use.
Claims (8)
1. photocatalyst air purifying liquid is characterized in that, is that the raw materials mix by following parts by weight forms:
Nano titanium oxide: 4-6 part,
Nano silicon: 1-3 part,
Tripolycyanamide or sodium sulfate: 3-10 parts,
Polyethylene Glycol: 15-25 parts,
Water: 50-70 parts.
2. photocatalyst air purifying liquid according to claim 1 is characterized in that, also is added with silicon third in the mixed material: 2-4 part.
3. photocatalyst air purifying liquid according to claim 1 is characterized in that, also is added with acetic acid in the mixed material: 5-15 part.
4. photocatalyst air purifying liquid according to claim 1 is characterized in that the particle diameter of nano titanium oxide is between 5-10 nanometers.
5. photocatalyst air purifying liquid according to claim 1 is characterized in that, said water is distilled water.
6. photocatalyst air purifying liquid according to claim 1 is characterized in that the temperature of said water is between 50-90 ℃.
7. photocatalyst air purifying liquid according to claim 6 is characterized in that the temperature of said water is between 60-80 ℃.
8. the manufacture method of photocatalyst air purifying liquid according to claim 1 is characterized in that, is that above-mentioned raw materials is mixed in proportion, and promptly can be made into said photocatalyst air purifying liquid through the emulsifying dispersion treatment.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103248518A CN102416187A (en) | 2011-10-24 | 2011-10-24 | Photocatalyst air purifying liquid and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103248518A CN102416187A (en) | 2011-10-24 | 2011-10-24 | Photocatalyst air purifying liquid and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102416187A true CN102416187A (en) | 2012-04-18 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011103248518A Pending CN102416187A (en) | 2011-10-24 | 2011-10-24 | Photocatalyst air purifying liquid and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN102416187A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103146263A (en) * | 2013-03-11 | 2013-06-12 | 山东红太阳保温材料有限公司 | Photocatalyst indoor paint and manufacturing method thereof |
| CN104174256A (en) * | 2014-08-19 | 2014-12-03 | 西安交通大学 | Combination solution for purifying air and application thereof |
| CN106334400A (en) * | 2016-08-31 | 2017-01-18 | 刘卫东 | Vertical sieve plate type air purification device |
| CN114700117A (en) * | 2022-03-28 | 2022-07-05 | 苏州旭晟新材料科技有限公司 | Preparation method of novel visible light photocatalyst |
| US11771787B2 (en) | 2020-07-16 | 2023-10-03 | Grand Mate Co., Ltd. | Disinfection system and elevator equipment having the same |
Citations (8)
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| US20040163941A1 (en) * | 2003-02-21 | 2004-08-26 | Dae-Sik Yun | Method for purification of poisonous gas |
| TW200502014A (en) * | 2003-07-11 | 2005-01-16 | Yueh Cheng Technology Co Ltd | Method for producing antibacterial spray |
| CN1788794A (en) * | 2004-12-13 | 2006-06-21 | 谢家忠 | Nanometer photo-catalytic sterilizing and air-cleaning agent |
| CN1788799A (en) * | 2004-12-13 | 2006-06-21 | 张贵洲 | Air deodorant agent |
| CN101318129A (en) * | 2008-07-23 | 2008-12-10 | 刘守新 | Supported optical catalyst and preparation method thereof |
| CN101569815A (en) * | 2008-04-28 | 2009-11-04 | 上海立昌环境工程有限公司 | Strippable protective film capable of purifying air |
| EP2192146A1 (en) * | 2008-11-26 | 2010-06-02 | Colotex Industrieal Co., LTD. | A process for producing porous polymer masterbatch and fiber thereof having anti-bacterial and odor eliminating functions |
| WO2011033286A1 (en) * | 2009-09-17 | 2011-03-24 | Tioxide Europe Limited | Stable nano titania sols and a process for their production |
-
2011
- 2011-10-24 CN CN2011103248518A patent/CN102416187A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040163941A1 (en) * | 2003-02-21 | 2004-08-26 | Dae-Sik Yun | Method for purification of poisonous gas |
| TW200502014A (en) * | 2003-07-11 | 2005-01-16 | Yueh Cheng Technology Co Ltd | Method for producing antibacterial spray |
| CN1788794A (en) * | 2004-12-13 | 2006-06-21 | 谢家忠 | Nanometer photo-catalytic sterilizing and air-cleaning agent |
| CN1788799A (en) * | 2004-12-13 | 2006-06-21 | 张贵洲 | Air deodorant agent |
| CN101569815A (en) * | 2008-04-28 | 2009-11-04 | 上海立昌环境工程有限公司 | Strippable protective film capable of purifying air |
| CN101318129A (en) * | 2008-07-23 | 2008-12-10 | 刘守新 | Supported optical catalyst and preparation method thereof |
| EP2192146A1 (en) * | 2008-11-26 | 2010-06-02 | Colotex Industrieal Co., LTD. | A process for producing porous polymer masterbatch and fiber thereof having anti-bacterial and odor eliminating functions |
| WO2011033286A1 (en) * | 2009-09-17 | 2011-03-24 | Tioxide Europe Limited | Stable nano titania sols and a process for their production |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103146263A (en) * | 2013-03-11 | 2013-06-12 | 山东红太阳保温材料有限公司 | Photocatalyst indoor paint and manufacturing method thereof |
| CN104174256A (en) * | 2014-08-19 | 2014-12-03 | 西安交通大学 | Combination solution for purifying air and application thereof |
| CN106334400A (en) * | 2016-08-31 | 2017-01-18 | 刘卫东 | Vertical sieve plate type air purification device |
| US11771787B2 (en) | 2020-07-16 | 2023-10-03 | Grand Mate Co., Ltd. | Disinfection system and elevator equipment having the same |
| CN114700117A (en) * | 2022-03-28 | 2022-07-05 | 苏州旭晟新材料科技有限公司 | Preparation method of novel visible light photocatalyst |
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Application publication date: 20120418 |