CN102391615A - Aviation fiber reinforcement and thermosetting light fireproofing material and production process thereof - Google Patents
Aviation fiber reinforcement and thermosetting light fireproofing material and production process thereof Download PDFInfo
- Publication number
- CN102391615A CN102391615A CN2011102549363A CN201110254936A CN102391615A CN 102391615 A CN102391615 A CN 102391615A CN 2011102549363 A CN2011102549363 A CN 2011102549363A CN 201110254936 A CN201110254936 A CN 201110254936A CN 102391615 A CN102391615 A CN 102391615A
- Authority
- CN
- China
- Prior art keywords
- fiber reinforcement
- thermosetting light
- fiber
- proof material
- aviation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Reinforced Plastic Materials (AREA)
Abstract
The invention relates to an aviation fiber reinforcement and thermosetting light fireproofing material. The aviation fiber reinforcement and thermosetting light fireproofing material mainly comprises fibers, impregnating resin, surfactant, a curing agent and a foaming agent, and is characterized in that the impregnating resin is a modified phenolic resin which is obtained by modifying astage phenolic resin by using a toughening agent. The processing technology comprises the following steps of: preparing the modified phenolic resin serving as a substrate which is named a material A for short; 2, uniformly stirring the material A, the curing agent, the foaming agent, the surfactant and the like to obtain a material B; 3, immersing the fibers in the material B; 4, drying the immersed fibers in hot air at the temperature of between 40 and 45 DEG C and prefoaming; and 5, putting the prefoamed material in a mould or a hot-pressing tank and foaming by heating and pressurizing to obtain a finished product. The invention has the advantages that: the material is light, and is high in fire resistance, and the processing technology is simple and low in cost. The prepared product is suitable for interior materials of aircraft cabins, train coaches, automobiles, ships and the like.
Description
Technical field
The present invention relates to a kind of fire-retardant material, specifically a kind of aviation is with fiber reinforcement thermosetting light fire-proof material and production technique thereof.
Background technology
Current domestic and international space shuttle cabin inside gadget adopts aluminium honeycomb or NOMEX honeycomb (adopting aramid fiber paper impregnated phenolic resin to process) mostly; Because honeycomb core material in use needs high maintenance and repair expense; When if crack and hole appear in panel in some cases; Water and steam just get into honeycomb at an easy rate, and under low temperature condition, the water that gets in the honeycomb hole can be expanded by after freezing; With the bonding of destroying contiguous honeycomb hole lattice, this is with regard to the performance that reduced sandwich structure and must place under repair.
Summary of the invention
The objective of the invention is: to above reality, provide a kind of aviation with fiber reinforcement thermosetting light fire-proof material and production technique thereof, material is light, and fire resistance is strong, and complete processing is simple simultaneously, and cost is low.
Based on above purpose; The present invention takes following technical scheme to realize: a kind of aviation is with fiber reinforcement thermosetting light fire-proof material; Its main composition comprises fiber, solvent impregnated resin, tensio-active agent, solidifying agent and whipping agent; It is characterized in that: said solvent impregnated resin is a modified phenolic resins, and said modified phenolic resins is by resole and toughening agent modified making.
Above-mentioned a kind of aviation uses the complete processing of fiber reinforcement thermosetting light fire-proof material to be: the first step is processed modified phenolic resins earlier and is matrix, is called for short A material (solvent impregnated resin); It is that B expects that second step stirred A material and solidifying agent, whipping agent, tensio-active agent etc.; The 3rd step flooded fiber through the B material; The fiber that the 4th step will be passed through dipping carries out dry pre-frothing through the warm air under 40-45 ℃; The 5th the step will through the material after the pre-frothing put into foam under mould or the autoclave heating and pressurizing aviation with fiber reinforcement thermosetting light fire-proof finished material.
Because the present invention has adopted above technical scheme, the present invention has the following advantages: material is light, and fire resistance is strong, and complete processing is simple simultaneously, and cost is low.Made product is applicable to that space shuttle cabin, high-speed train envelope, automobile, naval vessel etc. do interior material.
Embodiment
Below in conjunction with embodiment the present invention is described further.
Embodiment one
A kind of aviation is with fiber reinforcement thermosetting light fire-proof material; Its main composition comprises fiber, solvent impregnated resin, tensio-active agent, solidifying agent and whipping agent; It is characterized in that: said solvent impregnated resin is a modified phenolic resins, and said modified phenolic resins is resole and toughening agent modified gained.The quality proportioning of each component is: in modified phenolic resins is 100, tensio-active agent 2-10, solidifying agent 10-35, whipping agent 2-25, fiber 5-40.Concrete test composition and performance see the following form:
Annotate: component A is a modified phenolic resins, and B is a tensio-active agent, and C is a solidifying agent, and D is a whipping agent, and E is a fiber, and the performance index I is density kg/cm
3, II is a rate of closed hole, and III is compressive strength (10%) MPa, and IV is thermal conductivity W/ (m.k), and V is critical oxygen index %.
Above-mentioned a kind of aviation uses the complete processing of fiber reinforcement thermosetting light fire-proof material to be: the first step is matrix to resole and the toughening agent modified modified phenolic resins of processing earlier, is called for short the A material; It is that B expects that second step stirred A material and solidifying agent, whipping agent, tensio-active agent etc.; The 3rd step flooded fiber through the B material; The fiber that the 4th step will be passed through dipping carries out dry pre-frothing through the warm air under 40-45 ℃; The 5th the step will through the material after the pre-frothing put into foam under mould or the autoclave heating and pressurizing aviation with fiber reinforcement thermosetting light fire-proof finished material.
Embodiment two
With fiber reinforcement thermosetting light fire-proof material, its characteristic difference is: described toughner is one or more in vinyl cyanide/methylmethacrylate copolymer, silicon midbody, the polyurethanes compound with a kind of aviation of embodiment one.
Embodiment three
With fiber reinforcement thermosetting light fire-proof material, its characteristic difference is: said fiber is one or more in thomel, basalt fibre, the spun glass with a kind of aviation of embodiment one, and through Surface Treatment with Plasma.
Embodiment four
With fiber reinforcement thermosetting light fire-proof material, its characteristic difference is: said spun glass is one or more in alkali free glass fibre, medium-alkali glass fibre, the resurrection glass fibre with a kind of aviation of embodiment one.
Embodiment five
With a kind of aviation of embodiment one with fiber reinforcement thermosetting light fire-proof material; Its characteristic difference is: said basalt fibre roving; Be with sub-thread or the parallel continuous basalt fiber precursor of multiply under the state of not twisting and close the basalt fibre rove that forms, filament diameter is generally at 11 μ m-25 μ m.
Embodiment six
With fiber reinforcement thermosetting light fire-proof material, its characteristic difference is: said thomel is viscose-based carbon fiber or PAN-based carbon fiber or its mixed thing with a kind of aviation of embodiment one.
Embodiment seven
With fiber reinforcement thermosetting light fire-proof material, its characteristic difference is: said tensio-active agent is one or more in dimethyl siloxane, sorbitan fatty acid ester Soxylat A 25-7, the dodecylbenzene sulfonate with a kind of aviation of embodiment one.
Embodiment eight
With fiber reinforcement thermosetting light fire-proof material, its characteristic difference is: said solidifying agent is for being hydrochloric acid, sulfuric acid, phosphoric acid, mahogany acid or tosic acid with a kind of aviation of embodiment one.
Embodiment nine
With fiber reinforcement thermosetting light fire-proof material, its characteristic difference is: said whipping agent is Skellysolve A, normal butane, iso-pentane, sherwood oil or methylene dichloride with a kind of aviation of embodiment one.
Except that the foregoing description, the present invention can also have other embodiments.All employings are equal to the technical scheme of replacement or equivalent transformation formation, all drop in the protection domain of requirement of the present invention.
Claims (11)
1. an aviation is with fiber reinforcement thermosetting light fire-proof material; Its main composition comprises fiber, solvent impregnated resin, tensio-active agent, solidifying agent and whipping agent; It is characterized in that: said solvent impregnated resin is a modified phenolic resins, and said modified phenolic resins is resole and toughening agent modified gained.
2. a kind of aviation according to claim 1 is characterized in that with fiber reinforcement thermosetting light fire-proof material: the proportioning of its main composition is 100 in modified phenolic resins, tensio-active agent 2-10, solidifying agent 10-35, whipping agent 2-25, fiber 5-40.
3. a kind of aviation according to claim 1 is characterized in that with fiber reinforcement thermosetting light fire-proof material: described toughner is one or more in resole and vinyl cyanide/methylmethacrylate copolymer, silicon midbody, the polyurethanes compound.
4. a kind of aviation according to claim 1 is with fiber reinforcement thermosetting light fire-proof material, and it is characterized in that: said fiber is one or more in thomel, basalt fibre, the spun glass, and through Surface Treatment with Plasma.
5. a kind of aviation according to claim 4 is characterized in that with fiber reinforcement thermosetting light fire-proof material: said spun glass is one or more in alkali free glass fibre, medium-alkali glass fibre, the resurrection glass fibre.
6. a kind of aviation according to claim 4 is with fiber reinforcement thermosetting light fire-proof material; It is characterized in that: said basalt fibre roving; Be with sub-thread or the parallel continuous basalt fiber precursor of multiply under the state of not twisting and close the basalt fibre rove that forms, filament diameter is generally at 11 μ m-25 μ m.
7. a kind of aviation according to claim 4 is characterized in that with fiber reinforcement thermosetting light fire-proof material: said thomel is viscose-based carbon fiber or PAN-based carbon fiber or its mixed thing.
8. a kind of aviation according to claim 1 is characterized in that with fiber reinforcement thermosetting light fire-proof material: said tensio-active agent is one or more in dimethyl siloxane, sorbitan fatty acid ester Soxylat A 25-7, the dodecylbenzene sulfonate.
9. a kind of aviation according to claim 1 is characterized in that with fiber reinforcement thermosetting light fire-proof material: said solidifying agent is for being hydrochloric acid, sulfuric acid, phosphoric acid or tosic acid.
10. a kind of aviation according to claim 1 is characterized in that with fiber reinforcement thermosetting light fire-proof material: said whipping agent is Skellysolve A, normal butane, iso-pentane, sherwood oil or methylene dichloride.
11. a kind of aviation as claimed in claim 1 is with fiber reinforcement thermosetting light fire-proof material, its complete processing is: it is matrix that the first step is processed modified phenolic resins earlier, is called for short the A material; It is that B expects that second step stirred A material and solidifying agent, whipping agent, tensio-active agent etc.; The 3rd step flooded fiber through the B material; The fiber that the 4th step will be passed through dipping carries out dry pre-frothing through the warm air under 40-45 ℃; The 5th the step will through the material after the pre-frothing put into foam under mould or the autoclave heating and pressurizing finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102549363A CN102391615A (en) | 2011-08-31 | 2011-08-31 | Aviation fiber reinforcement and thermosetting light fireproofing material and production process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102549363A CN102391615A (en) | 2011-08-31 | 2011-08-31 | Aviation fiber reinforcement and thermosetting light fireproofing material and production process thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102391615A true CN102391615A (en) | 2012-03-28 |
Family
ID=45859006
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011102549363A Pending CN102391615A (en) | 2011-08-31 | 2011-08-31 | Aviation fiber reinforcement and thermosetting light fireproofing material and production process thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102391615A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102731964A (en) * | 2012-06-29 | 2012-10-17 | 武汉德丽宝建筑节能技术有限公司 | Method for producing constructional foam boards by using acrylic elastomer modified phenolic resin |
| CN103172924A (en) * | 2013-04-17 | 2013-06-26 | 天津大学 | High-thermal conductivity polymer composite material and preparation method thereof |
| CN103737992A (en) * | 2013-12-24 | 2014-04-23 | 唐地源 | Preparation method of fiber-reinforced composite board and obtained composite board |
| CN104073016A (en) * | 2014-07-03 | 2014-10-01 | 丹阳市新美龙汽车软饰件有限公司 | Lightweight high-strength fireproof composite and preparation method thereof |
| CN105899765A (en) * | 2014-01-09 | 2016-08-24 | 斯奈克玛 | Fire protection of a fan casing made of composite |
| CN106195610A (en) * | 2016-08-08 | 2016-12-07 | 山西晋投玄武岩开发有限公司 | A kind of basalt fibre grille section peculiar to vessel and the grid peculiar to vessel made of it |
| CN107129657A (en) * | 2017-07-05 | 2017-09-05 | 肥西县碧涛建材有限公司 | A kind of fire proofing material and preparation method thereof |
| CN108892919A (en) * | 2018-04-16 | 2018-11-27 | 安徽昊森新材料科技有限公司 | A kind of light sound-proof phenolic resin |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1200078A (en) * | 1996-09-04 | 1998-11-25 | 住友电木株式会社 | Flame-retardant or incombustible decorative laminated sheet |
| CN1428372A (en) * | 2001-12-26 | 2003-07-09 | 广州擎天新材料研究开发有限公司 | Phenolic foam plastic composite product and its production and forming process |
| CN1844233A (en) * | 2006-03-21 | 2006-10-11 | 上海胜星树脂涂料有限公司 | Method for preparing high temperature resistant phenol-formaldehyde foam composite thermal-insulating materials |
-
2011
- 2011-08-31 CN CN2011102549363A patent/CN102391615A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1200078A (en) * | 1996-09-04 | 1998-11-25 | 住友电木株式会社 | Flame-retardant or incombustible decorative laminated sheet |
| CN1428372A (en) * | 2001-12-26 | 2003-07-09 | 广州擎天新材料研究开发有限公司 | Phenolic foam plastic composite product and its production and forming process |
| CN1844233A (en) * | 2006-03-21 | 2006-10-11 | 上海胜星树脂涂料有限公司 | Method for preparing high temperature resistant phenol-formaldehyde foam composite thermal-insulating materials |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102731964A (en) * | 2012-06-29 | 2012-10-17 | 武汉德丽宝建筑节能技术有限公司 | Method for producing constructional foam boards by using acrylic elastomer modified phenolic resin |
| CN102731964B (en) * | 2012-06-29 | 2013-12-25 | 武汉德丽宝建筑节能技术有限公司 | Method for producing constructional foam boards by using acrylic elastomer modified phenolic resin |
| CN103172924A (en) * | 2013-04-17 | 2013-06-26 | 天津大学 | High-thermal conductivity polymer composite material and preparation method thereof |
| CN103737992A (en) * | 2013-12-24 | 2014-04-23 | 唐地源 | Preparation method of fiber-reinforced composite board and obtained composite board |
| CN105899765A (en) * | 2014-01-09 | 2016-08-24 | 斯奈克玛 | Fire protection of a fan casing made of composite |
| CN104073016A (en) * | 2014-07-03 | 2014-10-01 | 丹阳市新美龙汽车软饰件有限公司 | Lightweight high-strength fireproof composite and preparation method thereof |
| CN106195610A (en) * | 2016-08-08 | 2016-12-07 | 山西晋投玄武岩开发有限公司 | A kind of basalt fibre grille section peculiar to vessel and the grid peculiar to vessel made of it |
| CN106195610B (en) * | 2016-08-08 | 2018-09-04 | 山西晋投玄武岩开发有限公司 | A kind of basalt fibre grille section peculiar to vessel and grid peculiar to vessel with its making |
| CN107129657A (en) * | 2017-07-05 | 2017-09-05 | 肥西县碧涛建材有限公司 | A kind of fire proofing material and preparation method thereof |
| CN108892919A (en) * | 2018-04-16 | 2018-11-27 | 安徽昊森新材料科技有限公司 | A kind of light sound-proof phenolic resin |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102391615A (en) | Aviation fiber reinforcement and thermosetting light fireproofing material and production process thereof | |
| CN104073016B (en) | A kind of high-strength light Flameproof composite material and manufacture method thereof | |
| Wang et al. | Polymer matrix composites and technology | |
| Kulshreshtha et al. | Handbook of polymer blends and composites | |
| CN102731960B (en) | Preparation method of high-toughness flame retardation phenolic prepreg composite material | |
| CN104098869A (en) | Manufacturing method of high-intensity, lightweight and fireproof decorative material | |
| CN104629238A (en) | Halogen-free flame retardant basalt fiber reinforced unsaturated polyester resin composite material and preparation method thereof | |
| CN104497473B (en) | Fiber reinforced phenolic foam composite material and preparation method thereof | |
| CN104890262A (en) | Method for manufacturing corrosion-resistant and flame-retardant glass steel grid through pultrusion profile production system | |
| CN101920587B (en) | High-performance fire-retarding epoxy resin composite material and preparation thereof | |
| Farzana et al. | Properties and application of jute fiber reinforced polymer-based composites | |
| CN108342053A (en) | A kind of cable trough composite material, preparation method and its cable trough | |
| Gao et al. | Investigation of novel lightweight phenolic foam‐based composites reinforced with flax fiber mats | |
| EP3184294A1 (en) | Flame-retardant lightweight structural core and manufacturing method therefor | |
| CN102468635B (en) | Preparation technology of conductor spacer used by power transmission line | |
| Scarponi et al. | Green composites for aircraft interior panels | |
| CN104356325B (en) | Phenolic resin of nano layered silicate clay alteration and preparation method thereof | |
| CN105968622A (en) | Lightweight high-strength polyvinyl chloride foam tube | |
| US11701870B2 (en) | Structural and decorative composite material, preparation method therefor, and article containing same | |
| CN203514930U (en) | Medium-thickness glass fiber reinforced plastic chimney | |
| CN113354335A (en) | Heat insulation composite material and preparation method and application thereof | |
| CN103526977B (en) | A kind of fiber glass reinforced plastic chimney | |
| CN203514928U (en) | Glass steel chimney with novel liner functional layer structure and chimney | |
| CN104045972A (en) | Prepreg and fiber-reinforced compound foam material | |
| CN105090729A (en) | Fiber-reinforced melamine foam board |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20120328 |