CN102101732A - Method for recovering hydrazine sulfate and chromium hydroxide from chromium-containing waste acid - Google Patents
Method for recovering hydrazine sulfate and chromium hydroxide from chromium-containing waste acid Download PDFInfo
- Publication number
- CN102101732A CN102101732A CN201110007594.5A CN201110007594A CN102101732A CN 102101732 A CN102101732 A CN 102101732A CN 201110007594 A CN201110007594 A CN 201110007594A CN 102101732 A CN102101732 A CN 102101732A
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- CN
- China
- Prior art keywords
- chromium
- sulfate
- hydrazine
- liquid separation
- waste acid
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- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 title claims abstract description 23
- 239000002253 acid Substances 0.000 title claims abstract description 23
- 239000011651 chromium Substances 0.000 title claims abstract description 20
- 229910052804 chromium Inorganic materials 0.000 title claims abstract description 19
- VQWFNAGFNGABOH-UHFFFAOYSA-K chromium(iii) hydroxide Chemical compound [OH-].[OH-].[OH-].[Cr+3] VQWFNAGFNGABOH-UHFFFAOYSA-K 0.000 title claims abstract description 18
- 238000000034 method Methods 0.000 title claims abstract description 13
- 239000002699 waste material Substances 0.000 title abstract description 6
- FUSNOPLQVRUIIM-UHFFFAOYSA-N 4-amino-2-(4,4-dimethyl-2-oxoimidazolidin-1-yl)-n-[3-(trifluoromethyl)phenyl]pyrimidine-5-carboxamide Chemical compound O=C1NC(C)(C)CN1C(N=C1N)=NC=C1C(=O)NC1=CC=CC(C(F)(F)F)=C1 FUSNOPLQVRUIIM-UHFFFAOYSA-N 0.000 title abstract 5
- 229910000377 hydrazine sulfate Inorganic materials 0.000 title abstract 5
- 239000012493 hydrazine sulfate Substances 0.000 title abstract 5
- 239000007788 liquid Substances 0.000 claims abstract description 17
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 claims abstract description 11
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000000926 separation method Methods 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000003513 alkali Substances 0.000 claims abstract description 6
- GRWVQDDAKZFPFI-UHFFFAOYSA-H chromium(III) sulfate Chemical compound [Cr+3].[Cr+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRWVQDDAKZFPFI-UHFFFAOYSA-H 0.000 claims abstract description 6
- 238000004065 wastewater treatment Methods 0.000 claims abstract description 5
- 238000001035 drying Methods 0.000 claims abstract description 4
- 238000006386 neutralization reaction Methods 0.000 claims abstract description 4
- ZGCHATBSUIJLRL-UHFFFAOYSA-N hydrazine sulfate Chemical compound NN.OS(O)(=O)=O ZGCHATBSUIJLRL-UHFFFAOYSA-N 0.000 claims description 18
- 238000001556 precipitation Methods 0.000 claims description 5
- 238000013019 agitation Methods 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 238000001953 recrystallisation Methods 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 239000012535 impurity Substances 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 238000005406 washing Methods 0.000 abstract description 4
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 abstract description 3
- 238000003756 stirring Methods 0.000 abstract description 3
- 239000002244 precipitate Substances 0.000 abstract description 2
- 230000002378 acidificating effect Effects 0.000 abstract 2
- 239000013078 crystal Substances 0.000 abstract 1
- 238000007865 diluting Methods 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 239000002351 wastewater Substances 0.000 abstract 1
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000012065 filter cake Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000010413 mother solution Substances 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- HFLBGLHPZPFPAU-UHFFFAOYSA-N 1-amino-2-[5-(1-amino-9,10-dioxoanthracen-2-yl)-1,3,4-oxadiazol-2-yl]anthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=C(N)C(C4=NN=C(O4)C4=C(C=5C(=O)C6=CC=CC=C6C(=O)C=5C=C4)N)=CC=C3C(=O)C2=C1 HFLBGLHPZPFPAU-UHFFFAOYSA-N 0.000 description 1
- KSPIHGBHKVISFI-UHFFFAOYSA-N Diphenylcarbazide Chemical compound C=1C=CC=CC=1NNC(=O)NNC1=CC=CC=C1 KSPIHGBHKVISFI-UHFFFAOYSA-N 0.000 description 1
- 238000005267 amalgamation Methods 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 description 1
- 229940045511 barium chloride Drugs 0.000 description 1
- 229910001626 barium chloride Inorganic materials 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000002920 hazardous waste Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 238000002798 spectrophotometry method Methods 0.000 description 1
Landscapes
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
The invention discloses a method for recovering hydrazine sulfate and chromium hydroxide from chromium-containing waste acid, which comprises the following steps of: diluting hydrazine hydrate, slowly adding waste acid into the hydrazine hydrate with stirring, ensuring an acid adding end point when the pH of feed liquid is 0.8-1.2, and reacting hexavalent chromium in the waste acid with the hydrazine hydrate to reduce the hexavalent chromium into trivalent chromium and generate indissoluble hydrazine sulfate crystals; performing solid-liquid separation to obtain crude hydrazine sulfate and acidic chromium sulfate solution; adding alkali into acidic chromium sulfate solution for neutralization to obtain a chromium hydroxide precipitate, performing solid-liquid separation, washing with water, and drying to obtain an industrial product chromium hydroxide meeting quality requirement; and treating wastewater subjected to solid-liquid separation and washing in a wastewater treatment device for up-to-standard emission. The method is easy to operate, and the chromium-containing waste acid is treated for up-to-standard emission; meanwhile, the hydrazine sulfate and chromium hydroxide are recovered, so that the resources are reasonably utilized and the economic benefit is obvious.
Description
Technical field
The present invention relates to contain the improvement and the resource recycling of chromium spent acid.
Background technology
Vat Red 31 is a kind of important dyestuff, but in it is produced, only could guarantee that with the sexavalent chrome oxidation coloured light is accurate in the strongly-acid medium, thus, produce a large amount of spent acid, about 10 tons/ton, the about 55-68% of acidity contains organism about 0.5%, it is about 3% to contain total chromium, wherein, contains sexavalent chrome about 0.6%.
This spent acid becomes Hazardous wastes owing to contain chromium, and it is three prices that current enterprise takes to add earlier the S-WAT reduction of hexavalent chromium, adds the alkali neutralization again, and the method that generates chromium hydroxide and reclaim need expend a large amount of alkali, produces a large amount of brine wastes simultaneously, and processing cost is difficult to bear.
This contains the chromium spent acid also can hydro-oxidation barium or bariumchloride, generates barium sulfate precipitate, continues to add alkali after the separation again and generates chromium hydroxide.But it is lower that barium sulfate is worth, so this method does not have the industrial implementation meaning.
Summary of the invention
The present invention proposes and a kind of this spent acid is handled the method for making hydrazonium sulfate and chromium hydroxide, with reclaim(ed) sulfuric acid and chromium.
Technical scheme of the present invention is as follows:
A kind of from contain the chromium spent acid method of reclaim(ed) sulfuric acid hydrazine and chromium hydroxide, it comprises the steps:
(1) hydrazine hydrate being diluted to mass percentage concentration is the aqueous solution below 20%, after will containing the chromium spent acid and removing solid impurity after filtration, under agitation slowly join in the hydrazine hydrate, control adds the pH=0.8-1.2 of sour terminal point to feed liquid, sexavalent chrome in the spent acid and hydrazine hydrate reaction, be reduced into trivalent chromium, generate the hydrazonium sulfate xln of indissoluble simultaneously;
(2) solid-liquid separation obtains thick hydrazonium sulfate and acid chromium sulfate solution;
(3) with thick hydrazonium sulfate through recrystallization, the industrial goods hydrazonium sulfate that obtains conforming to quality requirements;
(4) the oxytropism chromium sulfate solution adds alkali, and neutralization generates chromium hydroxide precipitation, and solid-liquid separation washes after drying with water, promptly obtains the industrial goods chromium hydroxide that conforms to quality requirements;
(5) send wastewater treatment equipment to handle back qualified discharge (wastewater treatment is an ordinary method, not in present method scope) step 4 solid-liquid separation and washes.
The inventive method is simple to operate, has both administered to contain the chromium spent acid, makes its qualified discharge, has reclaimed hydrazonium sulfate and chromium hydroxide simultaneously, makes resource obtain reasonable utilization, and economic benefit is obvious.
Embodiment
Further specify technological process of the present invention below by embodiment.
Embodiment:
Getting mass percentage concentration is that 40% hydrazine hydrate 49.5mL is diluted to 20% solution, get 40mL and contain chromium spent acid (acidity 65%) filtration, under agitation slowly be added drop-wise in 20% hydrazine hydrate solution, dropping time 2h, control adds sour terminal point material liquid pH=0.8, generate white crystalline hydrazonium sulfate precipitation, reaction formula is as follows:
NH
2-NH
2·H
2O+H
2SO
4=?NH
2-NH
2·H
2SO
4
2Cr
2O
7 2-+4H
++3N
2H
4·H
2O→4Cr(OH)
3+N
2+5H
2O
2Cr(OH)
3+3H
2SO
4→Cr
2(SO4)
3+6H
2O
Leave standstill 0.5h, put into 2h in 5 ℃ the refrigerator then.
Filter, with a small amount of cold clear water (5 ℃) washing hydrazonium sulfate filter cake, filtrate merges in the synthesis mother liquid.Get the 155mL clear water and be heated to 60 ℃ (27.65g/100g, 60 ℃), will wash back hydrazonium sulfate filter cake and add stirring and dissolving, cooling, crystallization merges in crystalline mother solution and the synthesis mother liquid.
Hydrazonium sulfate oven dry behind the recrystallization, analyzing its content is 98.1%, gets hydrazonium sulfate 42.25 g, calculates with this, the vitriolic rate of recovery is about 78%.
Under agitation, in crystalline mother solution and synthesis mother liquid amalgamation liquid, drip 30%NaOH, about control pH=7.5, generate the sap green chromium hydroxide precipitation, continue to stir 0.5h, leave standstill 0.5h, filter, filter cake is with a small amount of clear water washed twice, washing water and mother liquor merge, through the diphenyl carbazide spectrophotometry analysis, total chromium concn is 0.38mg/L, goes wastewater treatment.
Chromium hydroxide precipitation drying, content are 92.4%.
Claims (1)
1. the method for reclaim(ed) sulfuric acid hydrazine and chromium hydroxide from contain the chromium spent acid is characterized in that it comprises the steps:
(1) hydrazine hydrate being diluted to mass percentage concentration is the aqueous solution below 20%, after will containing the chromium spent acid and removing solid impurity after filtration, under agitation slowly join in the hydrazine hydrate, control adds the pH=0.8-1.2 of sour terminal point to feed liquid, sexavalent chrome in the spent acid and hydrazine hydrate reaction, be reduced into trivalent chromium, generate the hydrazonium sulfate xln of indissoluble simultaneously;
(2) solid-liquid separation obtains thick hydrazonium sulfate and acid chromium sulfate solution;
(3) with thick hydrazonium sulfate through recrystallization, the industrial goods hydrazonium sulfate that obtains conforming to quality requirements;
(4) the oxytropism chromium sulfate solution adds alkali, and neutralization generates chromium hydroxide precipitation, and solid-liquid separation washes after drying with water, promptly obtains the industrial goods chromium hydroxide that conforms to quality requirements;
(5) send wastewater treatment equipment to handle the back qualified discharge step 4 solid-liquid separation and washes.
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CN201110007594.5A CN102101732A (en) | 2011-01-14 | 2011-01-14 | Method for recovering hydrazine sulfate and chromium hydroxide from chromium-containing waste acid |
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CN201110007594.5A CN102101732A (en) | 2011-01-14 | 2011-01-14 | Method for recovering hydrazine sulfate and chromium hydroxide from chromium-containing waste acid |
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CN201110007594.5A Pending CN102101732A (en) | 2011-01-14 | 2011-01-14 | Method for recovering hydrazine sulfate and chromium hydroxide from chromium-containing waste acid |
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Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106277420A (en) * | 2015-06-03 | 2017-01-04 | 中国科学院过程工程研究所 | A kind of dechromium method of organic reducing Cr VI alkaline waste liquor |
CN108862217A (en) * | 2018-07-09 | 2018-11-23 | 郭秦 | A kind of thiocarbohydrazide production wastewater treatment process |
RU2678287C1 (en) * | 2017-10-30 | 2019-01-24 | Акционерное общество "Радиевый институт им. В.Г. Хлопина" | Method for decontamination of aqueous solutions containing compounds of hexavalent chrome |
CN110395815A (en) * | 2019-07-13 | 2019-11-01 | 河南大学 | A kind of processing method of acidity electroplating wastewater of chromium |
CN111186940A (en) * | 2020-01-19 | 2020-05-22 | 西安瑞联新材料股份有限公司 | Industrial treatment method of high-valence chromium wastewater |
CN111484079A (en) * | 2020-04-23 | 2020-08-04 | 成都铬科高化工技术有限责任公司 | Method for preparing chromium oxide green from chromium-containing waste liquid in naphthoquinone production |
CN112159016A (en) * | 2020-09-16 | 2021-01-01 | 内蒙古格林特制药有限责任公司 | Method for recovering and treating waste acid water generated in amantadine synthesis |
CN113912119A (en) * | 2021-10-08 | 2022-01-11 | 上海交通大学 | Treatment process of waste chromium plating bath solution |
CN114105105A (en) * | 2020-08-31 | 2022-03-01 | 中国科学院过程工程研究所 | Chromium-containing waste acid cleaning and regenerating method |
CN115285952A (en) * | 2022-07-09 | 2022-11-04 | 黄淮学院 | Method for preparing hydrazine sulfate by utilizing waste water generated in synthesis of aromatic hydrazide compounds |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1763262A (en) * | 2005-09-09 | 2006-04-26 | 桂林工学院 | Method for recovering and treating chromium from waste chromium electrodeposition solution |
CN101875520A (en) * | 2010-08-10 | 2010-11-03 | 南京师范大学 | Processing method of electroplating wastewater containing cyanogens and chrome |
-
2011
- 2011-01-14 CN CN201110007594.5A patent/CN102101732A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1763262A (en) * | 2005-09-09 | 2006-04-26 | 桂林工学院 | Method for recovering and treating chromium from waste chromium electrodeposition solution |
CN101875520A (en) * | 2010-08-10 | 2010-11-03 | 南京师范大学 | Processing method of electroplating wastewater containing cyanogens and chrome |
Non-Patent Citations (2)
Title |
---|
《环境保护科学》 19911231 毛继红等 活性炭-水合肼处理镀铬废水的研究 24-27、38 1 第17卷, 第4期 2 * |
《精细石油化工进展》 20060430 蒋小友等 用水合肼回收电沉积铬废液中铬的工艺条件研究 25-26、30 1 第7卷, 第4期 2 * |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106277420A (en) * | 2015-06-03 | 2017-01-04 | 中国科学院过程工程研究所 | A kind of dechromium method of organic reducing Cr VI alkaline waste liquor |
CN106277420B (en) * | 2015-06-03 | 2019-07-23 | 中国科学院过程工程研究所 | A kind of dechromium method of organic reducing Cr VI alkaline waste liquor |
RU2678287C1 (en) * | 2017-10-30 | 2019-01-24 | Акционерное общество "Радиевый институт им. В.Г. Хлопина" | Method for decontamination of aqueous solutions containing compounds of hexavalent chrome |
CN108862217A (en) * | 2018-07-09 | 2018-11-23 | 郭秦 | A kind of thiocarbohydrazide production wastewater treatment process |
CN110395815A (en) * | 2019-07-13 | 2019-11-01 | 河南大学 | A kind of processing method of acidity electroplating wastewater of chromium |
CN111186940A (en) * | 2020-01-19 | 2020-05-22 | 西安瑞联新材料股份有限公司 | Industrial treatment method of high-valence chromium wastewater |
CN111484079A (en) * | 2020-04-23 | 2020-08-04 | 成都铬科高化工技术有限责任公司 | Method for preparing chromium oxide green from chromium-containing waste liquid in naphthoquinone production |
CN111484079B (en) * | 2020-04-23 | 2022-08-02 | 成都铬科高化工技术有限责任公司 | Method for preparing chromium oxide green from chromium-containing waste liquid in naphthoquinone production |
CN114105105A (en) * | 2020-08-31 | 2022-03-01 | 中国科学院过程工程研究所 | Chromium-containing waste acid cleaning and regenerating method |
CN112159016A (en) * | 2020-09-16 | 2021-01-01 | 内蒙古格林特制药有限责任公司 | Method for recovering and treating waste acid water generated in amantadine synthesis |
CN113912119A (en) * | 2021-10-08 | 2022-01-11 | 上海交通大学 | Treatment process of waste chromium plating bath solution |
CN115285952A (en) * | 2022-07-09 | 2022-11-04 | 黄淮学院 | Method for preparing hydrazine sulfate by utilizing waste water generated in synthesis of aromatic hydrazide compounds |
CN115285952B (en) * | 2022-07-09 | 2023-09-29 | 黄淮学院 | Method for preparing hydrazine sulfate by utilizing aromatic hydrazide compound synthetic wastewater |
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Application publication date: 20110622 |