CN102061225B - Fatty acid candle and method for manufacturing same - Google Patents

Fatty acid candle and method for manufacturing same Download PDF

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Publication number
CN102061225B
CN102061225B CN201010520388.XA CN201010520388A CN102061225B CN 102061225 B CN102061225 B CN 102061225B CN 201010520388 A CN201010520388 A CN 201010520388A CN 102061225 B CN102061225 B CN 102061225B
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fatty acid
acid
candle
mixt
hexadecanoic
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CN102061225A (en
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王瑛
姜永波
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Ningbo Kwung's Home Interior & Gift Co ltd
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Ningbo Kwung's Home Interior & Gift Co ltd
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Abstract

The invention discloses a fatty acid candle and a method for manufacturing the same; the candle comprises a surface crystallization regulator and a fatty acid mixture consisting of hexadecanoic acid and octadecanoic acid; the weight percentages of hexadecanoic acid and octadecanoic acid in the fatty acid mixture can be divided into two ratio zones: 65-80% of hexadecanoic acid and 20-35% of octadecanoic acid are contained in one ratio zone; and 30-50% of hexadecanoic acid and 50-70% of octadecanoic acid are contained in the other ratio zone. The method for manufacturing the fatty acid candle comprises the following steps: after heating the object to the temperature of 120 DEG C, pouring into a mould and naturally cooling to form a hard husk; and adding the solid crushed blocks that are the same as the poured liquid mixture in components, or pouring into the stainless steel candle machine mould cylinder at the temperature of 30-35 DEG C; and after fully cooling, de-molding to obtain a fatty acid candle with a smooth and uniform surface. The fatty acid candle has the advantages of being reproducible, biologically degradable, nontoxic and low-cost; and the manufacturing method enables the surface of the candle to be smooth and free from cracking.

Description

Fatty acid candle and preparation method thereof
Technical field:
The present invention relates to a kind of fatty acid candle and preparation method thereof.
Background technology:
At present, the tradition candle be take paraffin and is made as material of main part, but, the paraffin of take is made candle as material of main part and had following three shortcomings: 1,, due to the continuous consumption of Global Oil resource, oil supply totally is becoming tight, and price is totally tended towards superiority, therefore, the paraffin that derives from oil is also more and more wellr sold and in short supply, and price is also constantly soaring, thereby has greatly increased the cost of manufacture of candle; 2, paraffin can not biological degradation, and the candle that the paraffin of take is made as material of main part still in use all can produce some rubbish that contain paraffin and increases environmental pressure producing; Can produce harmful material when 3, wax candle is burnt.For above-mentioned three shortcomings, many candles manufacturer has started to attempt substituting paraffin with some renewable, biodegradable, nontoxic, eco-friendly materials such as lipid acid in the world, but because the workability of these materials is poorer than paraffin, in making the candle process, easily ftracture, be not easy to form evenly unified surface effect, poor ductility, can not use the powder extrusion molding, easily produce the reasons such as cavity during cast, therefore can only in paraffin, add suitable ratio, part substitutes paraffin and manufactures candle.
Summary of the invention:
The technical problem to be solved in the present invention is, provide a kind of not only have advantages of renewable, biodegradable, nontoxic, cost of manufacture is low, but also can make surface of candle smooth, is not easy fatty acid candle of cracking and preparation method thereof.
First technical solution of the present invention is, a kind of fatty acid candle that includes fatty acid mixt is provided, wherein, it also comprises the surface crystallization conditioning agent, fatty acid mixt is comprised of hexadecanoic acid and octadecanoic acid, the weight percent of hexadecanoic acid and the shared fatty acid mixt of octadecanoic acid can be divided between two proportional bands, account for 65~80% of fatty acid mixt weight for hexadecanoic acid between a proportional band, octadecanoic acid accounts for 20~35% of fatty acid mixt weight, between another proportional band, be hexadecanoic acid account for fatty acid mixt weight 30~50%, octadecanoic acid accounts for 50~70% of fatty acid mixt weight.
Fatty acid candle of the present invention, wherein, the surface crystallization conditioning agent can be polyol mono fatty acid ester or ethene polymers, the adding proportion of described polyol mono fatty acid ester is 0.5~3% of fatty acid mixt weight, and described polyvinyl adding proportion is 0.1~1.0% of fatty acid mixt weight.
Fatty acid candle of the present invention, wherein, the polyol mono fatty acid ester is three polyglycerol list octadecane acid esters, six polyglycerol monostearates or polyethylene glycol mono stearate etc., ethene polymers is VYBAR103, VYBAR260.
Fatty acid candle of the present invention, wherein, the weight percent that hexadecanoic acid accounts for fatty acid mixt is 30% or 40% or 50% or 65% or 67% or 80%, and the weight percent that described octadecanoic acid accounts for fatty acid mixt is 70% or 60% or 50% or 35% or 33% or 20% with respect to hexadecanoic acid.
Second technical solution of the present invention is that a kind of making method of the fatty acid candle comprised the following steps is provided:
1, under 20 ℃~30 ℃ of envrionment temperatures, the solid-state fatty acid mixt of particulate state that first will be comprised of hexadecanoic acid and octadecanoic acid and granular surface crystallization conditioning agent join in a stainless steel cask simultaneously, wherein, the weight percent of hexadecanoic acid and the shared fatty acid mixt of octadecanoic acid can be divided between two proportional bands, account for 65~80% of fatty acid mixt weight for hexadecanoic acid between a proportional band, octadecanoic acid accounts for 20~35% of fatty acid mixt weight, between another proportional band, be hexadecanoic acid account for fatty acid mixt weight 30~50%, octadecanoic acid accounts for 50~70% of fatty acid mixt weight,
2, then constantly stir and slow hexadecanoic acid, octadecanoic acid and the surface crystallization conditioning agent in the heating stainless steel cask, stop heating when hexadecanoic acid, octadecanoic acid and surface crystallization conditioning agent are fused into liquid mixture fully and make the temperature of this liquid mixture be raised to 120 ℃;
3, then with the hot water of 35 ℃ by water tank preheating stainless steel wax machine to 30~35 ℃, then the liquid mixture of 120 ℃ in step 2 is poured in the stainless steel wax machine mould cylinder of 30~35 ℃, drain for carrying out cooling to the cold water that passes into 20 ℃ in water tank again after the hot water of heating, the cooling rear demoulding fully, obtain the uniform fatty acid candle of smooth surface.
The method of making fatty acid candle of the present invention, wherein, the temperature after the preheating of stainless steel wax machine is 30 ℃, 32 ℃ or 35 ℃.
Meanwhile, the present invention also provides a kind of method with making fatty acid candle of following steps:
1, under 20 ℃~30 ℃ of envrionment temperatures, the solid-state fatty acid mixt of particulate state that first will be comprised of hexadecanoic acid and octadecanoic acid and granular surface crystallization conditioning agent join in a stainless steel cask simultaneously, wherein, the weight percent of hexadecanoic acid and the shared fatty acid mixt of octadecanoic acid can be divided between two proportional bands, account for 65~80% of fatty acid mixt weight for hexadecanoic acid between a proportional band, octadecanoic acid accounts for 20~35% of fatty acid mixt weight, between another proportional band, be hexadecanoic acid account for fatty acid mixt weight 30~50%, octadecanoic acid accounts for 50~70% of fatty acid mixt weight,
2, then constantly stir and slow hexadecanoic acid, octadecanoic acid and the surface crystallization conditioning agent in the heating stainless steel cask, stop heating when hexadecanoic acid, octadecanoic acid and surface crystallization conditioning agent are fused into liquid mixture fully and make the temperature of this liquid mixture be raised to 120 ℃;
3, the liquid mixture of 120 ℃ in step 2 is poured in plastics candle mould, naturally cooling, during the duricrust of 0.5~1 centimetre of thickness of the cooling formation of the liquid mixture shell in mould to be cast, knock openning open from the die casting mouth, add shift to an earlier date ready with the cast liquid mixture with the solid fragment of sample ingredient, the cooling rear demoulding fully, obtain a uniform fatty acid candle of smooth surface.
Method according to making fatty acid candle of the present invention, wherein, the weight percent that hexadecanoic acid accounts for fatty acid mixt is 30% or 40% or 50% or 65% or 67% or 80%, and the weight percent that octadecanoic acid accounts for fatty acid mixt is 70% or 60% or 50% or 35% or 33% or 20% with respect to hexadecanoic acid.
Method according to making fatty acid candle of the present invention, wherein, the surface crystallization conditioning agent can be polyol mono fatty acid ester or ethene polymers, the adding proportion of described polyol mono fatty acid ester is 0.5~3% of fatty acid mixt weight, described polyvinyl adding proportion is 0.1~1.0% of fatty acid mixt weight, said polyol mono fatty acid ester is three polyglycerol list octadecane acid esters, six polyglycerol monostearates or polyethylene glycol mono stearate etc., and ethene polymers is VYBAR103, VYBAR260.
Because the material of main part adopted in fatty acid candle of the present invention and preparation method thereof is mainly the mixture that hexadecanoic acid and octadecanoic acid form, this fatty acid mixt can be the fatty acid mixt that the refining hydrolysis distillation of Vegetable oil lipoprotein or animal grease obtains, current this lipid acid price is than the low 3500-4000 yuan/ton of paraffin, in addition, avoided the proportional range of the loose coarse crystallization of easy formation between the hexadecanoic acid in the present invention and the proportional band of octadecanoic acid, make product surface easily form the smooth effect of the tiny densification of crystallization, the polyol mono fatty acid ester is that rely on the polarity of its many alcoholic extract hydroxyl groups and fatty acid carbon chain nonpolar strengthened the consistency under differing temps between different lipid acid, thereby make the fine and close smooth cracking that is not easy of surface crystallization, and ethene polymers be by its higly branched chain structural strengthening the consistency under differing temps between different lipid acid.Utilize the water tank of stainless steel wax machine first to lead to hot water logical cold water again, make the synchronous cooling in whole mould cylinder surface, crystallization is even.The single mode cast, knock openning open from the die casting mouth, adds and shift to an earlier date ready and pour into a mould the solid fragment of liquid mixture with sample ingredient, greatly eliminated the cracking produced because of surface heat stress.In sum, that fatty acid candle of the present invention not only has advantages of is renewable, biodegradable, nontoxic, cost of manufacture is low, and its making method can also make surface of candle smooth, is not easy cracking.
Specific embodiment:
Below in conjunction with specific embodiment, fatty acid candle of the present invention and preparation method thereof is described further:
One, fatty acid candle of the present invention has following six kinds of specific embodiments:
Embodiment 1
Fatty acid candle of the present invention comprises fatty acid mixt and surface crystallization conditioning agent, fatty acid mixt is comprised of hexadecanoic acid and octadecanoic acid, the weight percent that hexadecanoic acid accounts for fatty acid mixt is 80%, the weight percent of the shared fatty acid mixt of octadecanoic acid is 20%, what the surface crystallization conditioning agent adopted is three polyglycerol list octadecane acid esters, and its adding proportion is 0.5% of fatty acid mixt total amount.
Embodiment 2
Fatty acid candle of the present invention comprises fatty acid mixt and surface crystallization conditioning agent, fatty acid mixt is comprised of hexadecanoic acid and octadecanoic acid, the weight percent that hexadecanoic acid accounts for fatty acid mixt is 67%, the weight percent of the shared fatty acid mixt of octadecanoic acid is 33%, that the surface crystallization conditioning agent adopts is the VYBAR103 that U.S. Petrolite company produces, and its adding proportion is 0.2% of fatty acid mixt total amount.
Embodiment 3
Fatty acid candle of the present invention comprises fatty acid mixt and surface crystallization conditioning agent, fatty acid mixt is comprised of hexadecanoic acid and octadecanoic acid, the weight percent that hexadecanoic acid accounts for fatty acid mixt is 65%, the weight percent of the shared fatty acid mixt of octadecanoic acid is 35%, that the surface crystallization conditioning agent adopts is the VYBAR103 that U.S. Petrolite company produces, and its adding proportion is 0.2% of fatty acid mixt total amount.
Embodiment 4
Fatty acid candle of the present invention comprises fatty acid mixt and surface crystallization conditioning agent, fatty acid mixt is comprised of hexadecanoic acid and octadecanoic acid, the weight percent that hexadecanoic acid accounts for fatty acid mixt is 40%, the weight percent of the shared fatty acid mixt of octadecanoic acid is 60%, that the surface crystallization conditioning agent adopts is the VYBAR103 that U.S. Petrolite company produces, and its adding proportion is 0.5% of fatty acid mixt total amount.
Embodiment 5
Fatty acid candle of the present invention comprises fatty acid mixt and surface crystallization conditioning agent, fatty acid mixt is comprised of hexadecanoic acid and octadecanoic acid, the weight percent that hexadecanoic acid accounts for fatty acid mixt is 50%, the weight percent of the shared fatty acid mixt of octadecanoic acid is 50%, that the surface crystallization conditioning agent adopts is the VYBAR103 that U.S. Petrolite company produces, and its adding proportion is 0.2% of fatty acid mixt total amount.
Embodiment 6
Fatty acid candle of the present invention comprises fatty acid mixt and surface crystallization conditioning agent, fatty acid mixt is comprised of hexadecanoic acid and octadecanoic acid, the weight percent that hexadecanoic acid accounts for fatty acid mixt is 30%, the weight percent of the shared fatty acid mixt of octadecanoic acid is 70%, that the surface crystallization conditioning agent adopts is the VYBAR103 that U.S. Petrolite company produces, and its adding proportion is 0.1% of fatty acid mixt total amount.
Two, the method that the present invention makes fatty acid candle has following six kinds of specific embodiments
Embodiment 1
Under 25 ℃ of envrionment temperatures, the solid-state fatty acid mixt of particulate state that the octadecanoic acid that the hexadecanoic acid that will be first 80% by weight percent content and weight percent content are 20% forms and granular three polyglycerol list octadecane acid esters as the surface crystallization conditioning agent join in a stainless steel cask simultaneously, and wherein the ratio of three polyglycerol list octadecane acid esters is 0.5% of fatty acid mixt gross weight; Then constantly stir and slow hexadecanoic acid, octadecanoic acid and three polyglycerol list octadecane acid esters in the heating stainless steel cask, stop heating when hexadecanoic acid, octadecanoic acid and surface crystallization conditioning agent are fused into liquid mixture fully and make the temperature of this liquid mixture be raised to 120 ℃; Then pass through water tank preheating stainless steel wax machine to 30 ℃ with the hot water of 35 ℃, finally the liquid mixture of 120 ℃ is poured in the mould cylinder of stainless steel wax machine of 30 ℃, the cold water that passes into again 20 ℃ after the hot water of draining for heating carries out cooling, the cooling rear demoulding fully, obtain the uniform fatty acid candle of smooth surface.
Embodiment 2
Under 30 ℃ of envrionment temperatures, the solid-state fatty acid mixt of particulate state that the octadecanoic acid that the hexadecanoic acid that will be first 67% by weight percent content and weight percent content are 33% forms and the granular VYBAR103 produced by U.S. Petrolite company as the surface crystallization conditioning agent join in a stainless steel cask simultaneously, and wherein the adding proportion of VYBAR103 is 0.2% of fatty acid mixt gross weight; Then constantly stir and slow hexadecanoic acid, octadecanoic acid and the VYBAR103 in the heating stainless steel cask, stop heating when hexadecanoic acid, octadecanoic acid and VYBAR103 are fused into liquid mixture fully and make the temperature of this liquid mixture be raised to 120 ℃; Finally the liquid mixture of 120 ℃ is poured in plastics candle mould, naturally cooling, during the duricrust of 0.5~1 centimetre of thickness of the cooling formation of the liquid mixture shell in mould to be cast, knock openning open from the die casting mouth, add shift to an earlier date ready with the cast liquid mixture with the solid fragment of sample ingredient, the cooling rear demoulding fully, obtain a uniform fatty acid candle of smooth surface.
Embodiment 3
Under 30 ℃ of envrionment temperatures, the solid-state fatty acid mixt of particulate state that the octadecanoic acid that the hexadecanoic acid that will be first 65% by weight percent content and weight percent content are 35% forms and the granular VYBAR103 produced by U.S. Petrolite company as the surface crystallization conditioning agent join in a stainless steel cask simultaneously, and wherein the adding proportion of VYBAR103 is 0.2% of fatty acid mixt gross weight; Then constantly stir and slow hexadecanoic acid, octadecanoic acid and the VYBAR103 in the heating stainless steel cask, stop heating when hexadecanoic acid, octadecanoic acid and VYBAR103 are fused into liquid mixture fully and make the temperature of this liquid mixture be raised to 120 ℃; Finally the liquid mixture of 120 ℃ is poured in plastics candle mould, naturally cooling, during the duricrust of 0.5~1 centimetre of thickness of the cooling formation of the liquid mixture shell in mould to be cast, knock openning open from the die casting mouth, add shift to an earlier date ready with the cast liquid mixture with the solid fragment of sample ingredient, the cooling rear demoulding fully, obtain a uniform fatty acid candle of smooth surface.
Embodiment 4
Under 20 ℃ of envrionment temperatures, the solid-state fatty acid mixt of particulate state that the octadecanoic acid that the hexadecanoic acid that will be first 40% by weight percent content and weight percent content are 60% forms and the granular VYBAR103 produced by U.S. Petrolite company as the surface crystallization conditioning agent join in a stainless steel cask simultaneously, and wherein the adding proportion of VYBAR103 is 0.5% of fatty acid mixt gross weight; Then constantly stir and slow hexadecanoic acid, octadecanoic acid and the VYBAR103 in the heating stainless steel cask, stop heating when hexadecanoic acid, octadecanoic acid and VYBAR103 are fused into liquid mixture fully and make the temperature of this liquid mixture be raised to 120 ℃; Then pass through water tank preheating stainless steel wax machine to 32 ℃ with the hot water of 35 ℃, finally the liquid mixture of 120 ℃ is poured in the mould cylinder of stainless steel wax machine of 32 ℃, drain for carrying out cooling to the cold water that passes into 20 ℃ in water tank again after the hot water of heating, the cooling rear demoulding fully, obtain the uniform fatty acid candle of smooth surface.
Embodiment 5
Under 30 ℃ of envrionment temperatures, the solid-state fatty acid mixt of particulate state that the octadecanoic acid that the hexadecanoic acid that will be first 50% by weight percent content and weight percent content are 50% forms and the granular VYBAR103 produced by U.S. Petrolite company as the surface crystallization conditioning agent join in a stainless steel cask simultaneously, and wherein the adding proportion of VYBAR103 is 0.2% of fatty acid mixt gross weight; Then constantly stir and slow hexadecanoic acid, octadecanoic acid and the VYBAR103 in the heating stainless steel cask, stop heating when hexadecanoic acid, octadecanoic acid and VYBAR103 are fused into liquid mixture fully and make the temperature of this liquid mixture be raised to 120 ℃; Finally the liquid mixture of 120 ℃ is poured in plastics candle mould, naturally cooling, during the duricrust of 0.5~1 centimetre of thickness of the cooling formation of the liquid mixture shell in mould to be cast, knock openning open from the die casting mouth, add shift to an earlier date ready with the cast liquid mixture with the solid fragment of sample ingredient, the cooling rear demoulding fully, obtain a uniform fatty acid candle of smooth surface.
Embodiment 6
Under 25 ℃ of envrionment temperatures, the particulate state fatty acid mixt that the octadecanoic acid that the hexadecanoic acid that will be first 30% by weight percent content and weight percent content are 70% forms and the granular VYBAR103 produced by U.S. Petrolite company as the surface crystallization conditioning agent join in a stainless steel cask simultaneously, and wherein the adding proportion of VYBAR103 is 0.1% of fatty acid mixt gross weight; Then constantly stir and slow hexadecanoic acid, octadecanoic acid and the VYBAR103 in the heating stainless steel cask, stop heating when hexadecanoic acid, octadecanoic acid and VYBAR103 are fused into liquid mixture fully and make the temperature of this liquid mixture be raised to 120 ℃; Then pass through water tank preheating stainless steel wax machine to 35 ℃ with the hot water of 35 ℃, finally the liquid mixture of 120 ℃ is poured in the mould cylinder of stainless steel wax machine of 35 ℃, drain for carrying out cooling to the cold water that passes into 20 ℃ in water tank again after the hot water of heating, the cooling rear demoulding fully, obtain the uniform fatty acid candle of smooth surface.
The candle that the light face fatty acid candle that above examples of implementation obtain is material of main part with paraffin is compared, and the one, surface is Paint Gloss, the glossy aesthetic feeling that strengthened; The 2nd, harder at the envrionment temperature lower surface of transportation, storage and sales field, can softening transform; The 3rd, this fatty acid candle burning is bright especially clean smokeless.The American-European smog index measuring method regulation generally adopted is once measured three candles, average smog index≤1.0 per hour, single per hour smog index≤2.0 be qualified, and the present invention makes fatty acid candle can accomplish every per hour smog index≤0.1 by above-described embodiment.

Claims (4)

1. a method of making fatty acid candle, it is comprised of following steps:
1., under 20 ℃~30 ℃ of envrionment temperatures, the solid-state fatty acid mixt of particulate state that first will be comprised of hexadecanoic acid and octadecanoic acid and granular surface crystallization conditioning agent join in a stainless steel cask simultaneously, wherein, hexadecanoic acid accounts for 65~80% of fatty acid mixt weight, 20~35% of octadecanoic acid fatty acid mixt weight, described surface crystallization conditioning agent is the polyol mono fatty acid ester, the adding proportion of polyol mono fatty acid ester is 0.5~3% of fatty acid mixt gross weight, described polyol mono fatty acid ester is three polyglycerol list octadecane acid esters, six polyglycerol monostearate or polyethylene glycol mono stearate,
2., then constantly stir and slow hexadecanoic acid, octadecanoic acid and the surface crystallization conditioning agent in the heating stainless steel cask, stop heating when hexadecanoic acid, octadecanoic acid and surface crystallization conditioning agent are fused into liquid mixture fully and make the temperature of this liquid mixture be raised to 120 ℃;
3., by step, the liquid mixture of 120 ℃ in 2. is poured in plastics candle mould, naturally cooling, during the duricrust of 0.5~1 centimetre of thickness of the cooling formation of the liquid mixture shell in mould to be cast, knock openning open from the die casting mouth, add shift to an earlier date ready with the cast liquid mixture with the solid fragment of sample ingredient, the cooling rear demoulding fully, obtain a uniform fatty acid candle of smooth surface.
2. the method for making fatty acid candle according to claim 1, it is characterized in that: the weight percent that hexadecanoic acid accounts for fatty acid mixt is 80%, and the weight percent of the shared fatty acid mixt of octadecanoic acid is 20%.
3. the method for making fatty acid candle according to claim 1, it is characterized in that: the weight percent that hexadecanoic acid accounts for fatty acid mixt is 67%, and the weight percent of the shared fatty acid mixt of octadecanoic acid is 33%.
4. the method for making fatty acid candle according to claim 1, it is characterized in that: the weight percent that hexadecanoic acid accounts for fatty acid mixt is 65%, and the weight percent of the shared fatty acid mixt of octadecanoic acid is 35%.
CN201010520388.XA 2010-10-23 2010-10-23 Fatty acid candle and method for manufacturing same Active CN102061225B (en)

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CN103060103A (en) * 2011-10-18 2013-04-24 栾清杨 Making method of low-cost smokeless candle
BE1020324A3 (en) * 2011-11-07 2013-08-06 Chemie Comm V N CANDLE WASHING INCLUDING A POLYMER AND METHOD OF MAKING CANDLE WASH.
CN103146494B (en) * 2012-12-31 2019-03-08 青岛金王应用化学股份有限公司 A kind of Low-shrink crystalline effect wax
CN103146491B (en) * 2012-12-31 2019-01-01 青岛金王应用化学股份有限公司 A kind of manufacture craft of 100% soya wax candle

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