CN101935160B - Raw material wetting agent used in process of plate glass for display and preparation method - Google Patents
Raw material wetting agent used in process of plate glass for display and preparation method Download PDFInfo
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- CN101935160B CN101935160B CN2010102379546A CN201010237954A CN101935160B CN 101935160 B CN101935160 B CN 101935160B CN 2010102379546 A CN2010102379546 A CN 2010102379546A CN 201010237954 A CN201010237954 A CN 201010237954A CN 101935160 B CN101935160 B CN 101935160B
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- China
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- wetting agent
- mixture
- weight
- organic acid
- plate glass
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- 239000000080 wetting agent Substances 0.000 title claims abstract description 37
- 239000005357 flat glass Substances 0.000 title claims abstract description 16
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000002994 raw material Substances 0.000 title abstract description 8
- 238000000034 method Methods 0.000 title abstract description 7
- 239000000203 mixture Substances 0.000 claims abstract description 42
- 150000007524 organic acids Chemical class 0.000 claims abstract description 23
- 239000012535 impurity Substances 0.000 claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 24
- 238000004519 manufacturing process Methods 0.000 claims description 15
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- 230000018044 dehydration Effects 0.000 claims description 3
- 238000006297 dehydration reaction Methods 0.000 claims description 3
- 239000002244 precipitate Substances 0.000 claims description 3
- -1 stirred 1~2 minute Substances 0.000 claims description 3
- 239000011521 glass Substances 0.000 abstract description 9
- 238000002156 mixing Methods 0.000 abstract description 5
- 230000008901 benefit Effects 0.000 abstract description 3
- 230000002708 enhancing effect Effects 0.000 abstract 2
- 125000005481 linolenic acid group Chemical group 0.000 abstract 2
- BNRRFUKDMGDNNT-JQIJEIRASA-N (e)-16-methylheptadec-2-enoic acid Chemical compound CC(C)CCCCCCCCCCCC\C=C\C(O)=O BNRRFUKDMGDNNT-JQIJEIRASA-N 0.000 abstract 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 abstract 1
- 235000005985 organic acids Nutrition 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 description 16
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 230000003628 erosive effect Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000000889 atomisation Methods 0.000 description 2
- 238000010835 comparative analysis Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000005329 float glass Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 235000017550 sodium carbonate Nutrition 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 230000033116 oxidation-reduction process Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Glass Compositions (AREA)
Abstract
The invention provides a raw material wetting agent used in a process of plate glass for a display and a preparation method, solving the technical problem of the enhancing of the mixture uniformity in a glass raw material. The wetting agent is prepared by the step of mixing organic acids. The organic acid mixture comprises the following compositions in percentage by weight: 50-68 percent of Cl8H32O2, 20-37 percent of C18H34O2, 2-10 percent of C16H32O2, 1-7 percent of C18H30O2, 0.6-6 percent of C18H36O2, 0.1-1 percent of C20H40O2 and the balance of organic impurity, wherein C18H30O2+C18H36O2+C20H40O2=4-10 percent. The wetting agent greatly enhances the mixture uniformity and has the advantages of high adhesion, little scattering quantity and weak condensability, thereby enhancing the quality of mixture.
Description
Technical field
The invention belongs to glass manufacturing area, relate to the former batching wetting agent and the preparation method that use in a kind of plate glass for display manufacture craft, particularly can improve the wetting agent of batching uniformity coefficient.
Background technology
On chemical physical property, necessary uniformity is if mix inhomogeneous with admixtion for glass, then the more part burn-off rate of lyotrope such as soda ash is fast, the more part of refractory compound, fusing are just relatively more difficult, even can fusing time be prolonged residual unfused quartz particles.So just destroy the homogeneity of glass, and easily produced defectives such as calculus, striped, bubble, and the more part of lyotrope, when contacting with pool wall, easily erosion of refractory also causes glass inhomogeneous.Particularly PDP glass melting temperature is higher than about general float glass 100 degree, and this has more quickened the erosion process of melting furnaces.But because various grain size of raw material differ bigger, moisture is different with material property, wants to reach to mix, and minimizing is dispersed, and is very difficult thing.
The method that domestic general employing adds water increases the adhesivity between each raw material, reach the uniformity coefficient requirement of compound, winter is because temperature is low, adds that soda ash and the saltcake in the compound still exists with the form of crystal water behind the water, cause the compound inequality, also do not reach processing requirement even add hot water.Reduction along with the material temperature produces new layering in the raw material course of conveying simultaneously, mixes and expects behind the furnace hopper because temperature rising moisture loss produces new layering again.Compound needs big energy when advancing behind the kiln moisture evaporation, has increased energy consumption like this, because part moisture evaporates in advance, compound still produces the serious phenomenon of dispersing in kiln, cause shortcomings such as checker obstruction, the erosion of kiln body simultaneously.
Summary of the invention
The objective of the invention is to improve the inhomogeneity technical barrier of compound in the frit in order to solve, the former batching wetting agent and the preparation method that use in a kind of plate glass for display manufacture craft have been designed, add water blended method with adding in the preparing glass charge in the alternative prior art of wetting agent of the present invention, and then improve the compound uniformity coefficient, significantly improve melting efficiency.
The present invention for realizing the technical scheme that goal of the invention adopts is, the former batching wetting agent that uses in the plate glass for display manufacture craft, and being mixed by organic acid forms, and the weight percent of each component in the above-mentioned organic acid mixture is:
C
18H
32O
2 50-68％，
C
18H
34O
2 20-37％，
C
16H
32O
2 2-10％，
C
18H
30O
2， 1-7％，
C
18H
36O
2 0.6-6％，
C
20H
40O
2 0.1-1％。
The invention still further relates to a kind of preparation method of wetting agent, described preparation method is: above-mentioned organic mixture is placed the container that fills water, stirred 1～2 minute, precipitate 1～2 minute, divide impurity dried up and that be dissolved in the water, the mixed organic acid weight after dehydration reaches 1.05～1.1 times of original mixture weight.
The present invention be directed to domestic glasswork raw material and mix the long-term a kind of alternative method that adopts water feeding method.Organic mixture sprays into mixing machine by hydraulic pressure heating atomization Weighing system, mixes 3-6 minute, can improve the compound uniformity coefficient greatly, has the adhesivity height, and the amount of dispersing is little, and the advantage that condensability is little has improved the quality of compound; Significantly improve melting efficiency, cut down the consumption of energy, increase output, reduce production costs, prolong melting furnaces work-ing life, can extensively promote, can produce considerable green economy benefit at glass industry.
Embodiment
The former batching wetting agent that uses in a kind of plate glass for display manufacture craft, being mixed by organic acid forms, and the weight percent of each component in the above-mentioned organic acid mixture is:
C
18H
32O
2 50-68％，
C
18H
34O
2 20-37％，
C
16H
32O
2 2-10％，
C
18H
30O
2， 1-7％，
C
18H
36O
2 0.6-6％，
C
20H
40O
2 0.1-1％。
C in the weight percent of above-mentioned organic acid component of mixture
18H
30O
2+ C
18H
36O
2+ C
20H
40O
2Be 4-10%.
In the weight percent of above-mentioned organic acid component of mixture: (C
18H
30O
2+ C
18H
36O
2+ C
20H
40O
2): C
16H
32O
2Be (8-15): 10.
In the weight percent of above-mentioned organic acid component of mixture: (0.3C
18H
30O
2+ 0.7C
18H
36O
2+ 0.7C
20H
40O
2): C
16H
32O
2Be (3-9): 10.
In the above-mentioned organic acid mixture: contained C
18H
30O
2Weight percent be 1-5%, C
18H
36O
2Weight percent be 3-5%, and C
18H
30O
2With C
18H
36O
2The weight percent of sum is 4-9%.
In described organic acid component of mixture, will account for the C of the 0.5-1% weight of mixture total weight
18H
32O
2Replace with the C of the 0.5-1% weight that accounts for mixture total weight
27H
46O.
In described organic acid component of mixture, will account for the C of the 0.6-0.8% weight of mixture total weight
18H
32O
2Replace with the C of the 0.6-0.8% weight that accounts for mixture total weight
27H
46O.
The preparation method of the former batching wetting agent that uses in a kind of plate glass for display manufacture craft, the mixture that said wetting agent disposes according to above-mentioned weight percent adds water and makes, described organic mixture is placed the container that fills water, stirred 1～2 minute, precipitate 1～2 minute, divide impurity dried up and that be dissolved in the water, the mixed organic acid weight after dehydration reaches 1.05～1.1 times of original mixture weight.
The temperature of above-mentioned water is 30～50 ℃.
Novel wetting agent experiment comparative analysis
(1) the physical and chemical parameter analysis of wetting agent of the present invention and water contrast
Physicochemical constant: water wetting agent
Relative density (d20 ℃ 4 ℃) 1 0.9150-0.9375
Viscosity (E020 ℃) about 1.0 about 8.5
Zero pour (℃) 0-18～-15
From above data contrast as can be seen, the viscosity of wetting agent of the present invention is 8.5 times of water, about zero pour is spent than water low 17, can increase the compound adhesivity so greatly and reduce condensability, significantly reduce compound layering and dispersing in transportation, improved the homogeneity and the stability of compound.
(2) composition and pyrolytic decomposition comparative analysis
Water: composition H
2O, high temperature becomes gaseous volatilization, wherein carbon containing reducer not.
Wetting agent: main component is C
16H
32O
2, C
18H
34O
2, C
18H
32O
2
Pyrolytic decomposition, chemical equation is as follows:
C
16H
32O
2+23O
2＝16CO
2+16H
2O
2C
18H
34O
2+51O
2＝36CO
2+34H
2O
C
18H
32O
2+25O
2＝18CO
2+16H
2O
From composition, wetting agent of the present invention does not contain any detrimental impurity, also can be used as carbon dust use in the reductive agent instead of part frit.The decomposition temperature that can reduce saltcake improves melting rate.
Now enumerate an embodiment, seven groups of embodiment by a cover hydraulic pressure heating atomization Weighing system, guarantee that pressure is more than 0.5 kilogram by forming wetting agent shown in the table 1, to the needs of carbon, calculate the wetting agent operating weight according to oxidation-reduction quality in the material side and saltcake consumption.Realize the automatization use of lubricant by the admixtion robot control system(RCS).And the glass compound character of working good detected.
Embodiment is at the ultra-thin float glass line of certain 180t/d, use same S-1125 mixing machine, divide and respectively selected a period in 3 days, water and wetting agent are respectively done once experiment contrast respectively, and mixing time 3 minutes is wherein done and mixed 30 seconds, wet mixing 2 minutes and 30 seconds, add water 2%, or add wetting agent 1%, carry moisture 2% in the compound.
Table 1:
From the simultaneous test data, make water obvious demixing phenomenon be arranged in course of conveying as wetting agent, use the compound uniformity coefficient of wetting agent of the present invention higher, be difficult for layering.And obviously reduce by observing to disperse with raw material in the wetting agent kiln of the present invention, flame is limpid, and the kiln hood dust obviously reduces, the fusing amount has had raising greatly, stockpile shortens about 20cm, and fuel consumption reduces about 1% simultaneously, can create considerable economic to enterprise.
Claims (9)
1. the former batching wetting agent that uses in the plate glass for display manufacture craft, being mixed by organic acid forms, and it is characterized in that: the weight percent of each component in the described organic acid mixture is:
C
18H
32O
2 50-68％，
C
18H
34O
2 20-37％，
C
16H
32O
2 2-10％，
C
18H
30O
2， 1-7％，
C
18H
36O
2 0.6-6％，
C
20H
40O
2 0.1-1％。
2. the former batching wetting agent that uses in the plate glass for display manufacture craft according to claim 1 is characterized in that: C in the weight percent of above-mentioned organic acid component of mixture
18H
30O
2+ C
18H
36O
2+ C
20H
40O
2Be 4-10%.
3. the former batching wetting agent that uses in the plate glass for display manufacture craft according to claim 1 is characterized in that: in the weight percent of above-mentioned organic acid component of mixture: (C
18H
30O
2+ C
18H
36O
2+ C
20H
40O
2): C
16H
32O
2Be (8-15): 10.
4. the former batching wetting agent that uses in the plate glass for display manufacture craft according to claim 1 is characterized in that: in the weight percent of above-mentioned organic acid component of mixture: (0.3C
18H
30O
2+ 0.7C
18H
36O
2+ 0.7C
20H
40O
2): C
16H
32O
2Be (3-9): 10.
5. the former batching wetting agent that uses in the plate glass for display manufacture craft according to claim 1 is characterized in that: in the above-mentioned organic acid mixture:
Contained C
18H
30O
2Weight percent be 1-5%, C
18H
36O
2Weight percent be 3-5%, and C
18H
30O
2With C
18H
36O
2The weight percent of sum is 4-9%.
6. the former batching wetting agent that uses in the plate glass for display manufacture craft according to claim 1 is characterized in that: the C that will account for the 0.5-1% weight of mixture total weight in described organic acid component of mixture
18H
32O
2Replace with the C of the 0.5-1% weight that accounts for mixture total weight
27H
46O.
7. the former batching wetting agent that uses in the plate glass for display manufacture craft according to claim 1 is characterized in that: the C that will account for the 0.6-0.8% weight of mixture total weight in described organic acid component of mixture
18H
32O2 replaces with the C of the 0.6-0.8% weight that accounts for mixture total weight
27H
46O.
8. the preparation method of the former batching wetting agent that uses in the plate glass for display manufacture craft, the mixture that said wetting agent disposes according to the weight percent described in the claim 1 adds water and makes, it is characterized in that: described organic mixture is placed the container that fills water, stirred 1～2 minute, precipitate 1～2 minute, divide impurity dried up and that be dissolved in the water, the mixed organic acid weight after dehydration reaches 1.05～1.1 times of original mixture weight.
9. the preparation method of wetting agent according to claim 8, it is characterized in that: the temperature of described water is 30～50 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102379546A CN101935160B (en) | 2010-07-28 | 2010-07-28 | Raw material wetting agent used in process of plate glass for display and preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102379546A CN101935160B (en) | 2010-07-28 | 2010-07-28 | Raw material wetting agent used in process of plate glass for display and preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101935160A CN101935160A (en) | 2011-01-05 |
| CN101935160B true CN101935160B (en) | 2011-11-30 |
Family
ID=43388765
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010102379546A Active CN101935160B (en) | 2010-07-28 | 2010-07-28 | Raw material wetting agent used in process of plate glass for display and preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101935160B (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1690004A (en) * | 2004-04-20 | 2005-11-02 | 陈松洲 | Method for treating glass surface before transfer printing of glass product |
| CN101681824A (en) * | 2007-05-18 | 2010-03-24 | 三菱化学株式会社 | Substrate cleaning solution for semiconductor device and method for manufacturing semiconductor device |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3983019B2 (en) * | 2001-08-24 | 2007-09-26 | シャープ株式会社 | Manufacturing method of substrate having embedded structure and manufacturing method of display device |
-
2010
- 2010-07-28 CN CN2010102379546A patent/CN101935160B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1690004A (en) * | 2004-04-20 | 2005-11-02 | 陈松洲 | Method for treating glass surface before transfer printing of glass product |
| CN101681824A (en) * | 2007-05-18 | 2010-03-24 | 三菱化学株式会社 | Substrate cleaning solution for semiconductor device and method for manufacturing semiconductor device |
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| Publication number | Publication date |
|---|---|
| CN101935160A (en) | 2011-01-05 |
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Assignee: Shijiazhuang Gemstone Electronic Glass Co.,Ltd. Assignor: TUNGHSU GROUP Co.,Ltd. Contract record no.: 2012110000115 Denomination of invention: Raw material wetting agent used in process of plate glass for display and preparation method Granted publication date: 20111130 License type: Exclusive License Open date: 20110105 Record date: 20120709 |
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| EM01 | Change of recordation of patent licensing contract |
Change date: 20140321 Contract record no.: 2012110000115 Assignee after: DONGXU OPTOELECTRONIC TECHNOLOGY Co.,Ltd. Assignee before: Shijiazhuang Gemstone Electronic Glass Co.,Ltd. |
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| LICC | Enforcement, change and cancellation of record of contracts on the licence for exploitation of a patent or utility model | ||
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Change date: 20140321 Contract record no.: 2012110000115 Assignee after: DONGXU OPTOELECTRONIC TECHNOLOGY Co.,Ltd. Assignee before: Shijiazhuang Gemstone Electronic Glass Co.,Ltd. |
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Effective date of registration: 20230105 Address after: 102200 201, floor 2, No. 2, yard 91, shashun Road, Changping District, Beijing Patentee after: Beijing Yuanda Xinda Technology Co.,Ltd. Address before: 050021 No. 94, Huitong Road, Hebei, Shijiazhuang Patentee before: TUNGHSU GROUP Co.,Ltd. |
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