CA2674246A1 - Oil sands treatment system and process - Google Patents
Oil sands treatment system and process Download PDFInfo
- Publication number
- CA2674246A1 CA2674246A1 CA 2674246 CA2674246A CA2674246A1 CA 2674246 A1 CA2674246 A1 CA 2674246A1 CA 2674246 CA2674246 CA 2674246 CA 2674246 A CA2674246 A CA 2674246A CA 2674246 A1 CA2674246 A1 CA 2674246A1
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- pulp mixture
- oil sands
- treatment
- operative
- reactor chamber
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/04—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by extraction
- C10G1/047—Hot water or cold water extraction processes
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Oil sands ore containing bitumen is treated in a reactor chamber by ultrasonic oscillations impact such that cavitation of ore molecules occurs. The disintegration of the pulsating bubbles in the cavitation results in the separation of the oil, water, sand and air fractions of the oil sands. The oil fraction may be continuously extracted for subsequent refining processes.
Description
OIL SANDS TREATMENT SYSTEM AND PROCESS
BACKGROUND OF THE INVENTION
This invention relates to a system and process for the treatment of oil sands for the recovery of their petroleum fraction or bitumen.
Crushed ore of oil sands consisting of bitumen and sand fractions is commonly treated through a water emulsifying process with warm or hot water followed by a vaporization process to extract their bitumen content which is subsequently refined to obtain various petroleum products. Such process is ineffective and costly to carry out due to the demand of a large amount of energy input in the process with a relatively low bitumen output. Chemical material such as sodium hydroxide also has been added into the warm or hot water treatment to increase the amount of bitumen extraction. The water as well as the chemical material discharged from such process are harmful to the natural environment, and the system occupies a large erection site.
A mechanical shearing method has also been employed to de-aerate the slurry of water and oil sands mixture for extracting the bitumen. The slurry is passed through a shearing impeller operated at various high speeds in a treatment tank. In such mechanical shearing process, sand and water settle to the bottom of the tank while the bitumen content is collected in the froth in the top portion of the tank. The process may be repeated in a plurality of tanks to remove further the water and sand contents. However, this method is also ineffective and costly to achieve and the removal process is not uniform and limited and it would rapidly reach a steady saturatedlevel with little increase in the bitumen extraction in the repeated process.
SUMMARY OF THE INVENTION
It is a principal object of the present invention to provide an oil sands treatment process -I-which is effective for separating the bitumen content from the sand of the oil sands ore.
It is an object of the present invention to subject the oil sands ore through highly intensive energy impact to produce cavitation for separating the bitumen content from the sand of the oil sands ore.
It is another object of the present invention to provide high intensity ultrasonic oscillation for creating advanced cavitations in the froth of the mixture of the oil sands ore with water so as to separate the bitumen from the sand.
It is yet another object of the present invention to provide a system which is relatively simple in construction and requires a relatively small site for its erection.
It is yet another object of the present invention to provide a process in which no harmful pollutants are discharged into the natural environment.
It is another object of the present invention to provide a process and system having a significant low power consumption and operating cost with high output efficiency.
The above objects of the present invention are achieved by the formation of cavitation in a pulp mixture of the oil sands ore and water by acoustic impact. The acoustic impact is provided by oscillating ultrasonic band waves which may be produced by means of resonant electromechanical transducers. Cavitation is the phenomenon of the formation of pulsating bubbles in a the oil sands and water mixture. These bubbles are filled with vapor, gas and a mixture of bitumen and other solid matters such as sand. The pulsating bubbles subsequently rupture under the acoustic impact; and with their disintegration, the vapor, gas, bitumen and the solid matters become separated from one another in an ultra dispersion, 5-10 microns, resulting in the extraction of the bitumen from the oil sands. The essential advantage of this method is the
BACKGROUND OF THE INVENTION
This invention relates to a system and process for the treatment of oil sands for the recovery of their petroleum fraction or bitumen.
Crushed ore of oil sands consisting of bitumen and sand fractions is commonly treated through a water emulsifying process with warm or hot water followed by a vaporization process to extract their bitumen content which is subsequently refined to obtain various petroleum products. Such process is ineffective and costly to carry out due to the demand of a large amount of energy input in the process with a relatively low bitumen output. Chemical material such as sodium hydroxide also has been added into the warm or hot water treatment to increase the amount of bitumen extraction. The water as well as the chemical material discharged from such process are harmful to the natural environment, and the system occupies a large erection site.
A mechanical shearing method has also been employed to de-aerate the slurry of water and oil sands mixture for extracting the bitumen. The slurry is passed through a shearing impeller operated at various high speeds in a treatment tank. In such mechanical shearing process, sand and water settle to the bottom of the tank while the bitumen content is collected in the froth in the top portion of the tank. The process may be repeated in a plurality of tanks to remove further the water and sand contents. However, this method is also ineffective and costly to achieve and the removal process is not uniform and limited and it would rapidly reach a steady saturatedlevel with little increase in the bitumen extraction in the repeated process.
SUMMARY OF THE INVENTION
It is a principal object of the present invention to provide an oil sands treatment process -I-which is effective for separating the bitumen content from the sand of the oil sands ore.
It is an object of the present invention to subject the oil sands ore through highly intensive energy impact to produce cavitation for separating the bitumen content from the sand of the oil sands ore.
It is another object of the present invention to provide high intensity ultrasonic oscillation for creating advanced cavitations in the froth of the mixture of the oil sands ore with water so as to separate the bitumen from the sand.
It is yet another object of the present invention to provide a system which is relatively simple in construction and requires a relatively small site for its erection.
It is yet another object of the present invention to provide a process in which no harmful pollutants are discharged into the natural environment.
It is another object of the present invention to provide a process and system having a significant low power consumption and operating cost with high output efficiency.
The above objects of the present invention are achieved by the formation of cavitation in a pulp mixture of the oil sands ore and water by acoustic impact. The acoustic impact is provided by oscillating ultrasonic band waves which may be produced by means of resonant electromechanical transducers. Cavitation is the phenomenon of the formation of pulsating bubbles in a the oil sands and water mixture. These bubbles are filled with vapor, gas and a mixture of bitumen and other solid matters such as sand. The pulsating bubbles subsequently rupture under the acoustic impact; and with their disintegration, the vapor, gas, bitumen and the solid matters become separated from one another in an ultra dispersion, 5-10 microns, resulting in the extraction of the bitumen from the oil sands. The essential advantage of this method is the
-2-relative simplicity in separating the components in the oil sands mixture without employing complex mechanical means.
BRIEF DESCRIPTION OF THE DRAWINGS
Other objects of this invention will appear in the following description and appended claims, reference being made to the accompanying drawings forming a part of the specification and illustrating an exemplary embodiment of the invention, in which Figure 1 is a schematic block diagram of the system according to the present invention.
Figure 2 is an isolated partially cut side elevation view of the ultrasonic transducer section of the reactor of the system of the present invention.
Figure 3 is a top elevation view of the ultrasonic transducer section of Figure 2.
Figure 4 is a sectional isolated side elevation view of the ultrasonic transducer section of Figure 2.
DESCRIPTION OF THE PREFERRED EMBODIMENT
As best shown in Figure 1, in the present invention, the oil sands ore is first crushed and deposited into a receiver bunker 1 for mixing with water to form a pulp mixture or sludge which is pumped into a reactor chamber 2 through an inlet port 3. The pulp mixture is sprayed into the reactor chamber 2 by a vortex nozzle so as to provide a uniform distribution and flow of the pulp mixture through the reactor chamber 2. In the mean time, ultrasound wave is generated in the reactor chamber 2 via two rows of transducers 4 by an ultrasound wave generator 5. These transducers may be magnetostrictive tranducers with in-phase excitation of active emitters of ultrasonic oscillations. One row of the transducers 4 produces an ultrasound oscillations of 18-22 KHz, while the other row of transducers 4 produces an ultrasonic oscillations of 5 to 9 KHz. The
BRIEF DESCRIPTION OF THE DRAWINGS
Other objects of this invention will appear in the following description and appended claims, reference being made to the accompanying drawings forming a part of the specification and illustrating an exemplary embodiment of the invention, in which Figure 1 is a schematic block diagram of the system according to the present invention.
Figure 2 is an isolated partially cut side elevation view of the ultrasonic transducer section of the reactor of the system of the present invention.
Figure 3 is a top elevation view of the ultrasonic transducer section of Figure 2.
Figure 4 is a sectional isolated side elevation view of the ultrasonic transducer section of Figure 2.
DESCRIPTION OF THE PREFERRED EMBODIMENT
As best shown in Figure 1, in the present invention, the oil sands ore is first crushed and deposited into a receiver bunker 1 for mixing with water to form a pulp mixture or sludge which is pumped into a reactor chamber 2 through an inlet port 3. The pulp mixture is sprayed into the reactor chamber 2 by a vortex nozzle so as to provide a uniform distribution and flow of the pulp mixture through the reactor chamber 2. In the mean time, ultrasound wave is generated in the reactor chamber 2 via two rows of transducers 4 by an ultrasound wave generator 5. These transducers may be magnetostrictive tranducers with in-phase excitation of active emitters of ultrasonic oscillations. One row of the transducers 4 produces an ultrasound oscillations of 18-22 KHz, while the other row of transducers 4 produces an ultrasonic oscillations of 5 to 9 KHz. The
-3-ultrasonic oscillations create a resonance concentrating zone in the space located between the two rows of transducers together with acoustic reflectors (not shown) in the path of the pulp mixture passing through the reactor chamber 2. The resonant ultrasonic oscillations exert an intense impact of an ultrasonic field energy density of more than 40 to 60 W/ cm2 on the pulp mixture molecules. Homogeneous exposure of the mixture molecules to the ultrasonic oscillations impact is enhanced by spreading the molecules between two mechanically operated screw blenders 6. As a result of the intensive ultrasonic oscillations impact upon the bitumen containing pulp mixture molecules, cavitations of the molecules occur. Through an actual duration of such a process, cavitational bubbles are formed within the viscous, liquid-dispersive medium of solid components, according to cavitational coefficient, under the implosions, which produces a maximum energy impact upon the material. The dimensions of the cavitational bubbles are from hundredth to thousandth of millimeter to few centimeters. High intensity treatment of the oil/sand fractions under the advanced cavitational process is only possible within a relatively thin fluid layer due to rising wave resistance of the gas/vapor mixture zone during such treatment and because of a strong tendency of ultrasonic wave attenuation. A spread zone of ultrasonic oscillations with a high energy component has been in practice limited to a few tens of millimeters. As ultrasonic, acoustic flows propagate within the viscous oil/sand mixture, they are intensely absorbed, which, in turn, imposes limitations onto a work zone of effective treatment in the reactor chamber. In order to expand the treatment work zone and to enhance the efficiency of the separating processes, it is necessary to utilize a scheme for a flow passage of input product, where the dispersive medium is passed and cycled through the active work zone of the reactor chamber several times. In the process, a peeling action occurs in the imbedded liquid /oil phase
-4-micro-clots from grains of sand and various solid admixture as well as the occurrence of their physical separation. The oil, water and air fractions of the molecules become separated from the solid fraction, namely sand, of the mixture molecule in the disintegration of the pulsating bubbles in the cavitation process. A high intensity impact of cavitation field can be obtained for the pulp mixture having a viscosity of not exceeding 200-500 CCT. For a pulp mixture having a higher viscosity, a preliminary thinning of the mixture may be necessary such as by thermally heating it to 40-70 C. The air fraction of the molecules is discharged from the reactor chamber 2 through an aerator 7 while the cavitated molecules are passed from the outlet port 8 through conducting pipe 9 to a series of separation towers 10. Two separation towers 10 are shown in Figure 1 for simplicity of illustration. The bitumen or oil fraction of the molecule flow from the separation towers 10 to a collection tank 11 for subsequent transportation and/or refining process into various petroleum products. The water and sand fall to the bottom portion of the separating towers 10 from which the water is retrieved to a water tank 12 while the sand and other solid fraction are discharged from the bottom of the separation towers 10 to a conveyor device 13 to be collected in a bin 14 for disposal.
The operation of the process of the present invention may be controlled by a central control unit 15.
It is to be understood that no additional water may be necessary to introduce into the oil sands ore deposited into the mixing tank since it may be inherently saturated with ground waters and thus possesses some degree of fluidity. Furthermore, the water extracted from the process may be recycled in the mixing tank for treatment of subsequent ore.
The simplicity of the system of the present invention offers significant savings in power
The operation of the process of the present invention may be controlled by a central control unit 15.
It is to be understood that no additional water may be necessary to introduce into the oil sands ore deposited into the mixing tank since it may be inherently saturated with ground waters and thus possesses some degree of fluidity. Furthermore, the water extracted from the process may be recycled in the mixing tank for treatment of subsequent ore.
The simplicity of the system of the present invention offers significant savings in power
-5-consumption and the reduction of cost of the bitumen recovery process, yet it produces no harmful pollutants into the natural environment. The water content can be recycled into the process. A high quality of bitumen may be continuously produced for subsequent refining process. The system may also be conveniently erected in a relatively small site.
Various modifications can be made without departing from the spirit of this invention or the scope of the appended claims. The embodiment of the invention set forth in this disclosure are given as examples and are in no way final or binding. In view of the above, it will be seen that several objects of the invention are achieved and other advantages are obtained. As many changes could be made in the above system and method without departing from the scope of the invention, it is intended that all matter contained in the above description shall be interpreted as illustrative and not in a limiting sense.
Various modifications can be made without departing from the spirit of this invention or the scope of the appended claims. The embodiment of the invention set forth in this disclosure are given as examples and are in no way final or binding. In view of the above, it will be seen that several objects of the invention are achieved and other advantages are obtained. As many changes could be made in the above system and method without departing from the scope of the invention, it is intended that all matter contained in the above description shall be interpreted as illustrative and not in a limiting sense.
-6-
Claims (12)
1. A method of treatment of oil sands ore comprising, mixing said oil sands ore in a crushed form with a predetermined amount of water to form a pulp mixture, injecting said pulp mixture into a reactor chamber, passing said pulp mixture in said reactor chamber between a resonant oscillation area located between at least two rows of ultrasonic oscillation generators, imposing a resonant wave of ultrasonic oscillations to said pulp mixture to cause cavitation to occur in said molecules of said pulp mixture, passing said pulp mixture following cavitation to a separation tower for water and sand fractions of said molecules of said pulp mixture to be separated from oil fraction of said pulp mixture, passing said oil fraction to a collection tank for further refining process, releasing said water fraction of said pulp mixture from a lower portion of said separation tower, and discharging said sand fraction of said pulp mixture from a bottom portion of said separation tower for disposal.
2. A method of treatment of oil sands ore according to Claim 1 including injecting said pulp mixture into said reaction chamber by a vortex nozzle.
3. A method of treatment of oil sands ore according to Claim 2 including for spreading said pulp mixture evenly within said resonant area of said reaction chamber and repeatedly passing said pulp mixture a plurality of times through said resonant oscillation area by mechanical blending means to ensure a homogeneous impact of said ultrasonic oscillations upon said molecules of said pulp mixture.
4. A method of treatment of oil sands ore according to Claim 3 wherein one row of said ultrasonic oscillators is a plurality of ultrasound transducers operative to produce ultrasound oscillations of 18-20 KHz, and a second row of said ultrasonic oscillators is a plurality of ultrasound transducers operative to produce ultrasound oscillations of 5 to 9 KHz.
5. A method of treatment of oil sands ore according to Claim 3 including discharging air fraction of said pulp mixture from said reactor chamber through an aerator.
6. A system of treatment of oil sands ore comprising, a receiver bunker operative for mixing said oil sands ore in a crushed state with a predetermined amount of water to form a pulp mixture, a reactor chamber having an inlet port connected to said receiver bunker and operative for receiving said pulp mixture injected therein, ultrasonic oscillations transducers located in an active zone in said reactor chamber and operative to produce a resonant ultrasonic oscillations to impact on molecules of said pulp mixture injected into said reactor chamber for causing cavitation to occur in said molecules of said pulp mixture, separation tower means connected to said reactor chamber and operative for separating oil fraction of said pulp mixture after having subjected to cavitation in said reactor chamber for separating oil, water and sand fractions of said pulp mixture.
7. A system of treatment of oil sands ore according to Claim 6 including a vortex jet located in said reactor chamber and operative for injecting said pulp mixture into said reactor chamber.
8. A system of treatment of oil sands ore according to Claim 7 including mechanically operative blending means in said reactor chamber operative for passing said pulp mixture a plurality of times repeatedly through said active zone of said reactor chamber.
9. A system of treatment of oil sands ore according to Claim 7 wherein said resonant ultrasonic oscillations imposes an intense impact of an ultrasonic field energy density of more than 40 to 60 W/cm2 on said pulp mixture.
10. A system of treatment of oil sands ore according to Claim 9 including a collection tank connected to said separation tower means and operative for receiving said oil fraction from said separation tower for subsequent refining process.
11. A system of treatment of oil sands ore according to Claim 10 including a water tank connected to a lower portion of said separation tower means and operative for receiving water fraction from said pulp mixture in said separation tower means.
12. A system of treatment of oil sands ore according to Claim 11 including a conveyer means connected to a bottom part of said separation tower means and operative for receiving and conveying sand and solid fractions of said pulp mixture from said separation tower means.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA2674246A CA2674246C (en) | 2009-07-29 | 2009-07-29 | Oil sands treatment system and process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA2674246A CA2674246C (en) | 2009-07-29 | 2009-07-29 | Oil sands treatment system and process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2674246A1 true CA2674246A1 (en) | 2011-01-29 |
| CA2674246C CA2674246C (en) | 2013-11-12 |
Family
ID=43514005
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2674246A Expired - Fee Related CA2674246C (en) | 2009-07-29 | 2009-07-29 | Oil sands treatment system and process |
Country Status (1)
| Country | Link |
|---|---|
| CA (1) | CA2674246C (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013172716A1 (en) * | 2012-05-16 | 2013-11-21 | Ennox Oil Solutions Inc. | Separating hydrocarbons and inorganic material |
| WO2014071495A1 (en) * | 2012-11-09 | 2014-05-15 | Lazarus Saidakovsky | Treatment process and apparatus for reducing high viscosity in petroleum products, derivatives, and hydrocarbon emulsions and the like |
| US9207019B2 (en) | 2011-04-15 | 2015-12-08 | Fort Hills Energy L.P. | Heat recovery for bitumen froth treatment plant integration with sealed closed-loop cooling circuit |
| WO2016064276A2 (en) | 2014-10-22 | 2016-04-28 | Ennox Technology As | Separation of hydrocarbons from inorganic material |
| US9546323B2 (en) | 2011-01-27 | 2017-01-17 | Fort Hills Energy L.P. | Process for integration of paraffinic froth treatment hub and a bitumen ore mining and extraction facility |
| US9587176B2 (en) | 2011-02-25 | 2017-03-07 | Fort Hills Energy L.P. | Process for treating high paraffin diluted bitumen |
| US9676684B2 (en) | 2011-03-01 | 2017-06-13 | Fort Hills Energy L.P. | Process and unit for solvent recovery from solvent diluted tailings derived from bitumen froth treatment |
| US9791170B2 (en) | 2011-03-22 | 2017-10-17 | Fort Hills Energy L.P. | Process for direct steam injection heating of oil sands slurry streams such as bitumen froth |
| US10041005B2 (en) | 2011-03-04 | 2018-08-07 | Fort Hills Energy L.P. | Process and system for solvent addition to bitumen froth |
| US10226717B2 (en) | 2011-04-28 | 2019-03-12 | Fort Hills Energy L.P. | Method of recovering solvent from tailings by flashing under choked flow conditions |
| US11261383B2 (en) | 2011-05-18 | 2022-03-01 | Fort Hills Energy L.P. | Enhanced temperature control of bitumen froth treatment process |
-
2009
- 2009-07-29 CA CA2674246A patent/CA2674246C/en not_active Expired - Fee Related
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9546323B2 (en) | 2011-01-27 | 2017-01-17 | Fort Hills Energy L.P. | Process for integration of paraffinic froth treatment hub and a bitumen ore mining and extraction facility |
| US10125325B2 (en) | 2011-02-25 | 2018-11-13 | Fort Hills Energy L.P. | Process for treating high paraffin diluted bitumen |
| US9587176B2 (en) | 2011-02-25 | 2017-03-07 | Fort Hills Energy L.P. | Process for treating high paraffin diluted bitumen |
| US9676684B2 (en) | 2011-03-01 | 2017-06-13 | Fort Hills Energy L.P. | Process and unit for solvent recovery from solvent diluted tailings derived from bitumen froth treatment |
| US10041005B2 (en) | 2011-03-04 | 2018-08-07 | Fort Hills Energy L.P. | Process and system for solvent addition to bitumen froth |
| US10988695B2 (en) | 2011-03-04 | 2021-04-27 | Fort Hills Energy L.P. | Process and system for solvent addition to bitumen froth |
| US9791170B2 (en) | 2011-03-22 | 2017-10-17 | Fort Hills Energy L.P. | Process for direct steam injection heating of oil sands slurry streams such as bitumen froth |
| US9207019B2 (en) | 2011-04-15 | 2015-12-08 | Fort Hills Energy L.P. | Heat recovery for bitumen froth treatment plant integration with sealed closed-loop cooling circuit |
| US10226717B2 (en) | 2011-04-28 | 2019-03-12 | Fort Hills Energy L.P. | Method of recovering solvent from tailings by flashing under choked flow conditions |
| US11261383B2 (en) | 2011-05-18 | 2022-03-01 | Fort Hills Energy L.P. | Enhanced temperature control of bitumen froth treatment process |
| WO2013172716A1 (en) * | 2012-05-16 | 2013-11-21 | Ennox Oil Solutions Inc. | Separating hydrocarbons and inorganic material |
| WO2014071495A1 (en) * | 2012-11-09 | 2014-05-15 | Lazarus Saidakovsky | Treatment process and apparatus for reducing high viscosity in petroleum products, derivatives, and hydrocarbon emulsions and the like |
| WO2016064276A2 (en) | 2014-10-22 | 2016-04-28 | Ennox Technology As | Separation of hydrocarbons from inorganic material |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2674246C (en) | 2013-11-12 |
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|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |
Effective date: 20220301 |
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| MKLA | Lapsed |
Effective date: 20200831 |