CA2057603C - Extruder for poorly miscible extrudates - Google Patents

Extruder for poorly miscible extrudates

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Publication number
CA2057603C
CA2057603C CA002057603A CA2057603A CA2057603C CA 2057603 C CA2057603 C CA 2057603C CA 002057603 A CA002057603 A CA 002057603A CA 2057603 A CA2057603 A CA 2057603A CA 2057603 C CA2057603 C CA 2057603C
Authority
CA
Canada
Prior art keywords
extruder
barrel
zone
screw
channels
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA002057603A
Other languages
French (fr)
Other versions
CA2057603A1 (en
Inventor
Gerd Capelle
Martin Preuss
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
KraussMaffei Extrusion GmbH
Original Assignee
Hermann Berstorff Maschinenbau GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE4039942A external-priority patent/DE4039942C1/de
Application filed by Hermann Berstorff Maschinenbau GmbH filed Critical Hermann Berstorff Maschinenbau GmbH
Publication of CA2057603A1 publication Critical patent/CA2057603A1/en
Application granted granted Critical
Publication of CA2057603C publication Critical patent/CA2057603C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/50Details of extruders
    • B29C48/68Barrels or cylinders
    • B29C48/685Barrels or cylinders characterised by their inner surfaces, e.g. having grooves, projections or threads
    • B29C48/687Barrels or cylinders characterised by their inner surfaces, e.g. having grooves, projections or threads having projections with a short length in the barrel direction, e.g. pins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/285Feeding the extrusion material to the extruder
    • B29C48/29Feeding the extrusion material to the extruder in liquid form
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/395Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/50Details of extruders
    • B29C48/505Screws
    • B29C48/56Screws having grooves or cavities other than the thread or the channel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/50Details of extruders
    • B29C48/505Screws
    • B29C48/63Screws having sections without mixing elements or threads, i.e. having cylinder shaped sections
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/50Details of extruders
    • B29C48/68Barrels or cylinders
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/50Details of extruders
    • B29C48/68Barrels or cylinders
    • B29C48/685Barrels or cylinders characterised by their inner surfaces, e.g. having grooves, projections or threads
    • B29C48/686Barrels or cylinders characterised by their inner surfaces, e.g. having grooves, projections or threads having grooves or cavities
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/92Measuring, controlling or regulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92009Measured parameter
    • B29C2948/92047Energy, power, electric current or voltage
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92009Measured parameter
    • B29C2948/92085Velocity
    • B29C2948/92095Angular velocity
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92009Measured parameter
    • B29C2948/92085Velocity
    • B29C2948/92104Flow or feed rate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92009Measured parameter
    • B29C2948/92209Temperature
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92009Measured parameter
    • B29C2948/92314Particular value claimed
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92323Location or phase of measurement
    • B29C2948/92485Start-up, shut-down or parameter setting phase; Emergency shut-down; Material change; Test or laboratory equipment or studies
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92504Controlled parameter
    • B29C2948/92514Pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92504Controlled parameter
    • B29C2948/92542Energy, power, electric current or voltage
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92504Controlled parameter
    • B29C2948/9258Velocity
    • B29C2948/9259Angular velocity
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92504Controlled parameter
    • B29C2948/9258Velocity
    • B29C2948/926Flow or feed rate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92504Controlled parameter
    • B29C2948/92704Temperature
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92819Location or phase of control
    • B29C2948/92857Extrusion unit
    • B29C2948/92876Feeding, melting, plasticising or pumping zones, e.g. the melt itself
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92819Location or phase of control
    • B29C2948/92857Extrusion unit
    • B29C2948/92876Feeding, melting, plasticising or pumping zones, e.g. the melt itself
    • B29C2948/92885Screw or gear
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92819Location or phase of control
    • B29C2948/92857Extrusion unit
    • B29C2948/92876Feeding, melting, plasticising or pumping zones, e.g. the melt itself
    • B29C2948/92895Barrel or housing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/0005Condition, form or state of moulded material or of the material to be shaped containing compounding ingredients

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)

Abstract

An extruder for poorly miscible extrudates is presented, in which the pin-lined barrel section and transfer mixing section, known per se and until now only used individually, are used together in an extruder. Restricting pins arranged in the transfer mixing section in the region of the greatest barrel channel volume permit universal use of the extruder with respect to the extrudate. The combination of the two mixing systems allows in a surprising way an increase in the material throughput of 60% to 100% with the mixing quality remain-ing the same and a halving of the drive torque. Due to a constant number of channels of the barrel channels and screw channels, the number of barrel flights and screw flights remains independent of the channel cross-sectional area of barrel and screw. A helical barrel groove in the feed zone of the extruder barrel addi-tionally improves the mixing quality of the extrudate and the output of the extruder.

Description

The invention relates to an extruder for the pocessing and production of rubber and thermoplastic mateials.
In the past, widespread use has been made of so-called pin-lined barrel extruders, such as are known from Canadian patent no. 1,106,316 issued on August 4, 1981. On extruders of this type, metal pins protrude radially through the extruder barrel into the processing space of the extruder, the extruder screw having interrupted screw flights in ths zone These extruders are distinguished by a very high output rate and good homogenizing effect on the material to be processed and, in addition, permit an increased - 2 - 205~603 material throughput per unit time at the same screw speed in comparison with conventional cold-feed extruders with a screw having a shear section. These advantages have resulted in pin-lined barrel extruders becoming the most frequently used extruders in the rubber industry in the last 15 years.

Independently of this, an extruder mixing section which has become known as the transfer mixing section (DE-A 1,142,839) has been developed. This mixing section essentially comprises the feature that both the extruder screw and the inner wall of the extruder barrel are provided with grooves and flights over a certain length, the channel depth of the extruder screw decreas-ing to zero and subsequently increasing again in the longitudinal direction of the extruder barrel to the same degree as the channel depth of the barrel grooves respec-tively increases and decreases again. Due to this design of extruder screw and barrel, a complete extrudate exchange between the screw grooves and the barrel grooves is possible, which causes a good mixing effect.
The transfer extruder was able to claim a certain share of the market over the pin-lined barrel extruder, in particular whenever the overall length of the extruder was to be kept small.
I n a d d i t i o n , i t i s t o p ro v i d e extruders with flow restricting components, by which the extrudate transport in the extruder can be variably controlled from the outside. According to this publication, an approximately cylind~ical component is A
arranged for this purpose on the screw shank of the extruder screw, which component rotates along with the screw and completely blocks the processing space down-stream. In the region of the cylindrical component, two restricting pins are led through the extruder barrel from outside radially into an axially directed overflow channel in each case, which is made in the inner wall of the extruder barrel.

With retracted restricting pins, part of the extrudate upstream of the cylindrical component can pass through these channels to the downstream extruder sect-ion. By moving the restricting pins into these overflow channels to different depths, this extrudate stream can be restricted.

In addition,~AnA~iAn Patent no. 1 106,316 ~i~çl~ a transfer extruder on which the number of flights in the barrel and on the screw in the transfer zone reduces as the cross-sectional area of the screw channels becomes greater, and increases as the cross-sectional area of the screw channels becomes smaller. In this case, screw channels of greater cross-sectional area have a greater width than screw channels of smaller cross-sectional area.
The tests carried out in the past on such mixing sections have indeed shown that comparatively good mixing qualities can be achieved with them, and that the mixing section is by all means self-cleaning. However, what was disadvantageous was that the design proposed there caused a relatively high manufacturing outlay, for which reason A

~ 4 ~ 2 0 S 7 603 the production costs were high.
Fi n a 1 1 y, it ifi known to provide the inner side of the extruder barrel of single-screw extruders with axial or helical barrel grooves in the feed zone. Such extruders are generally used for the extrusion of polymer materials of high melt viscosity, low thermal stability or low surface friction with 10respect to the metal surfaces of the extruder proces~ing space. Such an extruder allows a high output rate at low melt temperatures and high melt pressures even in the - case of those such extrudates which are difficult to process. In addition, due to the reduced shearing in the feed zone of the extruder, the extrudate can be plasti-cized gently and extruded surge-free.

Since, apart from improvements in details, the technology of mixing extruders has not changed in the last fifteen years, the invention was based on the ob~ect of presenting a mixing and homogenizing extruder which, in comparison with the known apparatuses, permits an increased output rate with reduced investment costs and at least equally good mixing effect, and allows a dis-tinctly shorter overall length and a broadening of the 30previous application areas of mixing and homogenizing extruders.
Finally, the plasticizing work which can be accomplished by this extruder should be freely ad~ustable in dependence on the properties of the extrudate.

20~7~03 According to the present invention there is provided an extruder for the processing and production of rubber and thermoplastic materials, comprising an extruder barrel having an inlet opening and an outlet opening as well as a drive for an extruder screw arranged rotatably about its longitudinal axis in the processing space of the barrel, wherein the extruder has two successively arranged mixing and homogenizing zones, wherein the one zone is designed as a pin-lined barrel zone with pins protruding radially into the processing space 10 of the barrel and interrupted screw flights in the region of the pins, wherein the other zone is designed as a transfer zone, in which the extruder screw has a constant reduction in its channel volume to zero from a feed zone to a discharge zone and then a channel volume increase up to a maximum value, and in which the extruder barrel has uninterrupted barrel channels, which increase their channel volume from zero to a maximum value from the feed zone to the discharge zone of the transfer section, to drop subsequently back to a channel ` volume of zero, and in which the barrel channels are disposed 20 approximately helically about an imaginary extruder longitudinal axis, wherein radially adjustable restricting pins are arranged in the region of the maximum channel volume of the barrel channels so as to protrude through the barrel and into the barrel channels as well as into the processing space, wherein the number of channels, and consequently the number of screw flights and barrel flights, is constant in the feed zone and in the discharge zone of the transfer zone independently of the barrel and screw channel cross-sectional areas, and wherein the barrel inner side is provided with a 30 helical groove in the feed section of the extruder.
According to the present invention, there is also provided an extruder for the processing and production of rubber and thermoplastics materials, comprising:
A

5a 2057603 - an extruder barrel having an inner surface and a longitudinal axis, an inlet opening in a feed zone, and an outlet opening, said inner surface of said barrel in said feed zone being formed with a helical groove;
- an extruder screw mounted for rotation about its longitudinal axis in said barrel, said screw being formed with screw flights having channels therebetween which define with said barrel a processing space, and means for driving said screw, and wherein - said extruder has successively arranged mixing and homogenizing zones, said mixing zone comprising a pin-lined barrel zone in which pins protrude radially into the processing space of the barrel, said screw flights being interrupted in the region of said pins to accommodate screw rotation.
- said homogenizing zone comprising a transfer section in which said extruder screw has a constant reduction in its channel volume to zero from a feed portion of said transfer section to a discharge portion of said transfer zone, 20 and then a channel volume increase up to a maximum value, and in which said extruder barrel has uninterrupted barrel channels which increase their channel volume from zero to a maximum value from said feed portion to said discharge portion of the transfer section, to drop subsequently back to a channel volume of zero, and in which the barrel channels are disposed approximately helically about the longitudinal axis of said extruder, radially adjustable restricting pins arranged in the region of the maximum channel volume of the barrel channels so as to protrude through the barrel and into 30 the barrel channels as well as into the processing space, and wherein the number of channels, and consequently the number of screw flights and barrel flights, is constant in the feed portion and in the discharge portion of the transfer section A

5b 2 0 5 7 6 o ~

independently of the barrel and screw channel cross-sectional areas.
Preferably, the pin-lined barrel zone is arranged upstream of the transfer zone and the extruder has upstream of the mixing and homogenizing zones a feed zone and downstream has a zone in which the extrudate can be extruded to the necessary die pressure.
Preferably, with an extruder length of screw diameters (D), the feed zone has a length 3 D, the pin-lined barrel zone has a length 1.5 to 2 D, the transfer zone has a length up to to 2.5 D and the pressure-increasing zone has a length about 3 D long.
One to five rows of pins may be arranged in the pin-lined barrel zone.
The transfer zone of the extruder may be designed in such a way that the angles between the flights of the extruder screw and the flights of the extruder barrel are 20 greater than or equal to 105 and do not form angles complementary to 90 The adjustable restricting pins may be arranged at the downstream end of the extruder.
The restricting pins can be moved by means of mechanically, pneumatically or hydraulically operable actuating mechanisms.
Preferably, the extruder screw has in the transfer zone flat and narrow grooves, which connect the screw channels on the feed side and on the discharge side to one another.
The groove may be made oppositely to the pitch in the feed zone of the extruder barrel of the extruder screw.
The groove may have a width and a depth which are greater than 0.3 cm, a groove width of 1 to 3 cm and a groove depth of 0.5 to 1.5 cm being preferred.
A

~- 5c 20~7603 In a preferred embodiment, the groove depth slowly decreases to zero in end zones, and the groove extends helically over a length of 1 to 3 screw diameters.
The extruder barrel may be temperature-controlled by means of temperature-controlled channels.
The extruder according to the present invention has considerable advantages over the mixing and homogenizing extruders of the prior art.
For instance, with an extruder having a pin-lined lo barrel zone and a transfer zone having additional pins, it could be found that, with the same mixing quality and the same screw speed, the drive power of the extruder could be reduced by up to 50% and the melt throughput increased by up to 60%
to 100%.
These excellent results bring about furthermore a 50% reduction in the drive torque, which results in a great reduction in the gear transmission costs in the production of the extruder. In addition, by combining the pin-lined barrel and transfer section technology, the component length of the 20 mixing zone necessary for the same mixing quality can be reduced by about 50% with respect to an extruder which operates only on the pin-lined barrel principle.
Due to the arrangement of radially adjustable restricting pins which protrude radially in the part of the transfer zone of the extruder barrel in which the barrel channels have approximately their greatest channel volume, the proposed extruder can be set for the processing of different rubber compounds. Consequently, A

- 6 _ 2~76~3 the plasticizing capacity or the frictional energy converted in the transfer section for the extrudate can be preselected as desired, and specifically for the particular compound, by the depth of penetration of the restricting pins into the barrel channels and into the processing space of the extruder. Consequently, along with the screw speed and the processing section temper-ature, recourse can be made to a further freely select-able process parameter in comparison with the previously known generic extruders.
The design of the extruder screw and of the barrel bush in the transfer zone also allows, inasmuch as the number of channels and consequently the number of flights is independent of the channel cross-sectional area, inexpensive manufacture while maintaining the self-cleaning capability and mixing quality of the extruder.
Finally, t h e u s e o f b a r r e 1 grooves in the feed zone of the extruder in combination with the pin-lined barrel ~ection and transfer section allows a further ~urprising improvement in the mixing quality and output rate of the extruder.
In particular in the case of rubber-based extrud-ates which are difficult to process, an extruder feed zone in which a helical groove was made in the extruder barrel inner wall, had its starting point below the feed-opening of the extruder and was formed downstream along a length of about 3 screw diameters proved to be particularly advantageous.
The groove had a maximum depth of about 1 cm and a constant width of 2.5 cm and ran slowly out at each of its ends to the barrel inner diameter. The pitch of the groove corresponded approximately to that of the extruder screw in the feed zone.
With a feed zone of such a design, the output of the extruder could be distinctly improved and the mixing quality of the extrudate increased still further. A
series of tests with an extruder of lesser groove depth (about 0.5 cm) showed clear deterioration~ both in the working characteristics and in the mixing quality. In addition, it was possible to verify that the same extruder with the described grooves in the feed zone and the described transfer section, but without the pin-lined barrel section arranged ahead of this transfer section, produced a distinctly poorer mixing quality. Special extrudates which can be mixed continuously only with difficulty, such as for instance rubber compounds for tank chain studs, could not be mixed satisfactorily with such an extruder. This makes it clear that the combin-ation of pin-lined barrel section and transfer section is necessary for the desired mixing result in the case of such extrudates. The helical groove improves the mixing quality and the output of the extruder still further, however.
The invention can be explained with reference to illustrative embodiments and with the aid of the drawing, in which:
Fig. 1 shows a longitudinal section through a single-screw extruder without restricting pins in the ` - 8 - 2057603 transfer section, Fig. 2 shows a longitudinal section through a single-screw extruder with restricting pins in the transfer section, Figs.3a-c show the graphical representation of test results with an extruder of the proposed design in comparison with the conventional pin-lined extruder, Fig. 4 shows a diagrammatical side view of a transfer screw section, Fig. 5 shows a diagrammatical side view of a cut-open transfer bush section, Fig. 6 shows a developed view of the bush section according to Fig. 5, Fig. 7 shows a longitudinal section through the extru-der barrel in the region of the feed zone.
Figure 1 represents a diagrammatical longitudinal section through a single-screw extruder 1. Arranged inside the extruder barrel 2 is an extruder screw 6, which can be driven about its longitudinal axis by a drive unit 5. The barrel 2 has in the region of its upstream end a feed opening 3 for the material to be extruded, which leaves the extruder ready-mixed and homogenized through the outlet opening 4.
The extruder screw 6 has in the feed zone 9 a screw geometry which is suitable for drawing the material fed through the feed opening 3 into the extruder and plasticizing it in a way known per se.
Provided downstream of this feed zone is a pin-lined barrel zone 7, in which two rows of pins 11 protrude radially through the extruder barrel 2, in the direction of the screw axis, into the processing space 14 of the extruder. In.this zone 7, the screw flights 12 are interrupted in a known way in the plane of the pins in order to avoid collision with the pins 11.
Arranged downstream of the pin-lined barrel zone 7 is a transfer zone 8, in which, in this illustrative embodiment, the angles between the flights 18 of the extruder screw 6 and the flights 13 of the extruder barrel 2 are greater than or equal to 105 and, with respect to one another, do not form angles complementary to 90.
The transfer zone 8 can be divided into a feed zone and a discharge zone, the two zones being separated from each other by the barrel channel of the greatest channel depth.
In this transfer zone 8 of the extruder, the number of channels is constant in the feed zone and discharge zone, as a result of which the number of flights in the feed zone or discharge zone i8 independent of the channel cross-section of the barrel channels 16 and screw channels 15.
- The last processing section of the extruder screw 6 is formed by the pressure increasing zone 10, in which the screw geometry is chosen such that the melt pressure can be raised to the necessary die pressure in a known way.
Apart from this illustrative embodiment, other - lo- 2057603 possible ways of realizing this pin transfer extruder are also conceivable. For example, the transfer zone 8 could also be arranged upstream of the pin-lined barrel zone 7, although the variant presented above yields the better mixing and homogenizing results. In addition, it should be mentioned here that the pin-lined barrel zone also fulfils its mixing and homogenizing function if it has more than two rows of pins. As far as the ratio between costs and mixing quality is concerned, the pin-lined barrel zone is best equipped with one to five rows of pins.
The preferred length of the individual extruder zones with an extruder length of 10 screw diameters (D) is about 3 D for the feed zone, 1.5 to 10 D, preferably 1.5 to 2 D, for the pin-lined barrel zone, 2 to 2.5 D for the transfer zone and about 3 D for the pressure build-up zone.
Independently of these specifications, however, additional processing zone~ can also be arranged, accord-ing to requirements, ahead of, after or between the pin-lined barrel zone and transfer zone, such as for example venting or kneading zones.
In Figure 2, a pin transfer extruder 1, with restricting pins 11 in the transfer component is re-presented. Here too, the feed zone 9 of this extruder corresponds to the usual cold-feed extruder and ha~ a ratio of screw length (D) to screw diameter of three.
Arranged after the feed zone 9 is an extruder ~ection of an overall length of 6 D, in which the pin-lined barrel zone 7 having two successively arranged planes of pins with extruder pins 11 is located. Provided downstream of the pin-lined barrel zone 7 is the transfer zone 8, of about 2 D, and the pressure build-up zone 9, of about 1.5 D in length.
The temperature control of the extruder barrel 2 is performed in a known way by temperature control bores 19 in the barrel wall 2. In this illustrative embodiment, the transfer section of the extruder barrel is arrested in the barrel 2 as barrel bush 20.
The pitch of the channels of extruder screw and transfer section bush are chosen such that the flights between the screw and the bush form an angle equal to or greater than 105. An advantageous result of this is that, on passing this transfer section, by virtue of the consequent great number of points of intersection between screw flights and bush flights per screw revolution, the extrudate is sub~ected to an intensive shearing process.
In contrast to the screw channels, the bush channels are not interrupted in the transfer section.
Rather, they wind continuously and constantly from the feed zone of the transfer section to its discharge zone in approximately increasing or decreasing spiral form about the imaginary longitudinal axis of the extruder.
In the first third of the transfer section, the screw core diameter increases from the max. channel depth to the outside diameter, i.e. the channel volume of the screw 6 drops from the maximum value in the feed zone to zero. The channel volumes of the bush 20 exhibit the converse tendency. Consequently, the passage volume effectively available for the extrudate is kept constant in the axial and radial directions of transport. Owing to these conditions, a one hundred percent extrudate ex-change inevitably takes place between screw 6 and barrel bush 20.
In the case of the about 1.4 D long outlet zone of the transfer section according to Figure 2, the channel volume of the screw 6 increases continuously and, in the case of the bush 20, it decreases continuously, the overall channel volume of screw and bush available for the extrudate again being kept constant.
In the case of this illustrative embodiment as well, the number of channels in the feed zone and in the discharge zone of the transfer zone 8 is constant, as a result of which the number of screw and barrel bush flights is independent of the screw and barrel channel cross-sectional areas.
Extensive investigations had the result that, in particular in the processing of high-viscosity natural rubber compounds, the preplasticizing of the extruder in the pin zone at low shear rates before the intensive plasticizing work in the transfer section has the effect both of increasing output and of positively influencing the surging behavior of the machine.
Along with the screw speed and the processing section temperatures, the machine has a further process parameter which is freely preselectable and broadens the universality of the machine with regard to the _ - 13 _ 2057603 process-ability of a wide range of different rubber compounds.
At the end of the first third of the transfer zone 8 there is in this embodiment a restricting element, which has pins 17 distributed symmetrically around the circumference of the transfer component, which pins can enter radially into the uninterrupted channels of the transfer section bush 20 and can reduce the channel volume of the bush 20 in thi~ zone from the maximum value to zero.
With these restricting pins 17, which are ad~ust-ed from outside either manually or hydraulically, the plasticizing capacity or the frictional energy converted in the transfer section for the extrudate can be preset as desired.
These restricting pins 17 can be accredited, inter alia, with the success for the first time of using the pin transfer extruder to process rubber compound grades which previously could not be processed with adequate homogeneity by cold-feed extrusion, not even by the use of specially optimized pin-lined barrel extruder~. The grades concerned are grade~ of natural rubber, for example for the production of tank chain studs, as well as tread rubber compounds with the 8ame base polymer for truck and EM tires.
If the test results achieved thus far with an extruder of type GE 150 STx9D are summarized, it may be stated that, in comparison with the pin-lined barrel extruder, increases in output rate of 25% to 50% can be achieved in the case of low-viscosity synthetic rubber compounds up to viscosities of 55 to 60 ML 1 + 4 (100C), with a reduction in the specific energy of up to 20%.
In the case of high-viscosity natural rubber grades which are difficult to process, between 90 and 120 ML 1 + 4 (100C), the advantages are even more relevant, since, as has been found, the limit of extrudate homogen-eity on the pin-lined barrel extruder is already reached at an output of about 800 - 1000 kg/h and, consequently, in individual cases doublings of output on the pin transfer extruder appear possible.
Figures 3 a-c show in graphical representation test results which were achieved with an extruder of the prior art (broken curves) and a laboratory transfer pin extruder (solid curves) of comparable size. A natural rubber compound NR 90-95 ML 1 + 4 (100C), which is known to have high viscosity and to be particularly difficult to process, was used as extrudate. In all three re-presentations, the speed of 25 revolutions per minute, up to which the conventional extruder was able to process such a rubber compound with acceptable quality, has been marked by a vertical line with shading.
In Figure 3a, the rubber output is plotted as a function of the screw speed, whereas Figure 3b represents the melt temperature and Figure 3c represents the spec-ific energy requirement per kg of extrudate, in each case as a function of the screw speed. Taken together, these three diagrams show that, with the extruder concept proposed here, a high extrudate output with excellent mixing and homogenizing effect is possible at an accept-able extrudate temperature and with considerably reduced use of energy.
Added to this was the fact that problems of product poroæity in the profile, which on the pin-lined barrel extruder occurred already in the lower output range, were not encountered at all on the pin transfer extruder.
In Fig. 4, the extruder screw 6 is represented in the transfer zone 8 in an illustrative embodiment. The increase and decrease of the screw channel cross-section-al areas in the feed zone and discharge zone, known in principle, is brought about here only by the conical variation of the core cross-section, that is the channel depth, of the screw. Although the number of channels in the feed zone differs to that in the discharge zone, it is constant in the respective zone. This has the con-sequence that the number of flights is independent of the channel cross-sectional area 22.
Fig. 4 also reveals in a further embodiment that the transfer screw has in the region of maximum extrudate transfer to the barrel channels, that is approximately in the region of the restricting pins 17, grooves 23 in the screw core. Although these y ooves 23 connect the screw channels in the feed zone and in the discharge zone to one another, they do not allow any material transport through them, owing to their small depth of about 1 mm and their small width of about 10 mm. Rather, with their help the ~ing efficiency of the transfer zone can be improved, even in the case of difficult extrudates. This take~ place essentially by virtue of the fact that additional shearing edges are made available by these grooves.
In Fig. S, a diagrammatic longitudinal section through a transfer barrel bush 20, interacting with the transfer screw according to Fig. 4, is represented. Here too it becomes clear that the number of barrel channels is constant in each case in the feed zone and in the discharge zone, so that the number of barrel flights remains independent of the barrel channel cross-section.
Due to this design, on the one hand excellent mixing quality with a very good self-cleaning effect is ensured, while it becomes clear particularly in conjunc-tion with the developed view of the bush component according to Fig. 5 and Fig. 6 that the manufacturing outlay for barrel (and screw) channels of the same width is reduced considerably.
In addition, it should be pointed out that the pin-lined barrel extruder proposed can be used with or without restricting pins in the transfer section, although restricting pins should not be dispensed with for the optimal type of design. Finally, by their positioning, the extruder can be adjusted to a very wide variety of rubber compounds and their processing para-meters and consequently can be used universally by the user. In a less than optimal embodiment, the adjustable restricting pins may also be arranged at the downstream end of the extruder, for instance at the end of the _ - 17 _ 2057603 pressure build-up zone 10.
Finally, in Fig. 7 a longitudinal section through the extruder barrel 2 with a barrel groove 24 in the feed zone 8 is represented. In this illustrative embodiment, the helical barrel groove 24 has a depth of about 1 cm and a width of about 2.5 cm, although other groove depths and widths are also conceivable. However, the groove depth should not be chosen to be greater than the groove width and groove depth and groove width should not be less than 0.3 cm. The pitch of the groove 24 corresponds approximately to the pitch of the extruder screw in this region and extends over a length of about 3 to 5 screw diameters. At it~ ends, the depth of the groove 24 decreases slowly, until finally the barrel inner wall is formed without grooves. In a preferred embodiment, the groove 24 spirals oppositely to the screw pitch (Fig. 2).
Due to the use of such a groove in the feed zone 9 of the extruder barrel 2, an increased barrel wall area is available to the extrudate to be plasticized and to be mixed, as a result of which, due to the thereby increased adhering effect, the feed performance and consequently the surging performance of the extruder are improved. In addition, an increased heat transfer area can be made available by the groove walls, this largely preventing undesired preplasticizing in the feed zone of the extruder, in particular in the case of a cooled extruder barrel (see cooling channel 19 in Fig. 7).

Claims (15)

The embodiments of the invention in which an exclusive property or privilege is claimed are defined as follows:
1. An extruder for the processing and production of rubber and thermoplastic materials, comprising an extruder barrel having an inlet opening and an outlet opening as well as a drive for an extruder screw arranged rotatably about its longitudinal axis in the processing space of the barrel, wherein the extruder has two successively arranged mixing and homogenizing zones, wherein the one zone is designed as a pin-lined barrel zone with pins protruding radially into the processing space of the barrel and interrupted screw flights in the region of the pins, wherein the other zone is designed as a transfer zone, in which the extruder screw has a constant reduction in its channel volume to zero from a feed zone to a discharge zone and then a channel volume increase up to a maximum value, and in which the extruder barrel has uninterrupted barrel channels, which increase their channel volume from zero to a maximum value from the feed zone to the discharge zone of the transfer section, to drop subsequently back to a channel volume of zero, and in which the barrel channels are disposed approximately helically about an imaginary extruder longitudinal axis, wherein radially adjustable restricting pins are arranged in the region of the maximum channel volume of the barrel channels so as to protrude through the barrel and into the barrel channels as well as into the processing space, wherein the number of channels, and consequently the number of screw flights and barrel flights, is constant in the feed zone and in the discharge zone of the transfer zone independently of the barrel and screw channel cross-sectional areas, and wherein the barrel inner side is provided with a helical groove in the feed section of the extruder.
2. The extruder as claimed in claim 1, wherein the pin-lined barrel zone is arranged upstream of the transfer zone.
3. The extruder as claimed in claim 1, wherein the extruder has upstream of the mixing and homogenizing zones a feed zone and downstream has a zone in which the extrudate can be extruded to the necessary die pressure.
4. The extruder as claimed in claim 3, wherein, with an extruder length of screw diameters (D), the feed zone has a length 3 D, the pin-lined barrel zone has a length 1.5 to 2 D, the transfer zone has a length up to to 2.5 D and the pressure-increasing zone has a length about 3 D long.
5. The extruder as claimed in claim 1, 2, 3 or 4, wherein one to five rows of pins are arranged in the pin-lined barrel zone.
6. The extruder as claimed in claim 1, 2, 3 or 4, wherein the transfer zone of the extruder is designed in such a way that the angles between the flights of the extruder screw and the flights of the extruder barrel are greater than or equal to 105 and do not form angles complementary to 90.
7. The extruder as claimed in claim 1, 2, 3 or 4, wherein the adjustable restricting pins are arranged at the downstream end of the extruder.
8. The extruder as claimed in claim 1, wherein the restricting pins can be moved by means of mechanically, pneumatically or hydraulically operable actuating mechanisms.
9. The extruder as claimed in claim 1, 2, 3 or 4, wherein the extruder screw has in the transfer zone flat and narrow grooves, which connect the screw channels on the feed side and on the discharge side to one another.
10. The extruderas claimed in claim 1, 2, 3 or 4, wherein the groove is made oppositely to the pitch in the feed zone of the extruder barrel of the extruder screw.
11. The extruder as claimed in claim 10, wherein the groove has a width and a depth which are greater than 0.3 cm.
12. The extruder as claimed in claim 11, wherein the groove depth slowly decreases to zero in end zones, and wherein the groove extends helically over a length of 1 to 3 screw diameters.
13. The extruder as claimed in claim 11 or 12, wherein the extruder barrel is temperature-controlled by means of temperature-controlled channels.
14. The extruder as claimed in claim 10, wherein the groove has a width of 1 to 3 cm and a depth of 0.5 to 1.5 cm.
15. An extruder for the processing and production of rubber and thermoplastics materials, comprising:
- an extruder barrel having an inner surface and a longitudinal axis, an inlet opening in a feed zone, and an outlet opening, said inner surface of said barrel in said feed zone being formed with a helical groove;
- an extruder screw mounted for rotation about its longitudinal axis in said barrel, said screw being formed with screw flights having channels therebetween which define with said barrel a processing space, and means for driving said screw, and wherein:
- said extruder has successively arranged mixing and homogenizing zones, said mixing zone comprising a pin-lined barrel zone in which pins protrude radially into the processing space of the barrel, said screw flights being interrupted in the region of said pins to accommodate screw rotation.
- said homogenizing zone comprising a transfer section in which said extruder screw has a constant reduction in its channel volume to zero from a feed portion of said transfer section to a discharge portion of said transfer zone, and then a channel volume increase up to a maximum value, and in which said extruder barrel has uninterrupted barrel channels which increase their channel volume from zero to a maximum value from said feed portion to said discharge portion of the transfer section, to drop subsequently back to a channel volume of zero, and in which the barrel channels are disposed approximately helically about the longitudinal axis of said extruder, radially adjustable restricting pins arranged in the region of the maximum channel volume of the barrel channels so as to protrude through the barrel and into the barrel channels as well as into the processing space, and wherein the number of channels, and consequently the number of screw flights and barrel flights, is constant in the feed portion and in the discharge portion of the transfer section independently of the barrel and screw channel cross-sectional areas.
CA002057603A 1990-12-14 1991-12-13 Extruder for poorly miscible extrudates Expired - Fee Related CA2057603C (en)

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
DEP4039942.7-16 1990-12-14
DE4039942A DE4039942C1 (en) 1990-12-14 1990-12-14
DE07/693,237 1991-04-29
US07/693,224 US5141426A (en) 1990-12-14 1991-04-29 Degassing extruder
US07/693,237 US5147198A (en) 1990-12-14 1991-04-29 High performance extruder with a constant number of threads in the inlet and outlet regions of a transfer shearing section
DE07/693,221 1991-04-29
US07/693,221 US5145352A (en) 1990-12-14 1991-04-29 Pin transfer extruder
DE07/693,224 1991-04-29

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CA2057603C true CA2057603C (en) 1996-09-24

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DE102009040047A1 (en) * 2009-09-04 2011-03-17 Bayer Materialscience Ag Process for incorporating solids into polymers
CN102114699B (en) * 2011-01-24 2013-06-05 无锡市江南橡塑机械有限公司 Mixed pin barrel cold feeding extruder
JP2014512994A (en) 2011-05-13 2014-05-29 エヌエフエム ウェルディング エンジニーアズ,インコーポレイテッド Improved dewatering machine and dewatering method
EP3053725A1 (en) * 2015-02-06 2016-08-10 LANXESS Deutschland GmbH Plug screw
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DE102019119533B3 (en) * 2019-07-18 2020-09-24 Gneuss Gmbh Extruder for the viscosity-increasing processing of meltable polymers
CN113752520B (en) * 2021-09-01 2023-04-14 青岛科技大学 Screw rod

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JPH0639901A (en) 1994-02-15
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ATE108364T1 (en) 1994-07-15
EP0490361B1 (en) 1994-07-13
CA2057603A1 (en) 1992-06-15
CN1062492A (en) 1992-07-08
CN1035547C (en) 1997-08-06

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