CA1315034C - Thermoplastic sheet material having improved tape adhesion - Google Patents
Thermoplastic sheet material having improved tape adhesionInfo
- Publication number
- CA1315034C CA1315034C CA000560724A CA560724A CA1315034C CA 1315034 C CA1315034 C CA 1315034C CA 000560724 A CA000560724 A CA 000560724A CA 560724 A CA560724 A CA 560724A CA 1315034 C CA1315034 C CA 1315034C
- Authority
- CA
- Canada
- Prior art keywords
- sheet material
- thermoplastic sheet
- tape
- polymer
- backsheet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
- A61F13/514—Backsheet, i.e. the impermeable cover or layer furthest from the skin
- A61F13/51496—Backsheet, i.e. the impermeable cover or layer furthest from the skin having visual effects
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
- A61F13/514—Backsheet, i.e. the impermeable cover or layer furthest from the skin
- A61F13/51401—Backsheet, i.e. the impermeable cover or layer furthest from the skin characterised by the material
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/56—Supporting or fastening means
- A61F13/5622—Supporting or fastening means specially adapted for diapers or the like
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Heart & Thoracic Surgery (AREA)
- Public Health (AREA)
- Engineering & Computer Science (AREA)
- Vascular Medicine (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Veterinary Medicine (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Absorbent Articles And Supports Therefor (AREA)
Abstract
THERMOPLASTIC SHEET MATERIAL HAVING IMPROVED
TAPE ADHESION
Abstract of the Disclosure Novel thermoplastic sheet materials for permitting positionable and repeated repositionable use of tape fasteners therewith without experiencing substantial loss of tape adhesion therebetween are disclosed. A novel thermoplastic sheet material generally comprises an ethylene polymer and an anti-popoff substance in an effective amount for increasing and substantially maintaining the tape adhesion. The increase in and substantial maintenance of the tape adhesion is accomplished without adversely affecting the properties or cost of the thermoplastic sheet material. A preferred formulation for producing the novel thermoplastic sheet material comprises polyethylene as the ethylene polymer and a polypropylene or alpha-methyl styrene as the anti-popoff substance. The novel thermoplastic sheet materials are especially suitable for use as films which can be used as backsheets in absorbent articles, such as, disposable diapers, bandages, surgical dressings or drapes and catamenial pads.
TAPE ADHESION
Abstract of the Disclosure Novel thermoplastic sheet materials for permitting positionable and repeated repositionable use of tape fasteners therewith without experiencing substantial loss of tape adhesion therebetween are disclosed. A novel thermoplastic sheet material generally comprises an ethylene polymer and an anti-popoff substance in an effective amount for increasing and substantially maintaining the tape adhesion. The increase in and substantial maintenance of the tape adhesion is accomplished without adversely affecting the properties or cost of the thermoplastic sheet material. A preferred formulation for producing the novel thermoplastic sheet material comprises polyethylene as the ethylene polymer and a polypropylene or alpha-methyl styrene as the anti-popoff substance. The novel thermoplastic sheet materials are especially suitable for use as films which can be used as backsheets in absorbent articles, such as, disposable diapers, bandages, surgical dressings or drapes and catamenial pads.
Description
3 ~
THERMOPLASTIC SHEET MATERIAL ~AVING IMPR~VED
TAPE ADHESION _ .
Field ~f the Invention The present invention relates to a thermo-plastic sheet material, and more particularly to a thermoplastic sheet material for use with absorbent -articles, such as disposable diapers, wherein the thermoplastic sheet material has improved tape adhesion with pressure-sensitive adhesive tape-tabs.
Background It has become common practice today to usè
disposable diapers with infants and incontinent people. Disposable diapers generally have a rectangular or hour glass shap~ and comprise an absorbent batt material sandwiched between an outer flexible polyethylene backsheet and an inner flexible, polypropylene or polyester nonwoven frontsheet. The outer backsheet typically, but not necessarily, is water-impervious to prevent voided liquid absorbed into the absorbent batt material from striking through the diaper and soiling the infant's adjacent clothing ,. , 1~ 3~
or bedding. The inner rontsheet on the other hand is water-pervious to permit the voided liquid to pass therethrough into the absorbent batt material to maintain the infant in a dry, comfortable state.
It is also well known and common practice in manufacturing disposable diapers to rely upon tape-tab fasteners as means for fastening the dia~ers about infants. The safety advantages and practicality of tape-tabs, rather than pins, is self evident.
However, there are several shortcomings associated with their use. One major shortcoming lies in the loss or lack of tape adhesion between the tape-tab fasteners and backsheets following the original closures preventing the tape-tab fasteners from being positioned or repositioned on the backsheets. This shortcoming becomes immediately apparent when users, such as nurses or parents, attempt to separate the tape-tab fasteners from the diapers to inspect for soiling and refasten them following their inspection or when the diapers fall off due to the failure of tape-tab fasteners.
Some backsheet materials available heretofore for disposable diapers have very poor tape adhesion, i.e., the pressure-sensitive adhesives of the tape-tab fasteners do not or cannot adhere to the backsheets, making positioning or repositioning very cumbersome, if not virtually impossible. Unfortun-ately, this results in unsoiled diapers being ~ 3 ~
discarded and wasted following routine inspection or childrens' participation in the toilet-training ritual. This lack of reusability not only is - inconvenient but also expensive because of the rising costs associated with disposable diapers.
In one attempt to solve the refastening problem, U.S. Patent No. 4,163,077, issu~d to Antonsen et al. on July 31, 1979, proposes to-formulate the pressure-sensitive adhesive of the tape-tab fasteners with a rubbery block copolymer tackified with a combination of certain liquid and solid tackifiers to improve adhesion and shear properties when the backsheet is contaminated with foreign substances, such as talcum powder.
~hile U.S. Pate~t No. 4,163,077 reflects one attempt, there have been other attempts made in the past to solve the repositioning problem.
Unfortunately, they have attempted to solve such problem by modifying either the tape-tab ~asteners, the pressure-sensitive adhesives used therewith or by coating the tape-tab fastener bonding regions located on ~he backsheets. These closure systems have the disadvantages of restricting the disposable diaper manufacturers to a particular tape-tab fastener ; 25 arrangement, a particular pressure-sensitive adhesive formulation or added manufacturing steps, and forcing them to select only those backsheets that are coated at the bonding regions or are compatible with such ~ . ~ , .. .... .
1 3 ~
arrangements or pressure~sensitive adhesive formulations in order to pxoduce an effective repositionable closure system. Such methods also have the disadvantage of adding to the cost of manufac-turing disposable diapers.
Consequently, there is a definite need for a repositionable yet inexpensive and flexible closure system that is not restricted to a particular tape-tab fastener arrangement, pressure-sensitive adhesive formulation or coated backsheet, that has good tape adhesion when the diapers are initially closed, and that does not lose substantial tape adhesion upon repeated use of the tape-tab fasteners following occasional inspection for soiling or childrens' participation in the toilet-training ritual permitting unsoiled diapers to be reused.
Summary of the Invention In brief, the present invention alleviates the above mentioned problems and shortcomings of the present state of the art through the discovery of a novel thermoplastic sheet material for permitting positionable and repeated repositionable use of a tape fastener therewith without experiencing substantial loss of tape adhesion therebetween. More particu-larly, the novel thermoplastic sheet material com-prises an sthylene polymer and an anti-popoff polymer in an effective amount which accounts for ~B
131~3~
the increase in and substantial maintenance of the tape adhesion. The ethylene polymer can be a low density polyethylene, a linear low density polyethylene, a high density polyethylene or suitable blends thereof. The anti-popoff polymer can be, for instance, polypropylene, alpha-methyl styrene, ethylene-propylene copolymer and styreni~ copolymers, such as styrene-butadiene-styrene block copolymer and styrene-isoprene-styrene block copolymer, which is preferably present in an amount of about greater than zero up to about ten percent by weight of the sheet material. The unique increase in and substantial maintenance of the tape adhesion associated with the thermoplastic sheet materials of this invention is accomplished without adversely affecting the properties or cost of the sheet material while ob-taining the desired advantage of permitting positionable and repeated repositionable use of tape fasteners therewith. Moreover, in following the teachings of the present invention, disposable diaper manufacturers are no longer restricted to a particular tape-tab fastener arrangement or pressure-sensitive adhesive formulation since the thermoplastic sheet materials of this invention, when used as backsheets, can be formulated for compatible use with almost any repositionable tape-tab fastener or system.
The novel thermoplastic sheet materials of this invention are especially suitable for use as ~ , , , 13~ ~3'1 films which can be used as backsheets in absorbent articles, such as bandages, surgical dressings or drapes and catamenial pads, and are especially suitable for use as backsheets in disposable diapers.
When the thermoplastic sheet materials of this invention are used to formulate the backsheets of disposable diapers, they uniquely afford cost saving and convenience advantages to users ~y permitting the tape-tab fasteners to be repositioned to the backsheets so that diapers can be reused with confidence following routine inspection or the toilet-training ritual. In other words, the refastened tape-tabs will adhere firmly to the backsheets, and the disposable diapers will remain in place following their opening or removal by the users.
The present invention therefore now makes it possible to initially close a disposable diaper with confidence and to open the originally closed diaper for occasional inspection without fear that the tape-tab fasteners will not reposition on the backsheet, or without fear that the disposable diaper will reopen at some point following the original closure or a subsequent closure.
The above features and advantages of the present invention will be better understood with reference to the accompanying Figs., Detailed Description and Examples. It also should be understood that the particular thermoplastic sheet _7_ 13~3~
materials, absorbent articles and methods of this invention are exemplary only and not to be reqarded as limitations of the invention.
Brief Description of the Fig.
Reference is now made to the accompanying Figs. from which the novel features and advantages of the present invention will be apparent:
Fig. 1 is a diagrammatic view in side elevation of a schematic system of an extrusion apparatus suitable for producing the thermoplastic sheet materials of the present invention;
Fig. 2 is a graphic illustration exemplifying the percent increase in tape adhesion of a thermoplastic polyethylene sheet material formulated with a polypropylene or alpha-methyl styrene anti-popoff polymer in accordance with the present invention; and Fig. 3 is a graphic illustration exemplifying the percent increase in tape adhesion of two different commercially available tape-tab fasteners when they are separated (Method C~ from a thermoplastic polyethylene sheet material formulated with various concentrations of a polypropylene anti-popoff polymer in accordance with the present invention.
Fig. 4 is a graphic illustration comparing the percent increase in tape adhesion between a ~B
polyethylene backsheet containing 5% polypropylene and a commercial tape-tab fastener designated herein as tape-tab fastener 5 over the tape adhesion between a similar polyethylene backsheet free of polypropylene and a similar commercial tape-tab fastener 5 following an initial fastening and four refastenings.
Detailed Description of the Invention By way of illustrating and providing a more complete appreciation of the present invention and many of the attendant advantages thereof, the fol-lowing detailed description and examples are given concerning the novel thermoplastic sheet materials, absorbent articles made therewith and methods of production and use thereof.
As used herein, the term "tape adhesion"
refers broadly to the force required to remove or separate a pressure-sensitive adhesive fastener from a thermoplastic sheet material. The force required to remove or separate the fastener from the thermoplastic ~heet material is generally measured at a specified angle and at a given speed. Tests to determine tape adhesion may be conducted with an one-inch width fastener, such as a pressure-sensitive adhesive tape-tab fastener, at 90 (Test method A ) and 180 (Test method B) angles of peel at a pull speed of approximately 12 inches per minute at any desirable speed. Of course, it should be understood that the ~31~;Q ~
g tape adhesion can be measured at any other angle, such as between 90 and 180 (Test method C) and at different pull speeds. The results may be expressed in grams per inch width of the tape-tab fastener or in percent increase as a function of the anti-popoff substance content.
Referring now more particular}y to the present invention, the thermoplastic sheet material comprises an ethylene polymer and an anti-popoff polymer in an effective amount for increasing and substantially maintaining the tape adhesion between the thermoplastic sheet material and a pressure-sensitive adhesive fastener adhered thereto.
In other words, the uniquely formulated thermoplastic sheet materials provide for improved tape adhesion following the original or subsequent bonding of a tape fastener to the thermoplastic sheet material. The ethylene polymers which may be used to formulate the thermoplastic sheet materials of the present invention can be homopolymers of ethylene made from ethylene monomers or comonomers of ethylene with, for example, butene, hexene, octene and methyl pentene. Particular ethylene polymers that are suitable for use in the ; present invention are polyethylenes and more particularly low, linear low or high density polyethylenes or any suitable blends thereof.
By the term "anti-popoff polymer," it is meant herein to refer broadly to any substance that, B
- . ~
.
J 31 r~
when combined with an ethylene polymer to form a thermoplastic sheet material of the present invention, can act to increase and substantially maintain the tape adhesion between the thermoplastic sheet material and a pressure-sensitive adhesive fastener for permitting positionable and repeated repositionable use of the fastener therewith. The uni~e formulation of an anti-popoff polymer in an effective amount with an ethylene polymer can ~e used to formulate a novel thermoplastic sheet material of the present invention which is believed to be more resistant to tape rastener peel following positioning or repositioning than heretofore achieved. In other words, the thermoplastic sheet materials of the present invention prevents pressure-sensitive adhesive fasteners from popping off of the sheet materials following their being initially positioned or repositioned thereon.
In determining how much of the anti-popoff polymer to incorporate into the thermoplastic sheet material, it is necessary to take into account the pressure-sensitive adhesive of the tape fastener selected for use. When anti-popoff polymers having high bonding affinities for the pressure-sensitive adhesives are selected, lesser amounts are required to be incorporated into the sheet materials than when anti-popoff polymers having low bonding affinities are selected. Nevertheless, it is found as a general 1`~
1 3 ~
rule that an effective amount can range from about greater than 0 up to about 10% and more paxticularly from about 0.75% to about 5% by weight of the thermoplastic sheet material. Regardless of the amount utilized, however, it is preferred to utilize an amount that does not cause the tape adhesion to exceed the tearing strength of the sheet material which can be determined by any conventional technique well known to those versed in the art. The tearing strength is a function of, inter alia, the thickness and components of the thermoplastic sheet materials.
Preferred anti-popoff polymers which may be used to formulate the thermoplastic sheet materials of the present invention are polyproylenes and copolymers thereof, alpha-methyl styrene and styrenic copolymers.
The preferred anti-popoff polymers include polypropylene, alpha-methyl styrene, ethylene-propylene copolymer, styrenic copolymers, such as styrene-butadiene-styrene block copolymer and styrene-isoprene-styrene block copolymer, and suitable mixtures thereof. The most preferred anti-popoff polymers are a polypropylene and an alpha-methyl styrene. Although the above represents preferred amounts and anti-popoff polymers, it should be understood that any effective amount of and any suitable substance, polymer or blends of polymers may be used as the anti-popo~f pol~me~. Of course, by the term "effective amount," it re~ers to any amount fB -11-1 ~ ~'3 of a suitable anti-popoff substance in an ethylene polymer sheet material that can increase and substantially maintain tape adhesion between the ethylene polymer sheet material and a tape-tab fastener following initial and/or repeated re-fastenable use.
Exemplary of two preferred formulations for producing a thermoplastic sheet material contemplated by the present invention comprises a polyethylene as the ethylene polymer and a polypropylene or alpha-methyl styrene as the anti-popoff substance.
Such formulations generally comprise by weight about-90 to about less than lO0~ polyethylene and about greater than 0 to about 10% polypropylene or alpha-methyl styrene. As reflected in Fig. 2, there is a dramatic increase in tape adhesion when polypro-pylene i5 selected as the anti-popoff substance.
There is, however, only a gradual increase in tape adhesion when alpha-methyl styrene is utilized as the anti-popoff substance. This is also reflected in Fig.
THERMOPLASTIC SHEET MATERIAL ~AVING IMPR~VED
TAPE ADHESION _ .
Field ~f the Invention The present invention relates to a thermo-plastic sheet material, and more particularly to a thermoplastic sheet material for use with absorbent -articles, such as disposable diapers, wherein the thermoplastic sheet material has improved tape adhesion with pressure-sensitive adhesive tape-tabs.
Background It has become common practice today to usè
disposable diapers with infants and incontinent people. Disposable diapers generally have a rectangular or hour glass shap~ and comprise an absorbent batt material sandwiched between an outer flexible polyethylene backsheet and an inner flexible, polypropylene or polyester nonwoven frontsheet. The outer backsheet typically, but not necessarily, is water-impervious to prevent voided liquid absorbed into the absorbent batt material from striking through the diaper and soiling the infant's adjacent clothing ,. , 1~ 3~
or bedding. The inner rontsheet on the other hand is water-pervious to permit the voided liquid to pass therethrough into the absorbent batt material to maintain the infant in a dry, comfortable state.
It is also well known and common practice in manufacturing disposable diapers to rely upon tape-tab fasteners as means for fastening the dia~ers about infants. The safety advantages and practicality of tape-tabs, rather than pins, is self evident.
However, there are several shortcomings associated with their use. One major shortcoming lies in the loss or lack of tape adhesion between the tape-tab fasteners and backsheets following the original closures preventing the tape-tab fasteners from being positioned or repositioned on the backsheets. This shortcoming becomes immediately apparent when users, such as nurses or parents, attempt to separate the tape-tab fasteners from the diapers to inspect for soiling and refasten them following their inspection or when the diapers fall off due to the failure of tape-tab fasteners.
Some backsheet materials available heretofore for disposable diapers have very poor tape adhesion, i.e., the pressure-sensitive adhesives of the tape-tab fasteners do not or cannot adhere to the backsheets, making positioning or repositioning very cumbersome, if not virtually impossible. Unfortun-ately, this results in unsoiled diapers being ~ 3 ~
discarded and wasted following routine inspection or childrens' participation in the toilet-training ritual. This lack of reusability not only is - inconvenient but also expensive because of the rising costs associated with disposable diapers.
In one attempt to solve the refastening problem, U.S. Patent No. 4,163,077, issu~d to Antonsen et al. on July 31, 1979, proposes to-formulate the pressure-sensitive adhesive of the tape-tab fasteners with a rubbery block copolymer tackified with a combination of certain liquid and solid tackifiers to improve adhesion and shear properties when the backsheet is contaminated with foreign substances, such as talcum powder.
~hile U.S. Pate~t No. 4,163,077 reflects one attempt, there have been other attempts made in the past to solve the repositioning problem.
Unfortunately, they have attempted to solve such problem by modifying either the tape-tab ~asteners, the pressure-sensitive adhesives used therewith or by coating the tape-tab fastener bonding regions located on ~he backsheets. These closure systems have the disadvantages of restricting the disposable diaper manufacturers to a particular tape-tab fastener ; 25 arrangement, a particular pressure-sensitive adhesive formulation or added manufacturing steps, and forcing them to select only those backsheets that are coated at the bonding regions or are compatible with such ~ . ~ , .. .... .
1 3 ~
arrangements or pressure~sensitive adhesive formulations in order to pxoduce an effective repositionable closure system. Such methods also have the disadvantage of adding to the cost of manufac-turing disposable diapers.
Consequently, there is a definite need for a repositionable yet inexpensive and flexible closure system that is not restricted to a particular tape-tab fastener arrangement, pressure-sensitive adhesive formulation or coated backsheet, that has good tape adhesion when the diapers are initially closed, and that does not lose substantial tape adhesion upon repeated use of the tape-tab fasteners following occasional inspection for soiling or childrens' participation in the toilet-training ritual permitting unsoiled diapers to be reused.
Summary of the Invention In brief, the present invention alleviates the above mentioned problems and shortcomings of the present state of the art through the discovery of a novel thermoplastic sheet material for permitting positionable and repeated repositionable use of a tape fastener therewith without experiencing substantial loss of tape adhesion therebetween. More particu-larly, the novel thermoplastic sheet material com-prises an sthylene polymer and an anti-popoff polymer in an effective amount which accounts for ~B
131~3~
the increase in and substantial maintenance of the tape adhesion. The ethylene polymer can be a low density polyethylene, a linear low density polyethylene, a high density polyethylene or suitable blends thereof. The anti-popoff polymer can be, for instance, polypropylene, alpha-methyl styrene, ethylene-propylene copolymer and styreni~ copolymers, such as styrene-butadiene-styrene block copolymer and styrene-isoprene-styrene block copolymer, which is preferably present in an amount of about greater than zero up to about ten percent by weight of the sheet material. The unique increase in and substantial maintenance of the tape adhesion associated with the thermoplastic sheet materials of this invention is accomplished without adversely affecting the properties or cost of the sheet material while ob-taining the desired advantage of permitting positionable and repeated repositionable use of tape fasteners therewith. Moreover, in following the teachings of the present invention, disposable diaper manufacturers are no longer restricted to a particular tape-tab fastener arrangement or pressure-sensitive adhesive formulation since the thermoplastic sheet materials of this invention, when used as backsheets, can be formulated for compatible use with almost any repositionable tape-tab fastener or system.
The novel thermoplastic sheet materials of this invention are especially suitable for use as ~ , , , 13~ ~3'1 films which can be used as backsheets in absorbent articles, such as bandages, surgical dressings or drapes and catamenial pads, and are especially suitable for use as backsheets in disposable diapers.
When the thermoplastic sheet materials of this invention are used to formulate the backsheets of disposable diapers, they uniquely afford cost saving and convenience advantages to users ~y permitting the tape-tab fasteners to be repositioned to the backsheets so that diapers can be reused with confidence following routine inspection or the toilet-training ritual. In other words, the refastened tape-tabs will adhere firmly to the backsheets, and the disposable diapers will remain in place following their opening or removal by the users.
The present invention therefore now makes it possible to initially close a disposable diaper with confidence and to open the originally closed diaper for occasional inspection without fear that the tape-tab fasteners will not reposition on the backsheet, or without fear that the disposable diaper will reopen at some point following the original closure or a subsequent closure.
The above features and advantages of the present invention will be better understood with reference to the accompanying Figs., Detailed Description and Examples. It also should be understood that the particular thermoplastic sheet _7_ 13~3~
materials, absorbent articles and methods of this invention are exemplary only and not to be reqarded as limitations of the invention.
Brief Description of the Fig.
Reference is now made to the accompanying Figs. from which the novel features and advantages of the present invention will be apparent:
Fig. 1 is a diagrammatic view in side elevation of a schematic system of an extrusion apparatus suitable for producing the thermoplastic sheet materials of the present invention;
Fig. 2 is a graphic illustration exemplifying the percent increase in tape adhesion of a thermoplastic polyethylene sheet material formulated with a polypropylene or alpha-methyl styrene anti-popoff polymer in accordance with the present invention; and Fig. 3 is a graphic illustration exemplifying the percent increase in tape adhesion of two different commercially available tape-tab fasteners when they are separated (Method C~ from a thermoplastic polyethylene sheet material formulated with various concentrations of a polypropylene anti-popoff polymer in accordance with the present invention.
Fig. 4 is a graphic illustration comparing the percent increase in tape adhesion between a ~B
polyethylene backsheet containing 5% polypropylene and a commercial tape-tab fastener designated herein as tape-tab fastener 5 over the tape adhesion between a similar polyethylene backsheet free of polypropylene and a similar commercial tape-tab fastener 5 following an initial fastening and four refastenings.
Detailed Description of the Invention By way of illustrating and providing a more complete appreciation of the present invention and many of the attendant advantages thereof, the fol-lowing detailed description and examples are given concerning the novel thermoplastic sheet materials, absorbent articles made therewith and methods of production and use thereof.
As used herein, the term "tape adhesion"
refers broadly to the force required to remove or separate a pressure-sensitive adhesive fastener from a thermoplastic sheet material. The force required to remove or separate the fastener from the thermoplastic ~heet material is generally measured at a specified angle and at a given speed. Tests to determine tape adhesion may be conducted with an one-inch width fastener, such as a pressure-sensitive adhesive tape-tab fastener, at 90 (Test method A ) and 180 (Test method B) angles of peel at a pull speed of approximately 12 inches per minute at any desirable speed. Of course, it should be understood that the ~31~;Q ~
g tape adhesion can be measured at any other angle, such as between 90 and 180 (Test method C) and at different pull speeds. The results may be expressed in grams per inch width of the tape-tab fastener or in percent increase as a function of the anti-popoff substance content.
Referring now more particular}y to the present invention, the thermoplastic sheet material comprises an ethylene polymer and an anti-popoff polymer in an effective amount for increasing and substantially maintaining the tape adhesion between the thermoplastic sheet material and a pressure-sensitive adhesive fastener adhered thereto.
In other words, the uniquely formulated thermoplastic sheet materials provide for improved tape adhesion following the original or subsequent bonding of a tape fastener to the thermoplastic sheet material. The ethylene polymers which may be used to formulate the thermoplastic sheet materials of the present invention can be homopolymers of ethylene made from ethylene monomers or comonomers of ethylene with, for example, butene, hexene, octene and methyl pentene. Particular ethylene polymers that are suitable for use in the ; present invention are polyethylenes and more particularly low, linear low or high density polyethylenes or any suitable blends thereof.
By the term "anti-popoff polymer," it is meant herein to refer broadly to any substance that, B
- . ~
.
J 31 r~
when combined with an ethylene polymer to form a thermoplastic sheet material of the present invention, can act to increase and substantially maintain the tape adhesion between the thermoplastic sheet material and a pressure-sensitive adhesive fastener for permitting positionable and repeated repositionable use of the fastener therewith. The uni~e formulation of an anti-popoff polymer in an effective amount with an ethylene polymer can ~e used to formulate a novel thermoplastic sheet material of the present invention which is believed to be more resistant to tape rastener peel following positioning or repositioning than heretofore achieved. In other words, the thermoplastic sheet materials of the present invention prevents pressure-sensitive adhesive fasteners from popping off of the sheet materials following their being initially positioned or repositioned thereon.
In determining how much of the anti-popoff polymer to incorporate into the thermoplastic sheet material, it is necessary to take into account the pressure-sensitive adhesive of the tape fastener selected for use. When anti-popoff polymers having high bonding affinities for the pressure-sensitive adhesives are selected, lesser amounts are required to be incorporated into the sheet materials than when anti-popoff polymers having low bonding affinities are selected. Nevertheless, it is found as a general 1`~
1 3 ~
rule that an effective amount can range from about greater than 0 up to about 10% and more paxticularly from about 0.75% to about 5% by weight of the thermoplastic sheet material. Regardless of the amount utilized, however, it is preferred to utilize an amount that does not cause the tape adhesion to exceed the tearing strength of the sheet material which can be determined by any conventional technique well known to those versed in the art. The tearing strength is a function of, inter alia, the thickness and components of the thermoplastic sheet materials.
Preferred anti-popoff polymers which may be used to formulate the thermoplastic sheet materials of the present invention are polyproylenes and copolymers thereof, alpha-methyl styrene and styrenic copolymers.
The preferred anti-popoff polymers include polypropylene, alpha-methyl styrene, ethylene-propylene copolymer, styrenic copolymers, such as styrene-butadiene-styrene block copolymer and styrene-isoprene-styrene block copolymer, and suitable mixtures thereof. The most preferred anti-popoff polymers are a polypropylene and an alpha-methyl styrene. Although the above represents preferred amounts and anti-popoff polymers, it should be understood that any effective amount of and any suitable substance, polymer or blends of polymers may be used as the anti-popo~f pol~me~. Of course, by the term "effective amount," it re~ers to any amount fB -11-1 ~ ~'3 of a suitable anti-popoff substance in an ethylene polymer sheet material that can increase and substantially maintain tape adhesion between the ethylene polymer sheet material and a tape-tab fastener following initial and/or repeated re-fastenable use.
Exemplary of two preferred formulations for producing a thermoplastic sheet material contemplated by the present invention comprises a polyethylene as the ethylene polymer and a polypropylene or alpha-methyl styrene as the anti-popoff substance.
Such formulations generally comprise by weight about-90 to about less than lO0~ polyethylene and about greater than 0 to about 10% polypropylene or alpha-methyl styrene. As reflected in Fig. 2, there is a dramatic increase in tape adhesion when polypro-pylene i5 selected as the anti-popoff substance.
There is, however, only a gradual increase in tape adhesion when alpha-methyl styrene is utilized as the anti-popoff substance. This is also reflected in Fig.
2. Even when minor amounts of polypropyl~ne are blended into the sheet materials, the tape adhesion still dramatically increases as compared to a similar thermoplastic polyethylene sheet material having no polypropylene incorporated therein. This can be observed in Table I (Test method A) and Table II (Test method B) where the polypropylene accounts for only 133L~ul~
about 0.75% and about 1.3~ of the weight of the sheet materials, respectively.
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As a further feature of the present invention, the tape adhesion between a sheet material having an anti-popoff substance and a tape-tab fastener remains substantially the same even after a repeated number of refastenings. This feature is demonstrated in Fig. 4 wherein the percent increase in tape adhesion between a polyethylene backsheet containing 5% polypropylene and commercial tape-tab fastener 5 remained virtually the same as when compared to the tape adhesion between a similar polyethylene backsheet free of polypropylene and commercial tape-tab fastener 5 after five refastenings.
It should be appreciated, however, that eventhough the tape adhesion between a sheet material of this invention and a tape-tab fastener following a repeated number of fastenings might be less than the original fastening, it is nevertheless believed that such tape adhesion will usually be greater than the adhesion between a sheet material free of an anti-popoff substance and a tape-tab fastener having an equal number of refastenings. Therefore, the term "substantially maintaining tape adhesion" is used herein in a broad sense to refer to not only those instances where the tape adhesion increases or remains substantially the same following repeated fastenings but also to those instances where there is any increase in tape adhesion between the sheet materials ;
1 3 ~ J '~
of the present invention and a tape-tab fastener over the tape adhesion between similar sheet materials free of anti-popoff substances and a tape-tab fastener following refastening.
While the inventors do not wish to be limited to any particular theory in which the tape adhesion is increased and substantially~maintained, they presently believe that the incorporation of a minor amount of an anti-popoff substance into a thermoplastic ethylene-based sheet material interrupts the surface packing of the ethylene polymer, particularly when the ethylene polymer is a polyethylene, resulting in higher surface free-energy associated with the sheet material thus improving the adhesion of pressure-sensitive adhesive fasteners thereto. It is also presently believed that the objectives of this invention can be easily met particularly when the pressure-sensitive adhesive formulation of the selected tape-tab to be used is known by selecting an anti-popoff substance that has a high bonding affinity for the particular pressure-sensitive adhesive. Even when the pressure-sensitive adhesive formulation is unknown, it is still believed that the objectives of this invention can be met by utilizing one of the polymeric substances employed to formulate the backsheet tab of the tape-tab fastener selected as the anti-popoff substance. Generally speaking, a polymeric substance 13.~5~3'~1 commonly utilized to formulate the backsheet tabs of tape-tabs today particularly in the disposable diaper industry is a polypropylene. Since polypropylene generally has a high bonding affinity for the pressure-sensitive adhesives utilized with the tape-tab fasteners and is the commonly employed polyolefin utilized to form the backsheet tabs of the tape-tab fasteners, these factors make polypropylene a preferred anti-popoff substance.
Basically any commercially available pressure-sensitive adhesive tapP-tab fasteners used in disposable diaper construction today are suitable for use with the thermoplastic sheet materials of the present invention. For example, SiY. different commercially available pressure-sensitive adhesive tape-tab fasteners have been utilized herein, and all six have been found to be substantially equally suitable. While the precise formulas of the pressure-sensitive adhesives utilized to form the six different tape-tab fasteners are unknown, it is presently believed that the pressure sensitive adhesive of tape-tab fastener 5 comprises a styrene-isoprene-styrene block copolymer ~ase, an aliphatic mixed olefin tackifying resin and an anti-oxidant. It is also believed that the backsheet tab of tape-tab fastener 5 is formed with a polypropylene. Of course, it should also be appreciated 'hat there are many other commercially 3 ~
available tape-tab fasteners being used by the disposable-diaper manufacturers that have pressure-sensitive adhesive formulations which are different than the pressure-sensitive adhesive formula of tape-tab fastener 5 described above that are also suitable for use with the present invention.
The commercial tape-tab fastener 5 referred to above can be easily prepared by any con~entional means, such as by coating the pressure-sensitive adhesive composition just described onto the face side of a polypropylene-backing tab.
With reference now to Fig. 1, a slot cast film extrusion method for making the thermoplastic sheet materia~s of the present will be described. In this method, the thermoplastic sheet materials are generated simply by blending a selected ethylene polymer with a particular anti-popoff substance in an effective amount and extruding the mixture through a conventional extrusion die adapter 1 and cast film die 2 to form the molten web 3. Molten web 3 is then rolled between a metal roll 4 and a rubber roll 5.
When an embossed film is desired, an embossing section 6 is located on metal roll 4. The sheet materials can be embossed with any suitable design according to any of a number of well-known techniques. For examp~e, embossing can be performed by the introduction of a pre-formed sheet material into a system of embossing rolls or by the introduction of an extruded melt of , the thermoplastic material through a slot-die between embossing rolls. The molten web 3 is then directed onto a chilled metal roll 7 to form the coo~ed extruded film 8 which is then wound onto a storage roll (not shown). While the above describes thermoplastic sheet materials of the present invention being produced by a slot cast film extrusion method, the thermoplastic sheet materials can be produced by blown film extrusion methods as well. These different processes of making and embossing are described in more detail in U.S. Patent Nos. 4,535,021, 4,546,029, 4,376,147 and 3,484,835.
In a further feature O$ the present invention, the thermoplastic sheet materials can be produced by either single extrusion or co-extrusion.
When the sheet materials are produced by slngle extrusion, the anti-popoff substance is generally dispersed throughout the single layer o. the films.
When the sheet materials are co-extruded, the anti-popoff substance can be generally dispersed either throughout each layer or throughout one or more layers of the films. For instance, the anti-popofC
substance can be generally dispersed throughout the 2S top andJor bottom layers of a two layer or the top, bottom and/or middle layers of a three layer co-extruded film. It is necessary, however, to disperse the anti-popoff substance at least throughout 3'~
the layer of the co-extruded sheet material that is to rec~ive the tape-tab fastener thereon.
Although the sheet materials can be formulated by adding the anti-popoff substance directly to the ethylene polymer to form a pre-extrusion mixture, it is found that better results are achieved when the selected ethylene polymer is blended with a concentrate containing,~~inter alia, the anti-popoff substance. The concentrate may also include, for instance, an ethylene polymer carrier, such as a conventional low density polyethylene or a conventional linear low density polyethylene, and titanium dioxide as a whitener. Preferred concentrates are those in which the anti-popoff substance is polypropylene wherein the polypropylene is present in an amount ranging from about 5 to about 50~ by weight of the concentrate. Such preferred concentrates can further include the ethyïene polymer carrier in an amount ranging from about 45% to about 0% and titanium dioxide (TiO2) in an amount of about 50~ by weight. Examples of three formulations of such preferred concentrates suitable for use in accordance with the teachings of the present invention are designated as Concentrates I-IV as follows:
~L3~3'f,l Concentrate I II III IV
polypropylene parts 5 25 45 50 polyethylene parts 45 25 5 0 TiO~ parts 50 50 50 50 Total Parts 100 lOO 100 100 The preferred concentrate should be intimately blended with an ethylene polymer and in particular a polyethylene in an amount ranging from about 8 to about 10 parts concentrate to about 100 parts polyethylene to form the pre-extrusion mixture which can then be extruded as described above to form liquid-pervious or liquid-impervious sheet materials, such as backsheets.
The thermoplastic sheet materials of the present invention are especially suitable for use with absorbent articles, such as disposable diapers, bandages, surgical dressings or drapes and catamenial pads and most particularly with disposable diapers.
When the thermoplastic sheet materials are to be used with the absorbent articles, they can be formulated into thin films that are either liquid-pervious or liquid-impervious, that have either smooth or embossed surfaces and that have either dull or glossy finishes.
The thickness of the film can vary over a wide range.
When the thermoplastic sheet materials are to be formulated into thin films that are to be used as backsheets for absorbent articles, it is preferred, ~ 3 ~
but not necessary, that th~ thin films are moisture-impervious having embossed surfaces and dull finishes. Typically, such thin backsheet films can have a thickness ranglng from about 0.5 mils to about 2.0 mils and preferably about 1.0 mils to about 1.5 mils, but these limitations are not critical. Of course, when selecting a film thickness, the tearing strength of the film should not be ove~looked so that the objectives of the present invention are not defeated.
A typical disposable diaper practicing the objectives of the present invention generally includes a moisture-pervious inner frontsheet, an outer ~acksheet of the present invention which is preferably moisture-impervious, an absorbent material or layer positioned between the outer backsheet and inner frontsheet and tape-tab fasteners secured to the disposable diaper. The moisture-pervious inner frontsheet forms the diaper inside surface for direction toward an infant and the outer backsheet forms a diaper outside surface for direction away from the infant when the disposable diaper is worn by the infant. To secure the tape-tab fasteners to the disposable diaper, the tape-tab fasteners generally speaking have anchoring ends which are secured to the disposable diaper and user ends which have on one side thereof a pressure-sensitive adhesive presenting tacky surfaces facing in the same direction as the diaper ~ 3 ~
inside surface for contact with the backsheet when the diaper is fitted about an infant. Other absorbent articles such as bandages, surqical dressings or drapes and catamenial pads, on the other hand, generally comprise the same three elements as the disposable diaper absent the tape-tab fasteners. As an additional benefit, the anti-popoff technology improves the ability to assemble the components of such absorbent products together, such as the glue, backsheets, etc.
Examples of the increase in tape adhesion between a thermoplastic sheet material of the present invention will now be further illustrated with reference to the following examples.
1 3 ~
Example I
A polyethylene in combination with anti-popoff substances are extruded to form the thermoplastic backsheets having increased tape adhesion for preventing the disposable diaper tape-tab fasteners from popping off the backsheets. For instance, about 5% of a conventional polypropylene and about 95~ of a conventional polyethylene can be blended and extruded into thin films in the range of about 1.0 to about 1.5 mils which can then be used as backsheets. As indicated in Tables III and IV, the tape adhesion dramatically increases with a thermoplastic sheet material having about 5%
polypropylene incorporated therein as when compared to a similar thermoplastic sheet material without polypropylene. It is also believed that any conventional polypropylene, such as shown in Tables I
and II, will have the same effect on increasing the tape adhesion.
More precisely, the amount of anti-popoff substance needed to increase tape adhesion depends of course upon the interaction of the pressure-sensitive adhesive of the tape-tab fasteners and the film.
Another example of an increase in tape adhesion attributed to the use of an anti-popoff substance is described in Example II.
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t ~ ~ 3 ~ ~_ ~ ~ D~ 3 n n ~ r~ I I n n o 1-- ~ 5 W ~ I I O 1-- O ~
:~ ~D (D ^ ~ ~D -- (D --~ ~ ~ YUl ~ U~ d. U~ OP
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Example II
The thermoplastic sheet materials and tape adhesions referred to in Tables I and II are prepared and determined as follows.
A first concentrate is prepared which comprises 40 parts of a conventional thermoplstic low density polyethylene, 10 parts of a conventional thermoplastic polypropylene and 50 parts titanium dioxide. Eight parts of the prepared concentrate are intimately blended with 100 parts of a conventional polyethylene to form a first pre-extrusion mixture.
The first pre-extrusion mixture is then extruded in -accordance with the extrusion equipment and procedures described herein to generate a first thin thermoplastic film which comprises by weight about 0.75% polypropylene, about 3.70% titanium dioxide and about 95.55% polyethylene. The first extruded film has a thickness of about 1.5 mils, an embossed surface, a dull finish and is moisture-impervious.
A second concentrate is prepared which comprises 35 parts of a conventional thermoplastic low density polyethylene, 15 parts of a conventional thermoplastic polypropylene and 50 parts titanium dioxide. Nine parts of the prepared concentrate are intimately blended with 100 parts of a conventional polyethylene to form a second pre-extrusion mixture.
The second pre-extrusion mixture is then extruded in accordance with the extrusion equipment and procedures , ,, .. i.. .... . .
13~311 described herein to generate a second, thin thermoplastic film which comprises by weight about 1.3% polypropylene, 4.1~ titanium dioxide and 94.6%
polyethylene. The second extruded film has a thickness of about 1.5 mils, an embossed surface and a dull finish and is moisture-impervious.
As indicated in Tables I and I--I, the tape adhesion for the first and second films when bonded with commercial diaper tape-tab fasteners 1 and 2 is expressed in percent (~) increase in tape adhesion of a polyethyelene film containing a polypropylene over a similar polyethylene film free of a polypropylene.
The 90 (Method A) and 180 (Method B) tape adhesions are determined as follows. Two 5-inch length and 1-inch width specimens of each commercial diaper tape-tab are applied to each film. Approximately 1 inch at the end of each tape-tab specimen is left free (unbonded). A roller is passed over each applied specimen once in a lengthwise direction. Care is exercised to ensure that no air bubbles are entrapped.
Following adhesion, the tests are conducted immediately. For determining the 90 (Method A) and 180 (Method B) tape adhesions, the free end of each specimen is double backed at an angle of 90 (Method A) or 180 (Method B) and 1 inch of the secured end of each tape-tab specimen is peeled from the film. The peeled end of the tape-tab specimen is then clamped into the lower jaw of the adhesion testing machine manufactured by Instron Corporation and the free end of the tape-tab specimen is changed into the upper jaw. The lower jaw of the testing machine is operated at 12 inches per minute. After the lower jaw is started in motion, the values obtained for the first inch of the tape-tab specimens are disregarded. The average pull value obtained during the peeling of the next 2 inches is used and recorded as the percent increase in tape adhesion of the tape-tab specimens.
The above as well as other suitable test procedures are described in the manual entitled "Test Methods for Pressure Sensitive Tapes", 7th ed., copyright 1976, -published by the Pressure Sensitive Tape Council which is incorporated herein in its entirety by reference.
In addition to the 90 (Method A) and 180 (Method B) angle test procedures for determining tape adhesion, there are other tests to develop the tape adhesion.
For example, as already indicated herein and illustrated in Fig. 3 and Tables III and IV, the tape adhesion can be determined at angles between 90 and 180 (Method C). Two different commerically available tape-tab fasteners are used in this example.
:' ~ 3 1~
Example III
The percent increase in tape adhesion betwen a polyethylene backsheet containing 5% polypropylene and a tape-tab fastener 5 described herein over the tape adhesion between a similar polyethylene backsheet but containing no polypropylene and a similar tape-tab fastener 5 is determined following an or~ginal fastening and four repeated refastenings of the tape-tab fastener 5 to the backsheets. The polyethylene backsheets containing polypropylene are similar to those described and referred to in Example I and Tables III and IV. Under Methods B and C as described herein and referred to in Fig. 4, the tape adhesion is determined. Similar backsheets and tape-tab fasteners 5 are used for both Methods B and C.
Under Method B, Fig. 4 reports that there is approximately a 33% increase in tape adhesion following the original fastening between a polyethylene backsheet containing 5% polypropylene and the tape-tab fastener 5 over the tape adhesion between a polyethylene backsheet free of polypropylene and a similar tape-tab fastener 5. Fig. 4 also demonstrates that there is a further increase in tape adhesion between the polyethylene backsheet containing 5%
polypropylene and the tape-tab fastener 5 over the polyethylene backsheet free of polypropylene and the 1 3 ~ '3 i tape-tab fastener 5 following four repeated refastenings.
Under Method C, Fig. 4 reports that there is approximately a 19~ increase in tape adhesion following the original fastening between a polyethylene backsheet containing 5% polypropylene and the tape-tab fastener 5 over the tape adhesion between a polyethyiene backsheet free of polypropylene and a similar tape-tab fastener 5. Fig. 4 also demonstrates that the percent increase in tape adhesion between the polyethylene backsheet containing 5~ polypropylene and the tape-tab fastener 5 is substantially maintained ~
over the tape adhesion between the polyethylene backsheet free of polypropylene and the tape-tab fastener 5 following four repeated refastenings.
The present invention may, of course, be carried out in other specific ways than those herein set forth without departing from the spirit and essential characteristics of the present invention.
The present embodiments are, therefore, to be considered in all respects as illustrative and not restrictive and any changes coming within the meaning and equivalency range of the appended claims are to be embraced therein.
1~
~ -30-
about 0.75% and about 1.3~ of the weight of the sheet materials, respectively.
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~ 13~3~
As a further feature of the present invention, the tape adhesion between a sheet material having an anti-popoff substance and a tape-tab fastener remains substantially the same even after a repeated number of refastenings. This feature is demonstrated in Fig. 4 wherein the percent increase in tape adhesion between a polyethylene backsheet containing 5% polypropylene and commercial tape-tab fastener 5 remained virtually the same as when compared to the tape adhesion between a similar polyethylene backsheet free of polypropylene and commercial tape-tab fastener 5 after five refastenings.
It should be appreciated, however, that eventhough the tape adhesion between a sheet material of this invention and a tape-tab fastener following a repeated number of fastenings might be less than the original fastening, it is nevertheless believed that such tape adhesion will usually be greater than the adhesion between a sheet material free of an anti-popoff substance and a tape-tab fastener having an equal number of refastenings. Therefore, the term "substantially maintaining tape adhesion" is used herein in a broad sense to refer to not only those instances where the tape adhesion increases or remains substantially the same following repeated fastenings but also to those instances where there is any increase in tape adhesion between the sheet materials ;
1 3 ~ J '~
of the present invention and a tape-tab fastener over the tape adhesion between similar sheet materials free of anti-popoff substances and a tape-tab fastener following refastening.
While the inventors do not wish to be limited to any particular theory in which the tape adhesion is increased and substantially~maintained, they presently believe that the incorporation of a minor amount of an anti-popoff substance into a thermoplastic ethylene-based sheet material interrupts the surface packing of the ethylene polymer, particularly when the ethylene polymer is a polyethylene, resulting in higher surface free-energy associated with the sheet material thus improving the adhesion of pressure-sensitive adhesive fasteners thereto. It is also presently believed that the objectives of this invention can be easily met particularly when the pressure-sensitive adhesive formulation of the selected tape-tab to be used is known by selecting an anti-popoff substance that has a high bonding affinity for the particular pressure-sensitive adhesive. Even when the pressure-sensitive adhesive formulation is unknown, it is still believed that the objectives of this invention can be met by utilizing one of the polymeric substances employed to formulate the backsheet tab of the tape-tab fastener selected as the anti-popoff substance. Generally speaking, a polymeric substance 13.~5~3'~1 commonly utilized to formulate the backsheet tabs of tape-tabs today particularly in the disposable diaper industry is a polypropylene. Since polypropylene generally has a high bonding affinity for the pressure-sensitive adhesives utilized with the tape-tab fasteners and is the commonly employed polyolefin utilized to form the backsheet tabs of the tape-tab fasteners, these factors make polypropylene a preferred anti-popoff substance.
Basically any commercially available pressure-sensitive adhesive tapP-tab fasteners used in disposable diaper construction today are suitable for use with the thermoplastic sheet materials of the present invention. For example, SiY. different commercially available pressure-sensitive adhesive tape-tab fasteners have been utilized herein, and all six have been found to be substantially equally suitable. While the precise formulas of the pressure-sensitive adhesives utilized to form the six different tape-tab fasteners are unknown, it is presently believed that the pressure sensitive adhesive of tape-tab fastener 5 comprises a styrene-isoprene-styrene block copolymer ~ase, an aliphatic mixed olefin tackifying resin and an anti-oxidant. It is also believed that the backsheet tab of tape-tab fastener 5 is formed with a polypropylene. Of course, it should also be appreciated 'hat there are many other commercially 3 ~
available tape-tab fasteners being used by the disposable-diaper manufacturers that have pressure-sensitive adhesive formulations which are different than the pressure-sensitive adhesive formula of tape-tab fastener 5 described above that are also suitable for use with the present invention.
The commercial tape-tab fastener 5 referred to above can be easily prepared by any con~entional means, such as by coating the pressure-sensitive adhesive composition just described onto the face side of a polypropylene-backing tab.
With reference now to Fig. 1, a slot cast film extrusion method for making the thermoplastic sheet materia~s of the present will be described. In this method, the thermoplastic sheet materials are generated simply by blending a selected ethylene polymer with a particular anti-popoff substance in an effective amount and extruding the mixture through a conventional extrusion die adapter 1 and cast film die 2 to form the molten web 3. Molten web 3 is then rolled between a metal roll 4 and a rubber roll 5.
When an embossed film is desired, an embossing section 6 is located on metal roll 4. The sheet materials can be embossed with any suitable design according to any of a number of well-known techniques. For examp~e, embossing can be performed by the introduction of a pre-formed sheet material into a system of embossing rolls or by the introduction of an extruded melt of , the thermoplastic material through a slot-die between embossing rolls. The molten web 3 is then directed onto a chilled metal roll 7 to form the coo~ed extruded film 8 which is then wound onto a storage roll (not shown). While the above describes thermoplastic sheet materials of the present invention being produced by a slot cast film extrusion method, the thermoplastic sheet materials can be produced by blown film extrusion methods as well. These different processes of making and embossing are described in more detail in U.S. Patent Nos. 4,535,021, 4,546,029, 4,376,147 and 3,484,835.
In a further feature O$ the present invention, the thermoplastic sheet materials can be produced by either single extrusion or co-extrusion.
When the sheet materials are produced by slngle extrusion, the anti-popoff substance is generally dispersed throughout the single layer o. the films.
When the sheet materials are co-extruded, the anti-popoff substance can be generally dispersed either throughout each layer or throughout one or more layers of the films. For instance, the anti-popofC
substance can be generally dispersed throughout the 2S top andJor bottom layers of a two layer or the top, bottom and/or middle layers of a three layer co-extruded film. It is necessary, however, to disperse the anti-popoff substance at least throughout 3'~
the layer of the co-extruded sheet material that is to rec~ive the tape-tab fastener thereon.
Although the sheet materials can be formulated by adding the anti-popoff substance directly to the ethylene polymer to form a pre-extrusion mixture, it is found that better results are achieved when the selected ethylene polymer is blended with a concentrate containing,~~inter alia, the anti-popoff substance. The concentrate may also include, for instance, an ethylene polymer carrier, such as a conventional low density polyethylene or a conventional linear low density polyethylene, and titanium dioxide as a whitener. Preferred concentrates are those in which the anti-popoff substance is polypropylene wherein the polypropylene is present in an amount ranging from about 5 to about 50~ by weight of the concentrate. Such preferred concentrates can further include the ethyïene polymer carrier in an amount ranging from about 45% to about 0% and titanium dioxide (TiO2) in an amount of about 50~ by weight. Examples of three formulations of such preferred concentrates suitable for use in accordance with the teachings of the present invention are designated as Concentrates I-IV as follows:
~L3~3'f,l Concentrate I II III IV
polypropylene parts 5 25 45 50 polyethylene parts 45 25 5 0 TiO~ parts 50 50 50 50 Total Parts 100 lOO 100 100 The preferred concentrate should be intimately blended with an ethylene polymer and in particular a polyethylene in an amount ranging from about 8 to about 10 parts concentrate to about 100 parts polyethylene to form the pre-extrusion mixture which can then be extruded as described above to form liquid-pervious or liquid-impervious sheet materials, such as backsheets.
The thermoplastic sheet materials of the present invention are especially suitable for use with absorbent articles, such as disposable diapers, bandages, surgical dressings or drapes and catamenial pads and most particularly with disposable diapers.
When the thermoplastic sheet materials are to be used with the absorbent articles, they can be formulated into thin films that are either liquid-pervious or liquid-impervious, that have either smooth or embossed surfaces and that have either dull or glossy finishes.
The thickness of the film can vary over a wide range.
When the thermoplastic sheet materials are to be formulated into thin films that are to be used as backsheets for absorbent articles, it is preferred, ~ 3 ~
but not necessary, that th~ thin films are moisture-impervious having embossed surfaces and dull finishes. Typically, such thin backsheet films can have a thickness ranglng from about 0.5 mils to about 2.0 mils and preferably about 1.0 mils to about 1.5 mils, but these limitations are not critical. Of course, when selecting a film thickness, the tearing strength of the film should not be ove~looked so that the objectives of the present invention are not defeated.
A typical disposable diaper practicing the objectives of the present invention generally includes a moisture-pervious inner frontsheet, an outer ~acksheet of the present invention which is preferably moisture-impervious, an absorbent material or layer positioned between the outer backsheet and inner frontsheet and tape-tab fasteners secured to the disposable diaper. The moisture-pervious inner frontsheet forms the diaper inside surface for direction toward an infant and the outer backsheet forms a diaper outside surface for direction away from the infant when the disposable diaper is worn by the infant. To secure the tape-tab fasteners to the disposable diaper, the tape-tab fasteners generally speaking have anchoring ends which are secured to the disposable diaper and user ends which have on one side thereof a pressure-sensitive adhesive presenting tacky surfaces facing in the same direction as the diaper ~ 3 ~
inside surface for contact with the backsheet when the diaper is fitted about an infant. Other absorbent articles such as bandages, surqical dressings or drapes and catamenial pads, on the other hand, generally comprise the same three elements as the disposable diaper absent the tape-tab fasteners. As an additional benefit, the anti-popoff technology improves the ability to assemble the components of such absorbent products together, such as the glue, backsheets, etc.
Examples of the increase in tape adhesion between a thermoplastic sheet material of the present invention will now be further illustrated with reference to the following examples.
1 3 ~
Example I
A polyethylene in combination with anti-popoff substances are extruded to form the thermoplastic backsheets having increased tape adhesion for preventing the disposable diaper tape-tab fasteners from popping off the backsheets. For instance, about 5% of a conventional polypropylene and about 95~ of a conventional polyethylene can be blended and extruded into thin films in the range of about 1.0 to about 1.5 mils which can then be used as backsheets. As indicated in Tables III and IV, the tape adhesion dramatically increases with a thermoplastic sheet material having about 5%
polypropylene incorporated therein as when compared to a similar thermoplastic sheet material without polypropylene. It is also believed that any conventional polypropylene, such as shown in Tables I
and II, will have the same effect on increasing the tape adhesion.
More precisely, the amount of anti-popoff substance needed to increase tape adhesion depends of course upon the interaction of the pressure-sensitive adhesive of the tape-tab fasteners and the film.
Another example of an increase in tape adhesion attributed to the use of an anti-popoff substance is described in Example II.
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Example II
The thermoplastic sheet materials and tape adhesions referred to in Tables I and II are prepared and determined as follows.
A first concentrate is prepared which comprises 40 parts of a conventional thermoplstic low density polyethylene, 10 parts of a conventional thermoplastic polypropylene and 50 parts titanium dioxide. Eight parts of the prepared concentrate are intimately blended with 100 parts of a conventional polyethylene to form a first pre-extrusion mixture.
The first pre-extrusion mixture is then extruded in -accordance with the extrusion equipment and procedures described herein to generate a first thin thermoplastic film which comprises by weight about 0.75% polypropylene, about 3.70% titanium dioxide and about 95.55% polyethylene. The first extruded film has a thickness of about 1.5 mils, an embossed surface, a dull finish and is moisture-impervious.
A second concentrate is prepared which comprises 35 parts of a conventional thermoplastic low density polyethylene, 15 parts of a conventional thermoplastic polypropylene and 50 parts titanium dioxide. Nine parts of the prepared concentrate are intimately blended with 100 parts of a conventional polyethylene to form a second pre-extrusion mixture.
The second pre-extrusion mixture is then extruded in accordance with the extrusion equipment and procedures , ,, .. i.. .... . .
13~311 described herein to generate a second, thin thermoplastic film which comprises by weight about 1.3% polypropylene, 4.1~ titanium dioxide and 94.6%
polyethylene. The second extruded film has a thickness of about 1.5 mils, an embossed surface and a dull finish and is moisture-impervious.
As indicated in Tables I and I--I, the tape adhesion for the first and second films when bonded with commercial diaper tape-tab fasteners 1 and 2 is expressed in percent (~) increase in tape adhesion of a polyethyelene film containing a polypropylene over a similar polyethylene film free of a polypropylene.
The 90 (Method A) and 180 (Method B) tape adhesions are determined as follows. Two 5-inch length and 1-inch width specimens of each commercial diaper tape-tab are applied to each film. Approximately 1 inch at the end of each tape-tab specimen is left free (unbonded). A roller is passed over each applied specimen once in a lengthwise direction. Care is exercised to ensure that no air bubbles are entrapped.
Following adhesion, the tests are conducted immediately. For determining the 90 (Method A) and 180 (Method B) tape adhesions, the free end of each specimen is double backed at an angle of 90 (Method A) or 180 (Method B) and 1 inch of the secured end of each tape-tab specimen is peeled from the film. The peeled end of the tape-tab specimen is then clamped into the lower jaw of the adhesion testing machine manufactured by Instron Corporation and the free end of the tape-tab specimen is changed into the upper jaw. The lower jaw of the testing machine is operated at 12 inches per minute. After the lower jaw is started in motion, the values obtained for the first inch of the tape-tab specimens are disregarded. The average pull value obtained during the peeling of the next 2 inches is used and recorded as the percent increase in tape adhesion of the tape-tab specimens.
The above as well as other suitable test procedures are described in the manual entitled "Test Methods for Pressure Sensitive Tapes", 7th ed., copyright 1976, -published by the Pressure Sensitive Tape Council which is incorporated herein in its entirety by reference.
In addition to the 90 (Method A) and 180 (Method B) angle test procedures for determining tape adhesion, there are other tests to develop the tape adhesion.
For example, as already indicated herein and illustrated in Fig. 3 and Tables III and IV, the tape adhesion can be determined at angles between 90 and 180 (Method C). Two different commerically available tape-tab fasteners are used in this example.
:' ~ 3 1~
Example III
The percent increase in tape adhesion betwen a polyethylene backsheet containing 5% polypropylene and a tape-tab fastener 5 described herein over the tape adhesion between a similar polyethylene backsheet but containing no polypropylene and a similar tape-tab fastener 5 is determined following an or~ginal fastening and four repeated refastenings of the tape-tab fastener 5 to the backsheets. The polyethylene backsheets containing polypropylene are similar to those described and referred to in Example I and Tables III and IV. Under Methods B and C as described herein and referred to in Fig. 4, the tape adhesion is determined. Similar backsheets and tape-tab fasteners 5 are used for both Methods B and C.
Under Method B, Fig. 4 reports that there is approximately a 33% increase in tape adhesion following the original fastening between a polyethylene backsheet containing 5% polypropylene and the tape-tab fastener 5 over the tape adhesion between a polyethylene backsheet free of polypropylene and a similar tape-tab fastener 5. Fig. 4 also demonstrates that there is a further increase in tape adhesion between the polyethylene backsheet containing 5%
polypropylene and the tape-tab fastener 5 over the polyethylene backsheet free of polypropylene and the 1 3 ~ '3 i tape-tab fastener 5 following four repeated refastenings.
Under Method C, Fig. 4 reports that there is approximately a 19~ increase in tape adhesion following the original fastening between a polyethylene backsheet containing 5% polypropylene and the tape-tab fastener 5 over the tape adhesion between a polyethyiene backsheet free of polypropylene and a similar tape-tab fastener 5. Fig. 4 also demonstrates that the percent increase in tape adhesion between the polyethylene backsheet containing 5~ polypropylene and the tape-tab fastener 5 is substantially maintained ~
over the tape adhesion between the polyethylene backsheet free of polypropylene and the tape-tab fastener 5 following four repeated refastenings.
The present invention may, of course, be carried out in other specific ways than those herein set forth without departing from the spirit and essential characteristics of the present invention.
The present embodiments are, therefore, to be considered in all respects as illustrative and not restrictive and any changes coming within the meaning and equivalency range of the appended claims are to be embraced therein.
1~
~ -30-
Claims (46)
1. A disposable diaper having an improved backsheet for increasing and substantially maintaining tape adhesion between a tape-tab fastener and the backsheet for permitting the tape-tab fastener to be positioned or repeatedly repositioned thereon, said disposable diaper comprises:
a liquid-pervious frontsheet which forms a diaper inside surface for direction toward an infant when the disposable diaper is worn by the infant;
a tape-tab fastener having an anchoring end and a user end, the anchoring end being secured to said disposable diaper and the user end having on one side thereof a pressure-sensitive adhesive presenting a tacky surface facing in the same direction as the diaper inside surface;
a backsheet which forms a diaper outside surface for direction away from the infant when the disposable diaper is worn by the infant, said backsheet comprises a blend of an ethylene polymer and an anti-popoff polymer in an effective amount for increasing and substantially, maintaining the tape adhesion between said backsheet and said tape-tab fastener when the tacky surface of the user end of said tape-tab fastener is positioned on said backsheet and adhered thereto via the pressure-sensitive adhesive for permitting said tape-tab fastener to be positioned or repeatedly repositioned thereon; and an absorbent layer positioned between said backsheet and said frontsheet.
a liquid-pervious frontsheet which forms a diaper inside surface for direction toward an infant when the disposable diaper is worn by the infant;
a tape-tab fastener having an anchoring end and a user end, the anchoring end being secured to said disposable diaper and the user end having on one side thereof a pressure-sensitive adhesive presenting a tacky surface facing in the same direction as the diaper inside surface;
a backsheet which forms a diaper outside surface for direction away from the infant when the disposable diaper is worn by the infant, said backsheet comprises a blend of an ethylene polymer and an anti-popoff polymer in an effective amount for increasing and substantially, maintaining the tape adhesion between said backsheet and said tape-tab fastener when the tacky surface of the user end of said tape-tab fastener is positioned on said backsheet and adhered thereto via the pressure-sensitive adhesive for permitting said tape-tab fastener to be positioned or repeatedly repositioned thereon; and an absorbent layer positioned between said backsheet and said frontsheet.
2. A disposable diaper of claim 1 wherein said backsheet has a tearing strength which is greater than the tape adhesion between said backsheet and said tape-tab fastener.
3. A disposable diaper of claim 1 wherein the anti-popoff polymer is selected from a group consisting of a polypropylene, an ethylene-propylene copolymer, an alpha-methyl styrene and a styrenic copolymer.
4. A disposable diaper of claim 3 wherein the styrenic polymer is selected from a group consisting of a styrene-butadiene-styrene block copolymer and a styrene-isoprene-styrene block copolymer.
5. A disposable diaper of claim 1 wherein said anti-popoff polymer is present in said backsheet in an amount by weight of from about greater than zero up to about ten percent.
6. A disposable diaper of claim 1 wherein said backsheet is liquid-impervious.
7. A disposable diaper of claim 1 wherein said ethylene polymer is a homopolymer or a copolymer of ethylene.
8. A disposable diaper of claim 1 wherein said ethylene polymer is a polyethylene.
9. A disposable diaper of claim 1 wherein said backsheet further includes titanium dioxide.
10. A disposable diaper of claim 1 wherein said ethylene polymer is a polyethylene and said anti-popoff polymer is selected from a group consisting of a polypropylene, an alpha-methyl styrene, an ethylene-propylene copolymer and a styrenic copolymer.
11. An improved thermoplastic sheet material for increasing and substantially maintaining tape adhesion between a tape fastener and said thermoplastic sheet material for permitting the tape fastener to be positioned or repeatedly repositioned thereon, said thermoplastic sheet material comprises a blend of:
an ethylene polymer; and an anti-popoff polymer in an effective amount for increasing and substantially maintaining tape adhesion between said thermoplastic sheet material and a tape fastener having on one side thereof a pressure-sensitive adhesive for permitting the tape fastener to be positioned or repeatedly repositioned thereon following the original attachment of the tape fastener to said thermoplastic sheet material via the pressure-sensitive adhesive, said thermoplastic sheet material having a tearing strength which is greater than the tape adhesion between said thermoplastic sheet material and the tape fastener.
an ethylene polymer; and an anti-popoff polymer in an effective amount for increasing and substantially maintaining tape adhesion between said thermoplastic sheet material and a tape fastener having on one side thereof a pressure-sensitive adhesive for permitting the tape fastener to be positioned or repeatedly repositioned thereon following the original attachment of the tape fastener to said thermoplastic sheet material via the pressure-sensitive adhesive, said thermoplastic sheet material having a tearing strength which is greater than the tape adhesion between said thermoplastic sheet material and the tape fastener.
12. A thermoplastic sheet material of claim 11 wherein the anti-popoff polymer is selected from a group consisting of a polypropylene, an ethylene-propylene copolymer, an alpha-methyl styrene and a styrenic copolymer.
13. A thermoplastic sheet material of claim 12 wherein the styrenic copolymer is selected from a group consisting of a styrene-butadiene-styrene block copolymer and a styrene-isoprene-styrene block copolymer.
14. A thermoplastic sheet material of claim 11 wherein said anti-popoff polymer is present in said thermoplastic sheet material in an amount by weight of from about greater than zero up to about ten percent.
15. A thermoplastic sheet material of claim 11 wherein said thermoplastic sheet material is liquid-impervious.
16. A thermoplastic sheet material of claim 11 wherein said ethylene polymer is a homopolymer or a copolymer of ethylene.
17. A thermoplastic sheet material of claim 11 wherein said ethylene polymer is a polyethylene.
18. A thermoplastic sheet material of claim 11 wherein said thermoplastic sheet material further includes titanium dioxide.
19. A thermoplastic sheet material of claim 11 wherein said ethylene polymer is a polyethylene and said anti-popoff polymer is selected from a group consisting of a polypropylene, an alpha-methyl styrene, an ethylene-propylene copolymer and a styrenic copolymer.
20. An absorbent article having an improved backsheet for increasing and substantially maintaining tape adhesion between a tape fastener and the backsheet for permitting a tape fastener to be positioned or repeatedly repositioned thereon, said absorbent article comprises:
a liquid-pervious frontsheet which forms an article inside surface for direction toward a person when the absorbent article is worn by the person;
a backsheet which forms an article outside surface for direction away from the person when the absorbent article is worn by the person, said backsheet comprises a blend of an ethylene polymer and an anti-popoff polymer in an effective amount for increasing and substantially maintaining tape adhesion between said backsheet and a tape fastener having on one side thereof a pressure-sensitive adhesive for permitting the tape fastener to be positioned on repeatedly repositioned thereon following the original attachment of the tape fastener to said backsheet via the pressure-sensitive adhesive; and an absorbent layer positioned between said backsheet and said frontsheet.
a liquid-pervious frontsheet which forms an article inside surface for direction toward a person when the absorbent article is worn by the person;
a backsheet which forms an article outside surface for direction away from the person when the absorbent article is worn by the person, said backsheet comprises a blend of an ethylene polymer and an anti-popoff polymer in an effective amount for increasing and substantially maintaining tape adhesion between said backsheet and a tape fastener having on one side thereof a pressure-sensitive adhesive for permitting the tape fastener to be positioned on repeatedly repositioned thereon following the original attachment of the tape fastener to said backsheet via the pressure-sensitive adhesive; and an absorbent layer positioned between said backsheet and said frontsheet.
21. An absorbent article of claim 20 wherein said absorbent article is selected from a group consisting of a disposable diaper, a bandage, a surgical dressing, a surgical drape and a catamenial pad.
22. An absorbent article of claim 20 wherein said backsheet has a tearing strength which is greater than the tape adhesion between said backsheet and the tape fastener.
23. An absorbent article of claim 20 wherein the anti-popoff polymer is selected from a group consisting of a polypropylene, an ethylene-propylene copolymer, an alpha-methyl styrene and a styrenic copolymer.
24. An absorbent article of claim 20 wherein the styrenic polymer is selected from a group consisting of a styrene-butadiene-styrene block copolymer and a styrene-isoprene-styrene block copolymer.
25. An absorbent article of claim 23 wherein said anti-popoff polymer is present in said backing sheet in an amount by weight from about greater than zero to about ten percent.
26. An absorbent article of claim 20 wherein said backsheet is liquid-impervious.
27. An absorbent article of claim 20 wherein said ethylene polymer is a homopolymer or a copolymer of ethylene.
28. An absorbent article of claim 20 wherein said ethylene polymer is a polyethylene.
29. An absorbent article of claim 20 wherein said backsheet further includes titanium dioxide.
30. An absorbent article of claim 20 wherein said ethylene polymer is a polyethylene and said anti-popoff polymer is selected from a group consisting of a polypropylene, an alpha-methyl styrene, an ethylene-propylene copolymer and a styrenic copolymer.
31. A thermoplastic sheet material of claim 11 which is produced by the process which comprises the step of:
extruding a mixture comprising the ethylene polymer and a concentrate containing the anti-popoff polymer to form the thermoplastic sheet material.
extruding a mixture comprising the ethylene polymer and a concentrate containing the anti-popoff polymer to form the thermoplastic sheet material.
32. A thermoplastic sheet material of claim 31 wherein the ethylene polymer is a homopolymer or a copolymer.
33. A thermoplastic sheet material of claim 31 wherein the ethylene polymer is a polyethylene.
34. A thermoplastic sheet material of claim 31 wherein the anti-popoff polymer is a polypropylene present in the concentrate in an amount ranging from about 5 to about 50 percent by volume.
35. A thermoplastic sheet material of claim 31 wherein the concentrate further contains an ethylene polymer carrier.
36. A thermoplastic sheet material of claim 31 wherein the anti-popoff polymer is a polypropylene and the concentrate contains the polypropylene in an amount ranging from about 5 to about 50%, an ethylene polymer carrier in an amount ranging from o to about 45 percent and titanium dioxide in an amount of about 50 percent by weight.
37. A thermoplastic sheet material of claim 36 wherein the mixture comprises the ethylene polymer in an amount ranging from about loo parts and the concentrate in an amount ranging from about 8 to about 10 parts.
38. A thermoplastic sheet material of claim 31 wherein the process further comprises the step of preparing the mixture prior to said extruding.
39. A thermoplastic sheet material of claim 31 wherein the anti-popoff polymer is selected from a group consisting of a polypropylene, an alpha-methyl styrene, an ethylene-propylene copolymer and a styrenic copolymer.
40. A thermoplastic sheet material of claim 39 wherein the styrenic copolymer is selected from a group consisting of a styrene-butadiene-styrene block copolymer and a styrene-isoprene-styrene block copolymer.
41. A thermoplastic sheet material of claim 11 which is produced by the process which comprises the step of:
extruding a mixture comprising the ethylene polymer and the anti-popoff polymer to form the thermoplastic sheet material.
extruding a mixture comprising the ethylene polymer and the anti-popoff polymer to form the thermoplastic sheet material.
42. A thermoplastic sheet material of claim 41 wherein the process further comprises the step of preparing the mixture prior to said extruding.
43. A thermoplastic sheet material of claim 41 wherein the mixture comprises the ethylene polymer in an amount ranging from about 90 parts up to less than about 100 parts and the anti-popoff polymer in an amount ranging from greater than about zero parts up to about 10 parts.
44. A thermoplastic sheet material of claim 41 wherein the anti-popoff polymer is selected from a group consisting of a polypropylene, an alpha-methyl styrene, an ethylene-propylene copolymer and a styrenic copolymer.
45. A thermoplastic sheet material of claim 44 wherein the styrenic copolymer is selected from a group consisting of a styrene-butadiene-styrene block copolymer and a styrene-isoprene-styrene block copolymer.
46. A thermoplastic sheet material of claim 41 wherein the ethylene polymer is a polyethylene.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US3200487A | 1987-03-27 | 1987-03-27 | |
| US032,004 | 1987-03-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1315034C true CA1315034C (en) | 1993-03-23 |
Family
ID=21862593
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000560724A Expired - Fee Related CA1315034C (en) | 1987-03-27 | 1988-03-07 | Thermoplastic sheet material having improved tape adhesion |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0353235A1 (en) |
| AU (1) | AU1499288A (en) |
| CA (1) | CA1315034C (en) |
| WO (1) | WO1988007336A1 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5399177A (en) * | 1991-10-25 | 1995-03-21 | The Procter & Gamble Company | Refastenable adhesive fastening systems for disposable absorbent articles |
| SG64910A1 (en) * | 1992-08-21 | 1999-05-25 | Procter & Gamble | Refastenable adhesive fastening systems for individually packaged disposable absorbent articles |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4296750A (en) * | 1979-06-22 | 1981-10-27 | Kimberly-Clark Corporation | Refastenable pressure-sensitive tape closure system for disposable diapers and method for its manufacture |
| US4662874A (en) * | 1983-08-03 | 1987-05-05 | Johnson & Johnson | Body member conformable disposable articles |
| CA1273189A (en) * | 1984-03-30 | 1990-08-28 | Ralf Korpman | Extruded absorbent article |
| US4655761A (en) * | 1984-08-06 | 1987-04-07 | Kimberly-Clark Corporation | Disposable diaper with refastenable tape system |
-
1988
- 1988-03-03 AU AU14992/88A patent/AU1499288A/en not_active Abandoned
- 1988-03-03 EP EP88903077A patent/EP0353235A1/en not_active Withdrawn
- 1988-03-03 WO PCT/US1988/000760 patent/WO1988007336A1/en not_active Application Discontinuation
- 1988-03-07 CA CA000560724A patent/CA1315034C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| WO1988007336A1 (en) | 1988-10-06 |
| EP0353235A1 (en) | 1990-02-07 |
| AU1499288A (en) | 1988-11-02 |
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