BG37678A3 - Method for preparing tertiary butylalkylethers - Google Patents
Method for preparing tertiary butylalkylethersInfo
- Publication number
- BG37678A3 BG37678A3 BG061013A BG6101383A BG37678A3 BG 37678 A3 BG37678 A3 BG 37678A3 BG 061013 A BG061013 A BG 061013A BG 6101383 A BG6101383 A BG 6101383A BG 37678 A3 BG37678 A3 BG 37678A3
- Authority
- BG
- Bulgaria
- Prior art keywords
- butene
- tertiary butyl
- hydrocarbons
- isobutene
- butyl alkyl
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 abstract 6
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 abstract 6
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 4
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 abstract 3
- -1 butyl alkyl ethers Chemical group 0.000 abstract 3
- IAQRGUVFOMOMEM-ONEGZZNKSA-N trans-but-2-ene Chemical compound C\C=C\C IAQRGUVFOMOMEM-ONEGZZNKSA-N 0.000 abstract 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 230000015572 biosynthetic process Effects 0.000 abstract 2
- 239000002994 raw material Substances 0.000 abstract 2
- 238000003786 synthesis reaction Methods 0.000 abstract 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract 1
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 abstract 1
- 230000002378 acidificating effect Effects 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 238000005194 fractionation Methods 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000003456 ion exchange resin Substances 0.000 abstract 1
- 229920003303 ion-exchange polymer Polymers 0.000 abstract 1
- 238000006317 isomerization reaction Methods 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- 229930195734 saturated hydrocarbon Natural products 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/02—Ethers
- C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
- C07C43/04—Saturated ethers
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/05—Preparation of ethers by addition of compounds to unsaturated compounds
- C07C41/06—Preparation of ethers by addition of compounds to unsaturated compounds by addition of organic compounds only
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Метод за получаване на третични бутилалкилетери от с долу 4-въглеродна суровина, съдържаща понякога с долу 3 и с долу 5 компоненти, от която предварително се отделя бутадиенът, чрез подаване на с долу 4-суровина, пречистена напълно или със следи от бутадиен, към секция за синтез, запълнена с катализатор, представляващ кисела йонообменна смола, по-специално сулфониран съполимер на стирол с дивинилбензол, в която секция изобутенът, съдържащ се в с долу 4-въглеводородната фрак ция, взаимодействува с алифатен алкохол до получаване на третичен бутилалкилетер, който се отделя от останалите с долу 4-въглеводороди, характеризиращ се с това, че останалите с долу 4-въглеводороди се подлагат на фракциониране в два или три стадия, при които се отделят наситените въглеводороди от бутен-1 и бутен-2, и бутен-1 и/или бутен-2 се подлагат на изомеризация, където частично се превръщат в изобутен и се получава една въглеводородна фракция, съдържаща предимно бутен1, бутен-2 и изобутен заедно с тежки продукти и наситени компоненти, която се подава към секцията за синтез на третичен бутилалкилетер. Патентните претенции са формулирани в 4 точки.Method for obtaining tertiary butyl alkyl ethers from a lower 4-carbon raw material, sometimes containing lower 3 and lower 5 components, from which the butadiene is previously separated, by feeding lower 4-raw material, completely purified or with traces of butadiene, to a synthesis section filled with a catalyst representing an acidic ion exchange resin, in particular a sulfonated copolymer of styrene with divinylbenzene, in which section the isobutene contained in the lower 4-hydrocarbon fraction reacts with an aliphatic alcohol to produce a tertiary butyl alkyl ether which is separated from the remaining lower 4-hydrocarbons, characterized in that the remaining lower 4-hydrocarbons are subjected to fractionation in two or three stages, in which the saturated hydrocarbons of butene-1 and butene-2, and butene- 1 and/or butene-2 are subjected to isomerization, where they are partially converted to isobutene and a hydrocarbon fraction containing mainly butene-1, butene-2 and isobutene together with heavy products and saturated components is obtained, which is fed to the synthesis section tertiary butyl alkyl ether. The patent claims are formulated in 4 points.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT21384/82A IT1151183B (en) | 1982-05-20 | 1982-05-20 | PROCEDURE FOR THE PRODUCTION OF TER-BUTYL ALCHYL ETHERS |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BG37678A3 true BG37678A3 (en) | 1985-07-16 |
Family
ID=11180967
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BG061013A BG37678A3 (en) | 1982-05-20 | 1983-05-18 | Method for preparing tertiary butylalkylethers |
Country Status (30)
| Country | Link |
|---|---|
| JP (1) | JPS58210039A (en) |
| KR (1) | KR860001854B1 (en) |
| AU (1) | AU1401783A (en) |
| BE (1) | BE896787A (en) |
| BG (1) | BG37678A3 (en) |
| BR (1) | BR8302433A (en) |
| CA (1) | CA1220230A (en) |
| CH (1) | CH653664A5 (en) |
| DD (1) | DD209803A5 (en) |
| DE (1) | DE3318301A1 (en) |
| DK (1) | DK221683A (en) |
| ES (1) | ES8500206A1 (en) |
| FR (1) | FR2527202B1 (en) |
| GB (1) | GB2121407B (en) |
| GR (1) | GR78857B (en) |
| IN (1) | IN159788B (en) |
| IT (1) | IT1151183B (en) |
| LU (1) | LU84805A1 (en) |
| MW (1) | MW1883A1 (en) |
| NL (1) | NL8301819A (en) |
| NO (1) | NO831759L (en) |
| NZ (1) | NZ204032A (en) |
| PH (1) | PH19481A (en) |
| PL (1) | PL242093A1 (en) |
| PT (1) | PT76730B (en) |
| SE (1) | SE8302577L (en) |
| TR (1) | TR21617A (en) |
| YU (1) | YU110083A (en) |
| ZA (1) | ZA833068B (en) |
| ZW (1) | ZW9783A1 (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4731490A (en) * | 1986-07-23 | 1988-03-15 | Arco Chemical Company | Process for methyl, tertiary butyl ether production |
| FR2614297B1 (en) * | 1987-04-24 | 1989-07-21 | Inst Francais Du Petrole | PROCESS FOR PRODUCING METHYL-TERTIOBUTYL-ETHER FROM N-BUTENES. |
| CA2111018A1 (en) * | 1993-01-06 | 1994-07-07 | Jacob N. Rubin | Integrated mtbe process |
| FR2710907B1 (en) * | 1993-10-08 | 1996-01-05 | Inst Francais Du Petrole | Process for the production of tertiary ethers from a catalytic cracking charge comprising two stages of extractive distillation. |
| IT1270675B (en) | 1994-10-19 | 1997-05-07 | Enichem Spa | PROCEDURE FOR THE SEPARATION OF PARAFFINS IN MIXTURE WITH OLEFINS |
| CN103755512B (en) * | 2013-12-24 | 2016-01-06 | 山东滨州裕华化工厂有限公司 | The technique of liquefied gas separation of C 4 cut after ether |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1224294B (en) * | 1961-01-09 | 1966-09-08 | Bayer Ag | Process for the production of tertiary butyl alkyl ethers |
| FR2455019A1 (en) * | 1979-04-24 | 1980-11-21 | Inst Francais Du Petrole | PROCESS FOR PRODUCING METHYLTERTIOBUTYL ETHER FROM METHANOL AND ISOBUTENE |
| DE2921576A1 (en) * | 1979-05-28 | 1980-12-04 | Davy International Ag | METHOD FOR THE PRODUCTION OF METHYL-TERT.-BUTYLAETHER |
-
1982
- 1982-05-20 IT IT21384/82A patent/IT1151183B/en active
-
1983
- 1983-04-28 GR GR71241A patent/GR78857B/el unknown
- 1983-04-28 NZ NZ204032A patent/NZ204032A/en unknown
- 1983-04-28 AU AU14017/83A patent/AU1401783A/en not_active Abandoned
- 1983-04-29 ZA ZA833068A patent/ZA833068B/en unknown
- 1983-04-29 ZW ZW97/83A patent/ZW9783A1/en unknown
- 1983-05-05 SE SE8302577A patent/SE8302577L/en not_active Application Discontinuation
- 1983-05-05 CH CH2465/83A patent/CH653664A5/en not_active IP Right Cessation
- 1983-05-06 BR BR8302433A patent/BR8302433A/en unknown
- 1983-05-12 GB GB08313098A patent/GB2121407B/en not_active Expired
- 1983-05-13 KR KR1019830002066A patent/KR860001854B1/en active
- 1983-05-13 LU LU84805A patent/LU84805A1/en unknown
- 1983-05-13 MW MW18/83A patent/MW1883A1/en unknown
- 1983-05-17 YU YU01100/83A patent/YU110083A/en unknown
- 1983-05-17 FR FR8308163A patent/FR2527202B1/en not_active Expired
- 1983-05-18 PH PH28926A patent/PH19481A/en unknown
- 1983-05-18 DK DK221683A patent/DK221683A/en not_active Application Discontinuation
- 1983-05-18 TR TR21617A patent/TR21617A/en unknown
- 1983-05-18 BG BG061013A patent/BG37678A3/en unknown
- 1983-05-18 NO NO831759A patent/NO831759L/en unknown
- 1983-05-19 CA CA000428516A patent/CA1220230A/en not_active Expired
- 1983-05-19 BE BE0/210806A patent/BE896787A/en not_active IP Right Cessation
- 1983-05-19 DD DD83251077A patent/DD209803A5/en unknown
- 1983-05-19 DE DE19833318301 patent/DE3318301A1/en not_active Withdrawn
- 1983-05-19 PT PT76730A patent/PT76730B/en unknown
- 1983-05-20 JP JP58087816A patent/JPS58210039A/en active Pending
- 1983-05-20 ES ES523006A patent/ES8500206A1/en not_active Expired
- 1983-05-20 IN IN632/CAL/83A patent/IN159788B/en unknown
- 1983-05-20 PL PL24209383A patent/PL242093A1/en unknown
- 1983-05-20 NL NL8301819A patent/NL8301819A/en not_active Application Discontinuation
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