AU668771B2 - Process for separating hydrocarbon mixtures by extractive distillation - Google Patents
Process for separating hydrocarbon mixtures by extractive distillation Download PDFInfo
- Publication number
- AU668771B2 AU668771B2 AU50718/93A AU5071893A AU668771B2 AU 668771 B2 AU668771 B2 AU 668771B2 AU 50718/93 A AU50718/93 A AU 50718/93A AU 5071893 A AU5071893 A AU 5071893A AU 668771 B2 AU668771 B2 AU 668771B2
- Authority
- AU
- Australia
- Prior art keywords
- solvent
- extractive distillation
- column
- process according
- distillation column
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/34—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping with one or more auxiliary substances
- B01D3/40—Extractive distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/04—Purification; Separation; Use of additives by distillation
- C07C7/05—Purification; Separation; Use of additives by distillation with the aid of auxiliary compounds
- C07C7/08—Purification; Separation; Use of additives by distillation with the aid of auxiliary compounds by extractive distillation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G7/00—Distillation of hydrocarbon oils
- C10G7/08—Azeotropic or extractive distillation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Water Supply & Treatment (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
Description
I'UU/U1l 2B/5/0I Rogulallon 3.2(2)
AUSTRALIA
Patents Act 1990
ORIGINAL
COMPLETE SPECIFICATION STANDARD PATENT Application Number: Lodged: Invention Title: PROCESS FOR SEPARATING HYDROCARBON MIXTURES BY EXTRACTIVE DISTILLATION The following statement is a full description of this invention, including the best method of performing it known to :-US KRUPP KOPPERS GMBH, ALTENDORFER STRASSE 120, 4300 ESSEN 1 Process for separating hydrocarbon mixtures by extractive distillation.
The invention relates to a process for separating hydrocarbon mixtures by extractive distillation with selective solvents or solvent mixtures, in which the feedstock is introduced in the central part of the extractive distillation column and the solvent or solvent mixture uqed is introduced into the upper part, and the lower boiling hydrocarbons of the feedstock in the solvent-hydrocarbon mixture are drawn from the extractive distillation column over the head, while the higher boiling hydrocarbons of the feedstock together with the greater part of the solvent are obtained as the bottom product of the extractive distillation, and the bottom product is transferred from the extractive distillation column into a downstream stripping column in which the hydrocarbons and the solvent are separated from one another by distillation.
S 20 Extractive distillations of .the type mentioned above are now used successfully in a whole series of industrial processes, for example for obtaining pure aromatic compounds or butadiene from feedstocks containing these compounds and for separating butanes and S 25 butenes. The N-substituted morpholines, especially N-formylmorpholine, as well as N-methylpyrrolidone and dimethylformamide, have proved to be particularly successful solvents. However, in all extractive distillation processes the process conditions and the solvent have hitherto been selected so that only one vapour phase and one liquid phase occured in the extractive distillation column. Those skilled in the art always started from the idea that the occurrence of systems with miscibility gaps, in which two liquid phases are formed in the extractive distillation column, must be avoided.
These ideas were chiefly based on the fact that under the 2 cfnditions which have so far been normal -xtractive distillation the presence of a second hydrocarbon-rich liquid phase substantially impairs the separation result or in some cases even makes the separation impossible. The reasons for the poor separation can be found on the one hand in the unfavourable mass transfer conditions, as it is usually much more difficult to establish thermodynamic equilibrium between two liquid phases than between a vapour phase and a liquid phase.
13 On the other hand the thermodynamic conditions for separation are impaired by the appearance of miscibility gaps, for example because of a relatively small change in vapour pressures or the formation of heteroazeotropes.
For the reasons mentioned, solvents which are in fact characterized by a high selectivity, i.e. a great influence on the relative volatility, towards the hydrocarbons to be separated but which form two liquid phases with them under the technically relevant concentration and/or temperature conditions have not so far been used 20 for extractive distillation. Tetramethylsulphone, known under the trivial name of sulfolan, which has only achieved any industrial significance in liquid-liquid extraction, can be cited as an example of this.
The object of the invention is to provide an extractive distillation process for separating hydrocarbon mixtures which is characterized by great economic improvements in areas of application known per se and which makes possible a greater selection of solvents.
The process of the type referred to at the outset 31 which solves this problem is characterized in accordance with the invention by the application of features a) to c) of the main claim.
Rejecting the previous notions of those skilled in the art, the invention starts from the knowledge that solvents which are characterized by a high selectivity for the particular separating task, but which also form 3 li:y gaps with the hydrocarbons in tne :ec s.c.
under the concentration and temperature conditions used in practice, can be used perfectly well in extractive distillation provided that very specific conditions are maintained in the extractive distillation.
The process according to the invention therefore, in particular, permits the use of those solvents which are characterized by a higher selectivity for the particular separating task than the solvents used previously but which have not been used because of the tendency to form miscibility gaps.
However, the process according to the invention also permits the use of those solvents the use of which is already known in extractive distillation for certain separation tasks. In this case it is then possible to work with substantially lower operating temperatures in the extractive distillation than was previously normal.
That is to say, it has been found for many solvents that o the tendency to form miscibility gaps only occurs at 20 relatively low temperatures. If, in spite of this, it is now possible in accordance with the invention to work in this temperature range, then this signifies a not inconsiderable energy saving. In addition to this the selectivity of the solvent for the given separation task increases with falling operating temperature.
When carrying out the process according to the invention the process conditions in the extractive distillation must however be selected so that two liquid phases occur over a considerable part of the total height of the extractive distillation column. Preferably, between 10 and 90% of the column height should lie in the region of two phase formation and only in the remaining lower part of the column should just one homogeneous liquid phase be present.
In addition to this the mass transfer conditions in the extractive distillation column must be configured 4 large exchange areas are present both between the :wo liquid phases and between the liquid phases and the vapour phase. This can be brought about, for example, by providing internal fittings or column packings in the extractive distillation column which ensure the formation of very thin liquid layers. On an industrial scale column packings which are specifically arranged for this purpose, e.g. so-called structured packings such as, for example, so-called Mellapack packings, or expanded metal internal fittings are provided. tis al posible fulfill the required mass transfer conditions b sing column trays designed specifically for t purpose.
These column trays ensure a good dis bution of the liquid phases between one another ith at the same time a high exchange area with t vapour phase. However, when these types of co mn trays are used a certain pressure drop must accepted in the extractive distillation column. inally, there is also the possibility of providin or the necessary mass transfer by mechanical 20 disp sion of the liquid phases and the vapour, e.g.
As the hydraulic conditions in the extractive distillation column, such as layer thickness and mixing of the two liquid phases, play a decisive role when carrying out the process according to the invention, it is advisable that the throughput quantity of feedstock and solvent does not exceed a value of 200 m 3 per m 2 column cross-section and hour. The maximum throughput quantity is particularly dependent on the type of column 30 internal fittings and the viscosity of the solvent. With the separation process and use of structured column packings described here the maximum throughput quantity is approximately 50 m 3 per m 2 column cross-section and hour.
The solvent used in accordance with the invention is characterized by a very high selectivity and a iel V l.w solvent power, so the lower solvent. pcwer results in a greater volatility, even for the components cf the feedstock to be withdrawn from the bottom of the extractive distillation column. In practice the bottom temperature in the extractive distillation column can therefore be set significantly lower than when using solvents with higher solvent powers. This results in a lower heat consumption for the extractive distillation, which also makes it possible to use a lower grade of 13 steam for heating the column system, e.g. low pressure steam instead of medium pressure steam.
The conventional apparatus and plant in general use for extractive distillation can be used for carrying out the process according to the invention. The process procedure for the mode of operation according to the invention is shown in simplified form in the flow diagram shown in the drawing. The hydrocarbon mixture to be separated is introduced in a liquid state through line 1 into the central part of the extractive distillation column 2 which is provided with the internal fittings needed to produce the necessary mass transfer conditions as described in greater detail above. The solvent is introduced through line 3 into the extractive distillation column 2 at the top and flows down over the internal fittings in this column during which it picks up the less volatile hydrocarbons. The more volatile hydrocarbons escape through line 4 at the top of the column and can be condensed in condensation equipment not shown in the flow diagram. The liquid bottom product consists of the solvent and the hydrocarbons dissolved therein, and is withdrawn from the extractive distillation column 2 through line 5 and passes into the stripping column 6 in which the hydrocarbons are separated from the solvent by distillation. The solvent is removed from the column bottom through line 7 and, after appropriate cooling which is generally achieved in an economical inter- -eat system within the plant, passes thru.
line 3 back into the extractive distillation column 2, while the hydrocarbon vapours escape from the stripping column 6 over the head and are transferred for further processing through line 8. Impurities can build up in the solvent in the course of time, so the branch line 9, through which, with valve 10 in the appropriate position, a part quantity of the solvent can pass to the regenerating device 11, is provided in the region of line 7.
The regenerated solvent is then returned through line 12 back into the circuit (line while the impurities removed are withdrawn from the regenerating device through line 13. Finally, line 14 serves for supplying fresh solvent. Naturally, the plant is provided with the necessary auxiliary equipment for carrying out the process according to the invention such as, for example, measuring and control equipment and heat exchangers.
However, as this auxiliary equipment is not directly necessary for describing the process sequence it has not 20 been shown in the drawing.
The process according to the invention can be t used for various separating tasks. For example, the process can be used for obtaining pure aromatic compounds from hydrocarbons containing aromatic compounds.
Sulphones or their mixtures, N-substituted morpholines or their mixtures and, preferably, a mixture of N-formylmorpholine and tetramethylsulphone (sulfolan) can be used here as the solvent. The use of N-substituted morpholines or their mixtures for the separating task 30 mentioned is in fact already known. However, the process according to the invention differs from the previously conventional mode of operation through the use of a lower i solvent feed temperature, lying between 50 and 70'C, in the extractive distillation. In this case the solvent feed temperature is approximately 10 to 30 0 C lower than with the known mode of operation with a homogeneous 7 i hase. A further area of application of t:e crccess according to the invention is the separation of diolefins, olefins and paraffins from hydrocarbon mixtures which contain these compounds and boil in the range between -12 and +50 0 C at normal pressure, using sulphones or their mixtures as the solvent. Finally, the process according to the invention can also be used for the separation of olefins and paraffins from hydrocarbon mixtures which contain these compounds and boil in the range between -12 and +50 0 C at normal pressure, in which N-substituted morpholines or their mixtures can again be used as the solvent. The use of these solvents for this separating task is in fact also already known, but the process according to the invention again differs from the previously normal mode of operation by the use of a lower solvent feed temperature, lying between 40 and 70 0 C, in the extractive distillation. Here again the solvent feed temperature is approximately 10 to 30 0 C lower than with the known mode of operation with a homogeneous liquid 20 phase.
The internal reflux in the extractive distillation column is increased in each case due to the lower solvent feed temperature. In this way the same separation efficiency as before is achieved at a lower 25 solvent:feedstock ratio, while at the same time the S'formation of two liquid phases in the extractive distillation column is achieved.
The effectiveness of the process according to the invention is substantiated by the two comparison trials described below: The first trial (Table 1) relates to the separation of butanes and butenes by extractive distillation, in which a C 4 cut from pyrolysis gasoline, which had previously passed through a butadiene extraction and etherification with methanol to give methyl tertiarybutyl ether with the removal of 2-methylpropene, was used as 3 k In part 1 of this trial a solvent mixture .as used which comprised 50% N-formylmorpholine (NFM) and morpholine as a solubilizer. In part 2, in contrast pure N-formylmorpholine (NFM) was used as the solveit.
The second comparison trial (Table 2) relates to obtaining pure aromatic compounds by extractive distillation from a mixture of pyrolysis gasoline and catalytic reformate. N-formylmorpholine (NFM) was used as the solvent in part 1 of the trial, and tetramethylene- 1D sulphone (sulfolan) in parts 2 and 3. In part 3 the operation was carried out with a lower solvent:feedstock ratio than in part 2. This leads to a lower heat consumption, but at the same time the purity of the benzene obtained drops somewhat lower.
Both comparison trials were carried out in an extractive distillation plant of the type described above in connection with the drawing. In parts 2 and 3 of the trials, in which two liquid phases are formed in the extractive distillation, structured packings made of expanded metal were placed in the extractive distillation column. At the same time the height of the extractive distillation column was reduced by about 30 for parts 2 and 3. In both comparison trials the trial conditions were kept constant over 72 hours. The important trial 25 conditions and separation results are summarized below in Tables 1 and 2.
9 caraticn of butanes and bulenes b:y extractive distillation Solvent 50'- NFM/50%- NFM solubilizer Solvent/feedstock kg/kg 17 17 ED column throughout kg/h cnetainwt.- (solvent free) head of ED column w.
iso-butane 23.72 23.72 n-butane Wt.% 73.32 73.79 1-butene 2.94 2.41 trans-2-butene 0.02 0.054 cis-2-butene wt.*6 0.0005 0.018 -feedstock w.
so-butane wt.*6 6.84 6.84 n-butane wt% 22.44 22.44 1-butene 43.04 43 .04 ::tran-3-2-butene Wt.% 11.97 11.97 cis-2-butene wt.% 15.71 15.71 -bottom of ED column wt.%6 iso-butane wt.-.
n-butane wt.1 1.85 1.67 1-butene wt.% 59.27 59.47 *trans-2-butene Wt.% 22.06 22.04 5cis-2-butene Wt.%6 16.82 16.81 Opertingtemperature ED column bottom 154 97.4 Operating pressure bar 5.9 5.9 10 liquid chase in the ED column 1100 22 Heat consumption rel.
Lo feedstock kcal/kg 1199 563 11 Generation of pure benzene by extractive distillation Solvent NFM sulfolan sulfolan Solvent/feedstock kg/kg 2.5 2.5 2.2 ED column throughout kg/h concentration (solvent free) head of ED column non-aromatics methylcyclohexane benzene feedstock non-aromatics methylcyclohexane benzene bottom of ED column non-aromatics methylcyclohexane benzene wt.% wt.% wt.% wt.% wt.% wt.% ppm ppm wt.% 97.20 97.12 0.54 0.62 2.26 2.26 46.1 46.1 0.3 0.3 53.6 53.6 97.20 0.54 2.26 46.1 0.3 53.6 e 795 94 99.92 99.99 788 99.92 Operating temp.
ED column bottom Operating pressure 156 158 151 bar 2.3 2.3 2.3 s Height of homogeneous liquid phase in the ED column 100 80 Heat consumption rel. kcal/kg 152 133 118 to feedstock 12 -hese trial results show that a significant reduction in heat consumption relative to the feedstock is achieved when using the process according to the invention, the energy consumption being almost halved in comparison trial 1. Added to this is also the reduction in plant costs arising from the reduction in height of the extractive distillation column. The desired objective of improved economy of the extractive distillation is therefore achieved.
e e* o a ee9 8
Claims (8)
1. Process for separating hydrocarbon mixtures by extractive distillation with selective solvents or solvent mixtures, in which the feedstock is introduced in the central part of the extractive distillation column and the solvent or solvent mixture used is introduced into the upper part, and the lower boiling hydrocarbons of tho feedstock in the solvent-hydrocarbon mixture are drawn from the extractive distillation column over the head, while the higher boiling hydrocarbons of the feedstock together with the greater part of the solvent are obtained as the bottom product of the extractive distillation, and the bottom product is transferred from the extractive distillation column into a downstream stripping column in which the hydrocarbons and the solvent are separated from one another by distillation, characterized in that a) solvents are used which are characterized by a high selectivity with respect to the particular separating task and which also form miscibility gaps with the hydrocarbons in the feedstock under the concentration and temperature conditions used, S b) the process conditions in the extractive distillation are selected so that two liquid phases occur over a considerable part of the total height of the extractive distillation column, and the mass transfer conditions in the extractive distillation column are configured so that large exchange areas are present both between the two liquid phases and between the liquid phases and the vapour nase, and d) the necessary mass transfer conditions in the extractive distillation column are ensured by using any sort of packed column and excludes the use of plate columns, and e) the optimum separating performance is achieved by selecting the solvent feed temperature.
2. The process according to claim 1, characterized in that the packed column has a random packing. 14
3. The process according to claim 1, characterized in that the packed column has a structured packing.
4. A process according to any one of claims 1 to 3, characterized in that the operating conditions are adjusted so that between 10 and 90% of the column height of the extractive distillation column lies in the region of the formation of two liquid phases and only in the remaining lower part of the extractive distillation column is one homogeneous liquid phase present. A process according to any one of claims 1 to 4, characterized in that the necessary mass transfer conditions in the extractive distillation column are ensured by placing column packings or internal fittings in the column which either guarantee the formation of very thin liquid layers or in some other way provide for good mixing and distribution of the individual phases. Q S6. A process according to any one of claims 1 to 5 characterized in that the throughput quantity of feedstock and solvent in the extractive distillation column does not exceed the value of 200 m 3 per m 2 column cross-section and hour.
7. A process according to claim 6 characterized in that the throughput quantity of feedstock and solvent in the extractive distillation column does not exceed the value of 50 m 3 per m 2 column cross-section and hour.
8. The use of the process according to claims 1 to 7 for obtaining pure aromatic compounds from hydrocarbon mixtures containing aromatic *©oe "compounds, characterized in that sulphones or their mixtures are used as the solvent. 9 The use of the process according to any one of claims 1 to 7 for obtaining pure aromatic compounds from hydrocarbon mixtures containing aromatic compounds using N-substituted morpholines or their mixtures as the solvent, characterized in that the extractive distllation is carried out at a solvent feed temperature between 50 and 700C. Application of the process according to claims 1 to 7 for obtaining pure aromatic compounds from hydrocarbon mixtures containing aromatic compounds, characterized in that a mixture of N-formylmorpholine and tetramethylenesulphone (sulfolan) is used as the solvent.
11. The use of the process according to any one of claims 1 to 7 for separating diolefins, olefins and paraffins from hydrocarbon mixtures which contain these compounds and boil in the range between -12 and +500C, characterized in that sulphones or their mixtures are used as the solvent.
12. The use of the process according to any one of cle 1 to 7 for separating olefins and paraffins from hydrocarbon mixtures whi lin these compounds and boil in the range between -12 and +50°C using N-substituted morpholines or their mixtures as the solvent, characterized in that the extractive distillation is carried out at a solvent feed temperature between 40 and 700C. DATED this 4th day of March, 1996 KRUPP KOPPERS GmbH WATERMARK PATENT TRADEMARK ATTORNEYS 290 BURWOOD ROAD HAWTHORN VICTORIA 3122 AUSTRALIA AU5071893.WPC[DOC. 006] IAS/JGC:EK 16 Process for separating hydrocarbon mixtures by extractive distillation. In this process solvents are used which are characterized by a high selectivity with respect to the particular separating task and which also form miscibility gaps with the hydrocarbons in the feedstock under the concentration and temperature conditions used. The mass transfer conditions in the extractive distilla- tion column are configured so that large exchange areas are present both between the two liquid phases and between the liquid phases and the vapour phase.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4238716 | 1992-11-17 | ||
DE4238716A DE4238716A1 (en) | 1992-11-17 | 1992-11-17 | Process for the separation of hydrocarbon mixtures by extractive distillation |
Publications (2)
Publication Number | Publication Date |
---|---|
AU5071893A AU5071893A (en) | 1994-06-02 |
AU668771B2 true AU668771B2 (en) | 1996-05-16 |
Family
ID=6473055
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AU50718/93A Ceased AU668771B2 (en) | 1992-11-17 | 1993-11-15 | Process for separating hydrocarbon mixtures by extractive distillation |
Country Status (8)
Country | Link |
---|---|
EP (1) | EP0598254A1 (en) |
JP (1) | JPH06228015A (en) |
KR (1) | KR940011409A (en) |
CN (1) | CN1091413A (en) |
AU (1) | AU668771B2 (en) |
DE (1) | DE4238716A1 (en) |
FI (1) | FI935052A (en) |
NO (1) | NO934100L (en) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1085646C (en) * | 1999-05-28 | 2002-05-29 | 中国石油化工集团公司 | Method for separating arene from hydrocarbons mixture by use of extraction and rectification |
CN1083819C (en) * | 1999-06-11 | 2002-05-01 | 中国石油化工集团公司 | Method for separating arene by using extraction and rectification |
KR100632602B1 (en) * | 2002-03-15 | 2006-10-09 | 에스케이 주식회사 | Non-crosslinked linear medium density polyethylene resin composition for hot water and heating pipes |
DE10217863A1 (en) * | 2002-04-22 | 2003-10-30 | Linde Ag | Process and apparatus for olefin production |
DE10217866A1 (en) * | 2002-04-22 | 2003-11-06 | Linde Ag | Process and apparatus for olefin production |
CN100418938C (en) * | 2005-09-07 | 2008-09-17 | 中国石油化工股份有限公司 | Method for separating product of carbonaceous olefin catalytic cracking |
CN101050159B (en) * | 2007-05-17 | 2010-06-23 | 新疆独山子天利高新技术股份有限公司 | Method for separating butane and butylenes, and dedicated installation |
EP2269728B1 (en) * | 2009-06-09 | 2018-01-31 | Basf Se | Use of ordered packages with one or more accumulation points and one or more separation points |
CN102126913B (en) * | 2010-12-03 | 2013-07-10 | 中国科学院过程工程研究所 | Method for separating indan and tetraline through composite extractive distillation |
CN102795957B (en) * | 2011-05-27 | 2014-12-03 | 中国石油化工股份有限公司 | Method for separating m-ethyltoluene and p-ethyltoluene by extractive distillation |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4053369A (en) * | 1974-05-30 | 1977-10-11 | Phillips Petroleum Company | Extractive distillation |
-
1992
- 1992-11-17 DE DE4238716A patent/DE4238716A1/en not_active Withdrawn
-
1993
- 1993-10-15 CN CN93118949A patent/CN1091413A/en active Pending
- 1993-10-27 EP EP93117377A patent/EP0598254A1/en not_active Ceased
- 1993-11-12 NO NO934100A patent/NO934100L/en unknown
- 1993-11-12 KR KR1019930024018A patent/KR940011409A/en not_active Application Discontinuation
- 1993-11-15 FI FI935052A patent/FI935052A/en unknown
- 1993-11-15 AU AU50718/93A patent/AU668771B2/en not_active Ceased
- 1993-11-16 JP JP5286546A patent/JPH06228015A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4053369A (en) * | 1974-05-30 | 1977-10-11 | Phillips Petroleum Company | Extractive distillation |
Also Published As
Publication number | Publication date |
---|---|
JPH06228015A (en) | 1994-08-16 |
KR940011409A (en) | 1994-06-21 |
FI935052A0 (en) | 1993-11-15 |
FI935052A (en) | 1994-05-18 |
EP0598254A1 (en) | 1994-05-25 |
NO934100L (en) | 1994-05-18 |
NO934100D0 (en) | 1993-11-12 |
DE4238716A1 (en) | 1994-05-19 |
AU5071893A (en) | 1994-06-02 |
CN1091413A (en) | 1994-08-31 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
AU754468B2 (en) | Method for separating a C4 hydrocarbon mixture | |
US5849982A (en) | Recovery of styrene from pyrolysis gasoline by extractive distillation | |
CA2493079C (en) | Continuous method for separating a c4 cut | |
AU2002244706B8 (en) | Method for recovering crude 1,3-butadiene by extractive distillation from a C4 cut | |
SE427457B (en) | PROCEDURE FOR SEPARATING A C? 714 PULVES MIXTURE BY EXTRACTIVE DISTILLATION USING A SELECTIVE SOLVENT | |
US7432411B2 (en) | Continuous method for obtaining butenes from a C4 fraction | |
JPS6051130A (en) | Method of obtaining high purity butene-1 with small energy consumption | |
JPS6230171B2 (en) | ||
US2508723A (en) | Separation of hydrocarbons | |
AU2004259076B2 (en) | Method for the separation of a crude C4 cut | |
AU668771B2 (en) | Process for separating hydrocarbon mixtures by extractive distillation | |
US4419188A (en) | Thermally coupled extractive distillation process | |
US4038156A (en) | Butadiene recovery process | |
US3803258A (en) | Production of pure conjugated c4 and c5 diolefins from hydrocarbon mixtures | |
JPH04295435A (en) | Method of separating aromatic substances from hydrocarbon mixture of arbitrary content of aromatic substances | |
JPH04312536A (en) | Method of separating butane from butene by extractive distillation | |
US4515661A (en) | Process for separating highly pure butene-1 and butene-2 | |
MXPA05000772A (en) | Method for working up crude 1,3-butadiene. | |
US2582443A (en) | Process for separation of hydrocarbons | |
US4097371A (en) | Separation of fluid mixtures | |
JP2013510078A (en) | Method for fractionating C4 fraction by extractive distillation using selective solvent | |
EP0085572B1 (en) | Process for separating hydrocarbon mixtures by extractive distillation | |
JPS6230174B2 (en) | ||
JPS60156623A (en) | Separation of c4-hydrocarbon mixture by extractive distillation | |
WO2011126698A2 (en) | Distillation column pressure control |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
MK14 | Patent ceased section 143(a) (annual fees not paid) or expired |