AU3979095A - Ion-conductive polymers - Google Patents
Ion-conductive polymersInfo
- Publication number
- AU3979095A AU3979095A AU39790/95A AU3979095A AU3979095A AU 3979095 A AU3979095 A AU 3979095A AU 39790/95 A AU39790/95 A AU 39790/95A AU 3979095 A AU3979095 A AU 3979095A AU 3979095 A AU3979095 A AU 3979095A
- Authority
- AU
- Australia
- Prior art keywords
- pct
- integer
- optionally substituted
- substituted phenyl
- ion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 229920001940 conductive polymer Polymers 0.000 title abstract 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 150000002431 hydrogen Chemical class 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 125000002723 alicyclic group Chemical group 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000000304 alkynyl group Chemical group 0.000 abstract 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 abstract 1
- 125000001589 carboacyl group Chemical group 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 1
- 125000002188 cycloheptatrienyl group Chemical group C1(=CC=CC=CC1)* 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical group 0.000 abstract 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/022—Electrolytes; Absorbents
- H01G9/025—Solid electrolytes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
- C08J5/22—Films, membranes or diaphragms
- C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
- C08J5/2218—Synthetic macromolecular compounds
- C08J5/2256—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions other than those involving carbon-to-carbon bonds, e.g. obtained by polycondensation
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
- G01N27/4073—Composition or fabrication of the solid electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
- H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
- H01B1/122—Ionic conductors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0565—Polymeric materials, e.g. gel-type or solid-type
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
- H01M6/181—Cells with non-aqueous electrolyte with solid electrolyte with polymeric electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/1025—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon and oxygen, e.g. polyethers, sulfonated polyetheretherketones [S-PEEK], sulfonated polysaccharides, sulfonated celluloses or sulfonated polyesters
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/1027—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having carbon, oxygen and other atoms, e.g. sulfonated polyethersulfones [S-PES]
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/1034—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having phosphorus, e.g. sulfonated polyphosphazenes [S-PPh]
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/1037—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having silicon, e.g. sulfonated crosslinked polydimethylsiloxanes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1067—Polymeric electrolyte materials characterised by their physical properties, e.g. porosity, ionic conductivity or thickness
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2383/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
- C08J2383/04—Polysiloxanes
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Electrochemistry (AREA)
- Manufacturing & Machinery (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Crystallography & Structural Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Power Engineering (AREA)
- General Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Polymers & Plastics (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Organic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Dispersion Chemistry (AREA)
- Silicon Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
- Secondary Cells (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Abstract
PCT No. PCT/DK95/00484 Sec. 371 Date Jul. 22, 1997 Sec. 102(e) Date Jul. 22, 1997 PCT Filed Nov. 30, 1995 PCT Pub. No. WO96/17359 PCT Pub. Date Jun. 6, 1996Ion-conductive polymers with high ion conductivity and containing covalently bound ion complexes of one of formulas (IA-IC), wherein M+ is H+, Li+, Na+, or K+; m is an integer in the range 0-4; m' is an integer in the rage 0-7; m'' is an integer in the range 0-8; and each R independently is halogen; -CO-O-, -CO-O-, M+, or -SO2-O-, M+; cyano; nitro; C1-5 alkoxy; optionally substituted phenyl or phenoxy; -CONR5R6 or -NR5R6 where R5 and R6 independently are hydrogen, C1-5 alkyl, optionally substituted phenyl, phenylcarbonyl, or C1-6 alkanoyl; -N(R6)-CO-R7 where R7 is hydrogen, C1-5 alkyl, C2-5 alkenyl, C2-5 alkynyl, or optionally substituted phenyl; R7-CO-, R7-O-CO-, or R7-O-CO-O-; cycloheptatrienyl; or one of the groups R is an ion complex of the type la, Ib, or Ic with the proviso that R cannot be a further ion complex of the type Ia, Ib, or Ic; or two groups R bound to two adjacent carbon together form a divalent aliphatic or alicyclic group with 3-8 carbon atoms and having at least 2 C-C double bonds, -CO-O-CO-, -CO-S-CO-, or -CO-N(R7)-CO-; and the free bond "a" either directly or through an intervening group, is bound to the polymer backbone.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DK1370/94 | 1994-12-01 | ||
DK137094 | 1994-12-01 | ||
PCT/DK1995/000484 WO1996017359A1 (en) | 1994-12-01 | 1995-11-30 | Ion-conductive polymers |
Publications (1)
Publication Number | Publication Date |
---|---|
AU3979095A true AU3979095A (en) | 1996-06-19 |
Family
ID=8104115
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AU39790/95A Abandoned AU3979095A (en) | 1994-12-01 | 1995-11-30 | Ion-conductive polymers |
Country Status (10)
Country | Link |
---|---|
US (1) | US5789106A (en) |
EP (1) | EP0795182B1 (en) |
JP (1) | JPH10510090A (en) |
AT (1) | ATE177248T1 (en) |
AU (1) | AU3979095A (en) |
CA (1) | CA2206207C (en) |
DE (1) | DE69508107T2 (en) |
DK (1) | DK0795182T3 (en) |
ES (1) | ES2132739T3 (en) |
WO (1) | WO1996017359A1 (en) |
Families Citing this family (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3724903B2 (en) * | 1996-12-26 | 2005-12-07 | 日立マクセル株式会社 | Ionic conductor and electrochemical device using the same |
AU5320199A (en) * | 1998-07-23 | 2000-02-14 | Massachusetts Institute Of Technology | Block copolymer electrolyte |
WO2000025323A1 (en) * | 1998-10-28 | 2000-05-04 | Kaneka Corporation | Curable composition for solid polymer electrolyte |
DE19851717A1 (en) * | 1998-11-10 | 2000-06-15 | Magna Reflex Holding Gmbh | Electrochromic glass assembly |
EP1107267A4 (en) * | 1999-03-23 | 2006-05-10 | Nisshin Spinning | Electrolyte composition for electric double layer capacitor, solid polymer electrolyte, composition for polarizable electrode, polarizable electrode, and electric double layer capacitor |
CN1249156C (en) * | 1999-03-23 | 2006-04-05 | 日清纺织株式会社 | Electrolyte composition for electric double layer capacitor, solid polymer electrolyte composition for polarizable electrode, polarizable electrode, and electric double layer capacitor |
WO2000056780A1 (en) * | 1999-03-23 | 2000-09-28 | Nisshinbo Industries, Inc. | Polymer, binder resin, composition for ionically conductive polymer electrolyte, and secondary battery |
US6759157B1 (en) * | 1999-06-11 | 2004-07-06 | The Penn State Research Foundation | Proton conducting polymer membranes |
WO2000077874A1 (en) * | 1999-06-11 | 2000-12-21 | The Penn State Research Foundation | Proton conducting polymer membranes |
DE19933024C2 (en) * | 1999-07-15 | 2003-03-13 | Medinnova Ges Med Innovationen | Cationic block copolymers |
JP3656244B2 (en) | 1999-11-29 | 2005-06-08 | 株式会社豊田中央研究所 | High durability solid polymer electrolyte, electrode-electrolyte assembly using the high durability solid polymer electrolyte, and electrochemical device using the electrode-electrolyte assembly |
JP4033595B2 (en) * | 2000-02-02 | 2008-01-16 | 三洋電機株式会社 | Lithium polymer secondary battery |
US6627065B1 (en) | 2000-11-20 | 2003-09-30 | The United States Of America As Represented By The Administrator Of The National Aeronautics & Space Administration | Liquid galvanic coatings for protection of imbedded metals |
US20060130709A1 (en) * | 2000-11-20 | 2006-06-22 | Miksic Boris A | Liquid galvanic coatings for protection of embedded metals |
EP1393394B1 (en) * | 2000-12-29 | 2006-11-22 | The University of Oklahoma | Conductive polyamine-based electrolyte |
AU2003240532A1 (en) * | 2002-06-03 | 2003-12-19 | Parallel Solutions, Inc. | Sulfonated polyphosphazenes, uses thereof, and methods for preparing same |
JP3922162B2 (en) | 2002-11-08 | 2007-05-30 | トヨタ自動車株式会社 | Proton conducting material |
KR100588475B1 (en) | 2004-06-07 | 2006-06-09 | 한국화학연구원 | Solid polymer electrolyte composite using polysiloxane-based compound |
US7582147B1 (en) * | 2004-08-19 | 2009-09-01 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Composite powder particles |
JP4811575B2 (en) * | 2005-02-28 | 2011-11-09 | 信越化学工業株式会社 | Curable resin composition for electrolyte membrane, method for producing electrolyte membrane, and method for producing electrolyte membrane / electrode assembly |
KR100762014B1 (en) * | 2006-07-24 | 2007-10-04 | 제일모직주식회사 | The conductive polymer composition comprising organic ionic salt and opto-electronic device using thereof |
CN103108927B (en) * | 2010-09-24 | 2015-12-16 | 可乐丽股份有限公司 | Thickener and using the polymer transducer of its film as dielectric film, electrode film |
JP5742638B2 (en) * | 2011-09-30 | 2015-07-01 | 日立化成株式会社 | Ionic polymer |
JP5742637B2 (en) * | 2011-09-30 | 2015-07-01 | 日立化成株式会社 | Resin composition for transparent conductive film and transparent conductive film |
US10707531B1 (en) | 2016-09-27 | 2020-07-07 | New Dominion Enterprises Inc. | All-inorganic solvents for electrolytes |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5196484A (en) * | 1986-10-27 | 1993-03-23 | The Secretary Of State For Defence In Her Britannic Majesty's Government Of The United Kingdom Of Great Britain And Northern Ireland | Polymeric ion conductors |
US4882243A (en) * | 1988-11-22 | 1989-11-21 | Polytechnic University | Preparation of metallic cation conducting polymers based on sterically hindered phenols containing polymeric systems |
JPH03115359A (en) * | 1989-09-28 | 1991-05-16 | Toray Dow Corning Silicone Co Ltd | Ionically conductive material and preparation thereof |
IT1236512B (en) * | 1989-10-06 | 1993-03-11 | Eniricerche Spa | POLYEPOXIDE BASED SOLID POLYMER ELECTROLYTE. |
JP2813834B2 (en) * | 1990-05-31 | 1998-10-22 | 第一工業製薬株式会社 | Ion conductive polymer electrolyte |
FR2673769B1 (en) * | 1991-03-07 | 1993-06-18 | Centre Nat Rech Scient | POLYMERIC MATERIALS WITH ION CONDUCTION. |
EP0581296A2 (en) * | 1992-07-30 | 1994-02-02 | Dow Corning Toray Silicone Co., Ltd. | Ionically conductive organosiloxane polymer compositions |
US5665265A (en) * | 1996-09-23 | 1997-09-09 | Motorola, Inc., | Non woven gel electrolyte for electrochemical cells |
US5681357A (en) * | 1996-09-23 | 1997-10-28 | Motorola, Inc. | Gel electrolyte bonded rechargeable electrochemical cell and method of making same |
-
1995
- 1995-11-30 AU AU39790/95A patent/AU3979095A/en not_active Abandoned
- 1995-11-30 AT AT95938374T patent/ATE177248T1/en not_active IP Right Cessation
- 1995-11-30 WO PCT/DK1995/000484 patent/WO1996017359A1/en active IP Right Grant
- 1995-11-30 DE DE69508107T patent/DE69508107T2/en not_active Expired - Fee Related
- 1995-11-30 CA CA002206207A patent/CA2206207C/en not_active Expired - Fee Related
- 1995-11-30 ES ES95938374T patent/ES2132739T3/en not_active Expired - Lifetime
- 1995-11-30 JP JP8518088A patent/JPH10510090A/en not_active Ceased
- 1995-11-30 US US08/849,090 patent/US5789106A/en not_active Expired - Fee Related
- 1995-11-30 DK DK95938374T patent/DK0795182T3/en active
- 1995-11-30 EP EP95938374A patent/EP0795182B1/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
US5789106A (en) | 1998-08-04 |
WO1996017359A1 (en) | 1996-06-06 |
DE69508107D1 (en) | 1999-04-08 |
CA2206207C (en) | 2001-07-17 |
DK0795182T3 (en) | 1999-10-04 |
ES2132739T3 (en) | 1999-08-16 |
JPH10510090A (en) | 1998-09-29 |
EP0795182B1 (en) | 1999-03-03 |
ATE177248T1 (en) | 1999-03-15 |
CA2206207A1 (en) | 1996-06-06 |
EP0795182A1 (en) | 1997-09-17 |
DE69508107T2 (en) | 1999-10-28 |
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