Chemistry:Rhodolite

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Short description: Rose-colored gemstone of the garnet group
Rhodolite
Rhodolite in Matrix-Garnet Group Magnesium iron aluminum silicate Macon County North Carolina 2904.jpg
General
CategoryPyrope variety, nesosilicate
Formula
(repeating unit)
(Mg,Fe)3Al2(SiO4)3
Crystal systemCubic
Identification
Colorlight to dark purplish red through reddish purple
Cleavagenone, may show indistinct parting
Fractureconchoidal
Mohs scale hardness7.0–7.5
|re|er}}greasy to vitreous
Specific gravity3.84±0.10
Polish lustervitreous
Optical propertiesSingle refractive, often anomalous double refractive
Refractive index1.760+0.010
−0.020
Birefringencenone
Pleochroismnone
Dispersion0.026
Ultraviolet fluorescenceinert
Absorption spectrausually at 504, 520, and 573 nm, may also have faint lines at 423, 460, 610, and 680–690 nm
References[1]

Rhodolite is a varietal name for rose-pink to red mineral pyrope, a species in the garnet group. It was first described from Cowee Valley, Macon County, North Carolina.[2] The name is derived from the Greek "rhodon" for "rose-like", in common with other pink mineral types (such as rhodochrosite, rhodonite). This coloration, and the commonly inclusion-free nature of garnet from this locality, has led to rhodolite being used as a gemstone. Rhodolite like other varietal names is not officially recognized as a mineralogical term, but rather used as an accepted trade name.[3][4]

Gemmological properties

Mineralogically and chemically, rhodolite garnets are members of the pyrope–almandine solid-solution series, with an approximate bulk garnet composition of Py70Al30.[1]

Rhodolites from different occurrences around the world have been characterized by crystal chemical and absorption spectral analysis showing that besides iron such elements as manganese, chromium and vanadium may effect the colour of rhodolites.[3][4]

Rhodolite garnets appear as transparent red-pink-purplish gemstones, including all the different colour shades between violet and red. The colors from different rhodolite sources may vary from a lavender pink to raspberry rose or raspberry red and from purplish-violet (grape) to purplish red.[5]

The color of rhodolites, combined with their brilliance, durability, and the accessibility of stones with no visible inclusions have brought about some demand for the stone in the jewelry industry. Rhodolites used in jewelry are generally faceted to make good use of their brilliance, though they also exist in cabochon form.[citation needed]

Some rhodolites will change color from purplish to a hessonite brown when heated to a temperature of 600 °C (1,100 °F). This process cannot be reversed.[6]

Natural sources

Many deposits of economic importance are found in countries that belong to the geological unit of the so called “Mozambique belt”, such as Kenya, Madagascar , Malawi, Mozambique, Tanzania, etc. Other sources of rhodolites are in Brazil , India (Odisha), Norway , United States and Sri Lanka.[2][3][4][6]

References

  1. 1.0 1.1 Gem Reference Guide. [Santa Monica, CA]: Gemological Institute of America, 1988. ISBN:0-87311-019-6.
  2. 2.0 2.1 Rhodolite on mindat.org
  3. 3.0 3.1 3.2 Lind, Thomas; Henn, Ulrich; Milisenda, Claudio C. (1998). "Comparative investigation of rhodolite garnets from different provenances". Gemmologie (Journal of the German Gemmological Association) 47 (1): 53–59. ISSN 0948-7395. 
  4. 4.0 4.1 4.2 Lind, Thomas (2015). "Crystal chemistry and colour of garnets of commercially relevant gemstone occurrences". Gemmologie (Journal of the German Gemmological Association) 64 (1–2): 1–41. ISSN 0948-7395. 
  5. "Rhodolite". https://www.lindgranat.com/rhodolite. 
  6. 6.0 6.1 "Rhodolite on Gemdat.org". https://www.gemdat.org/gem-6719.html.