Armstrong's mixture is a highly shock and friction sensitive[1] explosive. Formulations vary, but one consists of 67% potassium chlorate, 27% red phosphorus, 3% sulfur, and 3% calcium carbonate.[2][3] It is named for Sir William Armstrong, who invented it sometime prior to 1872 for use in explosive shells.[4][additional citation(s) needed]
Toys
editArmstrong's mixture can be used as ammunition for toy cap guns. The mixture is suspended in water with some gum arabic or similar binder and deposited in drops, each containing a few milligrams of explosive, to dry between layers of paper backing. The dots explode with some smoke when struck.[2]
Armstrong's mixture can be used in impact firecrackers known as cap torpedoes, which explode on impact when the ball (made of clay or papier-mâché) is thrown or (with some types) launched by slingshot. The firecrackers may include gravel with the explosive mixture to ensure enough friction is generated to produce a detonation.[3]
Military use
editWith the addition of a grit such as boron carbide (in a modified formulation given as 70% KClO3, 19% red phosphorus, 3% sulfur, 3% chalk, and 5% boron carbide by weight), Armstrong's mixture has been considered for use in firearm primers.[5] This use as primer for artillery propellants may have been Armstrong's original purpose.[6]
It also was seen in various patents for matches, novelty fireworks, and signalling devices.[6]
Armstrong's mixture has been used in thrown impact-detonated improvised explosive devices, made simply by loading it into hollow balls.[1][better source needed]
Safety
editArmstrong's mixture is both very sensitive and very explosive, a dangerous combination that limits its practical use to toy caps.[7] Such toy caps and fireworks typically contain no more than 10 milligrams each, but gram quantities can cause maiming hand injuries.[8][better source needed]
The mixture is likely to explode if mixed dry and is even dangerous wet. If the pH is not made neutral, phosphoric acids that may have been generated by oxidized phosphorus on contact with the water could cause it to deteriorate while slowly drying. Generally the wet slurry or paste is loaded into the final casing while wet and was heat-dried in rotating drums prior to being coated with water glass to securely protect them from leakage when globe torpedos were still in production commercially.[9][3][7]
Simple mixtures of red phosphorus and potassium chlorate can detonate at a wide range of proportions; a 20% phosphorus mixture had 27% of the equivalent power of a like mass of TNT in a laboratory experiment, and the detonation of the 10% and 20% phosphorus mixtures even in small unconfined samples of 1 gram was described by the authors of one study as "impressive" and "scary".[7]
Pyrotechnician John Donner wrote in 1996 that it "is the most hazardous mixture commonly used in small fireworks."[3]
Davis Tenney called it "a combination which is the most sensitive, dangerous, and unpredictable of the many with which the pyrotechnist has to deal. Their preparation ought under no conditions to be attempted by an amateur."[9]
Toy charges, such as the several-milligram dots used for cap guns, are individually harmless but potentially dangerous in large numbers.[2] On May 14, 1878, such an accident occurred in Paris. A store containing some six to eight million paper caps, totaling about 64 kilograms of explosive mass, caught fire and exploded, killing 14 and injuring 16 more.[6]
References
edit- ^ a b Laska, Paul R. (10 August 2015). Bombs, IEDs, and Explosives: Identification, Investigation, and Disposal Techniques. CRC Press. ISBN 9781498714501.
- ^ a b c J. B. Calvert. "Flash! Bang! Whiz!: An introduction to propellants, explosives, pyrotechnics and fireworks". Archived from the original on 15 November 2006. Retrieved 2006-11-11.
- ^ a b c d John Donner. "Impact Firecrackers" (PDF). p. 13. Archived from the original (PDF) on 2007-01-07. Retrieved 2006-11-11.
- ^ Wagner, Johannes Rudolf (1872). A Handbook of Chemical Technology. J. & A. Churchill. p. 546.
- ^ US patent 3973502, Charles R Olsen, "Tube primer", issued 1976-08-10
- ^ a b c Haarmann, Donald J. (1985). "Ask The Wiz". American Fireworks News (51). Archived from the original on 2001-02-16.
- ^ a b c Kosanke, B. J.; Kosanke, K. L. (1996). "Explosive Limit of Armstrong's Mixture" (PDF). American Fireworks News (177). Archived (PDF) from the original on 2019-07-10. Retrieved 2022-12-04.
- ^ "The powerful, unstable explosive found in children's toys". Gizmodo. 2013-04-09. Archived from the original on 2021-06-20. Retrieved 2022-12-04.
- ^ a b Davis, Tenney L. Chemistry of Powder and Explosives. pp. 105–106.