allylic


Also found in: Thesaurus, Medical.
Related to allylic: Allylic substitution

al·lyl

 (ăl′əl)
n.
The univalent, unsaturated organic group C3H5.
[Latin allium, garlic; see allium + -yl (so called because it was first obtained from garlic).]
al·lyl′ic (ə-lĭl′ĭk) adj.
American Heritage® Dictionary of the English Language, Fifth Edition. Copyright © 2016 by Houghton Mifflin Harcourt Publishing Company. Published by Houghton Mifflin Harcourt Publishing Company. All rights reserved.

allylic

(ˈælɪlɪk)
adj
characteristic of or involving an allyl
Collins English Dictionary – Complete and Unabridged, 12th Edition 2014 © HarperCollins Publishers 1991, 1994, 1998, 2000, 2003, 2006, 2007, 2009, 2011, 2014
ThesaurusAntonymsRelated WordsSynonymsLegend:
Adj.1.allylic - of or pertaining to the allyl radical
chemical science, chemistry - the science of matter; the branch of the natural sciences dealing with the composition of substances and their properties and reactions
Based on WordNet 3.0, Farlex clipart collection. © 2003-2012 Princeton University, Farlex Inc.
References in periodicals archive ?
As suitable modifiers triallyl cyanurate (TAC) with three allylic groups and divinylbenzene (DVB) with two vinyl groups were used to induce long-chain branching or crosslinking on PHB.
Thermal and Rheological Properties of Modified Polyhydroxybutyrate (PHB)
The prospect of an allylic resonance of the vinyl groups (OL 1170) with silicon d orbitals may play a role in its enhanced reactivity.
Novel POSS coagent additives for HNBRs
DORMAN & DEANS (2000) also detailed that an allylic side chain seem to enhance the inhibitory effects of the component, especially against Gram-negative bacteria and also compounds with isopropyl cyclohexane rings or unsaturation on the cyclohexane ring increase the antibacterial activity, such as sabinene.
Edible active coatings incorporated with Cinnamomum cassia and Myristica fragrans essential oils to improve shelf-life of minimally processed apples/ Revestimentos comestiveis ativos contendo oleos essenciais de Cinnamomum cassia e Myristica fragrans para aumentar a vida util de macas minimamente processadas
The signals at 1.99 ppm and 2.73 ppm correspond to the allylic protons (-C[H.sub.2]-CH=CH-) and internal allylic protons (-CH=CH-C[H.sub.2]-CH=CH-), respectively.
Evaluation of the Properties of Calotropis procera Oil Aiming the Production of Biodiesel
The Baylis-Hillman (BH) reaction is an important carbon-carbon bond forming synthetic transformation that provides highly substituted allylic alcohols and amines in one step [12-16].
Synthesis and Evaluation of Baylis-Hillman Reaction Derived Imidazole and Triazole Cinnamates as Antifungal Agents
[54] concluded that at high temperatures this olefinic fuel reacts rapidly, similar to related alkane fuels, but the pronounced thermal stability of the allylic pentenyl species inhibits low-temperature reactivity; so 2-methyl-2-butene does not produce cool flames or negative temperature coefficient (NTC) behavior as shown in Figure 5.
Review of Oxidation of Gasoline Surrogates and Its Components
Yamada, "A highly active and reusable self-assembled poly (imidazole/palladium) catalyst: allylic arylation/alkenylation," Angewandte Chemie International Edition, vol.
Coordination Behavior of [Ni.sup.2+], [Cu.sup.2+], and [Zn.sup.2+] in Tetrahedral 1-Methylimidazole Complexes: A DFT/CSD Study
The modification of jojoba removes reactive allylic and bis allylic protons which causes oxidation reactions to occur.
Physical Characteristics of Tetrahydroxy and Acylated Derivatives of Jojoba Liquid Wax in Lubricant Applications
In general, the hydrogen atoms of both the allylic and the bisallylic positions are the starting points for the oxidative degradation of biodiesel [14, 15].
Biodiesel from "Morelos" Rice: Synthesis, Oxidative Stability, and Corrosivity
Antioxidants are phenolic compounds which promote the removal or inactivation of free radicals produced, during the initiation and propagation reactions, through the donation of active hydrogen atoms which are removed by free radical more easily than the allylic protons of unsaturated molecules.
Modelling of relative protection factor of antioxidants TBHQ, BHT and BHA in mixture with biodiesel/Modelagem do fator de protecao relativo dos antioxidantes TBHQ, BHT e BHA em mistura com biodiesel
Dictionary browser ?
Full browser ?