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    Iron Iron Carbide Phase Diagram

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    Iron Iron Carbide Phase Diagram

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    272 views5 pages

    Iron Iron Carbide Phase Diagram

    Uploaded by

    ansari_muqueet16898

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 5

    fe3cdiagram

    Page 1 of 5

    Iron-Iron Carbide Diagram

    Figure 1. Iron-ironcarbide diagram

    CEMENTITE (Fe C):


    3 Cementite is also known as iron carbide which has a chemical formula, Fe3C. It contains 6.67 % Carbon by weight. It is a typical hard and brittle interstitial compound of low tensile strength (approximately 5,000 psi) but high compressive strength. Its crystal structure is orthorhombic.

    AUSTENITE ( iron):
    It is also known as ( ) gamma-iron, which is an interstitial solid

    https://info.lu.farmingdale.edu/depts/met/met205/fe3cdiagram.html

    07-Oct-08

    fe3cdiagram

    Page 2 of 5

    solution of carbon dissolved in iron with a face centered cubic crystal (F.C.C) structure. Average properties of austenite are:

    Tensile strength Elongation Hardness Toughness

    150,000 psi. 10 % in 2 in gage length. Rockwell C 40 High

    Table 1. Properties of Austenite

    Figure 2. Austenite (gamma iron) crystal structure Austenite is normally unstable at room temperature. Under certain conditions it is possible to obtain austenite at room temperature.

    FERRITE ( iron):
    It is also known as ( ) alpha -iron, which is an interstitial solid solution of a small amount of carbon dissolved in iron with a Body Centered Cubic (B.C.C.) crystal structure. It is the softest structure

    https://info.lu.farmingdale.edu/depts/met/met205/fe3cdiagram.html

    07-Oct-08

    fe3cdiagram

    Page 3 of 5

    on the iron-iron carbide diagram. Average properties are:

    Tensile Strength Elongation Hardness Toughness

    40,000 psi 40 % in 2 in gage length Less than Rockwell C 0 or less than Rockwell B 90. Low

    Table 2. Properties of Ferrite.

    Figure 2. Ferrite (alpha iron) crystal structure

    PEARLITE ( + Fe C)
    3 It is the eutectoid mixture containing 0.83 % Carbon and is formed at 1333oF on very slow cooling. It is very fine platelike or lamellar mixture of ferrite and cementite. The structure of pearlite includes a white matrix (ferritic background) which includes thin plates of cementite. Average properties are:

    Tensile Strength Elongation

    120,000 psi 20 % in 2 in gage length

    https://info.lu.farmingdale.edu/depts/met/met205/fe3cdiagram.html

    07-Oct-08

    fe3cdiagram

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    Hardness

    Rockwell C 20 or BHN 250300 Table 3. Properties of pearlite.

    Figure 3. Pearlite microstructure (Light background is the ferrite matrix, dark lines are the cementite network) A fixed amount of carbon and a fixed amount of iron are needed to form cementite (Fe3C). Also, pearlite needs fixed amounts of cementite and ferrite. If there is not enough carbon, that is less than 0.83 %, the carbon and the iron will combine to form Fe3C until all the carbon is consumed. This cementite will combine with the required amount of ferrite to form pearlite. The remaining amount of ferrite will stay in the structure as free ferrite. Free ferrite is also known as proeutectoid ferrite. The steel that contains proeutectoid ferrite is referred to as hypoeutectoid steel. If, however, there is an excess of carbon above 0.83 % in the austenite, pearlite will form, and the excess carbon above 0.83 % will form cementite. The excess cementite deposits in the grain boundaries. This excess cementite is also known as proeutectoid cementite.

    LEDEBURITE ( + Fe C)
    3 It is the eutectic mixture of austenite and cementite. It contains 4.3 % Carbon and represents the eutectic of cast iron. Ledeburite exists

    https://info.lu.farmingdale.edu/depts/met/met205/fe3cdiagram.html

    07-Oct-08

    fe3cdiagram

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    when the carbon content is greater than 2 %, which represents the dividing line on the equilibrium diagram between steel and cast iron.

    ( ) DELTA IRON:
    Delta iron exists between 2552 and 2802 oF. It may exist in combination with the melt to about 0.50 % Carbon, in combination with austenite to about 0.18 % Carbon and in a single phase state out to about 0.10 % carbon. Delta iron has the Body Centered Cubic (B.C.C) crystal structure and is magnetic.

    Back to Table of Contents


    Last Update: October 16, 1999 By: Serdar Z. Elgun

    https://info.lu.farmingdale.edu/depts/met/met205/fe3cdiagram.html

    07-Oct-08

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