Search Results (18,000)

Lighting is a fundamental driver of plant productivity in controlled-environment agriculture (CEA), directly affecting physiological processes, resource efficiency, and sustainability. This study evaluates the effects of distinct lighting systems, industrial Light-Emitting Diodes (iLEDs), horticultural LEDs (hLEDs), high-pressure sodium (HPS) lamps, and controls (no supplemental light), each providing unique light spectra, on cucumber (Cucumis sativus L.) growth, physiology, and environmental impact under a controlled light intensity of 250 µmol m⁻² s⁻¹ in a commercial CEA setup. The results indicated that iLEDs enhance intrinsic water use efficiency (35.65 µmol CO₂/mol H₂O) and reduce transpiration, reflecting superior physiological resource use. Electrophysiological measurements indicated significantly more stable stress responses in plants subjected to iLEDs and hLEDs as compared to HPS and control treatments, indicating the effectiveness of LED light spectra in mitigating stress-related physiological impacts. Furthermore, compact growth and shorter stem internodes were observed under iLEDs as well as hLEDs, highlighting the spectral effects on photomorphogenesis, likely caused by a balanced light spectrum. HPS lighting achieved the highest yield (42.86 kg m⁻²) but at a significant environmental cost, with 342.65 kg CO₂e m⁻² emissions compared to 204.29 kg CO₂e m⁻² for iLEDs, with competitive yield of 38.84 kg m⁻². Economic analysis revealed that iLEDs also offered the most cost-effective solution due to lower energy consumption and extended lifespan. This study focused on the interaction between light spectra, photosynthetic performance, stress resilience, and resource efficiency, advancing sustainable strategies for energy-efficient food production in CEA systems. Full article

In this research, a tungsten oxide was prepared via a green (biogenic) synthesis route where sodium tungstate dihydrate and Punica granatum peel extract were used as a precursor and a reducing/capping agent, respectively. The characterization of the prepared tungsten oxide was performed through various spectroscopic and microscopic techniques. The characterization results revealed the preparation of highly crystalline and nanorod-shaped (length = 123 nm and width = 31.3 nm) tungsten oxide with a probable chemical formula of W₅O₁₄. Various functional groups on the W₅O₁₄ surface were also reported. The prepared nanorods were further used for the removal of Bismarck Brown R (BBR) dye from water in a batch manner. By varying the dose of nanorods (0.5–3.0 g L⁻¹), BBR solution pH (2−10), contact time (15–120 min), BBR concentration in solution (10–60 mg L⁻¹), and temperature of BBR solution (30, 40, and 50 °C), the optimized condition for maximum adsorption efficiency was measured. The results revealed that 2.0 g L⁻¹ amount of nanorods of tungsten oxide were used to remove ~98% of BBR dye from its 10 mg L⁻¹ at 30 °C and 7.0 pH. The temperature-dependent adsorption data were fitted to different types of non-linear isotherm models (e.g., Langmuir and Freundlich) to assess the adsorption potential and adsorption mechanisms in relation to temperature impacts. The synthesized nano-adsorbent fits the Langmuir as well as the Freundlich isotherm model with a maximum adsorption capacity of 17.84 mg g⁻¹. Pseudo-first-order, pseudo-second-order, and Elovich kinetic models were used for the study of adsorption kinetics. BBR adsorption onto the W₅O₁₄ nanorods follows the pseudo-second-order rates. The present adsorption is governed by physico-chemical adsorption with predominant chemical interactions. Full article

Zr-containing silica residue (ZSR) is an industrial by-product of ZrOCl₂ production obtained through an alkali fusion process using zircon sand. In this study, low-cost and efficient Zr-doped mesoporous silica adsorption materials (Zr-MCM-41 and Zr-SBA-15) were prepared in one step via the hydrothermal synthesis method using ZSR as the silicon source for the removal of methylene blue (MB) from dye-contaminated wastewater. The samples were characterized using X-ray fluorescence (XRF) spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared (FT-IR) spectroscopy, thermogravimetry (TG), and N₂ adsorption–desorption measurements. The findings indicate that the synthesized Zr-MCM-41 and Zr-SBA-15 possess highly ordered mesoscopic structures with high specific surface areas of 910 and 846 m²/g, large pore volumes of 1.098 and 1.154 cm³/g, and average pore diameters of 4.18 and 5.35 nm, respectively. The results of the adsorption experiments show that the adsorbent has better adsorption properties under alkaline conditions. The adsorption process obeys the pseudo-quadratic kinetic model and the Freundlich adsorption isotherm model, indicating the coexistence of physical and chemisorption processes. The maximum adsorption capacities of Zr-MCM-41 and Zr-SBA-15 are 618.43 and 516.58 mg/g, respectively, as calculated by the Langmuir model (pH = 9, temperature of 25 °C). Compared with mesoporous silica prepared with sodium silicate as the silicon source, Zr-MCM-41 and Zr-SBA-15 have different structural properties and better adsorption properties due to Zr doping. These findings indicate that ZSR is the preferred silicon source for preparing mesoporous silica, and the mesoporous silica prepared using Zr silicon slag is a promising adsorbent and has great application potential in wastewater treatment. Full article

This article systematically investigated the improvement effect of polypropylene fiber (PPF) on the mechanical and freeze–thaw properties of alkali-activated fly ash slag concrete (AAFSC) with high fly ash content and cured at room temperature. Fly ash and slag were used as precursors, with fly ash accounting for 80% of the total mass. A mixed solution of sodium hydroxide and sodium silicate was used as alkali activator, and short-cut PPF was added to improve the performance of AAFSC. Firstly, the strength characteristics of AAFSC at different curing ages were studied. Then, key indicators such as morphology, residual compressive strength, weight loss, relative dynamic modulus of elasticity (RDME), and pore characteristics of AAFSC after different freeze–thaw cycles were tested and analyzed. The strength performance analysis showed that the optimal dosage of PPF was 0.90%. When the alkali equivalent of the alkali activator was increased from 4% to 6%, the frost resistance of AAFSC could be improved. Furthermore, adding 0.90% PPF could increase the freeze–thaw cycle number of AAFSC by about 50 times (measured by RDME). With the increase in freeze–thaw cycles, the porosity of AAFSC increased, the fractal dimension decreased, and the proportion of harmless and less harmful pores decreased, while the proportion of harmful and multiple harmful pores increased. The relationship model between the porosity and compressive strength of AAFSC after freeze–thaw cycles was established. Full article

The goal of this meta-analysis was to (i) identify any potential differences in the apparent and true digestibility, renal excretion, and retention between ponies and horses and (ii) examine the impact of work on these parameters. Additionally, the study aimed to (iii) evaluate the effects of water deficiency. This meta-analysis used data from 33 studies and plotted them in diagrams similar to the Lucas test against mineral intake. Three studies involved ponies that were later diagnosed with pituitary pars intermedia dysfunction (PPID). These were compared with other data to identify quantitative differences, as they may have clinical significance. If any significant difference was observed, the data were not used for the evaluation of the aforementioned goals. Data were compared within certain intake ranges using t-tests and ANOVA, followed by Holm–Sidak post hoc tests. Working equines showed significantly higher apparent and true Na digestibility and lower endogenous faecal Na losses compared to non-working ponies and horses, suggesting a rather important role of the gastrointestinal tract in the regulation of Na metabolism in equines. The true K digestibility was also significantly higher in working animals than in non-working ones, but the differences were quantitatively smaller than for Na. Retention plus sweat losses for Na, K and Cl were higher in working animals compared to equines in maintenance. Horses showed higher Na and K retention plus sweat losses compared to ponies. These effects are likely attributable to greater sweat losses in working equines, particularly horses. The apparent and true Cl digestibility was significantly higher in ponies than in horses. A clinical relevance of this observation is rather unlikely, as the digestibility remained very high in both. Water deprivation influenced serum Cl levels and increased renal K excretion, which subsequently led to reduced K retention. Compared to other animal species, no effects on blood K levels or Na metabolism were observed. The ponies diagnosed with PPID exhibited a significantly lower apparent K digestibility compared to healthy animals, which could be an important factor to consider when feeding soaked hay, due to potential electrolyte losses during soaking. Full article

Ultrahigh-molecular-weight-polyethylene (UHMWPE) is extensively applied to make bone and cartilage implants in the field of biomaterial application. UHMWPE matched with a metal or ceramic component withstands the long-term effect of cyclic stress, which induces UHMWPE serious wear, and affects the service life of the artificial joint. This investigation focuses on the influence of pores on the mechanical and tribological property of UHMWPE. The porosity, crystallinity, yield strength, tensile strength, hardness, compression yield strength, creep resistance, wettability, friction performance, and wear mechanism of solid and porous UHMWPE were evaluated and compared. The research results indicated that the pore had a remarkable influence on the mechanical, friction, and wear property of UHMWPE. The porosity of porous UHMWPE was 29.7% when 50 wt. % sodium chloride (NaCl) was added and the pore size was about 200 μm. The crystallinity, hardness, creep resistance, strength, and elongation decreased after NaCl was added and dissolved. However, the yield strength in the tensile and compression test was closer to that of the natural cartilage. The friction coefficient and wear loss of porous UHMWPE were higher than that of solid UHMWPE in dry conditions, but these values of porous UHMWPE were lower than that of solid UHMWPE in the calf serum lubrication condition. The main wear mechanism of porous and solid UHMWPE was abrasive. The lubricity of calf serum reduced wear surface scratches and furrows, especially for porous UHMWPE. Full article

Batteries are widely used in energy storage systems (ESS), and thermal runaway in different types of batteries presents varying safety risks. Therefore, comparative research on the thermal runaway behaviors of various batteries is essential. This study investigates the thermal runaway characteristics of sodium-ion batteries (NIBs), lithium iron phosphate batteries (LFP), and lithium-ion batteries with NCM523 and NCM622 cathodes. The experiments were conducted in a nitrogen-filled constant-volume sealed chamber. The results show that the critical surface temperatures at the time of thermal runaway are as follows: LFP (346 °C) > NIBs (292 °C) > NCM523 (290 °C) > NCM622 (281 °C), with LFP batteries exhibiting the highest thermal runaway critical temperature. NIBs have the lowest thermal runaway triggering energy (158 kJ), while LFP has the highest (592.8 kJ). During the thermal runaway of all four battery types, the primary gases produced include carbon dioxide, hydrogen, carbon monoxide, methane, ethylene, propylene, and ethane. For NCM622 and NCM523, carbon monoxide is the dominant combustible gas, with volume fractions of 35% and 29%, respectively. In contrast, hydrogen is the main flammable gas for LFP and NIBs, with volume fractions of 44% and 30%, respectively. Among these, NIBs have the lowest lower flammability limit (LFL), indicating the highest explosion risk. The thermal runaway characteristics of 50 Ah batteries provide valuable insights for battery selection and design in energy storage applications. Full article

Many pharmaceutical active compounds are prepared as hydrochlorides for quick release in the gastrointestinal tract upon oral administration. Their inadvertent escape into the water environment requires efficient analytical separation for accurate quantitation to monitor their environmental fate. The purpose of this study is to demonstrate how best to optimize a capillary electrophoresis method for the separation of four model pharmaceutical hydrochlorides. Concentration of sodium dibasic phosphate in the background electrolyte solution, pH adjustment with HCl or NaOH, and applied voltage across the capillary were the three key factors chosen for optimization. The peak resolutions and total migration time were examined as the response indicators to complete a central composite design in response surface methodology. The examination revealed that CE separation was driven significantly by a linear regression model and minimally by a quadratic regression model, based on the coefficient of determination, the lack of fit, the total sum of squares, and the p values. Under optimal conditions of the background electrolyte concentration of 75 mM, pH 9, and the applied voltage of 10 kV, the model hydrochlorides were separated within five minutes in the migration order of metformin (first) > phenformin > mexiletine > ranitidine (last). The limits of UV detection/quantification attained under optimal CE conditions were 0.015/0.045, 0.020/0.060, 0.142/0.426, and 0.017/0.051, respectively. Full article

Spray cooling, of which the essence is droplet impacting, is an efficient thermal management technique for dense electronic components in unmanned aerial vehicles (UAVs). Nanofluids are pointed as promising cooling dispersions. Since the nanofluids are unstable, a dispersant could be added to the fluid. However, the added dispersant may influence the droplet, thereby impacting behaviors. In this work, the effects of dispersant on the nanofluid droplet-impacting dynamics are studied experimentally. The base fluid is deionized water (DI water), and Al₂O₃ is the selected nanoparticle. Sodium dodecyl sulfate (SDS) is used as the dispersant. Five different concentrations of nanofluids are configured using a two-step method. Droplet impacting behaviors are observed by high-speed imaging techniques. The other effects, i.e., the nanofluid particle volume fraction and the Weber number on droplet impact dynamics, are also systematically investigated. The results illustrate that the surface tension of the Al₂O₃ nanofluid increases with increased nanofluid concentrations. The surface tension of Al₂O₃ nanofluid with SDS is lower than that of DI water. And the increase in droplet impact velocity increases the spreading morphology. Nanofluid droplets exhibit spreading and equilibrium process when SDS is added. Furthermore, as the concentration of the nanofluid increases, the spreading process is inhibited. Whereas without SDS, the droplets undergo spreading, receding, and equilibrium processes. Moreover, there is no appreciable change in the impacting process with concentration increase. The empirical models of maximum spreading factor should be established without SDS and with SDS, respectively. This study can provide theoretical basis and specific guidance for experimental characterization of UAVs’ electronic devices based on the mechanism of nanofluid droplet impact on the wall. Full article

Treating the surfaces of dental implants in an alkaline medium allows us to obtain microstructures of sodium titanate crystals that favor the appearance of apatite in the physiological environment, producing osteoconductive surfaces. In this research, 385 discs made of titanium used in dental implants underwent different NaOH treatments with a 6M concentration at 600 °C and cooling rates of 20, 50, 75, and 115 °C/h. Using high-resolution electron microscopy, the microstructures were observed, and the different crystal sizes were determined and compared with control samples (those without biomimetic treatment). Roughness, wettability, surface energy and the sodium content of the surface were determined. The different surfaces were cultured with human osteoblastic cells; cell adhesion was determined at 3 and 14 days, and the degree of mineralization was determined at 14 days via alkaline phosphatase levels. Variations in the microstructure and size of sodium titanate crystals in NaOH solutions rich (1 g/L) or low in calcium (approximately 100 ppm) were determined. The results show that as the cooling rate increases, the size of the crystals decreases (from 0.4 μm to 0.8 μm) except for the case of 115 °C/h, when the rate is too fast for crystalline nucleation to occur on the surface of the titanium. The thermochemical treatment does not influence the roughness or the cooling rate since a Sa of 0.21 μm is maintained. However, the presence of titanate causes a decrease in the contact angle from 70° to 42° and, in turn, causes an increase in the total surface energy from 35 to 49.5 mJ/m², with the polar component standing out in this energy increase. No variations were observed in the thermochemical treatments in the presence of sodium, which was around 1200 ppm. It was observed that as the size of the crystals decreases, cell adhesion increases at 3 days and decreases at 14 days. This is because finer crystals on the surface are already in the mineralization process, as demonstrated using the level of alkaline phosphatase that is maximal for the cooling rate of 75 °C/h. It was possible to confirm that the variations in the concentrated NaOH solutions with different calcium contents did not affect the crystal sizes or the microstructure of the surface. This research makes it possible to obtain dental implants with different mineralization speeds depending on the cooling rate applied. Full article

This study explores the development of core–shell electrocatalysts for efficient glycerol oxidation in alkaline media. Carbon-supported M@Pt/C (M = Co, Ni, Sn) catalysts with a 1:1 atomic ratio of metal (M) to platinum (Pt) were synthesized using a facile sodium borohydride reduction method. The analysis confirmed the formation of the desired core–shell structure, with Pt dominating the surface as evidenced by energy-dispersive X-ray spectroscopy (EDS). X-ray diffraction (XRD) revealed the presence of a face-centered cubic (fcc) Pt structure for Co@Pt/C and Ni@Pt/C. Interestingly, Sn@Pt/C displayed a PtSn alloy formation indicated by shifted Pt peaks and the presence of minor Sn oxide peaks. Notably, no diffraction peaks were observed for the core metals, suggesting their amorphous nature. Electrocatalytic evaluation through cyclic voltammetry (CV) revealed superior glycerol oxidation activity for Co@Pt/C compared to all other catalysts. The maximum current density followed the order Co@Pt/C > Ni@Pt/C > Sn@Pt/C > Pt/C. This highlights the effectiveness of the core–shell design in enhancing activity. Furthermore, Sn@Pt/C displayed remarkable poisoning tolerance attributed to a combined effect: a bifunctional mechanism driven by Sn oxides and an electronic effect within the PtSn alloy. These findings demonstrate the significant potential of core–shell M@Pt/C structures for designing highly active and poisoning-resistant electrocatalysts for glycerol oxidation. The presented approach paves the way for further development of optimized catalysts with enhanced performance and stability aiming at future applications in direct glycerol fuel cells. Full article

In recent years, liquid–solid triboelectric nanogenerators (L-S TENGs) have been rapidly developed in the field of liquid energy harvesting and self-powered sensing. This is due to a number of advantages inherent in the technology, including the low cost of fabricated materials, structural diversity, high charge-energy conversion efficiency, environmental friendliness, and a wide range of applications. As liquid phase dielectric materials typically used in L-S TENG, a variety of organic and inorganic single-phase liquids, including distilled water, acidic solutions, sodium chloride solutions, acetone, dimethyl sulfoxide, and acetonitrile, as well as paraffinic oils, have been used in experiments. However, it is noteworthy that the function of multiphase liquids as dielectric materials is still understudied. The “Multiphase Liquid Triboelectric Nanogenerator Prototype (ML-TENG Pro)” presented in this paper takes a single-electrode solid–liquid triboelectric nanogenerator as the basic model and uses lubricating oil and deionized water as dielectric materials. After verifying the stability of single-phase liquid materials (e.g., DI water, seawater, ethanol, etc.) for power generation, the power generation performances of oil–water two-phase, gas–oil–water three-phase (with a small number of bubbles), and gas–oil–water three-phase (with many bubbles) in open space are further investigated. COMSOL Multiphysics 6.0 software was used to investigate the material transport mechanism and formation of oil–water two-phase and gas–oil–water three-phase. Finally, this study presents the power generation performance of ML-TENG Pro in the extreme state of gas–oil–water three-phase “emulsification”. This paper outlines the limitations of the ML-TENG, named PRO, and suggests avenues for future improvement. The research presented in this paper provides a theoretical basis for evaluating the quality of lubricants for mechanical power equipment. Full article

Water scarcity challenges in agriculture are prompting the exploration of alternative irrigation sources, including treated effluents. This study investigates the effects of irrigation with treated slaughterhouse effluent on soybean productivity and development, with and without inoculation, over two cropping cycles. Plant performance was significantly influenced by environmental factors and the interaction between effluent and inoculation. Plant height and leaf area were greater in the second cycle, with effluent enhancing growth and foliar development. Fresh and dry shoot biomass showed significant interactions among cycle, inoculation, and effluent, with higher effluent concentrations combined with inoculation being most effective in the first cycle. Foliar nitrogen concentrations were higher in the first cycle, particularly at elevated effluent doses, while foliar sodium showed a positive correlation with nitrogen and a negative correlation with magnesium. Chlorophyll indices varied across developmental stages, with maximum chlorophyll b estimated at 85.35% effluent irrigation. Soybean yield did not vary significantly with effluent dilutions, suggesting environmental factors had a greater influence. In conclusion, treated effluent irrigation represents a sustainable strategy for soybean production, optimizing water and nutrient use while reducing reliance on chemical fertilizers. Full article

Apigenin (APG), a bioactive flavonoid with promising therapeutic potential, suffers from poor water solubility, which limits its bioavailability. To address this, solid dispersions of APG were prepared using ball milling with sodium alginate (SA), Pluronic^® F-68 (PLU68), Pluronic^® F-127 (PLU127), PVP K30, and PVP VA64 as polymeric excipients. These dispersions were screened for apparent solubility in water and buffers with pH 1.2, 5.5, and 6.8. Based on improved solubility after 60 min, APG–PLU68 and APG–PLU127 dispersions were selected for further study. DSC and FT-IR analysis confirmed molecular interactions between APG and the polymer matrices, contributing to enhanced solubility and dissolution rates. Dissolution rate studies showed that APG–PLU127 achieved 100% solubility at pH 6.8, suggesting its potential use in environments such as the small intestine. Additionally, APG–PLU127 exhibited 84.3% solubility at pH 1.2, indicating potential for solid oral dosage forms, where APG could be absorbed in the acidic conditions of the stomach. The stability study confirmed that storage for one year under ambient conditions does not cause chemical degradation but affects the physical state and solubility of the dispersion. Antioxidant activity was assessed using the ABTS assay. Freshly obtained APG–PLU127 showed 68.1% ± 1.94% activity, whereas APG–PLU127 stored for one year under ambient conditions exhibited 66.2% ± 1.62% (significant difference, p < 0.05). The difference was related to a slight decrease in the solubility of APG in the solid dispersion (T0 = 252 ± 1 μg∙mL⁻¹, T1 = 246 ± 1 μg∙mL⁻¹). The findings demonstrate the superior performance of PLU127 as a carrier for enhancing the solubility, release, and antioxidant activity of APG. Full article

Polysaccharide hydrocolloids have garnered increasing attention from consumers, experts, and food processing industries due to their advantages of abundant resources, favorable thickening properties, emulsification stability, biocompatibility, biodegradability, and high acceptance as food additives. This review focuses on the application of polysaccharide hydrocolloids and their beneficial roles in meat products by focusing on several commonly used polysaccharides (i.e., cellulose, chitosan, starch, sodium alginate, pectin, and carrageenan). Firstly, the recent advancements of polysaccharide hydrocolloids used in meat products are briefly introduced, along with their structure and potential application prospects. Then, the beneficial roles of polysaccharide hydrocolloids in meat products are comprehensively summarized and highlighted, including retarding lipid and protein oxidation, enhancing nutritional properties, improving texture and color quality, providing antibacterial activity, monitoring freshness, acting as a cryoprotectant, improving printability, and ensuring security. Finally, the challenges and opportunities of polysaccharide hydrocolloids in meat products are also introduced. Full article