KEGG   REACTION: R13155
Entry
R13155                      Reaction                               
Definition
Quillaic acid 3-O-beta-D-xylosyl-1,3-(beta-D-galactosyl-1,2)-beta-D-glucuronide <=> Quillaic acid 3-O-beta-D-xylosyl-1,3-(beta-D-galactosyl-1,2)-beta-D-glucuronide-28-O-beta-D-fucoside
Equation
C22654 <=> C22656
Comment
glycosyltransferase / dehydrogenase
unclear reaction
Reaction class
RC00523  C22654_C22656
Pathway
rn00999  Biosynthesis of various plant secondary metabolites
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00971  QS-7 biosynthesis, 2,3-epoxysqualene => QS-7
Orthology
K26487  quillaic acid 3-O-Xyl/L-Rha-1,3-(Gal-1,2)-GlcA 28-O-glycosyltransferase
K26488  4-keto-6-deoxyglucose 4-dehydrogenase
Reference
1  [PMID:36952412]
  Authors
Reed J, Orme A, El-Demerdash A, Owen C, Martin LBB, Misra RC, Kikuchi S, Rejzek M, Martin AC, Harkess A, Leebens-Mack J, Louveau T, Stephenson MJ, Osbourn A.
  Title
Elucidation of the pathway for biosynthesis of saponin adjuvants from the soapbark tree.
  Journal
Science 379:1252-1264 (2023)
DOI:10.1126/science.adf3727
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