KEGG   COMPOUND: C11998
Entry
C11998                      Compound                               
Name
Narbomycin
Formula
C28H47NO7
Exact mass
509.3353
Mol weight
509.67
Structure
Sequence
0 Mtk  1 Mtd  2 Man  3 Mte  4 Mtk  5 Mtn  6 Mtn
  Gene
0-2 pikA1 [UP:Q9ZGI5]; 3-4 pikA2 [UP:Q9ZGI4]; 5 pikA3
[UP:Q9ZGI3]; 6 pikA4 [UP:Q9ZGI2]
  Organism
Streptomyces venezuelae
  Type
PK
Reaction
R06461 R06464 R10626 R10627
Pathway
map00522  Biosynthesis of 12-, 14- and 16-membered macrolides
map01100  Metabolic pathways
map01110  Biosynthesis of secondary metabolites
Module
M00776  Pikromycin/methymycin biosynthesis, methylmalonyl-CoA + malonyl-CoA => narbonolide/10-deoxymethynolide => pikromycin/methymycin
Enzyme
1.14.15.33      2.4.1.277
Brite
Lipids [BR:br08002]
 PK  Polyketides
  PK04 Macrolides and lactone polyketides
   C11998  Narbomycin
Other DBs
CAS: 6036-25-5
PubChem: 14159
ChEBI: 29649
NIKKAJI: J39.493I
LinkDB
KCF data

ATOM        36
            1   C1y C    27.4802  -18.4694
            2   C1y C    27.5427  -19.9406
            3   C1y C    28.7431  -20.6826
            4   C1x C    30.0207  -19.9534
            5   C1y C    30.0282  -18.4822
            6   O2x O    28.7579  -17.7402
            7   C1a C    31.3059  -17.7533
            8   N1c N    28.7356  -22.1537
            9   O1a O    26.1948  -20.6697
            10  C1a C    27.4579  -22.8829
            11  C1a C    30.0059  -22.8957
            12  O2a O    26.2063  -17.7254
            13  C1y C    25.0006  -17.0341
            14  C1y C    24.9883  -15.6444
            15  C1x C    23.7953  -14.9679
            16  C1a C    26.1627  -14.9557
            17  C1y C    23.7953  -13.6091
            18  C5x C    22.6086  -12.9464
            19  C1a C    24.9514  -12.9526
            20  C2x C    21.4402  -13.6091
            21  O5x O    22.6086  -11.5920
            22  C2x C    21.4402  -14.9679
            23  C1y C    20.2412  -15.6444
            24  C1b C    19.0359  -17.7105
            25  C1y C    20.2228  -17.0095
            26  C1a C    19.0728  -14.9679
            27  O7x O    21.4039  -17.6942
            28  C1y C    23.7952  -17.7256
            29  C1a C    22.5842  -17.0248
            30  C5x C    23.7805  -19.1128
            31  C7x C    21.3955  -19.0532
            32  O6a O    20.2143  -19.7255
            33  C1y C    22.5681  -19.7401
            34  O5x O    24.9428  -19.8284
            35  C1a C    22.5546  -21.0891
            36  C1a C    17.8195  -17.0241
BOND        37
            1     1  12 1 #Down
            2     5   6 1
            3     6   1 1
            4    13  14 1
            5    14  15 1
            6    14  16 1 #Down
            7    15  17 1
            8    17  18 1
            9    17  19 1 #Down
            10   18  20 1
            11   18  21 2
            12   20  22 2
            13   22  23 1
            14   23  25 1
            15   23  26 1 #Down
            16   25  24 1 #Down
            17   25  27 1
            18    5   7 1 #Down
            19    1   2 1
            20   13  28 1
            21    3   8 1 #Down
            22   28  29 1 #Down
            23    2   3 1
            24   28  30 1
            25    2   9 1 #Up
            26   27  31 1
            27    3   4 1
            28   31  32 2
            29    8  10 1
            30   31  33 1
            31   33  30 1
            32    4   5 1
            33   30  34 2
            34    8  11 1
            35   33  35 1 #Up
            36   13  12 1 #Down
            37   24  36 1

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