| Entry |
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| Name |
9,9'-dicis-zeta-carotene desaturase;
zeta-carotene desaturase;
ZDS
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| Class |
Oxidoreductases;
Acting on the CH-CH group of donors;
With a quinone or related compound as acceptor
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| Sysname |
9,9'-dicis-zeta-corotene:quinone oxidoreductase
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| Reaction(IUBMB) |
9,9'-dicis-zeta-carotene + 2 quinone = 7,9,7',9'-tetracis-lycopene + 2 quinol (overall reaction) [RN: R07511];
(1a) 9,9'-dicis-zeta-carotene + a quinone = 7,9,9'-tricis-neurosporene + a quinol [RN: R09656];
(1b) 7,9,9'-tricis-neurosporene + a quinone = 7,9,7',9'-tetracis-lycopene + a quinol [RN: R09658]
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| Reaction(KEGG) |
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| Substrate |
9,9'-dicis-zeta-carotene [CPD: C15857];
quinone [CPD: C15602];
7,9,9'-tricis-neurosporene [CPD: C19759]
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| Product |
7,9,7',9'-tetracis-lycopene [CPD: C15858];
quinol [CPD: C15603];
7,9,9'-tricis-neurosporene [CPD: C19759]
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| Comment |
This enzyme is involved in carotenoid biosynthesis in plants and cyanobacteria.
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| History |
EC 1.3.5.6 created 1999 as EC 1.14.99.30, transferred 2011 to EC 1.3.5.6
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| Pathway |
| ec01110 | Biosynthesis of secondary metabolites |
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| Orthology |
| K00514 | zeta-carotene desaturase |
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| Genes |
| CSAT: | 104705395 104744597 104764122 |
| GHI: | 107888796 107893220 107920020 107945977 |
| HSYR: | 120138884 120161778 |
| LANG: | 109336428 109345421 109354942 |
| PAVI: | 110755575 110759721 |
| MSYL: | 126593685 126619154 |
| PALZ: | 118044066 118051360 118056983 118061421 |
| CANN: | 107839468 107839472 |
| NTA: | 107772271(ZDS) 107830915 |
| SIND: | 105162430 105172259 |
| EGT: | 105964808 105974162 105974562 |
| SSPL: | 121765143 121793432 121797720 121799747 |
| SMIL: | 130998871 130998879 |
| SHIS: | 125203525 125223442 |
| APAN: | 127245726 127260962 |
| PSOM: | 113332730 113347119 |
| TAES: | 100270658 123044758 123052650 |
| MFLO: | 136541581 136545392 |
| PVIR: | 120659662 120665630 |
| SMO: | SELMODRAFT_108745 SELMODRAFT_146971 |
| PPP: | 112277797 112292818 112294714 |
| CVR: | CHLNCDRAFT_141585(ZDS) |
| PTI: | PHATRDRAFT_53974(ZDS) |
| FCY: | FRACYDRAFT_291551(ZDS) |
| SYR: | SynRCC307_0275(crtQ) |
| SYX: | SynWH7803_2224(crtQ) |
| SYH: | Syncc8109_2460(crtQ) |
| SYNW: | SynWH8103_02544(zds) |
| TVN: | NIES2134_100610(crtQ) |
| LET: | O77CONTIG1_02617(pds_2) |
| SYP: | SYNPCC7002_A0529(crtQ) |
| SYNN: | NIES970_10330(crtQ) |
| MVZ: | myaer102_25870(crtQ) |
| ARP: | NIES39_B00980(crtQb) |
| PAGH: | NIES204_05360(crtQb) |
| PRUN: | PCC7821_03755(crtQ) |
| NSPH: | BDGGKGIB_04406(pds_4) |
| PROC: | Ptc2401_00675(pds_1) |
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| Reference |
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| Authors |
Albrecht M, Linden H, Sandmann G. |
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| Title |
Biochemical characterization of purified zeta-carotene desaturase from Anabaena PCC 7120 after expression in Escherichia coli. |
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| Journal |
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| Reference |
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| Authors |
Josse EM, Simkin AJ, Gaffe J, Laboure AM, Kuntz M, Carol P |
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| Title |
A plastid terminal oxidase associated with carotenoid desaturation during chromoplast differentiation. |
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| Journal |
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| Reference |
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| Authors |
Breitenbach J, Kuntz M, Takaichi S, Sandmann G |
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| Title |
Catalytic properties of an expressed and purified higher plant type zeta-carotene desaturase from Capsicum annuum. |
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| Journal |
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| Sequence |
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| Reference |
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| Authors |
Breitenbach J, Sandmann G |
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| Title |
zeta-Carotene cis isomers as products and substrates in the plant poly-cis carotenoid biosynthetic pathway to lycopene. |
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| Journal |
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| Sequence |
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| Other DBs |
| ExplorEnz - The Enzyme Database: | 1.3.5.6 |
| ExPASy - ENZYME nomenclature database: | 1.3.5.6 |
| BRENDA, the Enzyme Database: | 1.3.5.6 |
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| LinkDB |
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