Klein et al., 1987 - Google Patents

Plasma-initiated polymerization of hexachlorocyclotriphosphazene

Klein et al., 1987

Document ID
8264553959001189826
Author
Klein J
Bell A
Soong D
Publication year
Publication venue
Macromolecules

External Links

Snippet

Conclusions We have demonstrated that the rate of tungsten hexa-chloride/tetramethyltin- catalyzed olefin metathesis po-lymerization is independent of ring strain in the monomer but very dependent on the structure of the propagating carbene. The ease with which the closest …
Continue reading at pubs.acs.org (other versions)

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G79/00Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
    • C08G79/02Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing phosphorus
    • C08G79/025Polyphosphazenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78Preparation processes
    • C08G63/82Preparation processes characterised by the catalyst used
    • C08G63/84Boron, aluminium, gallium, indium, thallium, rare-earth metals, or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/18Polybenzimidazoles

Similar Documents

Publication Publication Date Title
Allcock et al. Polymerization of hexachlorocyclotriphosphazene. The role of phosphorus pentachloride, water, and hydrogen chloride
Neilson et al. Synthesis and characterization of poly (alkyl/arylphosphazenes)
Allcock et al. The thermal breakdown of poly (diphenoxyphosphazene)
Allcock et al. Synthesis of poly [(amino acid alkyl ester) phosphazenes]
Schaefgen et al. Synthesis of multichain polymers and investigation of their viscosities1
Chojnowski et al. Mechanism of the formation of macrocycles during the cationic polymerization of cyclotrisiloxanes. End to end ring closure versus ring expansion
Allcock et al. Thermolysis of Poly [bis (trifluoroethoxy) phosphazene]
Allcock et al. Phosphorus-nitrogen compounds. 27. Ring-ring and ring-chain equilibration of dimethylphosphazenes. Relation to phosphazene polymerization
Allcock et al. Strain-induced ring-opening polymerization of ferrocenylorganocyclotriphosphazenes: a new synthetic route to poly (organophosphazenes)
Klein et al. Plasma-initiated polymerization of hexachlorocyclotriphosphazene
Allcock et al. Poly (thiophosphazenes): new inorganic backbone polymers
Allcock et al. Synthesis of alkyphosphazene high polymers via the polymerization of monoalkylpentachlorocylotriphosphazenes
Maynard et al. Thermal degradation chemistry of poly (diphenoxyphosphazene)
Allcock et al. A new route for poly (organophosphazene) synthesis. Polymerization, copolymerization, and ring-ring equilibration of trifluoroethoxy-and chloro-substituted cyclotriphosphazenes1, 2
Denton III et al. The effect of radical trapping reagents upon formation of poly (α‐tetrahydrothiophenio para‐xylylene) polyelectrolytes by the wessling soluble precursor method
Allcock et al. Stereocontrolled polymerization within a cyclophosphazene clathrate tunnel system
Ganapathiappan et al. New initiators for the ring-opening thermal polymerization of hexachlorocyclotriphosphazene: synthesis of linear poly (dichlorophosphazene) in high yields
Allcock et al. Synthesis of Open-Chain Poly (difluorophosphazene) and Its Reactions with Alkoxides, Aryloxides, and Amines
Hultzsch et al. Polymerization of ϵ‐caprolactone using heterobimetallic lanthanocene complexes
Goldfarb et al. Thermal degradation of polybis (p‐isopropylphenoxy)‐phosphazene
Valaitis et al. Thermal stability of phosphonitrilic fluoroelastomers
Zeldin et al. Kinetics of Thermal Degradation of Poly [bis (2, 2, 2-trifluoroethoxy) phosphazene]
Bradbury et al. Experimental evidence for the assignment of. alpha.-CH peaks in the nuclear magnetic resonance spectra of polypeptides
Miyata et al. Functional monomers and polymers. XXXVIII. Postirradiation polymerization of 2, 3‐dimethylbutadiene in deoxycholic acid canal complexes
Fewell et al. Synthesis and thermal stability of carborane‐containing phosphazenes