Hall et al., 1993 - Google Patents

Synthesis and characterization of bis (pentamethylcyclopentadienyl) uranium (IV) and-thorium (IV) compounds containing the bis (trimethylsilyl) phosphide ligand

Hall et al., 1993

Document ID
3520044350724008588
Author
Hall S
Huffman J
Miller M
Avens L
Burns C
Sattelberger A
Arney D
England A
Publication year
Publication venue
Organometallics

External Links

Snippet

The chemistry of organoactinide complexes containing metal-heteroatom bonds, particularly those with functional groups such as oxides and imides capable of engaging in multiple bonding, is of great interest due to the inherently large ligand-metal charge separationin …
Continue reading at pubs.acs.org (other versions)

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C-Si linkages
    • C07F7/0803Compounds with Si-C or Si-Si linkages
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C-Si linkages
    • C07F7/12Organo silicon halides
    • C07F7/121Preparation or treatment not provided for in C07F7/14, C07F7/16 or C07F7/20
    • C07F7/122Preparation or treatment not provided for in C07F7/14, C07F7/16 or C07F7/20 by reactions involving the formation of Si-C linkages
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00Compounds containing elements of Groups 3 or 13 of the Periodic System
    • C07F5/02Boron compounds
    • C07F5/027Organoboranes and organoborohydrides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02Silicon compounds
    • C07F7/025Silicon compounds without C-silicon linkages
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • C07F17/02Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02Phosphorus compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00Compounds containing elements of Groups 1 or 11 of the Periodic System
    • C07F1/02Lithium compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/0006Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
    • C07F15/0073Rhodium compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00Compounds containing elements of Groups 2 or 12 of the Periodic System
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/06Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/12Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of boron, aluminium, gallium, indium, thallium or rare earths
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms

Similar Documents

Publication Publication Date Title
Hall et al. Synthesis and characterization of bis (pentamethylcyclopentadienyl) uranium (IV) and-thorium (IV) compounds containing the bis (trimethylsilyl) phosphide ligand
Evans et al. Reactivity of samarium complex [(C5Me5) 2Sm (. mu.-H)] 2 in ether and arene solvents. X-ray crystal structures of the internally metalated complex (C5Me5) 2Sm (. mu.-H)(. mu.-CH2C5Me4) Sm (C5Me5), the benzyl complex (C5Me5) 2Sm (CH2C6H5)(THF), and the siloxide complex [(C5Me5) 2Sm (THF)] 2 (. mu.-OSiMe2OSiMe2O)
Fagan et al. Synthesis and properties of bis (pentamethylcyclopentadienyl) actinide hydrocarbyls and hydrides. A new class of highly reactive f-element organometallic compounds
Van der Sluys et al. First example of a neutral homoleptic uranium alkyl. Synthesis, properties, and structure of U [CH (SiMe3) 2] 3
Watson et al. (Pentamethylcyclopentadienyl) ytterbium and-lutetium complexes by metal oxidation and metathesis
Ferrence et al. Stabilization of a discrete lanthanide (II) hydrido complex by a bulky hydrotris (pyrazolyl) borate ligand
Gade et al. Trisilylmethane as a structural backbone in multifunctional lithium amides: syntheses and structures of HC {(CH3) 2SiN (Li)-tert-Bu} 3 and its solvate HC {(CH3) 2SiN (Li)-tert-Bu} 3. cntdot. 2THF
Boaretto et al. Synthesis of a highly strained uranacycle: molecular structures of organometallic products arising from reduction, oxidation and protonolysis
Targos et al. Binuclear phosphido-bridged complexes that link titanium and zirconium to tungsten and iron. Crystal and molecular structure of ZrW (. mu.-PPh2) 2Cp2 (CO) 4
Schumann et al. Organometallic compounds of the lanthanides
Travia et al. Thorium-mediated ring-opening of tetrahydrofuran and the development of a new thorium starting material: preparation and chemistry of ThI 4 (DME) 2
Jantunen et al. Synthesis, characterization, and organometallic derivatives of diamidosilyl ether thorium (IV) and uranium (IV) halide complexes
Schumann et al. Organometallic compounds of the lanthanides. 24. Synthesis and x-ray crystallographic characterization of the first organolanthanide derivative with a lanthanide-silicon bond
Li et al. Facile transformations of lanthanocene alkyls to lanthanocene thiolate, sulfide, and disulfide derivatives by reaction with elemental sulfur
Stults et al. [Li (Me2NCH2CH2NMe2)][Li2 (Me2NCH2CH2NMe2) 2 (. mu.-. eta. 5,. eta. 5-MeC5H4)][(. eta. 5-MeC5H4) 6U2 (. mu.-Me)] 2: a compound with symmetrically bridging MeC5H4 and Me groups
Fryzuk et al. Thermal and photochemical transformations of organoiridium phosphide complexes. Mechanistic studies on carbon-phosphorus bond formation to generate cyclometalated hydride complexes by. alpha.-hydride abstraction
Kalb et al. Reactions at the metal vertex of a monometal metallacarborane cluster. Chemistry of [closo-3, 3-(PPh3) 2-3-HSO4-3, 1, 2-RhC2B9H11] and [closo-3-PPh3-3, 3-NO3-3, 1, 2-RhC2B9H11]
Deacon et al. Organolanthanoids. XVII. The Synthesis of Bis (diphenylphosphinocyclopentadienyl) ytterbium (II) and Derived Heterobimetallic Complexes [Yb (thf) n (C5H4PPh2) 2Z][Z= Ni (CO) 2, Mo (CO) 4 or PtMe2; n= 1 or 2; thf= Tetrahydrofuran]. The X-Ray Crystal-Structure of [Yb (thf) 2 (C5H4PPh2) 2Ni (CO) 2]
Cramer et al. Preparation, solution dynamics, and x-ray structure of bis (pentamethylcyclopentadienyl) actinide complexes of chelating phosphorus ylides
Doyle et al. Synthesis and reactions of the cationic thiocarbyne [HC (pz) 3](CO) 2W. ident. C-SMe+. Reactions of the thiocarbene [HC (pz) 3](CO) 2W [. eta. 2-CHSMe] 2+ with nucleophiles
Dash et al. Amine Elimination Reactions between Homoleptic Silylamide Lanthanide Complexes and an Isopropylidene-Bridged Cyclopentadiene− Fluorene System
Avent et al. Yttrium complexes incorporating the chelating diamides {ArN (CH 2) x NAr} 2−(Ar= C 6 H 3-2, 6-i Pr 2, x= 2, 3) and their unusual reaction with phenylsilane
Watson et al. Amido/phosphine pincer hydrides of ruthenium
Omori et al. Synthesis and molecular structure of a dinuclear ruthenium dihydride complex containing a perpendicularly bridging diphenylacetylene ligand
Barnhart et al. Solution Study of the Ambient Temperature Monomer-Dimer Equilibrium Th2 (OR) 8. dblharw. 2Th (OR) 4 (R= CH-i-Pr2) and X-ray Crystal Structures of Th2 (OCH-i-Pr2) 8, Th (OCH-i-Pr2) 4 (quin), and ThI (OCH-i-Pr2) 3 (py) 2