WO2009099179A1 - 太陽電池モジュール及び太陽電池 - Google Patents
太陽電池モジュール及び太陽電池 Download PDFInfo
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- WO2009099179A1 WO2009099179A1 PCT/JP2009/052044 JP2009052044W WO2009099179A1 WO 2009099179 A1 WO2009099179 A1 WO 2009099179A1 JP 2009052044 W JP2009052044 W JP 2009052044W WO 2009099179 A1 WO2009099179 A1 WO 2009099179A1
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Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/02—Details
- H01L31/0224—Electrodes
- H01L31/022408—Electrodes for devices characterised by at least one potential jump barrier or surface barrier
- H01L31/022425—Electrodes for devices characterised by at least one potential jump barrier or surface barrier for solar cells
- H01L31/022433—Particular geometry of the grid contacts
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/05—Electrical interconnection means between PV cells inside the PV module, e.g. series connection of PV cells
- H01L31/0504—Electrical interconnection means between PV cells inside the PV module, e.g. series connection of PV cells specially adapted for series or parallel connection of solar cells in a module
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/06—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by potential barriers
- H01L31/072—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by potential barriers the potential barriers being only of the PN heterojunction type
- H01L31/0745—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by potential barriers the potential barriers being only of the PN heterojunction type comprising a AIVBIV heterojunction, e.g. Si/Ge, SiGe/Si or Si/SiC solar cells
- H01L31/0747—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by potential barriers the potential barriers being only of the PN heterojunction type comprising a AIVBIV heterojunction, e.g. Si/Ge, SiGe/Si or Si/SiC solar cells comprising a heterojunction of crystalline and amorphous materials, e.g. heterojunction with intrinsic thin layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Definitions
- the present invention relates to a solar cell module including a plurality of solar cells connected to each other by a wiring material.
- Solar cells are expected as a new energy source because they can directly convert clean and infinitely supplied sunlight into electricity.
- the output per solar cell is about several watts. Therefore, when a solar cell is used as a power source for a house or a building, a solar cell module whose output is increased by connecting a plurality of solar cells is used.
- the plurality of solar cells are sealed with a sealing material between the light-receiving surface side protective material and the back surface side protective material.
- the solar cell includes a first connection electrode and a plurality of first thin wire electrodes formed on the light receiving surface, and a second connection electrode and a plurality of second thin wire electrodes formed on the back surface (for example, JP, 2002-359388, A).
- the wiring member is soldered to the first connection electrode of one solar cell and the second connection electrode of another solar cell. Thereby, one solar cell and another solar cell are electrically connected to each other.
- the wiring material when the wiring material is bonded, the wiring material can be pressed toward the solar cell to achieve good connection of the wiring material. That is, by causing the first and second fine wire electrodes to bite into the wiring material, electrical and mechanical connection between the wiring material and the first and second fine wire electrodes can be achieved.
- the first thin wire electrodes are formed in a smaller number and narrower than the second thin wire electrodes for the purpose of expanding the light receiving area. Therefore, the ratio of the area where the first thin wire electrode is formed to the area of the region where the wiring material is connected in the light receiving surface is such that the second thin wire electrode is formed relative to the area of the region where the wiring material is connected in the back surface. Less than the area ratio. Therefore, when connecting the wiring material, the amount of biting of the second thin wire electrode into the wiring material is smaller than that of the first thin wire electrode.
- This invention is made
- a solar cell module is connected to a solar cell, one wiring member connected to the light receiving surface of the solar cell, and a back surface provided on the opposite side of the light receiving surface of the solar cell.
- the solar cell includes a first member group including at least a plurality of first thin wire electrodes formed on the light receiving surface, and a second electrode formed on the back surface.
- the first member group has a first connection portion connected to one wiring material and a group of first exposed portions exposed from the one wiring material, and the second electrode is connected to another wiring material.
- the first ratio which is the ratio of the area where the first exposed portion is formed with respect to the area of the light receiving surface, is a back surface.
- the second ratio which is the ratio of the area where the second exposed portion is formed to the area of the first ratio
- the second ratio of the first ratio Is the area of the region of the back surface where the other wiring material is connected
- the third ratio which is the ratio of the area where the first connection part is formed to the area of the region where one wiring material is connected of the light receiving surface
- the gist is that the ratio is smaller than the ratio to the fourth ratio, which is the ratio of the area in which the second connection portion is formed.
- the second electrode includes a plurality of second thin wire electrodes, and the plurality of second thin wire electrodes includes a second connection portion and a second exposed portion. You may do it.
- the first connection portion may be connected in direct contact with one wiring member.
- the second connection portion may be connected in direct contact with another wiring material.
- At least two second thin wire electrodes among the plurality of second thin wire electrodes may be combined into one in a region to which another wiring material is connected. Good.
- At least one first thin wire electrode among the plurality of first thin wire electrodes may be branched into a plurality of wires in a region to which one wiring material is connected. Good.
- the first member group may include an island member formed in an island shape in a region to which one wiring member is connected.
- a solar cell module is connected to a solar cell, one wiring member connected to the light receiving surface of the solar cell, and a back surface provided on the opposite side of the light receiving surface of the solar cell.
- the solar cell has a first electrode formed on the light receiving surface and a second electrode formed on the back surface, and the first electrode is formed on one wiring material.
- the first connection part to be connected and the first exposed part exposed from one wiring material, and the second electrode is exposed from the second connection part connected to the other wiring material and the other wiring material.
- the area of the first exposed portion is smaller than the area of the second exposed portion, and the ratio of the area of the first exposed portion to the area of the second exposed portion is the area of the second connecting portion.
- the gist of the invention is that it is smaller than the ratio of the area of the first connecting portion to the above.
- a solar cell includes a photoelectric conversion unit, a first member group including at least a plurality of first thin wire electrodes formed on a first main surface of the photoelectric conversion unit, and a photoelectric conversion unit A second electrode formed on the second main surface, wherein one wiring member is electrically connected to the plurality of first thin wire electrodes, and another wiring member is electrically connected to the second electrode.
- the first member group includes a first connection portion connected to one wiring member and a first exposed portion exposed from the one wiring member, and the second electrode is connected to the other wiring.
- the first ratio which is the ratio of the area of the first exposed portion to the area of the first main surface, has a second connection portion connected to the material and a second exposed portion exposed from another wiring material.
- the ratio of the first ratio to the second ratio is smaller than the second ratio, which is the ratio of the area of the second exposed portion to the area of the two main surfaces, and the ratio of the first ratio to the second ratio is one wiring material among the first main surfaces.
- the ratio of the area of the second connection portion to the area of the region to which another wiring member of the second main surface is connected is the third ratio, which is the ratio of the area of the first connection portion to the area of the connected region.
- the gist is that it is smaller than the ratio to the fourth ratio.
- a solar cell includes a photoelectric conversion unit, a first electrode formed on the first main surface of the photoelectric conversion unit, and a second electrode formed on the second main surface of the photoelectric conversion unit.
- An electrode wherein one wiring member is electrically connected to the first electrode, and another wiring member is electrically connected to the second electrode, wherein the first electrode is one wiring member A first connecting portion connected to the first wiring portion and a first exposed portion exposed from one wiring material, and the second electrode includes a second connecting portion connected to the other wiring material and another wiring material.
- the area of the first exposed portion is smaller than the area of the second exposed portion, and the ratio of the area of the first exposed portion to the area of the second exposed portion is that of the second connecting portion.
- the gist is that it is smaller than the ratio of the area of the first connecting portion to the area.
- FIG. 1 is a plan view of a solar cell 10 according to a first embodiment of the present invention. It is a top view of the solar cell 10 which concerns on 2nd Embodiment of this invention. It is a top view of the solar cell 10 which concerns on 3rd Embodiment of this invention. It is a top view by the side of the light-receiving surface of the solar cell 10 which concerns on embodiment of this invention. It is a top view by the side of the light-receiving surface of the solar cell 10 which concerns on embodiment of this invention.
- FIG. 1 is a side view of a solar cell module 1 according to the present embodiment.
- FIG. 2A is a plan view of the light receiving surface side of the solar cell module 1.
- FIG. 2B is a plan view of the back surface side of the solar cell module 1.
- the solar cell module 1 includes a plurality of solar cells 10, a light receiving surface side protective material 2, a back surface side protective material 3, a sealing material 4, a wiring material 5, and a resin adhesive material 6.
- the plurality of solar cells 10 are sealed by the sealing material 4 between the light-receiving surface side protective material 2 and the back surface side protective material 3.
- the plurality of solar cells 10 are arranged along the first direction and are electrically connected to each other by the wiring member 5.
- the solar cell 10 includes a photoelectric conversion unit 11, a first electrode 12, and a second electrode 13.
- the photoelectric conversion unit 11 has a first main surface A and a second main surface B provided on the opposite side of the first main surface A.
- the first main surface A is disposed to face the light receiving surface side protective material 2
- the second main surface B is disposed to face the back surface side protective material 3.
- the first main surface A is the light receiving surface of the photoelectric conversion unit 11
- the second main surface B is the back surface of the photoelectric conversion unit 11.
- the photoelectric conversion unit 11 generates a photogenerated carrier by receiving light.
- the photogenerated carrier refers to holes and electrons generated when light is absorbed by the photoelectric conversion unit 11.
- the photoelectric conversion unit 11 has a semiconductor junction such as a semiconductor pn junction or a semiconductor pin junction as a basic structure.
- the photoelectric conversion unit 11 can be formed using a general semiconductor material such as a crystalline semiconductor material such as single crystal Si or polycrystalline Si, or a compound semiconductor material such as GaAs or InP.
- the photoelectric conversion unit 11 may have a so-called HIT structure in which a substantially intrinsic amorphous silicon layer is sandwiched between a single crystal silicon substrate and an amorphous silicon layer.
- the first electrode 12 is a collection electrode that collects photogenerated carriers generated by the photoelectric conversion unit 11. As shown in FIG. 2A, the first thin wire electrode 12A has a plurality of first thin wire electrodes 12A formed over substantially the entire area on the first main surface (light receiving surface) A.
- the plurality of first fine wire electrodes 12A can be formed by, for example, a printing method using a thermosetting or sintered conductive paste.
- the 13 first fine wire electrodes 12A are formed in a line shape along the second direction substantially orthogonal to the first direction.
- the number, size, and shape of the first fine wire electrodes 12A are not shown. Can be appropriately set in consideration of the size of the photoelectric conversion unit 11 and the like.
- the second electrode 13 is a collection electrode that collects photogenerated carriers generated by the photoelectric conversion unit 11.
- the second fine wire electrode 13A has a plurality of second fine wire electrodes 13A formed over substantially the entire area on the second main surface (back surface) B.
- the plurality of second thin wire electrodes 13A can be formed by the same technique as the plurality of first thin wire electrodes 12A.
- the 26 second fine wire electrodes 13A are formed in a line shape along the second direction, but the number, size, and shape of the second fine wire electrodes 13A are the same as the size of the photoelectric conversion unit 11. It can be set as appropriate in consideration of the above.
- Such a plurality of first fine wire electrodes 12A and a plurality of second fine wire electrodes 13A are directly connected so as to bite into the wiring member 5, as shown in FIG.
- the configuration of the first electrode 12 and the second electrode 13 will be described later.
- the light receiving surface side protective material 2 is disposed on the sealing material 4 and protects the surface of the solar cell module 1.
- glass having translucency and water shielding properties, translucent plastic, or the like can be used as the light-receiving surface side protective material 2.
- the back surface side protective material 3 is arrange
- a resin film such as PET (Polyethylene Terephthalate), a laminated film having a structure in which an Al foil is sandwiched between resin films, and the like can be used.
- the sealing material 4 seals the plurality of solar cells 10 between the light receiving surface side protective material 2 and the back surface side protective material 3.
- a translucent resin such as EVA, EEA, PVB, silicon, urethane, acrylic, or epoxy can be used.
- an Al frame (not shown) can be attached to the outer periphery of the solar cell module 1 having the above configuration.
- FIG. 3A is a plan view of the solar cell 10 on the first main surface (light receiving surface) A side.
- FIG. 3B is a plan view of the second main surface (back surface) B side of the solar cell 10.
- the 13 first thin wire electrodes 12 ⁇ / b> A include a first connection portion 12 a connected to the wiring material 5 and a first exposure exposed from the wiring material 5 on the first main surface A. Part 12b.
- the first connection portion 12a is located in the region C to which the wiring material 5 is connected.
- the wiring member 5 is electrically connected to the first connection portion 12a.
- Each of the 13 first thin wire electrodes 12A according to the present embodiment is formed with a uniform line width.
- the 26 second thin wire electrodes 13 ⁇ / b> A include the second connection portion 13 a connected to the wiring material 5 and the second exposure exposed from the wiring material 5 on the second main surface B. Part 13b.
- the 2nd connection part 13a is located in the area
- the wiring member 5 is electrically connected to the second connection portion 13a.
- the 26 second fine wire electrodes 13A are combined into a set of 13 second connection portions 13a by being coupled together in a set in the region D.
- the line width of the 2nd connection part 13a which concerns on this embodiment, and the 2nd exposure part 13b is substantially equivalent to 12A (1st connection part 12a and the 1st exposure part 12b) of 1st thin wire
- the ratio of the area where the first exposed portion 12b is formed to the area of the first main surface A is defined as a first value v.
- the ratio of the area where the second exposed portion 13b is formed to the area of the second main surface B is defined as a second value w.
- the ratio of the area where the first connection portion 12a is formed to the area of the region C is a third value x.
- the ratio of the area where the second connection portion 13a is formed to the area of the region D is a fourth value y.
- the first value v is smaller than the second value w. That is, (v / w) ⁇ 1 is satisfied (hereinafter referred to as “first relationship”).
- the electrode formation area per unit area is made smaller than that of the second main surface B for the purpose of increasing the light receiving area, and in the second main surface B, the unit for the purpose of reducing the resistance loss. This is because the electrode formation area per area is larger than that of the first main surface A.
- the ratio of the first value v to the second value w is smaller than the ratio of the third value x to the fourth value y. That is, (v / w) ⁇ (x / y) is established (hereinafter referred to as “second relationship”).
- the electrode formation area per unit area in the region D is made closer to the region C by coupling the 26 second thin wire electrodes 13A in a pair in the region D.
- the area of the second connection portion 13a is made closer to the area of the first connection portion 12a.
- a conductive paste is arranged on the first main surface A of the photoelectric conversion unit 11 in a pattern shown in FIG. Thereafter, the conductive paste is temporarily cured by heating.
- a conductive paste is arranged on the second main surface B of the photoelectric conversion unit 11 in a pattern shown in FIG. Thereafter, the conductive paste disposed on the first main surface A and the second main surface B is cured by heat treatment.
- the resin adhesive 6 is applied to the region C and the region D using a dispenser.
- the wiring member 5 is disposed on the resin adhesive 6 and heated while pressing the wiring member 5 toward the photoelectric conversion unit 11. Thereby, while connecting the 1st connection part 12a and the 2nd connection part 13a to the wiring material 5, the resin adhesive material 6 is hardened. By repeating the connection of the wiring member 5 as described above, the plurality of solar cells 10 are electrically connected.
- an EVA (sealing material 40) sheet, a plurality of solar cells 10, an EVA (sealing material 4) sheet, and a back side protection material 3 are sequentially laminated on the glass substrate (light-receiving surface side protection material 2).
- a laminate is used. EVA is cured by heating the laminate.
- the first electrode 12 includes a first connection portion 12a and a first exposed portion 12b
- the second electrode 13 includes a second connection portion 13a and a second exposed portion 13b.
- the first relationship ((v / w) ⁇ 1) and the second relationship ((v / w) ⁇ (x / y)) are established.
- the establishment of the first relationship indicates that in the solar cell 10, the electrode formation area per unit area on the first main surface A is smaller than that on the second main surface B. In other words, it indicates that the area of the first exposed portion 12b is smaller than the area of the second exposed portion 13b.
- the establishment of the second relationship indicates that the electrode formation area per unit area in the region D is close to the electrode formation area per unit area in the region C.
- the electrode forming area per unit area in the region D is made close to the region C by coupling the 26 second thin wire electrodes 13A into a set.
- connection area of the second connection portion 13a with the wiring material 5 is set to the wiring material 5 of the first connection portion 12a. It can be close to the connection area. Therefore, the second connection portion 13a can be sufficiently connected to the wiring member 5.
- FIG. 4A is a plan view of the first main surface (light receiving surface) A side of the solar cell 10.
- FIG. 4B is a plan view on the second main surface (back surface) B side of the solar cell 10.
- the first electrode 12 has 13 first thin wire electrodes 12A.
- the thirteen first thin wire electrodes 12 ⁇ / b> A have a first connection portion 12 a connected to the wiring material 5 and a first exposed portion 12 b exposed on the first main surface A from the wiring material 5.
- the first connection portion 12a is located in the region C to which the wiring material 5 is connected.
- each of the 13 first thin wire electrodes 12A is branched into a plurality of wires in the region C and connected to the 25 first connecting portions 12a.
- the first connecting portion 12a and the first exposed portion 12b have substantially the same line width.
- the second electrode 13 has 26 second fine wire electrodes 13A.
- the twenty-six second thin wire electrodes 13 ⁇ / b> A have second connection portions 13 a connected to the wiring material 5, and second exposed portions 13 b exposed from the wiring material 5 on the second main surface B.
- the 2nd connection part 13a is located in the area
- Each of the 26 second thin wire electrodes 13A is formed with a uniform line width.
- the line width of the 1st connection part 12a and the 1st exposed part 12b which concern on this embodiment is substantially equivalent to 13 A (2nd connection part 13a and the 2nd exposed part 13b).
- the first relationship is established because the electrode formation area per unit area is made smaller than the second main surface B for the purpose of expanding the light receiving area, and the second main surface B is used for the purpose of reducing the resistance loss. This is because the electrode formation area per unit area is larger than that of the first main surface A.
- the reason why the second relationship is established is that the electrode formation area per unit area in the region C is made closer to the region D by branching the 13 first fine wire electrodes 12A in the region C.
- the first relationship ((v / w) ⁇ 1) and the second relationship ((v / w) ⁇ (x / y)) are established.
- the establishment of the first relationship indicates that in the solar cell 10, the electrode formation area per unit area on the first main surface A is smaller than that on the second main surface B. In other words, it indicates that the area of the first exposed portion 12b is smaller than the area of the second exposed portion 13b.
- the establishment of the second relationship indicates that the electrode formation area per unit area in the region C is close to the electrode formation area per unit area in the region D.
- the 13 first thin wire electrodes 12A are branched to bring the electrode formation area per unit area in the region C closer to the region D.
- connection area of the first connection portion 12a with the wiring material 5 is set to the wiring material 5 of the second connection portion 13a. It can be close to the connection area. Therefore, the second connection portion 13a can be sufficiently connected to the wiring member 5.
- the thirteen first fine wire electrodes 12A are branched at positions separated from the region C. Therefore, even when the first thin wire electrode 12A is disconnected due to a temperature change when the wiring member 5 is thermally bonded, the photogenerated carriers can be collected through a portion that is not disconnected.
- FIG. 5A is a plan view of the solar cell 10 on the first main surface A side.
- FIG. 5B is a plan view of the solar cell 10 on the second main surface B side.
- the first electrode 12 has thirteen first thin wire electrodes 12A on the light receiving surface A.
- 24 island members 14 are formed in addition to the 13 first thin wire electrodes 12A.
- the 13 first thin wire electrodes 12 ⁇ / b> A and the 24 island members 14 are collectively referred to as a “first member group 12 ′”.
- the 1st member group 12 has the 1st connection part 12c connected to the wiring material 5, and the 1st exposed part 12b exposed from the wiring material 5 on the 1st main surface A.
- the first connection portion 12 c according to the present embodiment includes a part of the 13 first thin wire electrodes 12 ⁇ / b> A and the 24 island-like members 14.
- the island-like member 14 can be formed by using insulating silicon oxide or the like.
- the planar shape of the island-like member 14 is not limited to the elliptical shape illustrated in FIG. 5A, and may be, for example, a dot shape, a rectangular shape, or other shapes.
- the formation area of one island-like member 14 according to the present embodiment is substantially equal to one second connection portion 13a formed in the region D.
- the thickness of one island-like member 14 according to the present embodiment is substantially equal to the thickness of the first thin wire electrode 12A.
- the first relationship is established because, on the first main surface A, the electrode formation area per unit area is made smaller than that of the second main surface B for the purpose of enlarging the light receiving area. This is because the electrode formation area per unit area is made larger than the first main surface A for the purpose of reducing the loss.
- the second relationship is established by forming the plurality of island-shaped members 14 in the region C, thereby changing the formation area of the first member group 12 ′ per unit area in the region C to the unit area in the region D. This is because the contact electrode formation area is close.
- the first relationship ((v / w) ⁇ 1) and the second relationship ((v / w) ⁇ (x / y)) are established.
- the establishment of the first relationship indicates that, in the solar cell 10, the electrode formation area per unit area on the first main surface A is smaller than that on the second main surface B for the purpose of increasing the light receiving area. In other words, it indicates that the area of the first exposed portion 12b is smaller than the area of the second exposed portion 13b.
- the fact that the second relationship is established is that the formation area of the first member group 12 ′ per unit area in the region C and the electrode formation area per unit area in the region D are close to each other. It shows that.
- the formation area of the first member group 12 ′ per unit area in the region C is changed to the electrode formation area per unit area in the region D. It is approaching.
- connection area between the first connection portion 12a (including the plurality of island-shaped members 14) and the wiring material 5 is set.
- the connection area between the second connection portion 13a and the wiring member 5 can be made closer. Therefore, the second connection portion 13a can be sufficiently connected to the wiring member 5.
- the first and second thin wire electrodes are formed in a line shape along the second direction, but the shape of the thin wire electrode is not limited to this.
- wavy thin wire electrodes can be formed in a lattice shape.
- two second thin wire electrodes 13A are combined into one, but three or more second thin wire electrodes 13A may be combined into one.
- one first thin wire electrode 12A is branched into three, but it may be branched into two or four or more.
- the first thin wire electrode 12A is branched at a position away from the region C.
- the first thin wire electrode 12A may be branched in the region C.
- the first connection portion 12a can be formed as shown in FIG. Further, as shown in FIG. 7, the branched portion may not be along the first direction but may be formed in a zigzag shape.
- the first thin wire electrode 12A is branched in the region C, it is preferable that the first thin wire electrode 12A is branched in a region where one end of the wiring member 5 is crimped. Thereby, it can suppress that peeling generate
- the island-shaped member 14 is formed of an insulating member.
- the island-shaped member 14 may be formed using a conductive paste similar to the thin wire electrode.
- the second electrode 13 has a plurality of second fine wire electrodes 13A.
- the shape of the second electrode 13 is not limited to this.
- the second electrode 13 may be an electrode formed on the substantially entire second main surface (back surface) B.
- Example 1 First, an n-type single crystal silicon substrate having a size of 108 mm square, a thickness of 150 ⁇ m, and a resistivity of 1 ⁇ cm was prepared.
- an i-type amorphous silicon layer having a thickness of 5 nm and a p-type amorphous silicon layer having a thickness of 5 nm were sequentially formed on the light receiving surface of the substrate by using an RF plasma CVD method.
- an i-type amorphous silicon layer having a thickness of 5 nm and an n-type amorphous silicon layer having a thickness of 5 nm were sequentially formed on the back surface of the substrate.
- the conditions of the RF plasma CVD apparatus were set to a frequency of 13.56 MHz, a forming temperature of 100 to 200 ° C., a reaction pressure of 20 to 80 Pa, and an RF power of 10 to 100 W.
- an ITO film having a thickness of 100 nm was formed on the p-type and n-type amorphous silicon layers by using a magnetron sputtering method.
- the sputtering apparatus was set to a forming temperature of 50 to 200 ° C., an Ar gas flow rate of 200 sccm, an oxygen gas flow rate of 50 sccm, a power of 0.5 to 3 kW, and a magnetic field strength of 500 to 3000 gauss.
- the photoelectric conversion part was produced by the above.
- an epoxy thermosetting silver paste was printed with a pattern shown in FIG. 3A on the light receiving surface of the solar cell by using a screen printing method. Specifically, 52 thin wire electrodes (width 100 ⁇ m) were formed at intervals of 2 mm. The silver paste was temporarily cured by heating at 150 ° C. for 5 minutes.
- an epoxy thermosetting silver paste was printed on the back surface of the solar cell in the pattern shown in FIG. Specifically, 104 fine wire electrodes (width 100 ⁇ m) are formed at intervals of 1 mm, and in the region where the wiring material is connected, the 104 fine wire electrodes are joined together to form a set of 52 fine wires. Electrodes were formed at 2 mm intervals. Next, the silver paste on the light receiving surface and the back surface was cured by heating at 200 ° C. for 1 hour.
- an epoxy resin containing about 5% by volume of nickel particles was applied at a thickness of 30 ⁇ m on the light receiving surface and the back surface to the area where the wiring material was connected.
- an epoxy resin formed in a tape shape may be arranged on the light receiving surface and the back surface in the region where the wiring material is connected.
- a wiring material was placed on the applied epoxy resin and heated at 200 ° C. for about 1 hour while being pressurized at about 2 MPa. As a result, the thin wire electrode was bitten into the wiring material and the epoxy resin was cured. By repeating this, a solar cell string was produced.
- the solar cell string disposed between the glass and the PET film was sealed with EVA.
- 1000 solar cell modules according to Example 1 were manufactured.
- Example 2 1000 solar cell modules according to Example 2 were produced.
- the difference between Example 2 and Example 1 is that the silver paste was printed in the pattern shown in FIG.
- an epoxy thermosetting silver paste was printed in a pattern shown in FIG. 4 (a) on the light receiving surface of the solar cell by using a screen printing method.
- 52 fine wire electrodes are formed at intervals of 2 mm, and in the region where the wiring material is connected, one fine wire electrode is branched into two, so that 104 fine wire electrodes are formed. They were formed at 1 mm intervals.
- an epoxy thermosetting silver paste was printed on the back surface of the solar cell in the pattern shown in FIG. 4 (b). Specifically, 104 fine wire electrodes (width 100 ⁇ m) were formed at 1 mm intervals. The other points are the same as in the first embodiment.
- Comparative Example 1 1000 solar cell modules according to Comparative Example 1 were produced.
- the difference between Comparative Example 1 and Example 1 is that the thin wire electrode is not branched or joined in the region where the wiring material is connected.
- the temperature cycle test was performed in accordance with the provisions of JIS C 8917. Specifically, each sample is held in a thermostatic bath, raised from 25 ° C. to 90 ° C. over 45 minutes, held at this temperature for 90 minutes, and then lowered to ⁇ 40 ° C. over 90 minutes. Hold for 90 minutes and then increase to 25 ° C. over 45 minutes. This was regarded as one cycle (6 hours) and 600 cycles were performed.
- the output reduction rate of the solar cells according to Examples 1 and 2 was smaller than that of the solar cell according to the comparative example.
- the electrode formation area per unit area in the wiring material connection region on the back surface was brought close to the light receiving surface. Further, in the solar cell according to Example 2, the electrode formation area per unit area in the wiring material connection region on the light receiving surface was brought close to the back surface. That is, in the solar cells according to Examples 1 and 2, the first relationship ((v / w) ⁇ 1) and the second relationship ((v / w) ⁇ (x / y)) are established. .
- the amount of the fine wire electrode on the back surface digged into the wiring material was smaller than that of the fine wire electrode on the light receiving surface.
- a stress corresponding to a temperature change is applied from a sealing material (EVA) having a larger linear expansion coefficient than that of the wiring material, resulting in poor connection between the thin wire electrode on the back surface and the wiring material.
- EVA sealing material
- the thin wire electrode on the back surface is established by establishing the second relationship ((v / w) ⁇ (x / y)). It was confirmed that the electrical and mechanical connection between and the wiring material can be maintained well.
- the present invention it is possible to provide a solar cell module that can maintain a good connection between the thin wire electrode formed on the back surface of the solar cell and the wiring material, and thus is useful in the photovoltaic power generation field. It is.
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Abstract
Description
(太陽電池モジュールの概略構成)
本発明の第1実施形態に係る太陽電池モジュール1の概略構成について、図1及び図2を参照しながら説明する。図1は、本実施形態に係る太陽電池モジュール1の側面図である。図2(a)は、太陽電池モジュール1の受光面側の平面図である。図2(b)は、太陽電池モジュール1の裏面側の平面図である。
次に、第1電極12及び第2電極13の構成について、図3を参照しながら説明する。図3(a)は、太陽電池10の第1主面(受光面)A側の平面図である。図3(b)は、太陽電池10の第2主面(裏面)B側の平面図である。
以上より、第1電極12の形成面積と、第2電極13の形成面積との間には、次の関係が成立する。
次に、本実施形態に係る太陽電池モジュール1の製造方法について説明する。
本実施形態に係る太陽電池10において、第1電極12は、第1接続部12aと第1露出部12bとを有し、第2電極13は、第2接続部13aと第2露出部13bとを有する。この場合において、上記第1の関係((v/w)<1)と、上記第2の関係((v/w)<(x/y))とが成立する。
次に、本発明の第2実施形態について、図面を参照しながら説明する。本実施形態と上記第1実施形態との相違点は、領域Cにおける単位面積当たりの電極形成面積を、領域Dに近づけている点である。その他の点については上記第1実施形態と同様であるため、以下、相違点について主に説明する。
本実施形態に係る第1電極12及び第2電極13の構成について、図4を参照しながら説明する。図4(a)は、太陽電池10の第1主面(受光面)A側の平面図である。図4(b)は、太陽電池10の第2主面(裏面)B側の平面図である。
以上より、本実施形態においても、第1電極12の形成面積と第2電極13の形成面積との間には、上記第1実施形態と同様に、第1の関係((v/w)<1)と第2の関係((v/w)<(x/y))とが成立する。
本実施形態に係る太陽電池10においても、上記第1の関係((v/w)<1)と、上記第2の関係((v/w)<(x/y))とが成立する。
次に、本発明の第3実施形態について、図面を参照しながら説明する。本実施形態と上記第2実施形態との相違点は、領域Cに島状部材14が形成される点である。その他の点については上記第2実施形態と同様であるため、以下、相違点について主に説明する。
本実施形態に係る第1電極12及び第2電極13の構成について、図5を参照しながら説明する。図5(a)は、太陽電池10の第1主面A側の平面図である。図5(b)は、太陽電池10の第2主面B側の平面図である。
以上より、第1部材群12´の形成面積と複数本の第2細線電極13Aの形成面積との間において、上記第2実施形態と同様に、第1の関係((v/w)<1)と第2の関係((v/w)<(x/y))とが成立する。
本実施形態に係る太陽電池10においても、上記第1の関係((v/w)<1)と、上記第2の関係((v/w)<(x/y))とが成立する。
本発明は上記の実施形態によって記載したが、この開示の一部をなす論述及び図面はこの発明を限定するものであると理解すべきではない。この開示から当業者には様々な代替実施形態、実施例及び運用技術が明らかとなろう。
まず、寸法108mm角、厚み150μm、抵抗率1Ωcmのn型単結晶シリコン基板を準備した。
次に、実施例2に係る太陽電池モジュールを1000枚作製した。実施例2と上記実施例1との相違点は、銀ペーストを図4に示すパターンで印刷した点である。
次に、比較例1に係る太陽電池モジュールを1000枚作製した。比較例1と上記実施例1との相違点は、配線材を接続する領域において細線電極を分岐又は結合させない点である。
実施例1、実施例2及び比較例に係る太陽電池について、恒温槽を用いて温度サイクル試験を行い、試験後における太陽電池の出力低下率を比較した。測定結果を下表に示す。なお、下表中の数値は、1000枚の太陽電池についての平均値である。
Claims (10)
- 太陽電池と、
前記太陽電池の受光面上に接続される一の配線材と、
前記太陽電池の前記受光面の反対側に設けられる裏面上に接続される他の配線材とを備え、
前記太陽電池は、前記受光面上に形成される複数本の第1細線電極を少なくとも含む第1部材群と、前記裏面上に形成される第2電極とを有しており、
前記第1部材群は、前記一の配線材に接続される第1接続部と、前記一の配線材から露出する一群の第1露出部とを有し、
前記第2電極は、前記他の配線材に接続される第2接続部と、前記他の配線材から露出する第2露出部とを有しており、
前記受光面の面積に対する前記第1露出部が形成される面積の比率である第1比率は、前記裏面の面積に対する前記第2露出部が形成される面積の比率である第2比率より小さく、
前記第1比率の前記第2比率に対する比は、前記受光面のうち前記一の配線材が接続される領域の面積に対する前記第1接続部が形成される面積の比率である第3比率の、前記裏面のうち前記他の配線材が接続される領域の面積に対する前記第2接続部が形成される面積の比率である第4比率に対する比よりも小さい
ことを特徴とする太陽電池モジュール。 - 前記第2電極は、前記複数本の第2細線電極を有し、
前記複数本の第2細線電極は、前記第2接続部と前記第2露出部とを有する
ことを特徴とする請求項1に記載の太陽電池モジュール。 - 前記第1接続部は、前記一の配線材に直接接触して接続される
ことを特徴とする請求項1又は2に記載の太陽電池モジュール。 - 前記第2接続部は、前記他の配線材に直接接触して接続される
ことを特徴とする請求項1又は2に記載の太陽電池モジュール。 - 前記複数本の第2細線電極のうち少なくとも2本の第2細線電極は、前記他の配線材が接続される領域において1本に結合される
ことを特徴とする請求項2に記載の太陽電池モジュール。 - 前記複数本の第1細線電極のうち少なくとも1本の第1細線電極は、前記一の配線材が接続される領域において複数本に分岐される
ことを特徴とする請求項1又は2に記載の太陽電池モジュール。 - 前記第1部材群は、前記一の配線材が接続される領域内において島状に形成された島状部材を含む
ことを特徴とする請求項1又は2に記載の太陽電池モジュール。 - 太陽電池と、
前記太陽電池の受光面上に接続される一の配線材と、
前記太陽電池の前記受光面の反対側に設けられる裏面上に接続される他の配線材とを備え、
前記太陽電池は、前記受光面上に形成される第1電極と、前記裏面上に形成される第2電極とを有しており、
前記第1電極は、前記一の配線材に接続される第1接続部と、前記一の配線材から露出する第1露出部とを有し、
前記第2電極は、前記他の配線材に接続される第2接続部と、前記他の配線材から露出する第2露出部とを有し、
前記第1露出部の面積は、前記第2露出部の面積より小さく、
前記第2露出部の面積に対する前記第1露出部の面積の比率は、前記第2接続部の面積に対する前記第1接続部の面積の比率よりも小さい
ことを特徴とする太陽電池モジュール。 - 光電変換部と、
前記光電変換部の第1主面上に形成される複数本の第1細線電極を少なくとも含む第1部材群と、
前記光電変換部の第2主面上に形成される第2電極と
を備え、
前記複数本の第1細線電極に一の配線材が電気的に接続され、前記第2電極に他の配線材が電気的に接続される太陽電池であって、
前記第1部材群は、前記一の配線材に接続される第1接続部と、前記一の配線材から露出する第1露出部とを有し、
前記第2電極は、前記他の配線材に接続される第2接続部と、前記他の配線材から露出する第2露出部とを有し、
前記第1主面の面積に対する前記第1露出部の面積の比率である第1比率は、前記第2主面の面積に対する前記第2露出部の面積の比率である第2比率より小さく、
前記第2比率に対する前記第1比率の比は、前記第1主面のうち前記一の配線材が接続される領域の面積に対する前記第1接続部の面積の比率である第3比率の、前記第2主面のうち前記他の配線材が接続される領域の面積に対する前記第2接続部の面積の比率である第4比率に対する比よりも小さい
ことを特徴とする太陽電池。 - 光電変換部と、
前記光電変換部の第1主面上に形成される第1電極と、
前記光電変換部の第2主面上に形成される第2電極と
を備え、
前記第1電極に一の配線材が電気的に接続され、前記第2電極に他の配線材が電気的に接続される太陽電池であって、
前記第1電極は、前記一の配線材に接続される第1接続部と、前記一の配線材から露出する第1露出部とを有し、
前記第2電極は、前記他の配線材に接続される第2接続部と、前記他の配線材から露出する第2露出部とを有し、
前記第1露出部の面積は、前記第2露出部の面積より小さく、
前記第2露出部の面積に対する前記第1露出部の面積の比率は、前記第2接続部の面積に対する前記第1接続部の面積の比率よりも小さい
ことを特徴とする太陽電池。
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Also Published As
Publication number | Publication date |
---|---|
EP2267794A1 (en) | 2010-12-29 |
JP5367587B2 (ja) | 2013-12-11 |
CN101939847A (zh) | 2011-01-05 |
US20110011454A1 (en) | 2011-01-20 |
CN101939847B (zh) | 2012-04-25 |
EP2267794A4 (en) | 2015-10-14 |
JPWO2009099179A1 (ja) | 2011-05-26 |
KR20100124715A (ko) | 2010-11-29 |
KR101485623B1 (ko) | 2015-01-23 |
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