US7253117B2 - Methods for use of pulsed voltage in a plasma reactor - Google Patents

Methods for use of pulsed voltage in a plasma reactor Download PDF

Info

Publication number
US7253117B2
US7253117B2 US10/408,542 US40854203A US7253117B2 US 7253117 B2 US7253117 B2 US 7253117B2 US 40854203 A US40854203 A US 40854203A US 7253117 B2 US7253117 B2 US 7253117B2
Authority
US
United States
Prior art keywords
positive voltage
pedestal
delivering
spike
power source
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime, expires
Application number
US10/408,542
Other versions
US20030211754A1 (en
Inventor
Kevin G. Donohoe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
US Bank NA
Original Assignee
Micron Technology Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Micron Technology Inc filed Critical Micron Technology Inc
Priority to US10/408,542 priority Critical patent/US7253117B2/en
Publication of US20030211754A1 publication Critical patent/US20030211754A1/en
Application granted granted Critical
Publication of US7253117B2 publication Critical patent/US7253117B2/en
Assigned to U.S. BANK NATIONAL ASSOCIATION, AS COLLATERAL AGENT reassignment U.S. BANK NATIONAL ASSOCIATION, AS COLLATERAL AGENT SECURITY INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: MICRON TECHNOLOGY, INC.
Assigned to MORGAN STANLEY SENIOR FUNDING, INC., AS COLLATERAL AGENT reassignment MORGAN STANLEY SENIOR FUNDING, INC., AS COLLATERAL AGENT PATENT SECURITY AGREEMENT Assignors: MICRON TECHNOLOGY, INC.
Assigned to U.S. BANK NATIONAL ASSOCIATION, AS COLLATERAL AGENT reassignment U.S. BANK NATIONAL ASSOCIATION, AS COLLATERAL AGENT CORRECTIVE ASSIGNMENT TO CORRECT THE REPLACE ERRONEOUSLY FILED PATENT #7358718 WITH THE CORRECT PATENT #7358178 PREVIOUSLY RECORDED ON REEL 038669 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY INTEREST. Assignors: MICRON TECHNOLOGY, INC.
Assigned to JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT reassignment JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT SECURITY INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: MICRON SEMICONDUCTOR PRODUCTS, INC., MICRON TECHNOLOGY, INC.
Assigned to MICRON TECHNOLOGY, INC. reassignment MICRON TECHNOLOGY, INC. RELEASE BY SECURED PARTY (SEE DOCUMENT FOR DETAILS). Assignors: U.S. BANK NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Assigned to MICRON TECHNOLOGY, INC. reassignment MICRON TECHNOLOGY, INC. RELEASE BY SECURED PARTY (SEE DOCUMENT FOR DETAILS). Assignors: MORGAN STANLEY SENIOR FUNDING, INC., AS COLLATERAL AGENT
Assigned to MICRON TECHNOLOGY, INC., MICRON SEMICONDUCTOR PRODUCTS, INC. reassignment MICRON TECHNOLOGY, INC. RELEASE BY SECURED PARTY (SEE DOCUMENT FOR DETAILS). Assignors: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
Adjusted expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/302Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
    • H01L21/306Chemical or electrical treatment, e.g. electrolytic etching
    • H01L21/3065Plasma etching; Reactive-ion etching
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/32009Arrangements for generation of plasma specially adapted for examination or treatment of objects, e.g. plasma sources

Definitions

  • the reoriented trajectories result in more negatively charged electrons entering into a feature (such as a via being etched into a material layer over a semiconductor substrate) and increase the energy of the negatively charged electrons incident on the material layer to be etched, both of which increase etching efficiency.
  • a feature such as a via being etched into a material layer over a semiconductor substrate
  • the strong positive field at the bottom of the via i.e., illustrated with “+” indicia accelerates the negatively charged electrons toward the via, which results in the negatively charged electron striking the bottom of the via with higher energy.
  • FIG. 7 is a cross-sectional view of a via during a prior art etching process wherein feature charging results in the deflection of positively charged ions away from the bottom of the via and toward the sidewalls of the via;
  • a plasma 122 is maintained by inductively coupling energy from the first power source 104 into the plasma 122 , which comprises mobile, positively and negatively charged particles.
  • An electric field, or bias voltage develops in a sheath layer 124 around the plasma 122 , accelerating the electrons and ions (not shown) toward the semiconductor substrate 108 by electrostatic coupling.
  • the present invention is capable of providing a simple and controllable method of affecting the quality and efficiency of plasma etching and is easily implemented on most existing plasma reactors.
  • the present invention is useful in etching apertures having a length-to-diameter ratio of 5:1 or greater in insulating materials deposited by plasma enhanced chemical vapor deposition techniques. Such insulating materials include oxides, nitrides, polymers, combinations thereof, etc.
  • insulating materials include oxides, nitrides, polymers, combinations thereof, etc.

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Drying Of Semiconductors (AREA)
  • Plasma Technology (AREA)
  • Chemical Vapour Deposition (AREA)

Abstract

A method and apparatus for providing a positive voltage spike to a semiconductor substrate pedestal during a portion of a high voltage power bias oscillation cycle to reduce or eliminate the detrimental effects of feature charging during the operation of a plasma reactor.

Description

CROSS-REFERENCE TO RELATED APPLICATION
This application is a continuation of application Ser. No. 09/640,449, filed Aug. 17, 2000, now U.S. Pat. No. 6,544,895, issued Apr. 8, 2003.
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to plasma reactor apparatus and processes. More specifically, the present invention relates to spiking the voltage to a semiconductor substrate pedestal during a portion of a positive voltage power bias oscillation cycle to reduce or eliminate the detrimental effects of feature charging during the operation of a plasma reactor.
2. State of the Art
Higher performance, lower cost, increased miniaturization of electronic components, and greater density of integrated circuits are ongoing goals of the computer industry. One commonly used technique to increase the density of integrated circuits involves stacking of multiple layers of active and passive components one atop another to allow for multilevel electrical interconnection between devices formed on each of these layers. This multilevel electrical interconnection is generally achieved with a plurality of metal-filled vias (“contacts”) extending through dielectric layers which separate the component layers from one another. These vias are generally formed by etching through each dielectric layer by etching methods known in the industry, such as plasma etching. Plasma etching is also used in the forming of a variety of features for the electronic components of integrated circuits.
In plasma etching, a glow discharge is used to produce reactive species, such as atoms, radicals, and/or ions, from relatively inert gas molecules in a bulk gas, such as a fluorinated gas, such as CF4, CHF3, C2F6, CH2F2, SF6, or other freons, and mixtures thereof, in combination with a carrier gas, such as Ar, He, Ne, Kr, O2, or mixtures thereof. Essentially, a plasma etching process comprises: 1) reactive species are generated in a plasma from the bulk gas, 2) the reactive species diffuse to a surface of a material being etched, 3) the reactive species are absorbed on the surface of the material being etched, 4) a chemical reaction occurs that results in the formation of a volatile by-product, 5) the by-product is desorbed from the surface of the material being etched, and 6) the desorbed by-product diffuses into the bulk gas.
As illustrated in drawing FIG. 4, an apparatus 200 used in the plasma etching process consists of an etching chamber 202 in electrical communication with a first AC power source 204. The etching chamber 202 further includes a pedestal 206 to support a semiconductor substrate 208 and an electrode 212 opposing the pedestal 206. The electrode 212 is in electrical communication with a second AC power source 214. The pedestal 206 may have either an AC (alternating current) bias source or DC (direct current) bias source 216.
In the etching chamber 202, a plasma 222 is maintained by inductively coupling energy from the first power source 204 into the plasma 222, which comprises mobile, positively and negatively charged particles. An electric field, or bias voltage, develops in a sheath layer 224 around the plasma 222, accelerating the electrons and ions (not shown) toward the semiconductor substrate 208 by electrostatic coupling.
To assist with the etching, the potential difference between the plasma 222 and the semiconductor substrate 208 can be modulated by applying an oscillating bias power from the pedestal power bias source 216 to the pedestal 206, as illustrated in drawing FIG. 5 (showing the voltage profiles during such oscillation). During the positive voltage phase 232, the substrate collects electron current from electrons that have enough energy to cross the sheath. The difference between the instantaneous plasma potential and the surface potential defines the sheath potential drop. Since the plasma potential is more positive than the surface potential, this drop has a polarity that retards electron flow. Hence, only electrons with energy larger than this retarding potential are collected by the substrate. During the negative voltage phase 234, positive ions are collected by the substrate. These ions are accelerated by the sheath voltage drop and strike the substrate.
However, it is known that the plasma etching process (as well as ion implantation and other charge beam processes) may cause damage to the semiconductor substrate and to the devices and circuits formed therein or thereon. In particular, electrical charging is a well-known problem which can occur during the plasma processing of semiconductor devices, leading to the degradation of the device performance.
Illustrated in drawing FIG. 6 is the phenomenon of electrical charging on a semiconductor device in the process of a plasma etch. A material layer 244 to be etched is shown layered over a semiconductor substrate 242. A patterned photoresist layer 246 is provided on the material layer 244 for the etching of a via. During the plasma etching process, the patterned photoresist layer 246 and material layer 244 are bombarded with positively charged ions 248 and negatively charged electrons 252 (i.e., the reactive species). This bombardment results in a charge distribution being developed on the patterned photoresist layer 246 and/or the semiconductor substrate 242. This charge distribution is commonly called “feature charging.”
In order for feature charging to occur, the positively charged ions 248 and the negatively charged electrons 252 must become separated from one another. The positively charged ions 248 and negatively charged electrons 252 become separated by virtue of the structure being etched. As the structure (in this example a via 254) is formed by etching, the aspect ratio (height-to-width ratio) becomes greater and greater. During plasma etching, the positively charged ions 248 are accelerated (e.g., as a result of a DC bias at the semiconductor substrate 242) toward the patterned photoresist layer 246 and the material layer 244 in a relatively perpendicular manner, as illustrated by the arrows adjacent positively charged ions 248. The negatively charged electrons 252, however, are less affected by the DC bias at the semiconductor substrate 242 and, thus, move in a more random isotropic manner, as depicted by the arrows adjacent negatively charged electrons 252. This results in an accumulation of a positive charge at a bottom 256 of via 254 because, on average, positively charged ions 248 are more likely to travel vertically toward the substrate 208 than are negatively charged electrons 252. Thus, any structure with a high enough aspect ratio tends to charge more negatively at photoresist layer 246 and an upper portion of the material layer 244 to a distance A (i.e., illustrated with “−” indicia) and more positively at the via bottom 256 and the sidewalls 258 of the via 254 proximate the via bottom 256 (i.e., illustrated with “+” indicia).
As shown in drawing FIG. 7, the positively charged via bottom 256 deflects the positively charged ions 248 away from the via bottom 256 and toward the sidewalls 258 of the via 254, as a result of charge repulsion. The deflection results in an etching of the sidewalls 258 proximate the via bottom 256, known as “notching.” Furthermore, the presence of the positively charged via bottom 256 slows the positively charged ions 248 as they approach the positively charged via bottom 256, thereby reducing etching efficiency.
As shown in drawing FIG. 8, the negatively charged photoresist layer 246 and the upper portion of the material layer 244 deflect the negatively charged electrons 252 away from entering the via 254 or slows the negatively charged electrons 252 as they enter the via 254, both caused by charge repulsion and both of which reduce etching efficiency.
Thus, it can be appreciated that it would be advantageous to develop an apparatus and a process of utilizing a plasma reactor that eliminates or lessens the effect of feature charging, while using inexpensive, commercially available, semiconductor device fabrication components and without requiring complex processing steps.
BRIEF SUMMARY OF THE INVENTION
The present invention relates to an apparatus and method of both increasing the energy of electrons striking a material on a semiconductor substrate and reorienting electrons generated in a plasma reactor to strike a material on a semiconductor substrate in a substantially perpendicular trajectory, both of which reduce feature charging.
One embodiment of the present invention comprises an etching chamber in electrical communication with a first power source. The etching chamber further includes a pedestal to support a semiconductor substrate and an electrode opposing the pedestal. The electrode is in electrical communication with a first power source. The pedestal is in electrical communication with a second power source and a pulsed power source. When triggered, the pulsed power source delivers a timed, positive voltage spike to the pedestal. The pulsed power source is preferably in electrical communication with the second power source with a signal line.
As previously discussed, the potential difference between the plasma and the semiconductor substrate can be modulated by applying an oscillating bias power from the pedestal power bias source to the semiconductor substrate. During the positive voltage phase, the substrate collects electron current from electrons that have enough energy to cross the sheath. The difference between the instantaneous plasma potential and the surface potential defines the sheath potential drop. Since the plasma potential is more positive than the surface potential, this drop has a polarity that retards electron flow. Hence, only electrons with energy larger than this retarding potential are collected by the substrate. During the negative voltage phase 234, positive ions are collected by the substrate. These ions are accelerated by the sheath voltage drop and strike the substrate.
Negatively charged electrons are less affected by the typical DC bias at the semiconductor substrate than are positively charged ions and, thus, move in a more random manner, as depicted by the arrows adjacent negatively charged electrons. However, providing a positive voltage spike to the pedestal according to the present invention alters the difference between the potential of the plasma and the potential of the semiconductor substrate for a part of the positive voltage phase. The voltage spiking of the pedestal, thus, reorients the trajectory of negatively charged electrons into a more perpendicular path with respect to the semiconductor substrate. The reoriented trajectories result in more negatively charged electrons entering into a feature (such as a via being etched into a material layer over a semiconductor substrate) and increase the energy of the negatively charged electrons incident on the material layer to be etched, both of which increase etching efficiency. Additionally, the strong positive field at the bottom of the via (i.e., illustrated with “+” indicia) accelerates the negatively charged electrons toward the via, which results in the negatively charged electron striking the bottom of the via with higher energy. The increase in negatively charged electrons entering the via also reduces feature charging because the negative charge that tends to build up at the photoresist layer and an upper portion of the material layer, as previously discussed, penetrates deeper into the via a distance A′ (i.e., illustrated with “−” indicia). The deeper penetration of the negative charge distributes the negative charge over a greater volume or area, thereby reducing the local intensity of the negative charge which reduces or eliminates the negative charge's tendency to repel the negatively charged electrons from the via. Further, the deeper penetration of the negative charge reduces the positive charge buildup at the sidewalls of the via, thereby reducing, minimizing, or eliminating the previously discussed detrimental effect on the positively charged ions entering the via. In other words, providing a positive voltage spike to the pedestal reduces, minimizes or eliminates the problems associated with feature charging.
The delivery of the positive voltage spike is preferably controlled by the power output of the pulsed power source. Thus, when the power output of the second power source reaches a predetermined level, a signal is sent from the second power source (or from a sensor (not shown) coupled with the second power source) to the pulsed power source via the signal line. When the signal is received by the pulsed power source, the pulsed power source provides a positive voltage spike to the pedestal for a predetermined duration of time.
It is, of course, understood that if the second power source is capable of providing a positive voltage spike, the pulsed power source will not be necessary. When the power output level of the second power bias source is reached, a positive voltage spike is generated by the second power source and delivered to the pedestal for a predetermined duration of time.
Thus, the present invention is capable of providing a simple and controllable method of affecting the quality and efficiency of plasma etching and is easily implemented on most existing plasma reactors.
Although the examples presented are directed to the formation of a via, it is understood that the present invention may be utilized in a variety of feature formation and plasma processes.
BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWINGS
While the specification concludes with claims particularly pointing out and distinctly claiming that which is regarded as the present invention, the advantages of this invention can be more readily ascertained from the following description of the invention when read in conjunction with the accompanying drawings in which:
FIG. 1 is a schematic of a plasma etching apparatus according to the present invention;
FIG. 2 is an idealized graph of an oscillating voltage profile of a plasma etching apparatus pedestal according to the present invention;
FIG. 3 is a cross-sectional view of a via during an etching process according to the present invention;
FIG. 4 is a schematic of a prior art plasma etching apparatus;
FIG. 5 is an idealized graph of a prior art oscillating voltage profile of a plasma etching apparatus pedestal;
FIG. 6 is a cross-sectional view of a via during a prior art etching process that results in the phenomenon of feature charging;
FIG. 7 is a cross-sectional view of a via during a prior art etching process wherein feature charging results in the deflection of positively charged ions away from the bottom of the via and toward the sidewalls of the via; and
FIG. 8 is a cross-sectional view of a via during a prior art etching process wherein feature charging results in the deflection of negatively charged electrons away from entering the via or slows the negatively charged electrons as they enter the via.
DETAILED DESCRIPTION OF THE INVENTION
Illustrated in drawing FIGS. 1 through 3 are various schematics, views, and graphs of the present invention. It should be understood that the illustrations are not meant to be actual views of any particular semiconductor device, but are merely idealized representations that are employed to more clearly and fully depict the formation of contact interfaces in the present invention than would otherwise be possible. Additionally, elements common between drawing FIGS. 1 through 3 retain the same numerical designation.
As illustrated in drawing FIG. 1, one embodiment of an etching apparatus 100 of the present invention comprises an etching chamber 102 in electrical communication with a first power source 104, such as an AC power source, a microwave power source, etc. The etching chamber 102 further includes a pedestal 106 to support a semiconductor substrate 108 and an electrode, typically a coil or coils, 112 opposing the pedestal 106. The electrode 112 is in electrical communication with power source 114. The pedestal 106 is in electrical communication with a second power source 116.
In the etching chamber 102, a plasma 122 is maintained by inductively coupling energy from the first power source 104 into the plasma 122, which comprises mobile, positively and negatively charged particles. An electric field, or bias voltage, develops in a sheath layer 124 around the plasma 122, accelerating the electrons and ions (not shown) toward the semiconductor substrate 108 by electrostatic coupling.
The pedestal 106 is further in electric communication with a secondary pulsed power source 126. When triggered, the secondary pulsed power source 126 delivers a positive voltage spike to the pedestal 106. The second power source 116 is preferably in electrical communication with the secondary pulsed power source 126 with a signal line 132.
As previously discussed, the potential difference between the plasma 122 and the semiconductor substrate 108 can be modulated by applying an oscillating bias power from the secondary pulsed power source 126 to the semiconductor substrate 108, as illustrated in drawing FIG. 2 (showing the voltage profile during such oscillation). During the positive voltage phase 134, the deposition of the reactant species onto the semiconductor substrate 108 proceeds at a high rate. During the negative voltage phase 136, the diffusion of reaction by-products away from the semiconductor substrate 108 proceeds at a high rate. However, as also illustrated in drawing FIG. 2, the present invention comprises the delivery of a positive power spike to the pedestal 106 during the positive voltage phase 134 (i.e., during the time the electrons flow to the wafer) for a duration 138 of time.
As previously discussed and illustrated in prior art drawing FIG. 6, negatively charged electrons 252 are less affected by the typical DC bias at the semiconductor substrate than are positively charged ions and, thus, move in a more random manner, as depicted by the arrows adjacent negatively charged electrons 252 in prior art drawing FIG. 6. However, the delivery of a positive voltage spike to the pedestal 106, according to the present invention, alters the difference between the potential of the plasma 122 and the potential of the semiconductor substrate 108 for a part of the positive voltage phase 134, as shown in drawing FIG. 2. The delivery of the positive voltage spike to the pedestal 106, thus, reorients the trajectory of negatively charged electrons 142 into a more perpendicular path with respect to the semiconductor substrate 108, as shown in drawing FIG. 3. The reoriented trajectories result in more negatively charged electrons 142 accelerating toward the semiconductor substrate 108 and entering into the feature, specifically shown as an opening or via 144 being etched through a photoresist material 140 into a material layer 146 over a semiconductor support 148, and increases the energy of the negatively charge electrons 142 incident on the material layer 146, both of which increase etching efficiency. Additionally, a strong positive field at the bottom of the opening or via 144 (i.e., illustrated with “+” indicia) which results from the positive voltage spike accelerates the negatively charged electrons 142 toward the bottom of the via 144, which results in the negatively charged electrons 142 striking the bottom of the via 144 with higher energy (i.e., the use of the positive voltage spike permits control of the driving force for the electron acceleration). The increase in negatively charged electrons 142 entering the opening or via 144 also reduces feature charging because the negative charge, which tends to build up at the patterned photoresist layer 140 and an upper portion of the material layer 146, as previously discussed, penetrates deeper into the via a distance A′ (i.e., illustrated with “−” indicia). The deeper penetration of the negative charge distributes the negative charge over a greater area, thereby reducing or eliminating its detrimental effect on the negatively charged electrons 142. Further, the deeper penetration of the negative charge reduces the positive charge buildup at the sidewalls adjacent the bottom 152, thereby reducing or eliminating the previously discussed detrimental effect on the positively charged ions 248 entering the via 144. In other words, the positive voltage spike on the pedestal 106 reduces, minimizes or eliminates the problems associated with feature charging.
Referring to drawing FIG. 1, the secondary pulsed power source 126 is preferably controlled by the power output of the second power source 116. Thus, when the power output of second power source 116 reaches a predetermined level, a signal is sent from the second power source 116 (or from a sensor (not shown) coupled with the second power source 116) to the secondary pulsed power source 126 via the signal line 132. When the signal is received by the secondary pulsed power source 126, the secondary pulsed power source 126 delivers a positive voltage spike to the pedestal 106 for a predetermined duration of time. Thus, the positive voltage spike can be controlled to occur at any point and for any duration during the high voltage cycle to achieve the desired etching results for a particular semiconductor material.
It is, of course, understood that if the second power source 116 is capable of providing a positive voltage spike, the secondary pulsed power source 126 will not be necessary. When the power output of the second power source 116 is reached, a positive voltage spike is generated by the second power source 116 and delivered to the pedestal 106 for a predetermined duration of time.
It is further understood that an internal device, such as a microprocessor, may control both the oscillations of the second power source 116 and the delivery of the positive voltage spike, whether generated by the second power source 116 or the secondary pulsed power source 126.
Thus, the present invention is capable of providing a simple and controllable method of affecting the quality and efficiency of plasma etching and is easily implemented on most existing plasma reactors. The present invention is useful in etching apertures having a length-to-diameter ratio of 5:1 or greater in insulating materials deposited by plasma enhanced chemical vapor deposition techniques. Such insulating materials include oxides, nitrides, polymers, combinations thereof, etc. Furthermore, although the examples presented are directed to the formation of an opening or via, it is understood that the present invention may be utilized in a variety of feature formation and plasma processes.
Having thus described in detail preferred embodiments of the present invention, it is to be understood that the invention defined by the appended claims is not to be limited by particular details set forth in the above description as many apparent variations thereof are possible without departing from the spirit or scope thereof.

Claims (11)

1. A method for a plasma reactor comprising:
providing a plasma reactor including a pedestal for supporting a semiconductor substrate and a power source in electrical communication with said pedestal;
delivering an electrical signal to said pedestal from said power source, wherein a voltage of said electrical signal oscillates between a positive voltage phase having a duration of time and a negative voltage phase having a duration of time; and
delivering a positive voltage spike having a voltage higher than that of the maximum voltage of the positive voltage phase and having a duration of time less than the duration of time of the positive voltage phase to said pedestal during said positive voltage phase, said delivering said positive voltage spike to said pedestal comprising generating a positive voltage spike within a secondary power source and delivering said positive voltage spike to said pedestal during said positive voltage phase for a duration of time when a predetermined voltage level is reached.
2. The method of claim 1, wherein said delivering said positive voltage spike to said pedestal further comprises:
monitoring said voltage in said positive voltage phase until said voltage reaches said predetermined voltage level.
3. The method of claim 1, wherein said delivering said positive voltage spike to said pedestal comprises generating a positive voltage spike within said power source and delivering said positive voltage spike to said pedestal during said positive voltage phase.
4. An etching method for forming an opening in an insulating material deposited using a plasma enhanced chemical vapor deposition technique for a semiconductor device utilizing a plasma reactor chamber including a pedestal for supporting a semiconductor substrate and a power source in electrical communication with said pedestal, said pedestal including a switch in electrical communication therewith for opening and closing an electrical path, said method comprising:
placing said semiconductor substrate on said pedestal, said semiconductor substrate having a material layer thereover and a photoresist layer patterned on said material layer;
generating a plasma above said semiconductor substrate;
delivering an electrical signal to said pedestal from said power source, wherein a voltage of said electrical signal oscillates between a positive voltage phase having a duration of time and a negative voltage phase having a duration of time;
delivering a positive voltage spike having a voltage higher than that of the maximum voltage of the positive voltage phase and having a duration of time less than the duration of time of the positive voltage phase to said pedestal during said positive voltage phase, said delivering said positive voltage spike to said pedestal comprising generating a positive voltage spike within a secondary power source and delivering said positive voltage spike to said pedestal during said positive voltage phase when a predetermined voltage level is reached; and
forming at least a portion of an opening in an insulating material.
5. The method of claim 4, wherein said delivering said positive voltage spike to said pedestal further comprises:
monitoring said voltage in said positive voltage phase until said voltage reaches said predetermined voltage level.
6. The method of claim 4, wherein said delivering said positive voltage spike to said pedestal comprises generating a positive voltage spike within said power source and delivering said positive voltage spike to said pedestal during said positive voltage phase.
7. The method of claim 4, wherein said delivering said positive voltage spike to said pedestal comprises generating a positive voltage spike within a pulsed power source and delivering said positive voltage spike to said pedestal during said positive voltage phase.
8. A method of forming an opening in an insulating material for a semiconductor device utilizing a plasma reactor chamber including a pedestal for supporting a semiconductor substrate and a power source in electrical communication with said pedestal, said pedestal including a switch in electrical communication therewith for opening and closing an electrical path, said method comprising:
placing said semiconductor substrate on said pedestal, said semiconductor substrate having a material layer thereover and a photoresist layer patterned on said material layer, said material layer deposited by plasma enhanced chemical vapor deposition;
generating a plasma above said semiconductor substrate;
delivering an electrical signal to said pedestal from said power source, wherein a voltage of said electrical signal oscillates between a positive voltage phase having a duration of time and a negative voltage phase having a duration of time;
delivering a positive voltage spike having a voltage higher than that of the maximum voltage of the positive voltage phase and having a duration of time less than the duration of time of the positive voltage phase to said pedestal during said positive voltage phase, said delivering said positive voltage spike to said pedestal comprising generating a positive voltage spike within a secondary power source and delivering said positive voltage spike to said pedestal during said positive voltage phase when a predetermined voltage level is reached; and forming at least a portion of an opening in an insulating material.
9. The method of claim 8, wherein said delivering said positive voltage spike to said pedestal further comprises:
monitoring said voltage in said positive voltage phase until said voltage reaches said predetermined voltage level.
10. The method of claim 8, wherein said delivering said positive voltage spike to said pedestal comprises generating a positive voltage spike within said power source and delivering said positive voltage spike to said pedestal during said positive voltage phase.
11. The method of claim 8, wherein said delivering said positive voltage spike to said pedestal comprises generating a positive voltage spike within a pulsed power source and delivering said positive voltage spike to said pedestal during said positive voltage phase.
US10/408,542 2000-08-17 2003-04-07 Methods for use of pulsed voltage in a plasma reactor Expired - Lifetime US7253117B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US10/408,542 US7253117B2 (en) 2000-08-17 2003-04-07 Methods for use of pulsed voltage in a plasma reactor

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/640,449 US6544895B1 (en) 2000-08-17 2000-08-17 Methods for use of pulsed voltage in a plasma reactor
US10/408,542 US7253117B2 (en) 2000-08-17 2003-04-07 Methods for use of pulsed voltage in a plasma reactor

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
US09/640,449 Continuation US6544895B1 (en) 2000-08-17 2000-08-17 Methods for use of pulsed voltage in a plasma reactor

Publications (2)

Publication Number Publication Date
US20030211754A1 US20030211754A1 (en) 2003-11-13
US7253117B2 true US7253117B2 (en) 2007-08-07

Family

ID=24568283

Family Applications (3)

Application Number Title Priority Date Filing Date
US09/640,449 Expired - Fee Related US6544895B1 (en) 2000-08-17 2000-08-17 Methods for use of pulsed voltage in a plasma reactor
US10/408,542 Expired - Lifetime US7253117B2 (en) 2000-08-17 2003-04-07 Methods for use of pulsed voltage in a plasma reactor
US10/408,521 Abandoned US20030168010A1 (en) 2000-08-17 2003-04-07 Use of pulsed voltage in a plasma reactor

Family Applications Before (1)

Application Number Title Priority Date Filing Date
US09/640,449 Expired - Fee Related US6544895B1 (en) 2000-08-17 2000-08-17 Methods for use of pulsed voltage in a plasma reactor

Family Applications After (1)

Application Number Title Priority Date Filing Date
US10/408,521 Abandoned US20030168010A1 (en) 2000-08-17 2003-04-07 Use of pulsed voltage in a plasma reactor

Country Status (8)

Country Link
US (3) US6544895B1 (en)
JP (1) JP2004507080A (en)
KR (1) KR100841913B1 (en)
CN (1) CN100433236C (en)
AU (1) AU2001286521A1 (en)
DE (1) DE10196509T1 (en)
GB (1) GB2382459B (en)
WO (1) WO2002015222A2 (en)

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090139963A1 (en) * 2007-11-30 2009-06-04 Theodoros Panagopoulos Multiple frequency pulsing of multiple coil source to control plasma ion density radial distribution
US20100276273A1 (en) * 2009-05-01 2010-11-04 Advanced Energy Industries, Inc. Method and apparatus for controlling ion energy distribution
US9105447B2 (en) 2012-08-28 2015-08-11 Advanced Energy Industries, Inc. Wide dynamic range ion energy bias control; fast ion energy switching; ion energy control and a pulsed bias supply; and a virtual front panel
US9208992B2 (en) 2010-04-26 2015-12-08 Advanced Energy Industries, Inc. Method for controlling ion energy distribution
US9210790B2 (en) 2012-08-28 2015-12-08 Advanced Energy Industries, Inc. Systems and methods for calibrating a switched mode ion energy distribution system
US9309594B2 (en) 2010-04-26 2016-04-12 Advanced Energy Industries, Inc. System, method and apparatus for controlling ion energy distribution of a projected plasma
US9362089B2 (en) 2010-08-29 2016-06-07 Advanced Energy Industries, Inc. Method of controlling the switched mode ion energy distribution system
US9435029B2 (en) 2010-08-29 2016-09-06 Advanced Energy Industries, Inc. Wafer chucking system for advanced plasma ion energy processing systems
US9685297B2 (en) 2012-08-28 2017-06-20 Advanced Energy Industries, Inc. Systems and methods for monitoring faults, anomalies, and other characteristics of a switched mode ion energy distribution system
US9767988B2 (en) 2010-08-29 2017-09-19 Advanced Energy Industries, Inc. Method of controlling the switched mode ion energy distribution system
US10607813B2 (en) 2017-11-17 2020-03-31 Advanced Energy Industries, Inc. Synchronized pulsing of plasma processing source and substrate bias
US10707055B2 (en) 2017-11-17 2020-07-07 Advanced Energy Industries, Inc. Spatial and temporal control of ion bias voltage for plasma processing
US10811227B2 (en) 2017-11-17 2020-10-20 Advanced Energy Industries, Inc. Application of modulating supplies in a plasma processing system
US11615941B2 (en) 2009-05-01 2023-03-28 Advanced Energy Industries, Inc. System, method, and apparatus for controlling ion energy distribution in plasma processing systems
US11670487B1 (en) 2022-01-26 2023-06-06 Advanced Energy Industries, Inc. Bias supply control and data processing
US11887812B2 (en) 2019-07-12 2024-01-30 Advanced Energy Industries, Inc. Bias supply with a single controlled switch
US11942309B2 (en) 2022-01-26 2024-03-26 Advanced Energy Industries, Inc. Bias supply with resonant switching
US11978613B2 (en) 2022-09-01 2024-05-07 Advanced Energy Industries, Inc. Transition control in a bias supply
US12046448B2 (en) 2022-01-26 2024-07-23 Advanced Energy Industries, Inc. Active switch on time control for bias supply
US12125674B2 (en) 2020-05-11 2024-10-22 Advanced Energy Industries, Inc. Surface charge and power feedback and control using a switch mode bias system
US12142452B2 (en) 2021-11-17 2024-11-12 Advanced Energy Industries, Inc. Systems and methods for monitoring faults, anomalies, and other characteristics of a switched mode ion energy distribution system

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6544895B1 (en) * 2000-08-17 2003-04-08 Micron Technology, Inc. Methods for use of pulsed voltage in a plasma reactor
US6485572B1 (en) * 2000-08-28 2002-11-26 Micron Technology, Inc. Use of pulsed grounding source in a plasma reactor
US7109122B2 (en) * 2002-11-29 2006-09-19 Tokyo Electron Limited Method and apparatus for reducing substrate charging damage
KR100668956B1 (en) 2004-12-22 2007-01-12 동부일렉트로닉스 주식회사 Method for fabricating of the semiconductor
US7713430B2 (en) * 2006-02-23 2010-05-11 Micron Technology, Inc. Using positive DC offset of bias RF to neutralize charge build-up of etch features
US20080113108A1 (en) * 2006-11-09 2008-05-15 Stowell Michael W System and method for control of electromagnetic radiation in pecvd discharge processes
SG185321A1 (en) * 2007-10-26 2012-11-29 Oc Oerlikon Balzers Ag Application of high power magnetron sputtering to through silicon via metallization
US8614151B2 (en) * 2008-01-04 2013-12-24 Micron Technology, Inc. Method of etching a high aspect ratio contact
US8150588B2 (en) * 2008-11-25 2012-04-03 General Electric Company Methods and system for time of arrival control using time of arrival uncertainty
US8658541B2 (en) * 2010-01-15 2014-02-25 Applied Materials, Inc. Method of controlling trench microloading using plasma pulsing
KR20120022251A (en) * 2010-09-01 2012-03-12 삼성전자주식회사 Plasma etching method and apparatus thereof
CN103343324B (en) * 2013-07-04 2016-04-20 深圳先进技术研究院 Magnetron sputtering equipment
US10312048B2 (en) * 2016-12-12 2019-06-04 Applied Materials, Inc. Creating ion energy distribution functions (IEDF)
US10927449B2 (en) 2017-01-25 2021-02-23 Applied Materials, Inc. Extension of PVD chamber with multiple reaction gases, high bias power, and high power impulse source for deposition, implantation, and treatment

Citations (58)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3672985A (en) 1970-05-05 1972-06-27 Westinghouse Electric Corp Conductor elements spaced from microelectronic component surface and methods of making the same
US3860507A (en) 1972-11-29 1975-01-14 Rca Corp Rf sputtering apparatus and method
US4438315A (en) 1979-12-12 1984-03-20 Vlsi Technology Research Association High selectivity plasma etching apparatus
US4808258A (en) 1983-10-19 1989-02-28 Hitachi, Ltd. Plasma processing method and apparatus for carrying out the same
JPS6473620A (en) 1987-09-14 1989-03-17 Mitsubishi Electric Corp Plasma applying device
US4963239A (en) 1988-01-29 1990-10-16 Hitachi, Ltd. Sputtering process and an apparatus for carrying out the same
JPH0653176A (en) 1992-07-30 1994-02-25 Matsushita Electron Corp Dry etcher
US5315145A (en) 1993-07-16 1994-05-24 Board Of Trustees Of The Leland Stanford Junior University Charge monitoring device for use in semiconductor wafer fabrication for unipolar operation and charge monitoring
US5322806A (en) 1988-08-24 1994-06-21 Mitsubishi Denki Kabushiki Kaisha Method of producing a semiconductor device using electron cyclotron resonance plasma CVD and substrate biasing
US5344792A (en) 1993-03-04 1994-09-06 Micron Technology, Inc. Pulsed plasma enhanced CVD of metal silicide conductive films such as TiSi2
US5352324A (en) 1992-11-05 1994-10-04 Hitachi, Ltd. Etching method and etching apparatus therefor
US5362358A (en) 1992-05-14 1994-11-08 Nec Corporation Dry etching apparatus and method of forming a via hole in an interlayer insulator using same
JPH06338476A (en) 1993-03-31 1994-12-06 Tokyo Electron Ltd Plasma processing method
US5378311A (en) 1992-12-04 1995-01-03 Sony Corporation Method of producing semiconductor device
US5435886A (en) 1992-08-11 1995-07-25 Mitsubishi Denki Kabushiki Kaisha Method of plasma etching
US5460684A (en) 1992-12-04 1995-10-24 Tokyo Electron Limited Stage having electrostatic chuck and plasma processing apparatus using same
JPH07283206A (en) 1994-02-10 1995-10-27 Sony Corp Plasma device and plasma processing method using thereof
JPH0831596A (en) 1994-07-21 1996-02-02 Hitachi Ltd Plasma treating method and its device
JPH0845903A (en) 1994-07-27 1996-02-16 Hitachi Ltd Plasma etching method
JPH0883776A (en) 1994-09-13 1996-03-26 Aneruba Kk Surface-treating device
US5508227A (en) 1994-06-08 1996-04-16 Northeastern University Plasma ion implantation hydrogenation process utilizing voltage pulse applied to substrate
EP0710977A1 (en) 1994-11-04 1996-05-08 Hitachi, Ltd. Surface treatment method and system
JPH08124902A (en) 1994-10-25 1996-05-17 Hitachi Ltd Plasma processing system
US5520740A (en) 1989-06-28 1996-05-28 Canon Kabushiki Kaisha Process for continuously forming a large area functional deposited film by microwave PCVD method and apparatus suitable for practicing the same
US5527391A (en) 1989-06-28 1996-06-18 Canon Kabushiki Kaisha Method and apparatus for continuously forming functional deposited films with a large area by a microwave plasma CVD method
US5545258A (en) 1994-06-14 1996-08-13 Sumitomo Metal Industries, Ltd. Microwave plasma processing system
EP0734046A2 (en) 1995-03-23 1996-09-25 Applied Materials, Inc. Process and apparatus for patterning a masked metal layer in a RF plasma, comprising substrate bias amplitude modulation
JPH08255782A (en) 1995-03-16 1996-10-01 Toshiba Corp Plasma surface treating apparatus
JPH09260360A (en) 1996-11-06 1997-10-03 Hitachi Ltd Plasma treatment method and its equipment
US5705081A (en) 1994-09-22 1998-01-06 Tokyo Electron Limited Etching method
US5714010A (en) 1989-06-28 1998-02-03 Canon Kabushiki Kaisha Process for continuously forming a large area functional deposited film by a microwave PCVD method and an apparatus suitable for practicing the same
JPH10107012A (en) 1996-09-27 1998-04-24 Tokyo Electron Ltd Plasma processing apparatus
EP0854205A1 (en) 1997-01-16 1998-07-22 Nissin Electric Company, Limited Work surface treatment method and work surface treatment apparatus
US5810982A (en) * 1994-06-17 1998-09-22 Eni Technologies, Inc. Preferential sputtering of insulators from conductive targets
JPH10261498A (en) 1996-03-01 1998-09-29 Hitachi Ltd Plasma treatment apparatus and plasma treatment method
JPH10270419A (en) 1997-03-24 1998-10-09 Hitachi Ltd Plasma etching apparatus and method
US5859469A (en) 1997-07-18 1999-01-12 Advanced Micro Devices, Inc. Use of tungsten filled slots as ground plane in integrated circuit structure
US5869877A (en) 1997-04-23 1999-02-09 Lam Research Corporation Methods and apparatus for detecting pattern dependent charging on a workpiece in a plasma processing system
US5917286A (en) 1996-05-08 1999-06-29 Advanced Energy Industries, Inc. Pulsed direct current power supply configurations for generating plasmas
JPH11224796A (en) 1998-02-05 1999-08-17 Matsushita Electron Corp Apparatus and method for plasma treatment
JP2000054125A (en) 1998-08-10 2000-02-22 Nissin Electric Co Ltd Surface treating method and device therefor
US6051114A (en) 1997-06-23 2000-04-18 Applied Materials, Inc. Use of pulsed-DC wafer bias for filling vias/trenches with metal in HDP physical vapor deposition
JP2000188284A (en) 1998-12-22 2000-07-04 Hitachi Ltd Plasma treatment device
US6099747A (en) 1995-12-15 2000-08-08 Nec Corporation Chamber etching of plasma processing apparatus
JP2000224796A (en) 1999-01-29 2000-08-11 Shin Nippon Machinery Co Ltd Inspection window of rotating machine
JP2000223480A (en) 1998-11-27 2000-08-11 Tokyo Electron Ltd Plasma-etching device
US6121161A (en) 1997-06-11 2000-09-19 Applied Materials, Inc. Reduction of mobile ion and metal contamination in HDP-CVD chambers using chamber seasoning film depositions
US6136214A (en) 1996-04-26 2000-10-24 Hitachi, Ltd. Plasma processing method and apparatus
US6201208B1 (en) 1999-11-04 2001-03-13 Wisconsin Alumni Research Foundation Method and apparatus for plasma processing with control of ion energy distribution at the substrates
US6214160B1 (en) 1996-10-29 2001-04-10 Applied Materials, Inc. Method and apparatus for removing particulates from semiconductor substrates in plasma processing chambers
US6218196B1 (en) 1998-05-06 2001-04-17 Mitsubishi Denki Kabushiki Kaisha Etching apparatus, etching method, manufacturing method of a semiconductor device, and semiconductor device
US6217721B1 (en) 1995-08-07 2001-04-17 Applied Materials, Inc. Filling narrow apertures and forming interconnects with a metal utilizing a crystallographically oriented liner layer
US6220201B1 (en) 1993-08-27 2001-04-24 Applied Materials, Inc. High density plasma CVD reactor with combined inductive and capacitive coupling
US6344419B1 (en) * 1999-12-03 2002-02-05 Applied Materials, Inc. Pulsed-mode RF bias for sidewall coverage improvement
US6432834B1 (en) 1999-07-14 2002-08-13 Samsung Electronics Co., Ltd. Method for enhancing etch selectivity of metal silicide film to polysilicon film, and method for etching stacked film of metal silicide film and polysilicon film
US6485572B1 (en) 2000-08-28 2002-11-26 Micron Technology, Inc. Use of pulsed grounding source in a plasma reactor
US6544895B1 (en) * 2000-08-17 2003-04-08 Micron Technology, Inc. Methods for use of pulsed voltage in a plasma reactor
US6589437B1 (en) * 1999-03-05 2003-07-08 Applied Materials, Inc. Active species control with time-modulated plasma

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1030777C (en) * 1992-11-20 1996-01-24 哈尔滨工业大学 metal plasma source ion implantation method and device
JPH0982682A (en) * 1995-09-11 1997-03-28 Hitachi Ltd Plasma processing device
JPH10125654A (en) * 1996-10-21 1998-05-15 Sharp Corp Manufacture of semiconductor device
JP4680333B2 (en) * 1998-12-28 2011-05-11 東京エレクトロンAt株式会社 Plasma processing method, etching method, plasma processing apparatus and etching apparatus

Patent Citations (64)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3672985A (en) 1970-05-05 1972-06-27 Westinghouse Electric Corp Conductor elements spaced from microelectronic component surface and methods of making the same
US3860507A (en) 1972-11-29 1975-01-14 Rca Corp Rf sputtering apparatus and method
US4438315A (en) 1979-12-12 1984-03-20 Vlsi Technology Research Association High selectivity plasma etching apparatus
US4808258A (en) 1983-10-19 1989-02-28 Hitachi, Ltd. Plasma processing method and apparatus for carrying out the same
JPS6473620A (en) 1987-09-14 1989-03-17 Mitsubishi Electric Corp Plasma applying device
US4963239A (en) 1988-01-29 1990-10-16 Hitachi, Ltd. Sputtering process and an apparatus for carrying out the same
US5322806A (en) 1988-08-24 1994-06-21 Mitsubishi Denki Kabushiki Kaisha Method of producing a semiconductor device using electron cyclotron resonance plasma CVD and substrate biasing
US5520740A (en) 1989-06-28 1996-05-28 Canon Kabushiki Kaisha Process for continuously forming a large area functional deposited film by microwave PCVD method and apparatus suitable for practicing the same
US5527391A (en) 1989-06-28 1996-06-18 Canon Kabushiki Kaisha Method and apparatus for continuously forming functional deposited films with a large area by a microwave plasma CVD method
US5714010A (en) 1989-06-28 1998-02-03 Canon Kabushiki Kaisha Process for continuously forming a large area functional deposited film by a microwave PCVD method and an apparatus suitable for practicing the same
US5362358A (en) 1992-05-14 1994-11-08 Nec Corporation Dry etching apparatus and method of forming a via hole in an interlayer insulator using same
US5441595A (en) 1992-05-14 1995-08-15 Nec Corporation Dry etching apparatus and method of forming a via hole in an interlayer insulator using same
JPH0653176A (en) 1992-07-30 1994-02-25 Matsushita Electron Corp Dry etcher
US5435886A (en) 1992-08-11 1995-07-25 Mitsubishi Denki Kabushiki Kaisha Method of plasma etching
US5352324A (en) 1992-11-05 1994-10-04 Hitachi, Ltd. Etching method and etching apparatus therefor
US5378311A (en) 1992-12-04 1995-01-03 Sony Corporation Method of producing semiconductor device
US5460684A (en) 1992-12-04 1995-10-24 Tokyo Electron Limited Stage having electrostatic chuck and plasma processing apparatus using same
US5344792A (en) 1993-03-04 1994-09-06 Micron Technology, Inc. Pulsed plasma enhanced CVD of metal silicide conductive films such as TiSi2
JPH06338476A (en) 1993-03-31 1994-12-06 Tokyo Electron Ltd Plasma processing method
US5315145A (en) 1993-07-16 1994-05-24 Board Of Trustees Of The Leland Stanford Junior University Charge monitoring device for use in semiconductor wafer fabrication for unipolar operation and charge monitoring
US6220201B1 (en) 1993-08-27 2001-04-24 Applied Materials, Inc. High density plasma CVD reactor with combined inductive and capacitive coupling
JPH07283206A (en) 1994-02-10 1995-10-27 Sony Corp Plasma device and plasma processing method using thereof
US5508227A (en) 1994-06-08 1996-04-16 Northeastern University Plasma ion implantation hydrogenation process utilizing voltage pulse applied to substrate
US5545258A (en) 1994-06-14 1996-08-13 Sumitomo Metal Industries, Ltd. Microwave plasma processing system
US5810982A (en) * 1994-06-17 1998-09-22 Eni Technologies, Inc. Preferential sputtering of insulators from conductive targets
JPH0831596A (en) 1994-07-21 1996-02-02 Hitachi Ltd Plasma treating method and its device
JPH0845903A (en) 1994-07-27 1996-02-16 Hitachi Ltd Plasma etching method
JPH0883776A (en) 1994-09-13 1996-03-26 Aneruba Kk Surface-treating device
US5705081A (en) 1994-09-22 1998-01-06 Tokyo Electron Limited Etching method
JPH08124902A (en) 1994-10-25 1996-05-17 Hitachi Ltd Plasma processing system
US6231777B1 (en) 1994-11-01 2001-05-15 Hitachi, Ltd. Surface treatment method and system
EP0710977A1 (en) 1994-11-04 1996-05-08 Hitachi, Ltd. Surface treatment method and system
EP0710977B1 (en) 1994-11-04 2000-03-15 Hitachi, Ltd. Surface treatment method and system
JPH08139077A (en) 1994-11-04 1996-05-31 Hitachi Ltd Surface treatment and surface treating device
JPH08255782A (en) 1995-03-16 1996-10-01 Toshiba Corp Plasma surface treating apparatus
EP0734046A2 (en) 1995-03-23 1996-09-25 Applied Materials, Inc. Process and apparatus for patterning a masked metal layer in a RF plasma, comprising substrate bias amplitude modulation
US5614060A (en) 1995-03-23 1997-03-25 Applied Materials, Inc. Process and apparatus for etching metal in integrated circuit structure with high selectivity to photoresist and good metal etch residue removal
US6217721B1 (en) 1995-08-07 2001-04-17 Applied Materials, Inc. Filling narrow apertures and forming interconnects with a metal utilizing a crystallographically oriented liner layer
US6099747A (en) 1995-12-15 2000-08-08 Nec Corporation Chamber etching of plasma processing apparatus
JPH10261498A (en) 1996-03-01 1998-09-29 Hitachi Ltd Plasma treatment apparatus and plasma treatment method
US6136214A (en) 1996-04-26 2000-10-24 Hitachi, Ltd. Plasma processing method and apparatus
US5917286A (en) 1996-05-08 1999-06-29 Advanced Energy Industries, Inc. Pulsed direct current power supply configurations for generating plasmas
JPH10107012A (en) 1996-09-27 1998-04-24 Tokyo Electron Ltd Plasma processing apparatus
US6214160B1 (en) 1996-10-29 2001-04-10 Applied Materials, Inc. Method and apparatus for removing particulates from semiconductor substrates in plasma processing chambers
JPH09260360A (en) 1996-11-06 1997-10-03 Hitachi Ltd Plasma treatment method and its equipment
EP0854205A1 (en) 1997-01-16 1998-07-22 Nissin Electric Company, Limited Work surface treatment method and work surface treatment apparatus
JPH10270419A (en) 1997-03-24 1998-10-09 Hitachi Ltd Plasma etching apparatus and method
US5869877A (en) 1997-04-23 1999-02-09 Lam Research Corporation Methods and apparatus for detecting pattern dependent charging on a workpiece in a plasma processing system
US6121161A (en) 1997-06-11 2000-09-19 Applied Materials, Inc. Reduction of mobile ion and metal contamination in HDP-CVD chambers using chamber seasoning film depositions
US6051114A (en) 1997-06-23 2000-04-18 Applied Materials, Inc. Use of pulsed-DC wafer bias for filling vias/trenches with metal in HDP physical vapor deposition
US5859469A (en) 1997-07-18 1999-01-12 Advanced Micro Devices, Inc. Use of tungsten filled slots as ground plane in integrated circuit structure
JPH11224796A (en) 1998-02-05 1999-08-17 Matsushita Electron Corp Apparatus and method for plasma treatment
US6218196B1 (en) 1998-05-06 2001-04-17 Mitsubishi Denki Kabushiki Kaisha Etching apparatus, etching method, manufacturing method of a semiconductor device, and semiconductor device
JP2000054125A (en) 1998-08-10 2000-02-22 Nissin Electric Co Ltd Surface treating method and device therefor
JP2000223480A (en) 1998-11-27 2000-08-11 Tokyo Electron Ltd Plasma-etching device
JP2000188284A (en) 1998-12-22 2000-07-04 Hitachi Ltd Plasma treatment device
JP2000224796A (en) 1999-01-29 2000-08-11 Shin Nippon Machinery Co Ltd Inspection window of rotating machine
US6589437B1 (en) * 1999-03-05 2003-07-08 Applied Materials, Inc. Active species control with time-modulated plasma
US6432834B1 (en) 1999-07-14 2002-08-13 Samsung Electronics Co., Ltd. Method for enhancing etch selectivity of metal silicide film to polysilicon film, and method for etching stacked film of metal silicide film and polysilicon film
US6201208B1 (en) 1999-11-04 2001-03-13 Wisconsin Alumni Research Foundation Method and apparatus for plasma processing with control of ion energy distribution at the substrates
US6344419B1 (en) * 1999-12-03 2002-02-05 Applied Materials, Inc. Pulsed-mode RF bias for sidewall coverage improvement
US6544895B1 (en) * 2000-08-17 2003-04-08 Micron Technology, Inc. Methods for use of pulsed voltage in a plasma reactor
US6485572B1 (en) 2000-08-28 2002-11-26 Micron Technology, Inc. Use of pulsed grounding source in a plasma reactor
US20060194437A1 (en) 2000-08-28 2006-08-31 Hedberg Chuck E Use of pulsed grounding source in a plasma reactor

Non-Patent Citations (9)

* Cited by examiner, † Cited by third party
Title
International Search Report dated Mar. 28, 2002 (4 pages).
Kofuji et al., "Reduction in the Local Charge Build Up with Electron Acceleration Pulse Bias", Dry Process Symposium, 1995, pp. 39-44.
Onuki et al., "Formation of W Underlayer by Switching Bias Sputtering to Plug 0.25Tm Contact Holes", J. Vac. Sci. technol. B 17(3), May/Jun. 1999, pp. 1028-1033.
Onuki et al., "High-Reliability Interconnection Formation by a Two-Step Switching Bias Sputtering Process", Thin Solid Films 266, Jun. 16, 1995, pp. 182-188.
Onuki et al., "Study on Step Coverage and (111) Preferred Orientation of Aluminum Film Deposited by a New Switching Bias Sputtering Method", Appl. Phys. Lett. 53(11), Jul. 19, 1998, pp. 968-980.
PATENT ABSTRACTS OF JAPAN, Vol. 1999, No. 01, (29-01-1999); & JP 10 270 419 A (HITACHI LTD) (09-10-1998)
PATENT ABSTRACTS OF JAPAN, Vol. 1999, No. 13, (30-11-1999); & JP 11 224 796 A (MATSUSHITA ELECTRON CORP) (17-08-1999)
Shur et al., "Surface Discharge Plasma Induced by Spontaneous Polarization Switching", Appl. Phys. Lett. 70(5), Feb. 3, 1997, pp. 574-576.
Suwa et al., "Influence of Silicon Concentration and Layering of Molybdenum Silicide on the Reliability of Al-Si-Cu Interconnections", J. Vac. Sci. Technol. B 9(3), May/Jun. 1991, pp. 1487-1491.

Cited By (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090139963A1 (en) * 2007-11-30 2009-06-04 Theodoros Panagopoulos Multiple frequency pulsing of multiple coil source to control plasma ion density radial distribution
US9287092B2 (en) 2009-05-01 2016-03-15 Advanced Energy Industries, Inc. Method and apparatus for controlling ion energy distribution
US20100276273A1 (en) * 2009-05-01 2010-11-04 Advanced Energy Industries, Inc. Method and apparatus for controlling ion energy distribution
US11615941B2 (en) 2009-05-01 2023-03-28 Advanced Energy Industries, Inc. System, method, and apparatus for controlling ion energy distribution in plasma processing systems
US11011349B2 (en) 2009-05-01 2021-05-18 Aes Global Holdings, Pte. Ltd. System, method, and apparatus for controlling ion energy distribution in plasma processing systems
US9287086B2 (en) 2010-04-26 2016-03-15 Advanced Energy Industries, Inc. System, method and apparatus for controlling ion energy distribution
US9309594B2 (en) 2010-04-26 2016-04-12 Advanced Energy Industries, Inc. System, method and apparatus for controlling ion energy distribution of a projected plasma
US9208992B2 (en) 2010-04-26 2015-12-08 Advanced Energy Industries, Inc. Method for controlling ion energy distribution
US9362089B2 (en) 2010-08-29 2016-06-07 Advanced Energy Industries, Inc. Method of controlling the switched mode ion energy distribution system
US9435029B2 (en) 2010-08-29 2016-09-06 Advanced Energy Industries, Inc. Wafer chucking system for advanced plasma ion energy processing systems
US9767988B2 (en) 2010-08-29 2017-09-19 Advanced Energy Industries, Inc. Method of controlling the switched mode ion energy distribution system
US9210790B2 (en) 2012-08-28 2015-12-08 Advanced Energy Industries, Inc. Systems and methods for calibrating a switched mode ion energy distribution system
US9685297B2 (en) 2012-08-28 2017-06-20 Advanced Energy Industries, Inc. Systems and methods for monitoring faults, anomalies, and other characteristics of a switched mode ion energy distribution system
US11189454B2 (en) 2012-08-28 2021-11-30 Aes Global Holdings, Pte. Ltd. Systems and methods for monitoring faults, anomalies, and other characteristics of a switched mode ion energy distribution system
US9105447B2 (en) 2012-08-28 2015-08-11 Advanced Energy Industries, Inc. Wide dynamic range ion energy bias control; fast ion energy switching; ion energy control and a pulsed bias supply; and a virtual front panel
US10811227B2 (en) 2017-11-17 2020-10-20 Advanced Energy Industries, Inc. Application of modulating supplies in a plasma processing system
US11842884B2 (en) 2017-11-17 2023-12-12 Advanced Energy Industries, Inc. Spatial monitoring and control of plasma processing environments
US10896807B2 (en) 2017-11-17 2021-01-19 Advanced Energy Industries, Inc. Synchronization between an excitation source and a substrate bias supply
US10811229B2 (en) 2017-11-17 2020-10-20 Advanced Energy Industries, Inc. Synchronization with a bias supply in a plasma processing system
US10707055B2 (en) 2017-11-17 2020-07-07 Advanced Energy Industries, Inc. Spatial and temporal control of ion bias voltage for plasma processing
US10607813B2 (en) 2017-11-17 2020-03-31 Advanced Energy Industries, Inc. Synchronized pulsing of plasma processing source and substrate bias
US10811228B2 (en) 2017-11-17 2020-10-20 Advanced Energy Industries, Inc. Control of plasma processing systems that include plasma modulating supplies
US11887812B2 (en) 2019-07-12 2024-01-30 Advanced Energy Industries, Inc. Bias supply with a single controlled switch
US12125674B2 (en) 2020-05-11 2024-10-22 Advanced Energy Industries, Inc. Surface charge and power feedback and control using a switch mode bias system
US12142452B2 (en) 2021-11-17 2024-11-12 Advanced Energy Industries, Inc. Systems and methods for monitoring faults, anomalies, and other characteristics of a switched mode ion energy distribution system
US11670487B1 (en) 2022-01-26 2023-06-06 Advanced Energy Industries, Inc. Bias supply control and data processing
US11942309B2 (en) 2022-01-26 2024-03-26 Advanced Energy Industries, Inc. Bias supply with resonant switching
US12046448B2 (en) 2022-01-26 2024-07-23 Advanced Energy Industries, Inc. Active switch on time control for bias supply
US11978613B2 (en) 2022-09-01 2024-05-07 Advanced Energy Industries, Inc. Transition control in a bias supply

Also Published As

Publication number Publication date
DE10196509T1 (en) 2003-07-10
US20030211754A1 (en) 2003-11-13
US6544895B1 (en) 2003-04-08
GB0301969D0 (en) 2003-02-26
KR100841913B1 (en) 2008-06-30
JP2004507080A (en) 2004-03-04
GB2382459A (en) 2003-05-28
CN100433236C (en) 2008-11-12
GB2382459B (en) 2004-07-21
CN1451172A (en) 2003-10-22
KR20030031159A (en) 2003-04-18
AU2001286521A1 (en) 2002-02-25
WO2002015222A3 (en) 2002-06-13
WO2002015222A2 (en) 2002-02-21
US20030168010A1 (en) 2003-09-11

Similar Documents

Publication Publication Date Title
US7253117B2 (en) Methods for use of pulsed voltage in a plasma reactor
US6485572B1 (en) Use of pulsed grounding source in a plasma reactor
US8419958B2 (en) Using positive DC offset of bias RF to neutralize charge build-up of etch features
US6435131B1 (en) Ion flow forming method and apparatus
US7767561B2 (en) Plasma immersion ion implantation reactor having an ion shower grid
US8058156B2 (en) Plasma immersion ion implantation reactor having multiple ion shower grids
US6752912B1 (en) Laser selection of ions for sputter deposition of titanium containing films
US7029594B2 (en) Plasma processing method
US7314574B2 (en) Etching method and apparatus
US5433258A (en) Gettering of particles during plasma processing
US7083903B2 (en) Methods of etching photoresist on substrates
US20040094400A1 (en) Method of processing a surface of a workpiece
US5147465A (en) Method of cleaning a surface
WO2012029473A1 (en) Etching method and etching apparatus
US6504159B1 (en) SOI plasma source ion implantation
US7060931B2 (en) Neutral beam source having electromagnet used for etching semiconductor device
KR102442816B1 (en) A method and apparatus for providing an anisotropic and mono-energetic neutral beam by non-ambipolar electron plasma
JPH05102083A (en) Method and apparatus for dry etching
US5853521A (en) Multi-cathode electron beam plasma etcher
KR101016810B1 (en) Apparatus for surface treatment using plasma
JPH0637046A (en) Plasma etching apparatus
US20020025677A1 (en) Dry etching method and apparatus
JP2683509B2 (en) Ion implanter
JPH1092794A (en) Plasma treatment device and plasma treatment method

Legal Events

Date Code Title Description
FEPP Fee payment procedure

Free format text: PAYOR NUMBER ASSIGNED (ORIGINAL EVENT CODE: ASPN); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY

STCF Information on status: patent grant

Free format text: PATENTED CASE

FPAY Fee payment

Year of fee payment: 4

FPAY Fee payment

Year of fee payment: 8

AS Assignment

Owner name: U.S. BANK NATIONAL ASSOCIATION, AS COLLATERAL AGENT, CALIFORNIA

Free format text: SECURITY INTEREST;ASSIGNOR:MICRON TECHNOLOGY, INC.;REEL/FRAME:038669/0001

Effective date: 20160426

Owner name: U.S. BANK NATIONAL ASSOCIATION, AS COLLATERAL AGEN

Free format text: SECURITY INTEREST;ASSIGNOR:MICRON TECHNOLOGY, INC.;REEL/FRAME:038669/0001

Effective date: 20160426

AS Assignment

Owner name: MORGAN STANLEY SENIOR FUNDING, INC., AS COLLATERAL AGENT, MARYLAND

Free format text: PATENT SECURITY AGREEMENT;ASSIGNOR:MICRON TECHNOLOGY, INC.;REEL/FRAME:038954/0001

Effective date: 20160426

Owner name: MORGAN STANLEY SENIOR FUNDING, INC., AS COLLATERAL

Free format text: PATENT SECURITY AGREEMENT;ASSIGNOR:MICRON TECHNOLOGY, INC.;REEL/FRAME:038954/0001

Effective date: 20160426

AS Assignment

Owner name: U.S. BANK NATIONAL ASSOCIATION, AS COLLATERAL AGENT, CALIFORNIA

Free format text: CORRECTIVE ASSIGNMENT TO CORRECT THE REPLACE ERRONEOUSLY FILED PATENT #7358718 WITH THE CORRECT PATENT #7358178 PREVIOUSLY RECORDED ON REEL 038669 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY INTEREST;ASSIGNOR:MICRON TECHNOLOGY, INC.;REEL/FRAME:043079/0001

Effective date: 20160426

Owner name: U.S. BANK NATIONAL ASSOCIATION, AS COLLATERAL AGEN

Free format text: CORRECTIVE ASSIGNMENT TO CORRECT THE REPLACE ERRONEOUSLY FILED PATENT #7358718 WITH THE CORRECT PATENT #7358178 PREVIOUSLY RECORDED ON REEL 038669 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY INTEREST;ASSIGNOR:MICRON TECHNOLOGY, INC.;REEL/FRAME:043079/0001

Effective date: 20160426

AS Assignment

Owner name: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT, ILLINOIS

Free format text: SECURITY INTEREST;ASSIGNORS:MICRON TECHNOLOGY, INC.;MICRON SEMICONDUCTOR PRODUCTS, INC.;REEL/FRAME:047540/0001

Effective date: 20180703

Owner name: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT, IL

Free format text: SECURITY INTEREST;ASSIGNORS:MICRON TECHNOLOGY, INC.;MICRON SEMICONDUCTOR PRODUCTS, INC.;REEL/FRAME:047540/0001

Effective date: 20180703

AS Assignment

Owner name: MICRON TECHNOLOGY, INC., IDAHO

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:U.S. BANK NATIONAL ASSOCIATION, AS COLLATERAL AGENT;REEL/FRAME:047243/0001

Effective date: 20180629

MAFP Maintenance fee payment

Free format text: PAYMENT OF MAINTENANCE FEE, 12TH YEAR, LARGE ENTITY (ORIGINAL EVENT CODE: M1553); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY

Year of fee payment: 12

AS Assignment

Owner name: MICRON TECHNOLOGY, INC., IDAHO

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:MORGAN STANLEY SENIOR FUNDING, INC., AS COLLATERAL AGENT;REEL/FRAME:050937/0001

Effective date: 20190731

AS Assignment

Owner name: MICRON TECHNOLOGY, INC., IDAHO

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT;REEL/FRAME:051028/0001

Effective date: 20190731

Owner name: MICRON SEMICONDUCTOR PRODUCTS, INC., IDAHO

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT;REEL/FRAME:051028/0001

Effective date: 20190731