US2969475A - Method and installation for carrying out glow discharge processes - Google Patents
Method and installation for carrying out glow discharge processes Download PDFInfo
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- US2969475A US2969475A US671790A US67179057A US2969475A US 2969475 A US2969475 A US 2969475A US 671790 A US671790 A US 671790A US 67179057 A US67179057 A US 67179057A US 2969475 A US2969475 A US 2969475A
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/32009—Arrangements for generation of plasma specially adapted for examination or treatment of objects, e.g. plasma sources
- H01J37/32018—Glow discharge
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/087—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy
- B01J19/088—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges
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- the present invention relates to a method of and apparatus for performing metallurgical, chemical, or other technical processes under the influence of an electric glow discharge in a discharge vessel containing electrodes which carry an electric potential, and insulated leads for applying the potentials to the said electrodes.
- a discharge vessel containing electrodes which carry an electric potential, and insulated leads for applying the potentials to the said electrodes.
- the greatest concentration of energy is known to be located principally in the vicinity of the electrode which carries the negative potential, even if the latter acts only temporarily as a cathode as would be the case when the discharge vessel is operated by alternating current. Consequently such glow discharge phenomena are exceptionally useful for treating the surface of materials which operate as a cathode because the high concentration of energy is then localised directly on the treated metal surface.
- the present invention seeks to solve this problem by relieving at least one of the electrodes participating in the maintenance of the discharge of at least part of the load due to the energy of discharge in favour of part of the gas space surrounding the electrode and to this end, on the one hand, creates a pressure gradient in the zone around the electrode in which the gas pressure diminishes with increasing distance from the electrode and, on the other hand, suitably locates the cooperating electrodes to favour a migration of the discharge away from the electrode and into the zone of decreasing pressure.
- the apparatus for performing this method comprises a discharge space enclosed in an envelope and at least one nozzle which projects into said space and which is adapted to project a jet into the space through which the glow discharge passes.
- the discharge gap 1 is completely enclosed within a metal envelope 2 which may be jacketed for the purpose of permitting a coolant to be conducted in the direction indicated by arrow 3 through the space 4 between the envelope and the outside wall of the jacket.
- the top -then arise at every point within the said zone.
- an airtight cover 5 consisting of an electrically insulating material and containing a metal admission element 6 with a duct 7 which terminates inside the furnace chamber 1 in the shape of a nozzle 3.
- the wall which encloses the duct 7 and the nozzle 8 is provided with channels 9 and 10 for conveying a coolant such as water or liquid air, which enters in direction 11 and, after flowing round the nozzle 8, leaves in direction 12.
- a coolant such as water or liquid air
- a ring 15a which acts as a cooperating electrode is arranged in close proximity to and opposite the nozzle orifice, the said ring being supported by part of the lead-in 16a which passes into the chamber through an insulated bushing 17a.
- the internal diameter of ring 15a should be as small as possible but in no circumstances should it impede a gas jet issuing from the nozzle orifice.
- Ring 15a is connected through a switch 16a with the positive terminal of a source of electric potential 18, of which the negative terminal is connected with the in duction element 6 through a switch 16.
- switch 16a is connected with a source of potential 19, for the supply for instance of an alternating potential, which has a centre tapping joined to a lead-in 17b, for a ring 15b, whereas the other pole is connected via a third switch 160 and lead-in 17c with a ring 150.
- valve means 20 Through a pipe 21 controlled by valve means 20 the substance it is intended to process, such as for instance an atomised liquid, possibly suspended in a carrier gas, is supplied to the induction element 6.
- a fine dispersion of the liquid discharged from a hopper 25 is produced in a mixer 22 by a high-pressure current of gas which reaches an atomiser 24 through a pipe 23, and the mist created by the finely dispersed liquid suspended in the carrier gas is then conveyed through pipe 21 to the nozzle 8 as soon as valve 20 has been opened.
- the pressure P can be read on a pressure gauge 26.
- a suction pipe 27 connected through a stop valve 28 with a pumping set 29. This is designed to create in the furnace chamber 1 at the junction of the suction pipe 27 a desired pressure P which can be read on a pressure gauge 34, and to maintain this pressure even where a gas stream is injected through nozzle 8 at a pressure P
- the pressure ratio P :P may be raised to high values.
- valves 20 and 28 can be closed and an auxiliary gas inducted into the furnace chamber 1 through pipe 30 and valve 31, a pump 33 connected through a valve 32 with pipe 27 being at the same time arranged to evacuate the furnace chamber to a desired low level of pressure.
- the final product of the glow discharge process is removed from the furnace chamber 1 through a suitable gating device 35 which is not relevant to the invention and therefore need not be described.
- the suction head of pump 29 and the volume of gas inducted through nozzle 8 are relatively adjusted until a predetermined pressure ratio P :P for instance between :1 and 10:1 is established.
- P :P a pressure ratio
- the pressure will then exceed the pressure P; and a definite pressure gradient P-P smaller than the gradient P P will
- the shape of the jet and that of the associated isobars as well as thepressure gradient will vary, but in any case the pressure in the jet will decrease with increasing distance from the. orifice of nozzle 8.
- Such a zone of decreasing pressure adjoining the nozzle 8 which in this example is assumed to act as the cathode and to cooperate with the ring-shaped anode 15a results in a displacement of the high-energy glow discharge away from the orifice of the nozzle 8 towards the ring-shaped anode 15a.
- This result not only relieves the nozzle 8 of the load but the energy of discharge that becomes available within the zone of decreasing pressure or in parts of said zone will at the same time permitchemical reactions to be performed in the gas jet without adversely afiecting the neighbouring metal electrodes.
- a particularly useful feature is that the comparatively high velocity of the jet reduces the dwell of the reacting reagents in the high-energy Zone of the glow discharge and that the reaction products are rapidly carried out of the reaction zone.
- nozzle 8 The high energy load on nozzle 8 will already be relieved if, apart from the nozzle 8 of the induction element, potential is applied only to ring 15a to enable it to act as an anode, that is to say if only the two switches 16 and 16a are closed and the switches 16! and 160 remain open.
- the ring 15a may be replaced by an electrode of some other shape that is symmetrical in relation to the jet axis, for instance by a cylindrical electrode.
- the source of. potential supply 18 need-not be adirect current potential supply.
- An intermittentor pulsed direct current potential or. a. low or high-frequency alternating potential may likewisebe used.-.
- An alternativemethod ofoperation would be. for the nozzle 8- andthe.inducting'element 6 to.
- v the, nozzle; 8 or; the. induction, element should alwaysvactively participate inthe creation of. the discharge by acting. as one of the electrodes. For instance, if. switch 16 is opened; and only the three switches 16a, 16b;and 16c are closed and assuming the source19 to supply a direct current potential, then the ring electrode 15a may act as the cathode and the two ring electrodes 15b and 150 as two anodes.
- the gas jet will still create a zone of decreasing pressure in the neighbourhood of thisnew cathode 1Sa-and thereby induce the high-energy glow dischargeto detach itselffrom the cathode ring 15a and to migrate into the space'between the two electrodeslSa and 15b.
- a similar effect can be achieved by using a source. 19 which supplies an intermittent or pulsed direct current or a low-or highfrequency alternating current potential.
- the counter-electrodes 15a, 15b, 15c diagrammatically shown in the drawing may, of course, have some alternative shape, provided that when they cooperatewith the-relative cathode they: will favour the migration of the high-energy glow discharge from the saidcathode into the zone of decreasing pressure.
- the counter-electrodes 15b and 150 couldbe dispensedwith and the lower part of the discharge chamber 1 filled with a material it was desired to treat metallurgically, the said material being at a potential: difiering from that of nozzle 8 and the gasjet impinging upon the material.
- the direction of the jet issuing from the nozzle 8 should coincide with the lines of force of the electric field between the electrodes which maintain the discharge,
- the gas jet might be arranged to be at an angle or even normal thereto.
- several inducting elements 6 could be provided, each actingas-cathodes and each cooperatingwithits associated or with a common anode.
- the provision of several nozzles that do not participate in the discharge may in special cases be a useful arrange menti
- the method'that'has been described can be especially easily performed if P is maintained between 1 and 10 mm. mercury, because gaseous substances that are to be processed may then be. inducted through nozzles of 1 sq. mm. internal cross section.
- reaction vessel may be relatively compact and consist, for instance, of an iron vessel 60 cms. across and 100 cms. in height, and the dissipation of the generated heat will offer no special difiiculty.
- the pressure in the interior may at the same time be raised, conveniently to over 20 mm. Hg or even above 50 mm, Hg. If necessary, the pressure atwhich the substances for processing are forced through the nozzles may then likewise be raised. By reducing the vacuum to between 20 and 50 mm. Hg or even more, the delivery of the pump can be appreciably raised and a much higher throughput obtained.
- the present method permits the performance of glow discharge processes between reagents in gas or vapour form, but it may as well-be applied to liquid or solid substances that are finely dispersed in a carrier gas, provided suitable nozzles are employed for the purpose. Alttention must also be drawn to the fact that the injection of gas forming liquid or solid particles may sensibly affect the shape of thedecreasing pressure zone by the presence of the volume of gas that is formed.
- the location of the electrodes mustbe determined in a suitable way to favour the dis placement of the discharge away from the cathode into part of the decreasing pressure zone. If a metallic nozzle is used to serve at least temporarily as a negative electrode, then care must be taken to see that at least at the orifice of the nozzle a glow discharge is actually formed, which is capable of being displaced in the direction of the issuing jet.
- the migration of the discharge zone is also assisted by raising the temperature of the gas since it appears that a higher temperature promotes the development of discharge phenomena of greater intensity in parts of the decreasing pressure zone.
- the gas stream may be heated outside the discharge vessel or heat may be transferred to the gas as it passes through the nozzle.
- the steps which comprise charging a gas into the discharge vessel in the region of a first electrode and simultaneously withdrawing gas from the chamber at a point removed from the charging region and at such rates that a pressure gradient is created in the space surrounding the electrode in which the gas pressure diminishes with increasing distance from the electrode, and disposing a cooperating electrode at a distance from the first electrode and in the direction of diminishing pressure, whereby migration of the discharge away from the first electrode and into the zone of decreasing pressure is favored, and the first electrode is at least partly relieved of the load otherwise imposed thereon by the energy of the discharge.
- Apparatus for performing the method claimed in claim 1, comprising a discharge vessel enclosing a discharge space, means for creating a glow discharge in said vessel, at least one nozzle projecting into said space and adapted to project a jet into the space through which the glow discharge passes, said means including a ring-shaped electrode arranged co-axially with the axis of the nozzle, the said ring being insulated from the nozzle and connected with one terminal of a source of potential of which the other terminal is connected with the nozzle, additional ring-shaped electrodes arranged at a distance from the first ring-shaped electrode and likewise disposed co-axially with the axis of the nozzle, the said additional electrodes being insulated from each other; a source of potential associated with said additional electrodes and connected therewith and means for withdrawing gas from said vessel to provide a pressure drop in the glow discharge space.
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Description
Jan. 24, 1961 B. BERGHAUS METHOD AND INSTALLATION FOR CARRYING OUT GLOW DISCHARGE PROCESSES Filed July 15, 1957 INVENTOR ATTORNEY United States Patent METHOD AND INSTALLATION FOR CARRYING OUT GLOW DISCHARGE PROCESSES Bernhard Berghaus, Zurich, Switzerland, assignor to .Elektrophysikalische Anstalt Bernhard Berghaus, Vaduz, Liechtenstein Filed July 15, 1957, Ser. No. 671,790
Claims priority, application Switzerland July 14, 1956 8 Claims. (Cl. 313-231) The present invention relates to a method of and apparatus for performing metallurgical, chemical, or other technical processes under the influence of an electric glow discharge in a discharge vessel containing electrodes which carry an electric potential, and insulated leads for applying the potentials to the said electrodes. In such glow discharge vessels the greatest concentration of energy is known to be located principally in the vicinity of the electrode which carries the negative potential, even if the latter acts only temporarily as a cathode as would be the case when the discharge vessel is operated by alternating current. Consequently such glow discharge phenomena are exceptionally useful for treating the surface of materials which operate as a cathode because the high concentration of energy is then localised directly on the treated metal surface.
However, for the performance of processes which are not intended to take place on a metal surface, such as chemical reactions between gaseous media, the localisation of the exceptionally efiective discharge phenomena on the cathodic electrode is undesirable. On the one hand, it is difiicult to arrange that the entire volume of reacting gaseous media will pass through the glow discharge zone which develops on the cathode surface and, on the other hand, the presence of a metallic surface in the immediate vicinity of the reaction zone is often a drawback because of the tendency of the metal to participate in the reaction. To overcome these difficulties a proposal has already been made to enclose the metallic cathode in a chemically neutral material. However, the electric resistance of such materials is generally very high and therefore causes the energy density to fall to very low values.
The present invention seeks to solve this problem by relieving at least one of the electrodes participating in the maintenance of the discharge of at least part of the load due to the energy of discharge in favour of part of the gas space surrounding the electrode and to this end, on the one hand, creates a pressure gradient in the zone around the electrode in which the gas pressure diminishes with increasing distance from the electrode and, on the other hand, suitably locates the cooperating electrodes to favour a migration of the discharge away from the electrode and into the zone of decreasing pressure.
The apparatus for performing this method comprises a discharge space enclosed in an envelope and at least one nozzle which projects into said space and which is adapted to project a jet into the space through which the glow discharge passes.
The invention will be hereinafter described with reference to an illustrative embodiment of apparatus for performing the method shown in the accompanying drawmg.
The discharge gap 1 is completely enclosed within a metal envelope 2 which may be jacketed for the purpose of permitting a coolant to be conducted in the direction indicated by arrow 3 through the space 4 between the envelope and the outside wall of the jacket. The top -then arise at every point within the said zone.
of the chamber 1 has an airtight cover 5 consisting of an electrically insulating material and containing a metal admission element 6 with a duct 7 which terminates inside the furnace chamber 1 in the shape of a nozzle 3. The wall which encloses the duct 7 and the nozzle 8 is provided with channels 9 and 10 for conveying a coolant such as water or liquid air, which enters in direction 11 and, after flowing round the nozzle 8, leaves in direction 12. The joint between metal and insulating material in the cover plate 5 is protected in a well known manner by the provision of clearances 13 and 14 respectively.
Since the intention is at least partly to reduce the en ergy of glow discharge affecting the nozzle and that part of the admission element 6 which projects into the discharge chamber 1, whenever the admission element functions as cathode, a ring 15a which acts as a cooperating electrode is arranged in close proximity to and opposite the nozzle orifice, the said ring being supported by part of the lead-in 16a which passes into the chamber through an insulated bushing 17a. The internal diameter of ring 15a should be as small as possible but in no circumstances should it impede a gas jet issuing from the nozzle orifice. Ring 15a is connected through a switch 16a with the positive terminal of a source of electric potential 18, of which the negative terminal is connected with the in duction element 6 through a switch 16. On the other hand, switch 16a is connected with a source of potential 19, for the supply for instance of an alternating potential, which has a centre tapping joined to a lead-in 17b, for a ring 15b, whereas the other pole is connected via a third switch 160 and lead-in 17c with a ring 150.
Through a pipe 21 controlled by valve means 20 the substance it is intended to process, such as for instance an atomised liquid, possibly suspended in a carrier gas, is supplied to the induction element 6. To this end a fine dispersion of the liquid discharged from a hopper 25 is produced in a mixer 22 by a high-pressure current of gas which reaches an atomiser 24 through a pipe 23, and the mist created by the finely dispersed liquid suspended in the carrier gas is then conveyed through pipe 21 to the nozzle 8 as soon as valve 20 has been opened. The pressure P can be read on a pressure gauge 26.
At the bottom end of the furnace chamber 1 is a suction pipe 27 connected through a stop valve 28 with a pumping set 29. This is designed to create in the furnace chamber 1 at the junction of the suction pipe 27 a desired pressure P which can be read on a pressure gauge 34, and to maintain this pressure even where a gas stream is injected through nozzle 8 at a pressure P The pressure ratio P :P may be raised to high values.
For the purpose of starting-up, the valves 20 and 28 can be closed and an auxiliary gas inducted into the furnace chamber 1 through pipe 30 and valve 31, a pump 33 connected through a valve 32 with pipe 27 being at the same time arranged to evacuate the furnace chamber to a desired low level of pressure.
The final product of the glow discharge process is removed from the furnace chamber 1 through a suitable gating device 35 which is not relevant to the invention and therefore need not be described.
For establishing stationary operating conditions, the suction head of pump 29 and the volume of gas inducted through nozzle 8 are relatively adjusted until a predetermined pressure ratio P :P for instance between :1 and 10:1 is established. In the neighbourhood of the nozzle orifice and within a spatial zone which symmetrically surrounds the axis of the gas jet, for instance in the zone indicated by the dotted line 36, the pressure will then exceed the pressure P; and a definite pressure gradient P-P smaller than the gradient P P will According to the aerodynamic conditions produced by the gas ice jet which issues from the nozzle 8 the shape of the jet and that of the associated isobars as well as thepressure gradient will vary, but in any case the pressure in the jet will decrease with increasing distance from the. orifice of nozzle 8.
Such a zone of decreasing pressure adjoining the nozzle 8 which in this example is assumed to act as the cathode and to cooperate with the ring-shaped anode 15a results in a displacement of the high-energy glow discharge away from the orifice of the nozzle 8 towards the ring-shaped anode 15a. This result not only relieves the nozzle 8 of the load but the energy of discharge that becomes available within the zone of decreasing pressure or in parts of said zone will at the same time permitchemical reactions to be performed in the gas jet without adversely afiecting the neighbouring metal electrodes. A particularly useful feature is that the comparatively high velocity of the jet reduces the dwell of the reacting reagents in the high-energy Zone of the glow discharge and that the reaction products are rapidly carried out of the reaction zone.
The high energy load on nozzle 8 will already be relieved if, apart from the nozzle 8 of the induction element, potential is applied only to ring 15a to enable it to act as an anode, that is to say if only the two switches 16 and 16a are closed and the switches 16!) and 160 remain open. Of course, the ring 15a may be replaced by an electrode of some other shape that is symmetrical in relation to the jet axis, for instance by a cylindrical electrode. Moreover, the source of. potential supply 18 need-not be adirect current potential supply. An intermittentor pulsed direct current potential or. a. low or high-frequency alternating potential may likewisebe used.-. An alternativemethod ofoperation would be. for the nozzle 8- andthe.inducting'element 6 to. serve asa permanent anode-in cooperation with elec-. trode 15a as thecathode, because the vicinityof .the cathode will then still be a zone of decreasing pressure and a tendency for the glow discharge to shift away from the cathode intothis zone will again beobserved.
When the two switches 16b and 160 are closed the employment of the additional source of direct current or alternating current potential 19 and of the electrodes 15b and 15 will have the efiect of still further increasing the tendency of, the discharge to detachv itself: from nozzle 8 and to move-inthe direction of the'issuing jet.
It is by no meansessential to the; performance; of; the present method. that v the, nozzle; 8 or; the. induction, element should alwaysvactively participate inthe creation of. the discharge by acting. as one of the electrodes. For instance, if. switch 16 is opened; and only the three switches 16a, 16b;and 16c are closed and assuming the source19 to supply a direct current potential, then the ring electrode 15a may act as the cathode and the two ring electrodes 15b and 150 as two anodes. The gas jet will still create a zone of decreasing pressure in the neighbourhood of thisnew cathode 1Sa-and thereby induce the high-energy glow dischargeto detach itselffrom the cathode ring 15a and to migrate into the space'between the two electrodeslSa and 15b.. A similar effect can be achieved by using a source. 19 which supplies an intermittent or pulsed direct current or a low-or highfrequency alternating current potential.
The counter-electrodes 15a, 15b, 15c diagrammatically shown in the drawing may, of course, have some alternative shape, provided that when they cooperatewith the-relative cathode they: will favour the migration of the high-energy glow discharge from the saidcathode into the zone of decreasing pressure. Moreover, the counter-electrodes 15b and 150 couldbe dispensedwith and the lower part of the discharge chamber 1 filled with a material it was desired to treat metallurgically, the said material being at a potential: difiering from that of nozzle 8 and the gasjet impinging upon the material. Nor is it absolutely essential that the direction of the jet issuing from the nozzle 8 should coincide with the lines of force of the electric field between the electrodes which maintain the discharge, In fact, the gas jet might be arranged to be at an angle or even normal thereto. Moreover, several inducting elements 6 could be provided, each actingas-cathodes and each cooperatingwithits associated or with a common anode. Also the provision of several nozzles that do not participate in the discharge may in special cases be a useful arrange menti The method'that'has been described can be especially easily performed if P is maintained between 1 and 10 mm. mercury, because gaseous substances that are to be processed may then be. inducted through nozzles of 1 sq. mm. internal cross section. These will then create a readily reproducible reaction zone, for instance 200 mm. in length, and of 10 mm. maximum width. The reaction vessel may be relatively compact and consist, for instance, of an iron vessel 60 cms. across and 100 cms. in height, and the dissipation of the generated heat will offer no special difiiculty. To maintain a vacuum pressure of something like 5 to 10 mm. Hg the stated internal nozzle sections would require the provision of a pumping set capable of discharging cub. metres per hour. However, the quantitative throughout would then be of the order of something like 12 litres per minute.
In a plant intended for industrial applications it is principally the throughput that matters, so that greater nozzle sections or the provision of several nozzles work-- ing inparallel would be required, especially when dealing withsubstances in powder form. However, it will be readily understood.that atthe pressures which have been mentioned and which call for; a pumping capacity equal to something like aihundred times the volume of gastrelated to standard conditions) inducted throughthc nozzleduringthereferenceperiod; the necessary ma.- chinery would rapidly assume proportions which could not be accepted-in economical working conditions.
A careful study of the problem involved has, however, shown away of satisfactorily overcoming this difficulty and of makingthe method amendable to industrial application. As has beendescribed, (the performance of the method requires the creation of an inhomogeneous pressure distribution inside the reaction chamber, comprising a zone adjacent the nozzle orifice with a; steep pressure gradient from the higher pressure immediately at the nozzle orifice to the lower pressure in the more remote interior. This zone represents the space in which the reaction takes place and in which the processed substances dwell for a certain period of time which depends upon their velocity. However, it has been found that the ratio between maximum and minimum pressure within this reaction zone is not asimportant as the concentration of the major portion of the available pressure gradient within this zone. Consequently, when increasing theeffective nozzle sections the pressure in the interior may at the same time be raised, conveniently to over 20 mm. Hg or even above 50 mm, Hg. If necessary, the pressure atwhich the substances for processing are forced through the nozzles may then likewise be raised. By reducing the vacuum to between 20 and 50 mm. Hg or even more, the delivery of the pump can be appreciably raised and a much higher throughput obtained. The present method permits the performance of glow discharge processes between reagents in gas or vapour form, but it may as well-be applied to liquid or solid substances that are finely dispersed in a carrier gas, provided suitable nozzles are employed for the purpose. Alttention must also be drawn to the fact that the injection of gas forming liquid or solid particles may sensibly affect the shape of thedecreasing pressure zone by the presence of the volume of gas that is formed.
Ashasbeenmentioned, the location of the electrodes mustbe determined in a suitable way to favour the dis placement of the discharge away from the cathode into part of the decreasing pressure zone. If a metallic nozzle is used to serve at least temporarily as a negative electrode, then care must be taken to see that at least at the orifice of the nozzle a glow discharge is actually formed, which is capable of being displaced in the direction of the issuing jet. The migration of the discharge zone is also assisted by raising the temperature of the gas since it appears that a higher temperature promotes the development of discharge phenomena of greater intensity in parts of the decreasing pressure zone. The gas stream may be heated outside the discharge vessel or heat may be transferred to the gas as it passes through the nozzle. Another important factor is the nature of the gas that is employed since some gases favor the production of discharge phenomena in the decreasing pressure zone and these may then conveniently be. admixed as carrier gases to any gaseous reagent that was itself more difiicult to excite. The carrier gas might then be injected through the nozzle together with the gaseous reagent. It will also be clear that many of the reactions that occur in the high-energy zone of the discharge, once they have been initiated, will modify the pressure distribution in the decreasing pressure zone and the tendency of discharge phenomena to prefer one part of the zone to another. This may be due to rises in temperature, the evolution of gas, and the like. Moreover, by taking electrical measures such as by the superposition of pulses, low or high-frequency alternating currents, the creation of spark discharges, or of additional streams of ions or electrons, conditions may be established in the decreasing pressure zone which will favour the migration of the discharge. In principle any measures will serve this purpose, if they bring about reduction in the resistance to the discharge in the relative part of the zone.
I claim:
1, In a method of performing metallurgical, chemical or other technical processes under the influence of an electric glow discharge in a discharge vessel containing electrodes which carry an electric potential and provided with insulated leads for applying the potentials to the said electrodes, the steps which comprise charging a gas into the discharge vessel in the region of a first electrode and simultaneously withdrawing gas from the chamber at a point removed from the charging region and at such rates that a pressure gradient is created in the space surrounding the electrode in which the gas pressure diminishes with increasing distance from the electrode, and disposing a cooperating electrode at a distance from the first electrode and in the direction of diminishing pressure, whereby migration of the discharge away from the first electrode and into the zone of decreasing pressure is favored, and the first electrode is at least partly relieved of the load otherwise imposed thereon by the energy of the discharge.
2. A method as claimed in claim 1, wherein the gas is injected through a nozzle and wherein the nozzle is connected as an electrode for creating the electric field, and cooling at least the discharge orifice of the nozzle, whereby the energy density on the surface of the nozzle itself is reduced in favor of the gas-filled space in front of the nozzle.
3. A method as claimed in claim 1, wherein the migration of the discharge is promoted by reducing the resistance to the discharge in part of the decreasing pressure zone.
4. A method as claimed in claim 3, wherein the gas stream is additionally heated.
5. A method as claimed in claim 1, including the step of adding to the gas stream at least one gas which assists in producing a displacement of the discharge.
6. A method as claimed in claim 1, wherein the migration of the discharge is promoted by reducing the resistance to the discharge in part of the decreasing pressure zone and subjecting at least the said part of the decreasing pressure zone to the influence of an additional electric field.
7. A method as claimed in claim 6, characterized by the superposition of pulsed electric discharges.
8. Apparatus for performing the method claimed in claim 1, comprising a discharge vessel enclosing a discharge space, means for creating a glow discharge in said vessel, at least one nozzle projecting into said space and adapted to project a jet into the space through which the glow discharge passes, said means including a ring-shaped electrode arranged co-axially with the axis of the nozzle, the said ring being insulated from the nozzle and connected with one terminal of a source of potential of which the other terminal is connected with the nozzle, additional ring-shaped electrodes arranged at a distance from the first ring-shaped electrode and likewise disposed co-axially with the axis of the nozzle, the said additional electrodes being insulated from each other; a source of potential associated with said additional electrodes and connected therewith and means for withdrawing gas from said vessel to provide a pressure drop in the glow discharge space.
References Cited in the file of this patent UNITED STATES PATENTS 1,004,170 Jacoviello Sept. 26, 1911 2,059,257 Letterman Nov. 3, 1936 2,540,256 Gretener Feb. 6, 1951 2,668,260 Barnett et a1 Feb. 2, 1954 2,690,515 Mack Sept. 28, 1954 2,704,817 Millie Mar. 22, 1955 2,724,787 Gretener Nov. 22, 1955 2,753,479 Aughey et al. July 3, 1956 2,819,423 Clark Jan. 7, 1958 2,826,708 Foster Mar. 11, 1958 2,837,654 Berghaus June 3, 1958
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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US3143851A (en) * | 1960-03-23 | 1964-08-11 | Alwac International Inc | Method and apparatus for mixing combustible fluids |
US3156090A (en) * | 1961-09-18 | 1964-11-10 | Harold R Kaufman | Ion rocket |
US3414702A (en) * | 1965-05-28 | 1968-12-03 | Gen Electric | Nonthermionic electron beam apparatus |
US3603088A (en) * | 1970-05-18 | 1971-09-07 | Nasa | Ion thruster cathode |
US7929138B1 (en) * | 2008-02-15 | 2011-04-19 | The United States Of America As Represented By The United States Department Of Energy | Ambient-atmosphere glow discharge for determination of elemental concentration in solutions in a high-throughput or transient fashion |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1421049B1 (en) * | 1958-05-16 | 1970-01-29 | Berghaus Elektrophysik Anst | Device for carrying out reactions under electrical influence |
SE364520B (en) * | 1972-06-29 | 1974-02-25 | Aga Ab |
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US1004170A (en) * | 1910-03-12 | 1911-09-26 | Felice Jacoviello | Device for producing high-frequency oscillatory currents. |
US2059257A (en) * | 1934-10-15 | 1936-11-03 | William E Letterman | Spark plug |
US2540256A (en) * | 1948-04-09 | 1951-02-06 | Gretener Edgar | Ventilated arc |
US2668260A (en) * | 1951-02-07 | 1954-02-02 | Clarence F Barnett | Ion source |
US2690515A (en) * | 1953-07-22 | 1954-09-28 | Mack Julian Ellis | Method and apparatus for producing ions |
US2704817A (en) * | 1952-10-13 | 1955-03-22 | Genarco Inc | High temperature arc with method and means for preventing carbon accumulation |
US2724787A (en) * | 1952-08-07 | 1955-11-22 | Gretener Edgar | Arc lamps |
US2753479A (en) * | 1953-04-08 | 1956-07-03 | Du Pont | Spark cell assembly |
US2819423A (en) * | 1957-03-11 | 1958-01-07 | Gen Electric | Plasma transmitter |
US2826708A (en) * | 1955-06-02 | 1958-03-11 | Jr John S Foster | Plasma generator |
US2837654A (en) * | 1954-05-11 | 1958-06-03 | Berghaus Elektrophysik Anst | Process and apparatus for carrying out reactions by the action of electrical glow discharges |
-
1956
- 1956-07-14 CH CH349247D patent/CH349247A/en unknown
-
1957
- 1957-07-12 DE DEE14396A patent/DE1054427B/en active Pending
- 1957-07-13 FR FR1178871D patent/FR1178871A/en not_active Expired
- 1957-07-15 GB GB22314/57A patent/GB865455A/en not_active Expired
- 1957-07-15 US US671790A patent/US2969475A/en not_active Expired - Lifetime
Patent Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1004170A (en) * | 1910-03-12 | 1911-09-26 | Felice Jacoviello | Device for producing high-frequency oscillatory currents. |
US2059257A (en) * | 1934-10-15 | 1936-11-03 | William E Letterman | Spark plug |
US2540256A (en) * | 1948-04-09 | 1951-02-06 | Gretener Edgar | Ventilated arc |
US2668260A (en) * | 1951-02-07 | 1954-02-02 | Clarence F Barnett | Ion source |
US2724787A (en) * | 1952-08-07 | 1955-11-22 | Gretener Edgar | Arc lamps |
US2704817A (en) * | 1952-10-13 | 1955-03-22 | Genarco Inc | High temperature arc with method and means for preventing carbon accumulation |
US2753479A (en) * | 1953-04-08 | 1956-07-03 | Du Pont | Spark cell assembly |
US2690515A (en) * | 1953-07-22 | 1954-09-28 | Mack Julian Ellis | Method and apparatus for producing ions |
US2837654A (en) * | 1954-05-11 | 1958-06-03 | Berghaus Elektrophysik Anst | Process and apparatus for carrying out reactions by the action of electrical glow discharges |
US2826708A (en) * | 1955-06-02 | 1958-03-11 | Jr John S Foster | Plasma generator |
US2819423A (en) * | 1957-03-11 | 1958-01-07 | Gen Electric | Plasma transmitter |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3143851A (en) * | 1960-03-23 | 1964-08-11 | Alwac International Inc | Method and apparatus for mixing combustible fluids |
US3156090A (en) * | 1961-09-18 | 1964-11-10 | Harold R Kaufman | Ion rocket |
US3414702A (en) * | 1965-05-28 | 1968-12-03 | Gen Electric | Nonthermionic electron beam apparatus |
US3603088A (en) * | 1970-05-18 | 1971-09-07 | Nasa | Ion thruster cathode |
US7929138B1 (en) * | 2008-02-15 | 2011-04-19 | The United States Of America As Represented By The United States Department Of Energy | Ambient-atmosphere glow discharge for determination of elemental concentration in solutions in a high-throughput or transient fashion |
Also Published As
Publication number | Publication date |
---|---|
DE1054427B (en) | 1959-04-09 |
FR1178871A (en) | 1959-05-15 |
GB865455A (en) | 1961-04-19 |
CH349247A (en) | 1960-10-15 |
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