US1769577A - Method of protecting sheet metal - Google Patents

Method of protecting sheet metal Download PDF

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Publication number
US1769577A
US1769577A US17137927A US1769577A US 1769577 A US1769577 A US 1769577A US 17137927 A US17137927 A US 17137927A US 1769577 A US1769577 A US 1769577A
Authority
US
United States
Prior art keywords
metal
compound
coating
sheet metal
enamel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
Inventor
Ralph Z Hopkins
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
American Motors Corp
Original Assignee
Hudson Motor Car Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hudson Motor Car Co filed Critical Hudson Motor Car Co
Priority to US17137927 priority Critical patent/US1769577A/en
Application granted granted Critical
Publication of US1769577A publication Critical patent/US1769577A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
    • C23F11/10Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
    • C23F11/12Oxygen-containing compounds
    • C23F11/124Carboxylic acids
    • C23F11/126Aliphatic acids
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31678Of metal
    • Y10T428/31714Next to natural gum, natural oil, rosin, lac or wax

Definitions

  • MICHIGAN 'LS SIGNOB TO HUDSON MOTOR CAB COH- PANY, O! DETROIT, MICHIGAN, A CORPORATION OF MICHIGAN METHOD OI PROTECTING BH EET K ETAL
  • This invention relates to the protection of sheet metal, particularly during shipment from the mill and manufacture into automotive parts and its subsequent preparation to receive a permanent protective coating, such as paint, varnish, enamel or the like.
  • ' t is an object of the present invention to provide an economical method of protecting metal from rust and other damage during shipment and manufacture and at the same time leave the metal in suitable condition for the application of the final permanent coating.
  • a compound suitable for this purpose which has the capacity to combine with the permanent coating for the metal, and which is also soluble in water, so that it may be readily removed, merely by rinsing, to such an extent that any residue will not affect the adhesion of the permanent coating, is composed in large part of a substance containing a fatty acid, or a saponified vegetable oil.
  • a suitable soluble compound preferably a soap compound which is soluble in water or a light alkali cleaning solution, is applied to v the metal at the mills.
  • the compound preferably, should be of such nature that, when applied to the metal at a temperature of about 150 F., it will dry out and form a coating which will adhere to the metal during shipment.
  • the'same or a similar compound is used to lubricate the dies and the metal is pressed to the desired shape.
  • the compound is then removed and the metal cleaned by washing in water,-or other cleaning solution, and rinsed in hot water.
  • the metal is then dried and wiped and is ready for the application of a permanent coating of enamel, paint or the like.
  • a compound which has been found suitable is a soluble soap compound made by adding a mixture of sodium and potassium hydroxide to a mixture of vegetable oilscontaining six parts cocoanut oil, one part olive oil and one part palm oil,-whereby the oils are saponified. Sufiicient water is added I ployed in the practice to render the mixture soluble and-have the,
  • Another compound which has given satisfactory results in the practice of the invention is composed of 10 per cent. of animal wool fat and 90 per cent. of kerosene.
  • zVVhile various compounds may be emmay 'be applied to the metal by various methods, a soluble soap compound which may be applied to the metal at a temperature I of about 150 F. is that any thin film o which may adhere to terfere with the enamel to the metal referred. It is found such a soap compound characteristics' of the soap and the enamel or varnish and the like. may be used in the practice of the invention whlch will combine with the permanent finish coating in such a manner as not to afie'ct detrimentally its bond with the metal.
  • the invention particularly contemplates the protection of sheet metal during its able of dissolving in water fabrication into finished automobile pants,
  • the improved method which consists in coating sheet steel as it comes from the rolls with a protective coating of a water soluble soap compound, transportin the steel to the place of manufacture w ile so coated, shaping the steel with dies lubricated with a similar compound, and thereafter removing the compound, cleaning the metal and applying a permanent coating.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Description

R Drawing.
Patented July 1,
RALPH Z. HOPKINS, OI DETROIT,
MICHIGAN, 'LS SIGNOB TO HUDSON MOTOR CAB COH- PANY, O! DETROIT, MICHIGAN, A CORPORATION OF MICHIGAN METHOD OI PROTECTING BH EET K ETAL This invention relates to the protection of sheet metal, particularly during shipment from the mill and manufacture into automotive parts and its subsequent preparation to receive a permanent protective coating, such as paint, varnish, enamel or the like.
In'the manufacture of automotive parts from sheet metal, such as body panels, fenders and the like, great care has to be exercised to keep the metal free from rust and scale and-from becoming damaged during shipment or prior to manufacture. Heretofore sheet metal produced at the mill has been carefully freed of scale and then a protective coating applied. For this purpose mineral oil has ordinarily been used to protect the metal against rust. When the sheet metal has been made up into parts by means of presses and dies, the dies have been lubricated with an oil of the type with which the metal has been coated at the rolling mill.
11 order to prepare the metal for enameling or painting after the parts have been shaped in the presses, to remove the protective coating and the lubricant so that the permanent protective coating, such as paint, varnish, enamel or the like, will adhere properly, since the will not adhere properly to surfaceswhic have even a trace of mineral oil. Various methods have been employed to remove the mineral oil. Commonly, it has been burned off at a temperature of about 800 to 850 F. This temperature tends to produce a slight oxidation of the metal, formin a scale which prevents the proper adhesion of the permanent protective coatin The presence of any residue of the mineral oil film or of any scale causes a weak bond between the paint, enamel or like coating and the metal with the result that the paint or enamel eels oil or cracks.
' t is an object of the present invention to provide an economical method of protecting metal from rust and other damage during shipment and manufacture and at the same time leave the metal in suitable condition for the application of the final permanent coating.
it has been necessary Application filed February 88,- 182 7. Serial No. 171,879.
In accordance with protective compound which adheres to the metal during shipment or transportation to the place of manufacture and which can be removed easily without formation of scale, and if not completely removed will not affect the proper adhesion of the permanent finish coating, such as paint, enamel or the the invention the metal as it comes from the rolls is freed I from scale at the mill and is coated with a like. The same .or a similar compound is. I
used as a lubricant on the dies. A compound suitable for this purpose which has the capacity to combine with the permanent coating for the metal, and which is also soluble in water, so that it may be readily removed, merely by rinsing, to such an extent that any residue will not affect the adhesion of the permanent coating, is composed in large part of a substance containing a fatty acid, or a saponified vegetable oil. c
In general, in the practice of the invention a suitable soluble compound, preferably a soap compound which is soluble in water or a light alkali cleaning solution, is applied to v the metal at the mills. The compound, preferably, should be of such nature that, when applied to the metal at a temperature of about 150 F., it will dry out and form a coating which will adhere to the metal during shipment. In working the metal into finished parts, the'same or a similar compound is used to lubricate the dies and the metal is pressed to the desired shape.
The compound is then removed and the metal cleaned by washing in water,-or other cleaning solution, and rinsed in hot water. The metal is then dried and wiped and is ready for the application of a permanent coating of enamel, paint or the like.
A compound which has been found suitable is a soluble soap compound made by adding a mixture of sodium and potassium hydroxide to a mixture of vegetable oilscontaining six parts cocoanut oil, one part olive oil and one part palm oil,-whereby the oils are saponified. Sufiicient water is added I ployed in the practice to render the mixture soluble and-have the,
following composition:
. Per cent Anhydrous soag 22 to 23 Free fatty aci a"; 1 to 2 Free alkali -None.
Another compound which has given satisfactory results in the practice of the invention is composed of 10 per cent. of animal wool fat and 90 per cent. of kerosene.
zVVhile various compounds may be emmay 'be applied to the metal by various methods, a soluble soap compound which may be applied to the metal at a temperature I of about 150 F. is that any thin film o which may adhere to terfere with the enamel to the metal referred. It is found such a soap compound characteristics' of the soap and the enamel or varnish and the like. may be used in the practice of the invention whlch will combine with the permanent finish coating in such a manner as not to afie'ct detrimentally its bond with the metal.
Any compound .Water soluble as used in the appended claims means ca either pure or s ightly alkaline.
The invention particularly contemplates the protection of sheet metal during its able of dissolving in water fabrication into finished automobile pants,
such as fenders, like, and their the application. of a permanent coating of paint, enamel or the li not to be construed as so limited, as and application in other fields will stood by; those skilled in the art.
What I claim is:
The improved method which consists in coating sheet steel as it comes from the rolls with a protective coating of a water soluble soap compound, transportin the steel to the place of manufacture w ile so coated, shaping the steel with dies lubricated with a similar compound, and thereafter removing the compound, cleaning the metal and applying a permanent coating.
aprons, body panels and the rotective its scope be undern testimony whereof I afiix my signature.
. RALPH Z. HOPKINS.
of the invention and the metal does not inroper adhesion of the due to the similar basic subsequent preparation for e,'but is
US17137927 1927-02-26 1927-02-26 Method of protecting sheet metal Expired - Lifetime US1769577A (en)

Priority Applications (1)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2609594A (en) * 1949-10-18 1952-09-09 Gilron Products Company Method of producing vitreous enamelled metal articles
US2609780A (en) * 1949-11-01 1952-09-09 Gilron Products Company Method of producing metal articles with highly finished surfaces for coating
US2629673A (en) * 1946-09-18 1953-02-24 Field Crosby Method of coiling and coating flat metal stock and the article formed thereby
US2686488A (en) * 1948-01-14 1954-08-17 Harley A Montgomery Method of treating and cold deep drawing sheet metal

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2629673A (en) * 1946-09-18 1953-02-24 Field Crosby Method of coiling and coating flat metal stock and the article formed thereby
US2686488A (en) * 1948-01-14 1954-08-17 Harley A Montgomery Method of treating and cold deep drawing sheet metal
US2609594A (en) * 1949-10-18 1952-09-09 Gilron Products Company Method of producing vitreous enamelled metal articles
US2609780A (en) * 1949-11-01 1952-09-09 Gilron Products Company Method of producing metal articles with highly finished surfaces for coating

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