PE116299A1 - Catalizador de acetato de vinilo que esta compuesto por paladio y oro depositado sobre un portador con contenido de cobre - Google Patents

Catalizador de acetato de vinilo que esta compuesto por paladio y oro depositado sobre un portador con contenido de cobre

Info

Publication number
PE116299A1
PE116299A1 PE1998000445A PE00044598A PE116299A1 PE 116299 A1 PE116299 A1 PE 116299A1 PE 1998000445 A PE1998000445 A PE 1998000445A PE 00044598 A PE00044598 A PE 00044598A PE 116299 A1 PE116299 A1 PE 116299A1
Authority
PE
Peru
Prior art keywords
catalyst
paladium
gold
vinyl acetate
carrier
Prior art date
Application number
PE1998000445A
Other languages
English (en)
Inventor
Ioan Nicolau
Philip M Colling
Adolfo Aguilo
Original Assignee
Celanese Int Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese Int Corp filed Critical Celanese Int Corp
Publication of PE116299A1 publication Critical patent/PE116299A1/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8926—Copper and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

UN CATALIZADOR UTILIZADO EN LA PRODUCCION DE ACETATO DE VINILO MEDIANTE LA REACCION DE ETILENO, OXIGENO Y ACIDO ACETICO. EL CATALIZADOR CONSISTE EN UN SOPORTE POROSO DE SILICE, EN DONDE SE DEPOSITA CANTIDADES CATALITICAMENTE EFECTIVAS DE PALADIO, ORO Y COBRE METALICO, TENIENDO EN CUENTA QUE NINGUN COMPONENTE DEL CATALIZADOR SE MEZCLA. EL CATALIZADOR ES PREPARADO IMPREGNANDO UNA SOLUCION ACUOSA DE SAL DE COBRE HIDROSOLUBLE, FIJANDO DICHO COBRE EN FORMA DE COMPUESTO NO HIDROSOLUBLE MEDIANTE LA REACCION DE UN COMPUESTO ALCALINO APROPIADO, SEGUIDAMENTE ES IMPREGNADO CON UNA O MAS SOLUCIONES DE SALES DE PALADIO Y/U ORO HIDROSOLUBLES, DESPUES DE LA REDUCCION DEL PALADIO Y ORO TOTALES DEL CATALIZADOR, EL CATALIZADOR ES IMPREGNADO CON UNA SOLUCION DE ACETATO DE METAL ALCALINO QUE PUEDE SER ACETATO DE POTASIO
PE1998000445A 1997-06-03 1998-06-02 Catalizador de acetato de vinilo que esta compuesto por paladio y oro depositado sobre un portador con contenido de cobre PE116299A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/867,911 US5968869A (en) 1997-06-03 1997-06-03 Vinyl acetate catalyst comprising palladium and gold deposited on a copper containing carrier

Publications (1)

Publication Number Publication Date
PE116299A1 true PE116299A1 (es) 1999-11-22

Family

ID=25350704

Family Applications (1)

Application Number Title Priority Date Filing Date
PE1998000445A PE116299A1 (es) 1997-06-03 1998-06-02 Catalizador de acetato de vinilo que esta compuesto por paladio y oro depositado sobre un portador con contenido de cobre

Country Status (29)

Country Link
US (2) US5968869A (es)
EP (1) EP0986433B1 (es)
JP (1) JP4165663B2 (es)
KR (1) KR100516259B1 (es)
CN (1) CN1107538C (es)
AR (1) AR012901A1 (es)
AT (1) ATE203930T1 (es)
AU (1) AU724125B2 (es)
BR (1) BR9809715B1 (es)
CA (1) CA2289503C (es)
CZ (1) CZ298593B6 (es)
DE (1) DE69801324T2 (es)
ES (1) ES2161531T3 (es)
HU (1) HUP0003486A2 (es)
ID (1) ID22991A (es)
MY (1) MY117733A (es)
NO (1) NO319763B1 (es)
NZ (1) NZ501439A (es)
PE (1) PE116299A1 (es)
PL (1) PL190979B1 (es)
RU (1) RU2198731C2 (es)
SA (1) SA98190239B1 (es)
SK (1) SK164599A3 (es)
TR (1) TR199903000T2 (es)
TW (1) TW412526B (es)
UA (1) UA57077C2 (es)
WO (1) WO1998055225A1 (es)
YU (1) YU49183B (es)
ZA (1) ZA984729B (es)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5753542A (en) * 1985-08-02 1998-05-19 Semiconductor Energy Laboratory Co., Ltd. Method for crystallizing semiconductor material without exposing it to air
US6072078A (en) * 1997-12-12 2000-06-06 Celanese International Corporation Vinyl acetate production using a catalyst comprising palladium, gold, copper and any of certain fourth metals
US6013834A (en) * 1999-03-04 2000-01-11 Celanese International Corporation Production of vinyl acetate in a catalytic reactor equipped with filter and distribution bed
US6303537B1 (en) * 1999-11-17 2001-10-16 Celanese International Corporation Vinyl acetate catalyst comprising metallic palladium and gold and prepared utilizing sonication
US6509293B1 (en) * 2000-05-22 2003-01-21 Eastman Chemical Company Gold based heterogeneous carbonylation catalysts
US20020061277A1 (en) * 2000-09-25 2002-05-23 Engelhard Corporation Non-pyrophoric water-gas shift reaction catalysts
IL161418A0 (en) * 2001-10-15 2004-09-27 Immunomedics Inc Direct targeting binding proteins
TW201240725A (en) 2003-12-19 2012-10-16 Celanese Int Corp Layered support material for catalysts
CN100336593C (zh) * 2004-02-19 2007-09-12 中国石油化工股份有限公司 合成醋酸乙烯酯的负载型催化剂的制备方法
RU2422433C2 (ru) * 2004-12-20 2011-06-27 Селаниз Интернэшнл Корпорейшн Модифицированные материалы носителей для катализаторов
US8227369B2 (en) * 2005-05-25 2012-07-24 Celanese International Corp. Layered composition and processes for preparing and using the composition
US9527060B2 (en) * 2006-08-30 2016-12-27 Showa Denko K.K. Process for production of catalyst for alkenyl acetate production
US8507720B2 (en) * 2010-01-29 2013-08-13 Lyondell Chemical Technology, L.P. Titania-alumina supported palladium catalyst
US8329611B2 (en) 2009-12-16 2012-12-11 Lyondell Chemical Technology, L,P. Titania-containing extrudate
US8273682B2 (en) * 2009-12-16 2012-09-25 Lyondell Chemical Technology, L.P. Preparation of palladium-gold catalyst
TW202204039A (zh) 2020-06-11 2022-02-01 美商瑟蘭斯國際股份有限公司 用於乙酸乙烯酯製造之催化劑的製備方法
KR20230084256A (ko) * 2020-11-27 2023-06-12 가부시끼가이샤 레조낙 아세트산비닐 제조용 촉매의 제조 방법 및 아세트산비닐의 제조 방법
CN114618519A (zh) * 2020-12-11 2022-06-14 中国科学院大连化学物理研究所 一种负载型双金属催化剂制备丙酸甲酯的方法

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1618391C3 (de) * 1967-03-22 1975-08-14 Hoechst Ag, 6000 Frankfurt Verfahren zur Herstellung von Vinylacetat
CH534005A (de) * 1968-02-01 1973-02-28 Bayer Ag Verfahren zur Herstellung eines Palladium und Gold enthaltenden Katalysators
JPS4837245B1 (es) * 1969-10-02 1973-11-09
JPS514118A (en) * 1974-06-27 1976-01-14 Kuraray Co Sakusanbiniruno seizohoho
GB1571910A (en) * 1975-12-18 1980-07-23 Nat Distillers Chem Corp Vinyl acetate process and catalyst therefor
DE3200483A1 (de) * 1982-01-09 1983-07-21 Bayer Ag, 5090 Leverkusen Kieselsaeurehaltige formkoerper, verfahren zu ihrer herstellung und ihre verwendung
US5185308A (en) * 1991-05-06 1993-02-09 Bp Chemicals Limited Catalysts and processes for the manufacture of vinyl acetate
US5274181A (en) * 1991-05-06 1993-12-28 Bp Chemicals Limited Catalysts and processes for the manufacture of vinyl acetate
DE4120492A1 (de) * 1991-06-21 1992-12-24 Hoechst Ag Verfahren zur herstellung von vinylacetat
TW330160B (en) * 1992-04-08 1998-04-21 Hoechst Ag Supported catalyst, process for its preparation and its use for the preparation of vinyl acetate
US5332710A (en) * 1992-10-14 1994-07-26 Hoechst Celanese Corporation Vinyl acetate catalyst preparation method
US5347046A (en) * 1993-05-25 1994-09-13 Engelhard Corporation Catalyst and process for using same for the preparation of unsaturated carboxylic acid esters
DE19501891C1 (de) * 1995-01-23 1996-09-26 Degussa Verfahren zur Herstellung eines Trägerkatalysators und seine Verwendung für die Produktion von Vinylacetat
US5691267A (en) * 1996-04-16 1997-11-25 Hoechst Celanese Corporation Two step gold addition method for preparing a vinyl acetate catalyst
SA97180048B1 (ar) * 1996-05-24 2005-12-21 هوكست سيلانس كوربوريشن محفز بلاديوم - ذهب palladium gold ثنائي المعدن متغاير الخواص heterogeneous bimetallic vinyl acetate لإنتاج أسيتات فينيل
US5693586A (en) * 1996-06-28 1997-12-02 Hoechst Celanese Corporation Palladium-gold catalyst for vinyl acetate production
US5731457A (en) * 1997-06-03 1998-03-24 Hoechst Celanese Corporation Vinyl acetate process utilizing a palladium-gold-copper catalyst

Also Published As

Publication number Publication date
TR199903000T2 (xx) 2000-05-22
YU24698A (en) 1999-11-22
NO319763B1 (no) 2005-09-12
CA2289503A1 (en) 1998-12-10
BR9809715B1 (pt) 2009-01-13
HUP0003486A2 (hu) 2001-02-28
NO995873D0 (no) 1999-12-01
ZA984729B (en) 1999-12-02
DE69801324D1 (de) 2001-09-13
PL337162A1 (en) 2000-07-31
SK164599A3 (en) 2000-05-16
KR20010013308A (ko) 2001-02-26
DE69801324T2 (de) 2002-05-23
JP2002508703A (ja) 2002-03-19
CZ436599A3 (cs) 2000-06-14
AR012901A1 (es) 2000-11-22
US5968869A (en) 1999-10-19
CZ298593B6 (cs) 2007-11-21
NZ501439A (en) 2001-11-30
CA2289503C (en) 2007-06-26
NO995873L (no) 1999-12-01
JP4165663B2 (ja) 2008-10-15
PL190979B1 (pl) 2006-02-28
UA57077C2 (uk) 2003-06-16
RU2198731C2 (ru) 2003-02-20
ATE203930T1 (de) 2001-08-15
BR9809715A (pt) 2000-07-11
SA98190239B1 (ar) 2006-05-01
CN1259060A (zh) 2000-07-05
ES2161531T3 (es) 2001-12-01
WO1998055225A1 (en) 1998-12-10
CN1107538C (zh) 2003-05-07
KR100516259B1 (ko) 2005-09-20
AU7488998A (en) 1998-12-21
EP0986433B1 (en) 2001-08-08
ID22991A (id) 1999-12-23
AU724125B2 (en) 2000-09-14
MY117733A (en) 2004-07-31
YU49183B (sh) 2004-07-15
EP0986433A1 (en) 2000-03-22
TW412526B (en) 2000-11-21
US6107514A (en) 2000-08-22

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