KR20130123513A - Temporary hair dye cosmetic composition - Google Patents

Abstract

The present invention relates to a solid phase hair dye cosmetic composition which contains silicone oil and a silicone-based coating agent and has a temporary hair dyeing effect with pigments using hydroxyl apatite and plasticized silica and a method for manufacturing the same. Particularly, the present invention related to a solid phase hair dye cosmetic composition characterized by containing 10-50 wt% of silicone oil, 2-20 wt% of silicone-based coating agent, 3.0-20.0 wt% of wax, 0.1-5 wt% of hydroxyl apatite, 0.05-1.5 wt% of plasticized silica, 1.0-30.0 wt% of pigments, 5.0-40.0 wt% of body pigments, and 0.2-10.0 wt% of an oil thickener. The solid phase hair dye cosmetic composition has strong resistance to rainwater and sweat using dimethicone, cyclopentasiloxane, methyl trimethicone, cyclohexasiloxane, carprylylmethicone, phenyltrimethicone, diphenyl dimethicone, and the like with superior water-proofing properties as a main base and reduces washing-off due to friction or sebum using the silicone-based coating agent. The solid phase hair dye cosmetic composition improves adhesion onto hair mixing hydroxyl apatite with the pigments, thereby enabling long-term maintenance of hair dyeing effect at a desired part. The solid phase hair dye cosmetic composition is able to cleanly wash hair by a detergent such as a general shampoo and the like containing silicone ingredients and minimizes hair damages.

Description

Hair dye cosmetic composition having a temporary dyeing effect {TEMPORARY HAIR DYE COSMETIC COMPOSITION}

The present invention is a solid hair dye cosmetic composition using a silicone oil and wax silicone-based film formers as a thin and naturally attached when applied to the hair to be expressed in a desired color, in more detail semi-permanent dye and then dye It is to provide a solid hair dyeing cosmetic composition and a method for producing the same, such as white hair, sachet hair, etc., which have grown up to a long time, into a desired color such as black and brown.

Such a composition of the present invention is difficult to continuous dyeing for hair regrown upon semi-permanent dyeing, while solving the problem of hair damage due to dyeing, while having a temporary dyeing effect powder type, mascara type, cover foundation type sweat By solving the problem of erasing the rainwater, it maintains excellent water resistance and durability and can realize the effect of dyeing without additional use all day.

Conventional hair dyes avoided frequent dyeing due to hair damage in the process of converting the hair to acid to facilitate hair penetration of the dye. In order to solve this problem, products have been developed to solve the problems such as hair damage by adjusting the pH of the hair or applying it to the surface without chemical treatment and to temporarily have a dyeing effect.

However, those products that use dyes as liquid formulations have problems such as dyeing on the skin as well as hair, or smearing some of the rain on the garments.The mascara type with pigments is applied to sweat, rain, and sebum after application. There is a problem that the hair color is easily restored by the original color recovery.

In order to solve the problem of water resistance, silicone coated powder or silicone-based solid cream type products were released, which improved the problem of dyeing and sustained by general level of sweat, but it was weak in rainwater or sebum due to weak formation of the ultimate waterproof film. In addition, the reduced durability caused by wear did not completely solve the need for frequent reapplication or clothing contamination.

In addition, the Republic of Korea Patent Publication No. 10-2010-0090404 (published Aug. 16, 2010) is a temporary hair coating agent using bamboo charcoal powder, hydrophobic waterproofing film, low alcohol and propellant as a temporary hair coating agent compared to the existing hair coating agent for a long time Although the composition to increase the amount is disclosed, it is a hair spray material in the form of a spray spray containing a propellant, and the hydrophobic waterproofing agent is a water-based composition using methacryloyl ethyl betaine / acrylate copolymer and alcohol and water resistance accompanied with friction This low persistence problem is not completely solved.

Patent Publication No. 2007-53924 (published May 28, 2007) includes water in silicone (W / S) including wax, cyclomethicone, silicone organic polymer, silicone-based emulsifier, inorganic colorant, additives and residual amount of water. oil) As an emulsified temporary hair dye composition, it has a feature of being more water-resistant than a conventional hair coating agent, but it is inevitable to contain an emulsifier having both hydrophilicity and lipophilic properties in the form of an emulsified formulation. Excellent water resistance cannot be expected for long exposure to moisture such as branches and rainwater, and when silicone organic copolymers such as acrylate / dimethicone copolymers or nylon / dimethicone copolymers are used as the film forming agent, friction is accompanied by water. If the film is weakened, the dyeing site is easily peeled off.

In order to solve the problems of the prior art, the present inventors exclude all of an aqueous phase component which may have hydrophilicity, an emulsifier and a film forming agent having a hydrophilic component, and use silicone oil, a silicone film forming agent, and an oil phase component. By using hydroxyapatite powder, it improves the adhesion to the hair while washing or erasing it by sweat or rain water, preventing it from getting on clothes or skin after drying and minimizing hair damage, It is an object of the present invention to provide a cosmetic composition capable of giving hair similar effects with improved durability.

In order to achieve the above object, the present invention is a solid hair containing silicone oil, silicone film formers, waxes, hydroxyapatite, extender pigments, oil thickener and calcined silica and pigments. It is characterized by providing a dyeing cosmetic composition and its preparation method.

The cosmetic of the present invention does not pass through the hair permanently, by applying a color to the beginning of the hair that grew after dyeing, to minimize the hair damage caused by frequent dyeing to protect the hair, rain water compared to conventional temporary dyes It is a very useful and excellent effect that can prevent contamination such as durability, durability and clothing that are not erased by sweat, sebum, and the like.

Hereinafter, the present invention will be described in more detail.

The present invention is a solid composition capable of temporarily giving a dyeing effect to the hair to maintain a natural hair color without additional dyeing.

The hair dye cosmetic composition of the present invention is to give a basic water resistance based on the silicone oil as a main base, the content is preferably contained 10 to 50% by weight, which is when the silicone oil in the hair cosmetic composition within 10% by weight of the water resistance effect It is not enough to exhibit the effect, and when it exceeds 50% by weight, the silicone oil property of the interfacial tension is low, so it may be smeared or smeared on an undesired area or skin, and the viscosity may be lowered during application. .

Silicone oils that can be used in the present invention include dimethicone, cyclopentasiloxane, methyltrimethicone, cyclohexasiloxane, caprylylmethicone, phenyltrimethicone, diphenyl dimethicone, etc., at least one of which is used as a raw material. do.

In the makeup cosmetic composition of the present invention, in order to increase the durability with water resistance, a silicone film-forming agent was used, and the content is preferably contained in an amount of 2 to 20% by weight, which is less than 2% by weight of the silicone film-forming agent in the hair cosmetic composition. This is because the effect of improving sustainability cannot be sufficiently confirmed, and when the amount exceeds 20% by weight, the viscosity of the product is excessively increased, making it difficult to manufacture, the feeling of use is not smooth, and there is a problem that the cleaning after application is not completely cleaned.

As the silicone-based coating agent, at least one of trimethylsiloxysilicate and bishydroxylauryl dimethicone / ipdiaicopolymer having excellent compatibility with the silicone oil is used as a raw material.

In addition, in order to solve the problem of poor adhesion due to the repulsive force between the hair and the pigment, by using hydroxy apatite predispersed and mixed with the pigment, the pigment persistence and adhesion is improved, and the content is preferably contained 0.1 to 5% by weight If the hydroxyapatite is within 0.1% by weight of the hair cosmetic composition, it is impossible to sufficiently confirm the effect of improving the adhesion of the pigment, and when it exceeds 5% by weight, the viscosity of the product is excessively increased, making it difficult to manufacture and softening the feeling of use. Because there may be a problem.

In addition, calcined silica, which has a water resistance and absorbs sebum, reduces the excessive oiliness, and preferably contains 0.05 to 1.5% by weight, and at 0.05% by weight or less, the absorption effect of sebum and the like is insignificant and 1.5% by weight. This is because there may be a problem that the manufacturing of the product becomes difficult when exceeded. The calcined silica uses one or more of silica dimethyl silylate and silica silylate.

It is preferable to contain 3.0 to 20.0% by weight of wax, which maintains the solid state and secures the stability of the contents at high temperature, and is less than 3.0% by weight when it is applied and does not solidify in the container. This is because it is inconvenient to use and if it contains more than 20.0% by weight, it may be difficult to take the contents with a brush or a sponge. The wax uses at least one of candelilla wax, carnauba wax, ceresin, and polyethylene wax.

In order to reduce artificial glossiness after applying hair with powdery finish, and to reduce hair entanglement, sieving pigments are preferably contained in the range of 5.0 to 40.0% by weight. This is because the powdery sieving pigment can be easily dropped by friction when it exceeds 40.0% by weight. Sieving pigments may be used as is, at least one of silica, talc, mica, PMMA, nylon powder, aluminum oxide as it is or in the surface treatment state such as coating.

It is preferable to contain 1.0 to 30.0% by weight of the pigment used to give color to the hair, since the color development is low due to the temporary dyeing effect at 1.0% by weight or less, and if it exceeds 30.0% by weight, it may get on the skin or clothing. . As the pigment, at least one of black iron oxide, red iron oxide, yellow iron oxide, titanium dioxide, ultramarine, red 201, red 202, red 226, yellow 4, yellow 5 and blue 1 is used.

It is preferable to contain the oil thickener which reduces fluidity at high temperature and maintains high temperature stability and maintains proper viscosity.It is preferable to contain 0.2 ~ 10.0% by weight. If so, it is difficult to mix due to high viscosity during manufacturing. As the oil thickener, at least one of disteadimonium hectorite, glyceryl behenate / eicosadiate, and quaternium-18 hectorite is used.

The hair dye cosmetic composition of the present invention can be prepared in a solid or semi-solid formulation according to the content of the wax and the oil thickener.

The method for preparing the hair dye cosmetic composition is first added 1.0 to 30.0% by weight of hydroxyapatite, 0.1 to 5% by weight of hydroxyapatite, and 5.0 to 40.0% by weight of sieving pigment in the Henschel mixer, and then dispersed / mixed twice at a speed of 1,200 rpm. After the first step of grinding and

0.05 to 1.5% by weight of the mixed pulverized pigment, hydroxyapatite, extender pigment mixture and calcined silica of the first step, 3.0 to 20.0% by weight of wax, 10 to 50% by weight of silicone oil, and 2 to 20% by weight of silicone film-forming agent And a second step of dispersing 0.2-10.0% by weight of the oil phase thickener into a dissolution tank heated and dissolved at 70-80 ° C.

Hereinafter, the present invention will be described in more detail with reference to Examples and Experimental Examples, but the present invention is not limited only to these examples.

[Comparative Examples 1 to 4 and Examples of the Invention]

In Comparative Examples 1 to 4 and Examples of the present invention, the respective hair makeup cosmetic compositions were prepared with the ingredients and contents shown in Table 1 below.

At this time, Comparative Example 1 of Table 1 is a component and content of a conventional mascara hair makeup cosmetic composition, Comparative Example 2 is a component and content of a powder makeup cosmetic composition in the form of powder, Comparative Example 3 contains a silicone oil And a hair makeup cosmetic composition formulated with a general iron oxide, and Comparative Example 4 is a hair makeup cosmetic composition prescribed with a silicone oil, a silicone film-forming agent and a general iron oxide, and in the embodiment of the present invention, a silicone oil, a silicone film-forming agent, A hydroxy apatite and iron oxide are mixed and pulverized in powder form to make up a hair makeup cosmetic composition.

ingredient Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Example 1. Water To 100 - - - - 2. Talc - To 100 10.0 10.0 10.0 3. Cyclohexasiloxane - - To 100 To 100 To 100 4. nylon powder - 5.0 - - - 5. Acrylate Copolymer 23.0 - - - - 6. Beads wax 10.0 - - - - 7. Stearic acid 5.0 - - - - 8. TI 1.5 - - - - 8. Butylene glycol 5.0 - - - - 9. Candelilla Wax 5.0 - 10.0 10.0 10.0 10.Monmorillonite 1.0 - - - - 11.silica - 10.0 5.0 5.0 5.0 12. Mica - 10.0 10.0 10.0 10.0 13. Red iron oxide 0.5 1.0 0.5 0.5 0.5 14. Yellow Iron Oxide 2.0 4.0 2.0 2.0 2.0 15. Black Iron Oxide 10.0 20.0 10.0 10.0 10.0 16. Titanium Dioxide 2.0 4.0 2.0 2.0 2.0 17. Hydroxyapatite - - - - 1.0 18. Phenyltrimethicone - 15.0 10.0 10.0 10.0 19. Silica Dimethyl Silylate 0.2 0.2 0.2 20. Disteadimonium hectorite - - 1.0 1.0 1.0 21.Trimethylsiloxysilicate - - - 10.0 10.0 22. Preservatives Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount

The manufacturing method of Comparative Example 1 is as follows.

First, the raw materials 1, 5 to 10, and 22 are heated and emulsified at 80 ° C., and then, the raw materials 13 to 16 are mixed and ground by mixing and grinding the raw material 13-16 with a Henschel mixer.

In the preparation method of Comparative Example 2, first, raw materials 2, 4, 11 to 16 were weighed into a Henschel mixer, and then the raw materials 18 were evenly dispersed to obtain a mixture.

The preparation method of Comparative Example 3 is a method of mixing and pulverizing the raw materials 2, 11 to 16 with a Henschel mixer and mixing the rest of the raw materials 3, 9, 18 to 20, 22 in a mixture obtained by heating and dissolving at 70 ~ 80 ℃ Prepared and stored.

The preparation method of Comparative Example 4 was prepared by mixing and grinding the raw materials 2, 11 to 16 with a Henschel mixer and mixing the remaining raw materials 3, 9, 18 to 22 with a mixture in which the raw materials were heated and dissolved at 70 to 80 ° C. Stored.

Example preparation method of the present invention is to prepare a cosmetic composition by mixing and grinding the raw materials 2, 11 to 17 with a Henschel mixer and mixing the remaining raw materials 3, 9, 18 to 22 in a mixture that is heated and dissolved at 70 ~ 80 ℃ Stored.

[Test Example 1] Evaluation of usability, burying, persistence, coverage, cleaning power of the makeup

On the hair of the makeup cosmetic composition prepared in Comparative Examples 1 to 4 and the examples of the present invention, the usability, the color covering power of the hair, the staining, the persistence, and the cleaning power on whether there is a residue remaining when the hair is washed Twenty panelists (women aged 25 to 40 years) were compared and evaluated, and the results are shown in Table 2 below.

At this time, the worst evaluation score was 1 and the best evaluation score was 9 using a scoring method.

Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Example Usability 8.0 6.3 7.6 7.4 7.4 Buried 6.5 3.2 6.2 7.8 8.5 Persistence 6.7 6.4 7.0 8.4 8.8 Coverage 6.4 4.3 6.8 6.8 7.4 Hair cleansing power 8.5 8.3 8.7 8.7 8.8

As shown in Table 2, the case where the silicone oil, the silicone-based coating agent, the hydroxyapatite and the pigment were mixed and pulverized in the powder state and prescribed for use was highly evaluated as a whole.

The results of usability of the makeup were evaluated in the case of Comparative Example 1, but the viscosity of the contents is lower than the Examples, it is judged to be highly evaluated for the soft applicability when applying the hair with a brush, hair color coverage, burying after application The persistence evaluation was highly evaluated by the examples of the present invention.

In comparison with Comparative Example 3 and the embodiment of the present invention, even in the same pigment content, Comparative Example 3 has only silicone oil, and there is no silicone-based film-forming agent, so that the viscosity is low when the product is used. It adhered well to clothes or hands and showed a marked drop in persistence, and it could be seen that partial staining function was not sufficiently performed in the overall function.

On the other hand, in the case of Comparative Example 4 and the embodiment of the present invention, the extract did not adhere to clothes, hands, etc. by using the silicone film-forming agent, and thus it was confirmed that the partial dyeing effect could be maintained for a long time without being erased due to its excellent durability.

As can be seen from the examples of the present invention, the use of hydroxyapatite at the time of dye mixing is superior to Comparative Examples 3 and 4 using the same amount of dye in terms of the ability to cover the partial hair requiring dyeing in the desired color. It is believed that hydroxyapatite improves adhesion and coverage by minimizing repulsion between pigment and hair.

In the case of a product having a temporary dyeing effect is not erased well in use, but also clean in the case of cleaning is also important matters, it was evaluated that the embodiment of the present invention has the best cleaning effect.

As described above, the embodiment including both the hydroxyapatite and the silicon-based film forming agent of the present invention was evaluated to be superior to the comparative examples.

Test Example 2 Water Resistance Film Formation Confirmation Test

In order to confirm the formation of a water-resistant coating of hair dye cosmetics, experiments on rainwater and sweat were performed for Comparative Examples 1 to 4 and Examples of the present invention.

The above five compositions were applied to experimental hairs, and left to dry for 20 minutes, and then shaken 50 times in purified water and artificial sweat solution, and soaked for 30 minutes.

Then, the solution was removed from the solution and pressed with a white cloth made of cotton.

As a result, in Comparative Example 1, the coating film was peeled off from the purified water and the artificial sweat solution, and it was confirmed that the coating film was partially separated after 30 minutes.In the case of Comparative Example 2, the coating film was maintained with a thin coating film. Although it could not be confirmed correctly, both solutions were found to be turbid.

On the other hand, Comparative Examples 3, 4 and Examples of the present invention was confirmed that the solution was kept clear, the coating film is also maintained as it is.

Experiment for confirming the stain by pressing with a white cloth was smeared as a powder in the case of Comparative Example 1, in the case of Comparative Examples 2, 3, the dye was lightly buried on the white cloth, and Comparative Example 4 and using a silicone film-forming agent In the case of the embodiment of the present invention it was confirmed that the white cloth is still kept clean.

As a result, Comparative Example 4 and the Example of the present invention confirmed that the result of forming a water-resistant coating on the hair can maintain the dyeing effect for a long time.

As a result of the experiment, it can be seen that the hair dye cosmetic composition of the present invention is much superior to the comparative examples in terms of overall satisfaction such as hair dyeing and water resistance.

The present invention described above is merely exemplary of the present invention, which is used only for the purpose of illustrating the present invention, and is not used to limit the scope of the present invention described in the meaning or claims.

Therefore, those skilled in the art will appreciate that various modifications and equivalent embodiments are possible without departing from the scope of the present invention.

Accordingly, the true scope of the present invention should be determined by the technical idea of the appended claims.

Claims (5)

10 to 50% by weight of silicone oil, 2 to 20% by weight of silicone film forming agent, 3.0 to 20.0% by weight of wax, 0.1 to 5% by weight of hydroxyapatite, 0.05 to 1.5% by weight of calcined silica, 1.0 to 30.0% by weight of pigment A solid hair dye cosmetic composition comprising 5.0 to 40.0% by weight of a pigment and 0.2 to 10.0% by weight of an oil thickener. The method of claim 1, wherein the silicone oil is at least one selected from the group consisting of dimethicone, cyclopentasiloxane, methyltrimethicone, cyclohexasiloxane, caprylylmethicone, phenyltrimethicone, diphenyl dimethicone. A solid hair dye cosmetic composition characterized by the above. The solid hair dye cosmetic composition according to claim 1, wherein the silicone-based coating agent is at least one of trimethylsiloxy silicate and bishydroxylauryl dimethicone / IP diaicopolymer. The solid hair dye cosmetic composition according to claim 1, wherein the calcined silica is at least one of silica dimethyl silylate and silica silylate. A first step of grinding 1.0 to 30.0% by weight of pigment, 0.1 to 5% by weight of hydroxyapatite, and 5.0 to 40.0% by weight of extender pigment to a Henschel mixer, and then dispersing and mixing;
0.05 to 1.5% by weight of the mixed pulverized pigment, hydroxyapatite, extender pigment mixture and calcined silica of the first step, 3.0 to 20.0% by weight of wax, 10 to 50% by weight of silicone oil, and 2 to 20% by weight of silicone film-forming agent And a second step of dispersing 0.2-10.0 wt% of the oil phase thickener into a dissolution tank heated and dissolved at 70-80 ° C., and dispersing and mixing the solid hair dye cosmetic composition.