JPS649206A - Polymerization of olefin - Google Patents
Polymerization of olefinInfo
- Publication number
- JPS649206A JPS649206A JP62095445A JP9544587A JPS649206A JP S649206 A JPS649206 A JP S649206A JP 62095445 A JP62095445 A JP 62095445A JP 9544587 A JP9544587 A JP 9544587A JP S649206 A JPS649206 A JP S649206A
- Authority
- JP
- Japan
- Prior art keywords
- olefin
- transition metal
- compound
- group
- aluminoxane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
PURPOSE:To obtain a polymer having a high mol.wt. with excellent polymerization activity, by (co)polymerizing an olefin in the presence of a catalyst prepared from a transition metal compound, aluminoxane and an organoaluminum compound. CONSTITUTION:An olefin is polymerized or copolymerized in the presence of a catalyst prepared from a transition metal compound (A) of a metal of Group IV B of the periodic table, aluminoxane (B) and a compound (C) of formula I or II. In the formulae, R1, R2 and R3 are each a hydrocarbon group; R4 is a hydrocarbon group, alkoxy, aryl or oxy; 0<m<3; and 0<n<3. The Group IV B transition metal in the catalyst component (A) is selected from Ti, Zr and Hf, among them Ti and Zr are preferred, with Zr especially preferred. The present polymerization method is particularly effective in the manufacture of an ethylene polymer and a copolymer of ethylene with an alpha-olefin.
Priority Applications (11)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62095445A JPH0794498B2 (en) | 1987-04-20 | 1987-04-20 | Olefin Polymerization Method |
CN 88100256 CN1031579C (en) | 1987-04-20 | 1988-01-25 | Catalyst for polymerization of alpha-olefine and polymerization process |
US07/290,110 US5122491A (en) | 1987-04-20 | 1988-04-19 | Catalyst for polymerizing an olefin and process for polymerizing an olefin |
PCT/JP1988/000384 WO1988008432A1 (en) | 1987-04-20 | 1988-04-19 | Olefin polymerization catalyst and process for polymerizing olefin |
EP88903383A EP0314797B1 (en) | 1987-04-20 | 1988-04-19 | Olefin polymerization catalyst and process for polymerizing olefin |
DE3855955T DE3855955T2 (en) | 1987-04-20 | 1988-04-19 | OLEFIN POLYMERIZATION CATALYST AND METHOD FOR POLYMERIZING OLEFIN |
AT88903383T ATE154943T1 (en) | 1987-04-20 | 1988-04-19 | OLEFIN POLYMERIZATION CATALYST AND METHOD FOR POLYMERIZING OLEFIN |
KR1019880701697A KR920002769B1 (en) | 1987-04-20 | 1988-04-19 | Olefin polymerization catalyst and process for polymerizing olefin |
CN88103215A CN1020735C (en) | 1987-04-20 | 1988-04-20 | Catalyst for olefin polymerization and process for olefin polymerization |
CA000586300A CA1325629C (en) | 1987-04-20 | 1988-12-19 | Catalyst for polmerizing an olefin and process for polymerizing an olefin by using such catalyst |
US07/860,014 US5206199A (en) | 1987-04-20 | 1992-03-30 | Catalyst for polymerizing an olefin and process for polymerizing an olefin |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62095445A JPH0794498B2 (en) | 1987-04-20 | 1987-04-20 | Olefin Polymerization Method |
CA000586300A CA1325629C (en) | 1987-04-20 | 1988-12-19 | Catalyst for polmerizing an olefin and process for polymerizing an olefin by using such catalyst |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS649206A true JPS649206A (en) | 1989-01-12 |
JPH0794498B2 JPH0794498B2 (en) | 1995-10-11 |
Family
ID=25672314
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP62095445A Expired - Lifetime JPH0794498B2 (en) | 1987-04-20 | 1987-04-20 | Olefin Polymerization Method |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0794498B2 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6445406A (en) * | 1987-08-14 | 1989-02-17 | Mitsubishi Petrochemical Co | Polymerization of ethylene |
JPH08301916A (en) * | 1995-04-28 | 1996-11-19 | Idemitsu Petrochem Co Ltd | Method for storing homogeneous polymerization catalyst |
US5704130A (en) * | 1992-01-22 | 1998-01-06 | Raytec Ag | Measuring instrument |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57135805A (en) * | 1981-02-16 | 1982-08-21 | Asahi Chem Ind Co Ltd | Catalyst for olefin polymerization |
JPS60260602A (en) * | 1984-06-07 | 1985-12-23 | Idemitsu Kosan Co Ltd | Production of polyolefin |
JPS63501369A (en) * | 1985-11-15 | 1988-05-26 | エクソン・ケミカル・パテンツ・インク | supported polymerization catalyst |
-
1987
- 1987-04-20 JP JP62095445A patent/JPH0794498B2/en not_active Expired - Lifetime
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57135805A (en) * | 1981-02-16 | 1982-08-21 | Asahi Chem Ind Co Ltd | Catalyst for olefin polymerization |
JPS60260602A (en) * | 1984-06-07 | 1985-12-23 | Idemitsu Kosan Co Ltd | Production of polyolefin |
JPS63501369A (en) * | 1985-11-15 | 1988-05-26 | エクソン・ケミカル・パテンツ・インク | supported polymerization catalyst |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6445406A (en) * | 1987-08-14 | 1989-02-17 | Mitsubishi Petrochemical Co | Polymerization of ethylene |
US5704130A (en) * | 1992-01-22 | 1998-01-06 | Raytec Ag | Measuring instrument |
JPH08301916A (en) * | 1995-04-28 | 1996-11-19 | Idemitsu Petrochem Co Ltd | Method for storing homogeneous polymerization catalyst |
Also Published As
Publication number | Publication date |
---|---|
JPH0794498B2 (en) | 1995-10-11 |
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