JPS56133252A - Production of cyanoethylaminobenzene derivative - Google Patents
Production of cyanoethylaminobenzene derivativeInfo
- Publication number
- JPS56133252A JPS56133252A JP3671980A JP3671980A JPS56133252A JP S56133252 A JPS56133252 A JP S56133252A JP 3671980 A JP3671980 A JP 3671980A JP 3671980 A JP3671980 A JP 3671980A JP S56133252 A JPS56133252 A JP S56133252A
- Authority
- JP
- Japan
- Prior art keywords
- water
- reaction
- acrylonitrile
- transition metal
- produce
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
PURPOSE: The reaction between an aromatic amine and acrylonitrile is conducted in the presence of a transition metal catalyst and water to produce the titled compound used as a synthetic intermediate of dyes in high purity and high yield.
CONSTITUTION: The reaction between an aromatic amine and acrylonitrile is carried out in the presence of a transition metal catalyst such as ferrous chloride or copper acetate and water to produce the titled compound almost quantitatively. The amount of the added water is more than 0.1wt% based on the amine, preferably more than 1wt%. When necessary, a phase transfer catalyst or organic solvent is added. The addition of water promotes the reaction and prohibits the formation of biscyanoethylated product, resulting in selective formation of monocyanoethylated product.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3671980A JPS56133252A (en) | 1980-03-21 | 1980-03-21 | Production of cyanoethylaminobenzene derivative |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3671980A JPS56133252A (en) | 1980-03-21 | 1980-03-21 | Production of cyanoethylaminobenzene derivative |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS56133252A true JPS56133252A (en) | 1981-10-19 |
JPS616064B2 JPS616064B2 (en) | 1986-02-24 |
Family
ID=12477552
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP3671980A Granted JPS56133252A (en) | 1980-03-21 | 1980-03-21 | Production of cyanoethylaminobenzene derivative |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS56133252A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102241606A (en) * | 2011-05-10 | 2011-11-16 | 浙江闰土股份有限公司 | Clean production method of N-cyanoethylaniline |
CN103539700A (en) * | 2013-10-25 | 2014-01-29 | 浙江迪邦化工有限公司 | Preparation method of N-cyanoethylaniline |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5295895A (en) * | 1976-02-05 | 1977-08-11 | Johnson & Johnson | Throwaway electrode |
JPS5477489A (en) * | 1977-11-07 | 1979-06-20 | Hymes Alan C | Medical electrode |
-
1980
- 1980-03-21 JP JP3671980A patent/JPS56133252A/en active Granted
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5295895A (en) * | 1976-02-05 | 1977-08-11 | Johnson & Johnson | Throwaway electrode |
JPS5477489A (en) * | 1977-11-07 | 1979-06-20 | Hymes Alan C | Medical electrode |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102241606A (en) * | 2011-05-10 | 2011-11-16 | 浙江闰土股份有限公司 | Clean production method of N-cyanoethylaniline |
CN103539700A (en) * | 2013-10-25 | 2014-01-29 | 浙江迪邦化工有限公司 | Preparation method of N-cyanoethylaniline |
Also Published As
Publication number | Publication date |
---|---|
JPS616064B2 (en) | 1986-02-24 |
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