JPH067996B2 - Laser overlay welding method - Google Patents
Laser overlay welding methodInfo
- Publication number
- JPH067996B2 JPH067996B2 JP60227815A JP22781585A JPH067996B2 JP H067996 B2 JPH067996 B2 JP H067996B2 JP 60227815 A JP60227815 A JP 60227815A JP 22781585 A JP22781585 A JP 22781585A JP H067996 B2 JPH067996 B2 JP H067996B2
- Authority
- JP
- Japan
- Prior art keywords
- metal
- overlay
- laser beam
- metal foil
- workpiece
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/20—Bonding
- B23K26/32—Bonding taking account of the properties of the material involved
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/34—Laser welding for purposes other than joining
- B23K26/342—Build-up welding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2103/00—Materials to be soldered, welded or cut
- B23K2103/50—Inorganic material, e.g. metals, not provided for in B23K2103/02 – B23K2103/26
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Engineering & Computer Science (AREA)
- Plasma & Fusion (AREA)
- Mechanical Engineering (AREA)
- Laser Beam Processing (AREA)
Description
【発明の詳細な説明】 [産業上の利用分野] 本発明は、レーザビームにより肉盛用金属を溶融させて
被加工物の表面に溶着金属を形成するレーザ肉盛溶接方
法に関するものである。Description: TECHNICAL FIELD The present invention relates to a laser overlay welding method for forming a weld metal on the surface of a workpiece by melting a overlay metal with a laser beam.
[従来の技術] 機械部品等の金属製被加工物の耐摩耗性を高めたり、耐
食性を持たせたりする目的で、被加工物の表面に耐摩耗
性合金や耐食性合金等の異種の金属を肉盛溶接すること
が行われている。肉盛用金属を溶融させる熱源としてレ
ーザビームが用いられる場合には、被加工物の上方にレ
ーザ加工ヘッドが配置され、該レーザ加工ヘッドと被加
工物との間に集光されたレーザビームにより肉盛用金属
が溶融される。[Prior Art] In order to improve the wear resistance of metal workpieces such as machine parts and to provide them with corrosion resistance, dissimilar metals such as wear-resistant alloys and corrosion-resistant alloys are applied to the surface of the workpieces. Overlay welding is performed. When a laser beam is used as a heat source for melting the overlay metal, a laser processing head is arranged above the work piece, and a laser beam focused between the laser processing head and the work piece is used. The overlay metal is melted.
被加工物に耐摩耗性や耐食性を付与するために用いられ
る肉盛用金属としては、コバルト基合金、ニッケル基合
金、パーライト系鋼、マルテンサイト系鋼、クロム鋼、
マンガン・オーステナイト系鋼、16Mn−16Crオ
ーステナイト系鋼、高クロム鉄系合金、タングステン炭
化物合金等多種類のものが実用化されている。As the overlaying metal used to impart wear resistance and corrosion resistance to the workpiece, cobalt-based alloys, nickel-based alloys, pearlite-based steels, martensitic steels, chrome steels,
Many types of manganese / austenitic steels, 16Mn-16Cr austenitic steels, high chromium iron alloys, tungsten carbide alloys and the like have been put to practical use.
これらの肉盛用金属は一般に高硬質で可撓性を有してい
ないため、細径のワイヤや薄板または箔の形に形成して
リールに巻き取ることが困難である。特にコバルト基合
金のうち、クロム30%、タングステン4〜8%、炭素
1%、鉄2%等を含むステライト、タングステン炭化物
合金、クロム炭化物等は耐摩耗性に優れているが、金属
組織の硬さが大きく、柔軟性の無いため薄板や細径のワ
イヤの形に形成することが困難である。そのためこれら
の高硬質の肉盛用金属は30cm乃至1m程度の溶接棒
の形に形成せざるを得なかった。Since these build-up metals are generally highly rigid and not flexible, it is difficult to form them in the form of thin wires, thin plates or foils and wind them up on reels. In particular, among cobalt-based alloys, stellite containing 30% chromium, 4-8% tungsten, 1% carbon, 2% iron, etc., tungsten carbide alloys, chromium carbides, etc. have excellent wear resistance, but the hardness of the metal structure is hard. Since it is large and has no flexibility, it is difficult to form it into a thin plate or a wire having a small diameter. Therefore, these high-hardness build-up metals had to be formed in the shape of a welding rod of about 30 cm to 1 m.
[発明が解決しようとする問題点] 上記のように、従来の肉盛溶接方法では高硬質の肉盛用
金属を用いる場合に該肉盛用金属を溶接棒の形に形成せ
ざるを得なかったため、、肉盛用金属を被加工物に自動
送給することができなかった。そのため溶接の際には肉
盛用金属を手動にて被加工物に供給する必要があり、溶
接速度が著しく遅くなるという問題があった。また肉盛
用金属を手動で供給すると肉盛溶着金属の厚さまで均一
にすることが困難になるという問題もあった。[Problems to be Solved by the Invention] As described above, in the conventional overlay welding method, when a high-hard overlay metal is used, the overlay metal must be formed in the shape of a welding rod. Therefore, the overlay metal cannot be automatically fed to the workpiece. Therefore, during welding, it is necessary to manually supply the overlay metal to the workpiece, and there is a problem that the welding speed is significantly reduced. In addition, there is a problem that it is difficult to make the thickness of the weld metal deposited evenly when the metal for overlay is manually supplied.
本発明の目的は、高硬質の肉盛用金属を用いる場合でも
該肉盛用金属の被加工物に自動送給することができるよ
うにして溶接速度の向上を図るとともに、溶着金属属の
厚みを均一にすることができるようにしたレーザ肉盛溶
接方法を提案することにある。An object of the present invention is to improve the welding speed by enabling automatic feeding to the work piece of the overlay metal even when using a high-hard overlay metal, and the thickness of the deposited metal group. The object is to propose a laser overlay welding method that can achieve uniform welding.
[問題点を解決するための手段] 本発明は、その実施例を示す第1図に見られるように、
肉盛用金属2を溶融させて被加工物1の表面に溶着金属
3を形成する肉盛溶接方法において、肉盛用金属2とし
て非晶質の連続帯状金属箔を用い、この連続帯状金属箔
を非加工物1に連続的または断続的に自動送給しつつ該
連続帯状金属箔をレーザビーム4により溶融させて溶着
金属3を形成する方法である。[Means for Solving Problems] The present invention, as seen in FIG.
In the overlay welding method of melting the overlay metal 2 to form the deposited metal 3 on the surface of the workpiece 1, an amorphous continuous strip metal foil is used as the overlay metal 2, and the continuous strip metal foil is used. Is continuously and intermittently automatically fed to the non-working product 1, and the continuous strip-shaped metal foil is melted by the laser beam 4 to form the deposited metal 3.
[発明の作用] 従来の肉盛溶接方法で用いられていた肉盛用金属は結晶
構造を有していたため、高硬質の肉盛用金属を用いる場
合には肉盛用金属を細径のワイヤや薄板または箔の形に
形成することができず、肉盛用金属の自動送給ができな
かったが、本発明のように肉盛用金属を非晶質にする
と、可撓性を有する連続帯状金属箔の形で肉盛用金属を
得ることができるため、これを送給機構を通して被加工
物に自動送給することが可能になる。そのため溶接速度
を向上させることができ、また溶着金属層の厚みをほぼ
均一にすることができる。[Advantageous Effects of the Invention] Since the overlay metal used in the conventional overlay welding method has a crystal structure, when the hard overlay metal is used, the overlay metal is a thin wire. It could not be formed into a thin plate or foil, and automatic feeding of the overlay metal was not possible. However, when the overlay metal is made amorphous like the present invention, it has flexibility and continuity. Since the build-up metal can be obtained in the form of a strip-shaped metal foil, it becomes possible to automatically feed this to the workpiece through the feeding mechanism. Therefore, the welding speed can be improved and the thickness of the deposited metal layer can be made substantially uniform.
[実施例] 以下添附図面を参照して本発明の実施例を説明する。Embodiments Embodiments of the present invention will be described below with reference to the accompanying drawings.
実施例では、ニッケル基合金及びコバルト基合金の非晶
質連続帯状金属箔を肉盛用金属として用いた。この非晶
質合金の金属箔は、肉盛溶接用金属の素材を溶融させて
急冷する通常の方法により得ることができる。現状で得
られる非晶質連続帯状金属箔は、厚み0.025〜0.06mm程
度、幅10〜100mm程度であり、従来の結晶構造の肉盛用
金属に比べて可撓性が極めて高い上に曲げ強度も大であ
る。従って非晶質連続帯状金属箔はリールに巻取ること
が可能であり、送給機構を通して被加工物に自動送給す
ることが可能である。In the examples, an amorphous continuous band-shaped metal foil of nickel-based alloy and cobalt-based alloy was used as the overlay metal. The metal foil of the amorphous alloy can be obtained by a usual method of melting the material for the overlay welding metal and quenching it. The amorphous continuous strip metal foil obtained at present has a thickness of about 0.025 to 0.06 mm and a width of about 10 to 100 mm, and has extremely high flexibility and bending strength as compared with the conventional overlay metal having a crystal structure. Is also large. Therefore, the amorphous continuous strip-shaped metal foil can be wound on a reel and can be automatically fed to the workpiece through the feeding mechanism.
第1図において1は被加工物、2は非晶質の連続状金属
箔からなる肉盛用金属である。肉盛用金属箔2はリール
5に巻回されていて、電動機6により駆動される送給ロ
ーラ7と加圧ローラ8とからなる送給機構9と、ガイド
部材10内とを通して被加工物1の表面に自動送給され
ている。被加工物1の上方にレーザ加工ヘッド11が配
置され、被加工物の表面に供給された肉盛用金属2に、
加工ヘッド11から集光されたレーザビーム4が照射さ
れて肉盛用金属及び被加工物が溶融される。12はこの
レーザビームの照射により形成された溶融池を示してお
り、肉盛用金属2はガイド部材10によりこの溶融池1
2に向けて案内されてその先端が溶融池内に挿入され
る。被加工物1とレーザビーム4とを相対的に移動させ
ることにより溶融池12を移動させ、溶融した肉盛用金
属を冷却凝固させて肉盛溶着金属3を形成する。In FIG. 1, reference numeral 1 is a work piece, and 2 is a build-up metal composed of an amorphous continuous metal foil. The overlaying metal foil 2 is wound around a reel 5 and passes through a feeding mechanism 9 including a feeding roller 7 driven by an electric motor 6 and a pressure roller 8 and a guide member 10 to be processed 1 Is automatically fed to the surface of. A laser processing head 11 is arranged above the work piece 1, and the metal 2 for build-up is supplied to the surface of the work piece.
The laser beam 4 focused from the processing head 11 is irradiated to melt the overlay metal and the workpiece. Reference numeral 12 denotes a molten pool formed by the irradiation of the laser beam, and the overlaying metal 2 is guided by the guide member 10 to the molten pool 1
It is guided toward 2 and its tip is inserted into the molten pool. By moving the workpiece 1 and the laser beam 4 relatively, the molten pool 12 is moved, and the molten overlay metal is cooled and solidified to form the overlay weld metal 3.
電動機6は肉盛用金属の供給速度を適当な範囲に保つよ
うに図示しない制御装置により速度制御され、この電動
機により肉盛用金属2が連続的または断続的に自動送給
される。The speed of the electric motor 6 is controlled by a control device (not shown) so as to keep the supply speed of the overlay metal in an appropriate range, and the overlay metal 2 is automatically fed continuously or intermittently by this motor.
第2図は、本発明の方法で用いるのに好適な供給機構の
一例を示したもので、この例では送給ローラ7がほぼ鼓
状に形成されてその胴部の外周に浅いV字状の溝7aが
形成されている。また加圧ローラ8は送給ローラ7の胴
部外周のV字状溝7aと相補的なV字状の凸部8bを胴
部外周に有するほぼ太鼓状に形成され、非晶質連続帯状
金属箔からなる肉盛用金属2がこれらのローラ7,8の
間を通過する際に塑性変形されて浅いV字状の溝を有す
る形状に成形されるようになっている。なおこの場合送
給ローラ7の形状と加圧ローラ8の形状とを入替えても
良いのはもちろんである。FIG. 2 shows an example of a supply mechanism suitable for use in the method of the present invention. In this example, the feed roller 7 is formed in a substantially drum shape and has a shallow V-shape on the outer periphery of its body. Groove 7a is formed. The pressure roller 8 is formed in a substantially drum shape having a V-shaped convex portion 8b complementary to the V-shaped groove 7a on the outer periphery of the body of the feeding roller 7 on the outer periphery of the body. The overlaying metal 2 made of foil is plastically deformed when passing between the rollers 7 and 8 to be formed into a shape having a shallow V-shaped groove. In this case, of course, the shape of the feeding roller 7 and the shape of the pressure roller 8 may be interchanged.
非晶質連続帯状金属箔は非常に薄いため、変形し易く、
しかもその変形は一定ではないため、肉盛溶着金属の厚
さが変動するおそれがある。そこで第2図に示すような
送給機構を用いて帯状金属箔を強制的に一定の断面形状
に塑性変形させると、被加工物の表面に供給される金属
箔の形状を一定にして肉盛溶着金属の厚さが変動するお
それをなくすことができる。Since the amorphous continuous strip metal foil is very thin, it easily deforms,
Moreover, since the deformation is not constant, there is a possibility that the thickness of the overlay deposition metal may vary. Therefore, when the strip-shaped metal foil is forcibly plastically deformed into a constant cross-sectional shape by using a feeding mechanism as shown in FIG. 2, the shape of the metal foil supplied to the surface of the workpiece is kept constant and the overlay is built up. It is possible to eliminate the possibility that the thickness of the deposited metal fluctuates.
上記の実施例では、送給ローラと加圧ローラとの間を通
して帯状金属箔からなる肉盛用金属を被加工物に自動送
給するようにしたが、他の方法で自動送給するようにし
てもよい。例えば、第3図に示すように、モータ6によ
り回転駆動される回転円筒体13に連続帯状金属箔から
なる肉盛用金属2を螺旋状に巻きつけて、円筒体13を
回転させつつ肉盛用金属2を被加工物1に自動送給する
ようにしても高能率で均一な肉盛溶接を行わせることが
できる。In the above embodiment, the build-up metal consisting of the strip-shaped metal foil is automatically fed to the workpiece through the space between the feeding roller and the pressure roller, but it may be automatically fed by another method. May be. For example, as shown in FIG. 3, a build-up metal 2 made of a continuous strip of metal foil is spirally wound around a rotary cylinder 13 that is driven to rotate by a motor 6, and the build-up is performed while rotating the cylinder 13. Even if the working metal 2 is automatically fed to the workpiece 1, it is possible to perform the overlay welding with high efficiency and evenly.
本発明のように肉盛用金属を加熱溶融させる熱源として
レーザビームを用いると、微細な加工を容易に行うこと
がでいるというレーザビーム溶接を利点を活かして、し
かも肉盛溶接を能率良く行うことができる。When a laser beam is used as a heat source for heating and melting the overlay metal as in the present invention, the advantage of laser beam welding that fine processing can be easily performed, and overlay welding is performed efficiently be able to.
またレーザビームは高出力高エネルギ密度の熱源である
ため、肉盛溶接の熱源としてレーザビームを用いると、
溶融を急速に行わせて肉盛金属と母材とのぬれ性を良好
にすることができ、局所肉盛が可能となる。更にレーザ
ビームは光学的な手段等により時間的空間的な制御を正
確に行うことができるため、レーザビームを例えば連続
帯状金属箔からなる肉盛金属2の幅方向にオシレートさ
せることにより、肉盛用金属全体を均一に加熱すること
ができる。そのためレーザビームを用いると肉盛金属の
母材による希釈を最小限にして且つ均一な溶融を得るこ
とができ、肉盛部の性状を良好にすることができる。Also, since the laser beam is a high-output, high-energy-density heat source, if a laser beam is used as a heat source for overlay welding,
The melting can be performed rapidly to improve the wettability between the overlay metal and the base material, and local overlaying is possible. Further, since the laser beam can be accurately controlled in terms of time and space by an optical means or the like, the laser beam is oscillated in the width direction of the overlay metal 2 made of, for example, a continuous strip metal foil, so The whole metal can be heated uniformly. Therefore, when a laser beam is used, dilution of the overlay metal with the base material can be minimized and uniform melting can be obtained, and the properties of the overlay portion can be improved.
またレーザビームを熱源として用いた場合には母材への
入熱が少ないため、母材の歪みや変形を少なくすること
ができる。Further, when a laser beam is used as a heat source, heat input to the base material is small, so that distortion and deformation of the base material can be reduced.
レーザビームをオシレートさせる方法は種々知られてい
るが、第4図にその一例を示す。第4図に示した例で
は、レーザ発振器20から発生させたレーザビーム4を
集光ミラー21とオシレート用平面鏡22及び23とを
経て被加工物1に集光させ、オシレート用平面鏡22及
び23をオッシレートさせてレーザビーム4を肉盛用金
属2の幅方向にオシレートさせる。There are various known methods for oscillating a laser beam, one example of which is shown in FIG. In the example shown in FIG. 4, the laser beam 4 generated from the laser oscillator 20 is focused on the workpiece 1 via the focusing mirror 21 and the oscillating plane mirrors 22 and 23, and the oscillating plane mirrors 22 and 23 are The laser beam 4 is oscillated to oscillate in the width direction of the overlay metal 2.
レーザビームとしては連続的に発生するものを用いても
よく、またパルス状のレーザビームを用いてもよい。As the laser beam, one that is continuously generated may be used, or a pulsed laser beam may be used.
上記の各実施例において、帯状金属箔からなる肉盛用金
属2と被加工物との間にアークを継続的に発生させない
程度の低電圧を印加することにより肉盛用金属2に通電
して、該肉盛用金属を抵抗発熱により予備加熱すること
もできる。このように予備加熱を行うと被加工物1の表
面の溶込深さを大きくしなくても被加工物の表面に形成
される肉盛溶着金属の厚さを厚くすることができる。In each of the above-mentioned examples, the overlaying metal 2 is energized by applying a low voltage between the overlaying metal 2 made of a strip-shaped metal foil and the workpiece so as not to continuously generate an arc. Alternatively, the overlay metal can be preheated by resistance heating. If the preheating is performed in this manner, the thickness of the overlay welding metal formed on the surface of the workpiece can be increased without increasing the penetration depth of the surface of the workpiece 1.
[発明の効果] 以上のように、本発明の肉盛溶接方法によれば、肉盛用
金属を非晶質の連続帯状金属箔の形にして用いるので、
結晶構造を有する状態で硬度が高く、溶接棒の形をとら
ざるを得ないために自動送給を行うことが不可能である
場合でも、肉盛用金属を自動的に送給することができ、
溶着金属の厚さがほぼ均一な肉盛溶接を能率良く行うこ
とができる利点がある。[Advantages of the Invention] As described above, according to the overlay welding method of the present invention, the overlay metal is used in the form of an amorphous continuous strip-shaped metal foil.
Even if automatic feeding cannot be performed because the hardness is high in the state of having a crystalline structure and the shape of the welding rod is unavoidable, the overlay metal can be automatically fed. ,
There is an advantage that the overlay welding in which the thickness of the deposited metal is substantially uniform can be efficiently performed.
第1図は非晶質連続帯状金属箔を肉盛用金属として本発
明のレーザビーム肉盛溶接方法を行った実施例を示す説
明図、第2図は本発明の方法で用いるのに好適な肉盛用
金属の送給機構の一例を示した説明図、第3図は本発明
の他の実施例を示す説明図、第4図は溶接の際にレーザ
ビームをオシレートする方法を説明する説明図である。 1…被加工物、2…非晶質連続帯状金属箔からなる肉盛
用金属、3…肉盛溶着金属、4…レーザビーム。FIG. 1 is an explanatory view showing an embodiment in which the laser beam overlay welding method of the present invention is performed using an amorphous continuous strip metal foil as a overlay metal, and FIG. 2 is suitable for use in the method of the present invention. FIG. 3 is an explanatory view showing an example of a metal feeding mechanism for overlay welding, FIG. 3 is an explanatory view showing another embodiment of the present invention, and FIG. 4 is an explanation explaining a method of oscillating a laser beam during welding. It is a figure. DESCRIPTION OF SYMBOLS 1 ... Workpiece, 2 ... Overlay metal consisting of amorphous continuous strip metal foil, 3 ... Overlay weld metal, 4 ... Laser beam.
Claims (3)
溶着金属を形成する肉盛溶接方法において、 前記肉盛用金属として非晶質の連続帯状金属箔を用い、 前記連続帯状金属箔を前記被加工物に連続的または断続
的に自動送給しつつ該連続帯状金属箔をレーザビームに
より溶融させて溶着金属を形成するレーザ肉盛溶接方
法。1. A build-up welding method for forming a deposited metal on a surface of a workpiece by melting a build-up metal, wherein an amorphous continuous strip-shaped metal foil is used as the build-up metal. A laser overlay welding method of forming a weld metal by melting a continuous strip-shaped metal foil with a laser beam while automatically or continuously feeding the metal foil to the workpiece.
非晶質合金からなる特許請求の範囲第1項に記載のレー
ザ肉盛溶接方法。2. The laser overlay welding method according to claim 1, wherein the amorphous continuous strip metal foil is made of a cobalt-based amorphous alloy.
非晶質合金からなる特許請求の範囲第1項に記載のレー
ザ肉盛溶接方法。3. The laser overlay welding method according to claim 1, wherein the amorphous continuous strip metal foil is made of a nickel-based amorphous alloy.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP60227815A JPH067996B2 (en) | 1985-10-15 | 1985-10-15 | Laser overlay welding method |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP60227815A JPH067996B2 (en) | 1985-10-15 | 1985-10-15 | Laser overlay welding method |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6289591A JPS6289591A (en) | 1987-04-24 |
JPH067996B2 true JPH067996B2 (en) | 1994-02-02 |
Family
ID=16866809
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP60227815A Expired - Lifetime JPH067996B2 (en) | 1985-10-15 | 1985-10-15 | Laser overlay welding method |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH067996B2 (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5408065A (en) * | 1992-10-09 | 1995-04-18 | General Motors Corporation | Welding apparatus and process |
DE102010024233A1 (en) * | 2010-06-18 | 2011-12-22 | Forschungszentrum Jülich GmbH | Supplying a filler material during laser beam build-up welding, comprises placing the filler material either in the form of a foil or a filler material bound to the foil, in focused laser beam |
JP2015202594A (en) * | 2014-04-11 | 2015-11-16 | セイコーエプソン株式会社 | Molding device and molding method |
CN114918564B (en) * | 2022-04-18 | 2023-05-12 | 哈尔滨焊接研究院有限公司 | Build-up welding repair method for TC4 titanium alloy shell |
-
1985
- 1985-10-15 JP JP60227815A patent/JPH067996B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JPS6289591A (en) | 1987-04-24 |
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