JPH05171363A - Stainless steel for expansion antenna - Google Patents
Stainless steel for expansion antennaInfo
- Publication number
- JPH05171363A JPH05171363A JP33892891A JP33892891A JPH05171363A JP H05171363 A JPH05171363 A JP H05171363A JP 33892891 A JP33892891 A JP 33892891A JP 33892891 A JP33892891 A JP 33892891A JP H05171363 A JPH05171363 A JP H05171363A
- Authority
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- Prior art keywords
- corrosion resistance
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- antenna
- stainless steel
- content
- Prior art date
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Abstract
Description
【0001】[0001]
【産業上の利用分野】この発明は、自動車などにおいて
用いられる伸縮アンテナの素材として好適に利用される
伸縮アンテナ用ステンレス鋼に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to stainless steel for telescopic antennas, which is preferably used as a material for telescopic antennas used in automobiles and the like.
【0002】[0002]
【従来の技術】従来、自動車に用いられる伸縮アンテナ
の素材としては、例えば、オーステナイト系ステンレス
鋼である表1のNo.1欄に示す化学成分組成のSUS
304が多く使用されている。2. Description of the Related Art Conventionally, as a material for a telescopic antenna used in an automobile, for example, austenitic stainless steel No. 1 in Table 1 is used. SUS with the chemical composition shown in column 1
304 is often used.
【0003】このSUS304は、冷間引抜き加工を受
けることにより加工硬化を生じて強靭性が付与されると
共に、オーステナイト系ステンレス鋼の中では比較的安
価な材料であるため、伸縮アンテナの素材として広く採
用されている。[0003] This SUS304 is work-hardened by being subjected to cold drawing to impart toughness, and is a relatively inexpensive material among austenitic stainless steels, so that it is widely used as a material for elastic antennas. Has been adopted.
【0004】また、上記SUS304の耐食性を向上さ
せた表1のNo.2欄に示す化学成分組成のSUS31
5SNも一部で使用されている。Further, No. 1 in Table 1 having improved corrosion resistance of the above-mentioned SUS304. SUS31 with chemical composition shown in column 2
5SN is also used in part.
【0005】[0005]
【発明が解決しようとする課題】しかしながら、上記し
た従来の伸縮アンテナ用オーステナイト系ステンレス鋼
では、素材そのものや溶接部分が、伸管加工等の冷間加
工を受けた場合、あるいは表面研磨加工等を受けた場合
などにおいて、加工誘起マルテンサイトが発生し、耐食
性が低下することとなるため、伸縮アンテナとして使用
している間に湿潤環境や塩害などによって錆が発生する
ことがあり、外観が損われたり、伸縮が円滑でなくなっ
たりすることもありうるという問題点があり、このよう
な問題点を解決することが課題となっていた。However, in the above-mentioned conventional austenitic stainless steel for a telescopic antenna, when the material itself or the welded portion is subjected to cold working such as pipe drawing, or surface polishing is performed. When it is received, processing-induced martensite occurs and corrosion resistance decreases, so rust may occur due to a wet environment or salt damage while using it as a stretchable antenna, and the appearance is damaged. However, there is a problem that expansion and contraction may not be smooth, and it has been a problem to solve such a problem.
【0006】[0006]
【発明の目的】この発明は、上記した従来の課題にかん
がみてなされたものであって、伸縮アンテナを製造する
際のロール成形性や溶接性などの加工性に優れていると
共に、素材そのものや溶接部分において錆が発生しにく
い耐食性に優れた伸縮アンテナ用ステンレス鋼を提供す
ることを目的としている。SUMMARY OF THE INVENTION The present invention has been made in view of the above-mentioned conventional problems, and is excellent in workability such as roll formability and weldability when manufacturing a telescopic antenna, and the material itself and It is an object of the present invention to provide stainless steel for stretchable antennas, which is excellent in corrosion resistance in which rust is unlikely to occur in the welded portion.
【0007】[0007]
【課題を解決するための手段】この発明に係わる伸縮ア
ンテナ用ステンレス鋼は、重量%で、C:0.05%以
下、Si:1.0%以下、Mn:2.0%以下、P:
0.05%以下、S:0.001%以下、Ni:9〜1
4%、Cr:22〜24%、Mo:1〜2%、Cu:
0.1〜0.2%、N:0.1〜0.2%、残部Feお
よび不純物よりなる構成としたことを特徴としており、
このような伸縮アンテナ用ステンレス鋼に係わる発明の
構成をもって前述した従来の課題を解決するための手段
としている。The stainless steel for a telescopic antenna according to the present invention is, by weight%, C: 0.05% or less, Si: 1.0% or less, Mn: 2.0% or less, P:
0.05% or less, S: 0.001% or less, Ni: 9 to 1
4%, Cr: 22-24%, Mo: 1-2%, Cu:
0.1 to 0.2%, N: 0.1 to 0.2%, the balance Fe and impurities,
The structure of the invention relating to the stainless steel for a telescopic antenna is used as a means for solving the above-mentioned conventional problems.
【0008】次に、この発明に係わる伸縮アンテナ用ス
テンレス鋼の成分組成(重量%)の限定理由について説
明する。Next, the reasons for limiting the component composition (% by weight) of the stainless steel for a telescopic antenna according to the present invention will be described.
【0009】C:0.05%以下 Cは溶接による熱影響部における耐食性を劣化させるお
それがあるため、このような耐食性の劣化を防止するた
めに0.05%以下とした。C: 0.05% or less Since C may deteriorate the corrosion resistance in the heat affected zone due to welding, the content of C is set to 0.05% or less in order to prevent such deterioration of the corrosion resistance.
【0010】Si:1.0%以下 Siは鋼溶製時において脱酸剤として作用する元素であ
るが、このSiが多量に含まれていると熱間加工性を低
下させることとなるので0.1%以下とした。Si: 1.0% or less Si is an element which acts as a deoxidizing agent during steel melting, but if a large amount of this Si is contained, hot workability is deteriorated. 1% or less.
【0011】Mn:2.0%以下 Mnは鋼溶製時において脱酸剤および脱硫剤として作用
する元素であるが、このMnが多量に含まれていると冷
間加工性を低下させることとなるので2.0%以下とし
た。Mn: 2.0% or less Mn is an element which acts as a deoxidizing agent and a desulfurizing agent during the melting of steel, but if a large amount of this Mn is contained, cold workability is deteriorated. Therefore, it was set to 2.0% or less.
【0012】P:0.05%以下 P含有量が多いと冷間加工性を低下させることとなるの
で0.05%以下とした。P: 0.05% or less If the content of P is large, the cold workability is deteriorated, so the content is made 0.05% or less.
【0013】S:0.001%以下 S含有量が多くなると鋼中の介在物が増加して冷間加工
性を低下させることとなるので、0.001%以下とし
た。S: 0.001% or less If the S content increases, the inclusions in the steel increase and the cold workability deteriorates, so the content was made 0.001% or less.
【0014】Ni:9〜14% Niはオーステナイト生成元素であって鋼の耐食性向上
に有用な元素であるが、冷間加工に際して加工誘起マル
テンサイトの生成による耐食性の低下を防止するために
は9%以上含有させることが必要である。しかし、多く
含有してもコストの増加に見合う程の効果を得ることが
できないので14%以下とした。Ni: 9 to 14% Ni is an austenite forming element and is an element useful for improving the corrosion resistance of steel, but in order to prevent the deterioration of the corrosion resistance due to the formation of work-induced martensite during cold working, it is 9 % Or more is necessary. However, even if a large amount is contained, it is not possible to obtain the effect commensurate with the increase in cost, so the content is set to 14% or less.
【0015】Cr:22〜24% Crはフェライト生成元素であるが鋼の耐食性向上に有
用な元素であるので22%以上含有させることが必要で
ある。しかし、多く含有するとアンテナとして有害なフ
ェライト相を生成することとなるため、このようなフェ
ライト相の生成をおさえるために24%以下とした。Cr: 22-24% Cr is a ferrite forming element, but it is an element useful for improving the corrosion resistance of steel, so it is necessary to contain 22% or more. However, if a large amount is contained, a harmful ferrite phase is generated as an antenna. Therefore, the content is set to 24% or less in order to suppress the generation of such a ferrite phase.
【0016】Mo:1〜2% Moは耐食性の向上に有用な元素であり、錆の発生時期
を遅らせるためには1%以上含有させることが必要であ
る。しかし、多量に含有させてもコストの上昇に見合う
程の効果を得ることができないので2%以下とした。Mo: 1-2% Mo is an element useful for improving the corrosion resistance, and it is necessary to contain Mo in an amount of 1% or more in order to delay the rust generation time. However, even if it is contained in a large amount, it is not possible to obtain the effect commensurate with the cost increase, so the content was made 2% or less.
【0017】Cu:0.1〜0.2% Cuは耐食性の向上に有用な元素であり、このような効
果を得るためには0.1%以上含有させるのが良い。し
かし、多量に含有すると溶接性が低下するので0.2%
以下とした。Cu: 0.1 to 0.2% Cu is an element useful for improving the corrosion resistance, and in order to obtain such an effect, it is preferable to contain 0.1% or more. However, if it is contained in a large amount, the weldability deteriorates, so 0.2%
Below.
【0018】N:0.1〜0.2% Nはオーステナイト生成元素であって耐食性を向上させ
るので、0.1%以上含有させるのが良い。しかし、多
すぎると鋼の製造性を低下させるので0.2%以下とし
た。N: 0.1 to 0.2% N is an austenite forming element and improves the corrosion resistance, so it is preferable to contain N by 0.1% or more. However, if it is too large, the manufacturability of steel is deteriorated, so the content was made 0.2% or less.
【0019】[0019]
【発明の作用】この発明に係わる伸縮アンテナ用ステン
レス鋼は上記した成分組成を有するものであり、Cr−
Ni系ステンレス鋼を基本にして、冷間加工による加工
誘起マルテンサイトの生成による耐食性の劣化を防止す
る作用のあるNiの含有量を多くし、耐食性を向上させ
て錆の発生時期を延長する作用があるMoの含有量を多
目にし、錆の進行を防ぐ作用のあるCrの含有量を多く
し、ロール成形性や溶接性などの加工性や耐食性等に影
響するC,Si,Mn,P,S,Cu,N等の微量元素
を調整ないしは規制することとしたから、伸縮アンテナ
を製造する際のロール成形性や溶接性などの加工性に優
れていると共に、素材そのものや溶接部分が冷間加工や
表面研磨加工を受けたときでも加工誘起マルテンサイト
が生じがたく、加工誘起マルテンサイトの生成による耐
食性の低下が防止されて、素材そのものや溶接部分にお
いて錆が発生しにくい耐食性に優れたものとなる。The stainless steel for a telescopic antenna according to the present invention has the above-described composition and is made of Cr-
Based on Ni-based stainless steel, the action of increasing the content of Ni, which has the effect of preventing the deterioration of corrosion resistance due to the formation of work-induced martensite by cold working, improves corrosion resistance and extends the time of rust generation C, Si, Mn, P that increases the content of Mo, increases the content of Cr that has the effect of preventing the progress of rust, and affects the workability such as roll formability and weldability and corrosion resistance. , S, Cu, N and other trace elements have been adjusted or regulated, it has excellent workability such as roll formability and weldability when manufacturing a telescopic antenna, and the material itself and welded parts are cold. Even if it is subjected to hot working or surface polishing, processing-induced martensite is unlikely to occur, preventing deterioration of corrosion resistance due to the generation of processing-induced martensite and preventing rust from occurring in the material itself or the welded part. Have and excellent corrosion resistance.
【0020】[0020]
【実施例】表1に示した化学成分組成のオーステナイト
系ステンレス鋼を供試素材とし、耐食性および加工性の
評価試験を行った。[Examples] Austenitic stainless steels having the chemical composition shown in Table 1 were used as test materials, and evaluation tests of corrosion resistance and workability were performed.
【0021】これらのうち、耐食性試験は、CASS試
験を80時間行った後における錆の発生の有無を調べる
ことにより行い、一般部位における耐食性と溶接部位に
おける耐食性に分けて評価した。これらの結果を表2の
耐食性の欄に示す。Among these, the corrosion resistance test was carried out by examining the presence or absence of rust after performing the CASS test for 80 hours, and the corrosion resistance in the general part and the corrosion resistance in the welded part were evaluated separately. The results are shown in the column of corrosion resistance in Table 2.
【0022】また、加工性試験は、実際のアンテナ製造
工程におけるロール成形性および溶接性を調べ、比較例
No.1(SUS304)を基準として良否の評価を行
った。これらの結果を同じく表2の加工性の欄に示す。In the workability test, roll formability and weldability in the actual antenna manufacturing process were examined, and Comparative Example No. The quality was evaluated based on 1 (SUS304). These results are also shown in the processability column of Table 2.
【0023】[0023]
【表1】 [Table 1]
【0024】[0024]
【表2】 [Table 2]
【0025】表1および表2に示すように、Cr含有量
が少なすぎる比較例No.1〜3の鋼では、一般部位お
よび溶接部位における耐食性に劣るものとなっており、
Ni含有量およびMo含有量が多すぎる比較例No.4
の鋼ではロール成形性に劣っていると共にビード溶接性
にも劣っており、Cr含有量が多すぎると共にNi含有
量が少なすぎる比較例No.5の鋼ではロール成形性に
劣るものとなっており、Cr含有量が多すぎる比較例N
o.7の鋼ではロール成形性に劣るものとなっていた。As shown in Tables 1 and 2, Comparative Example No. 3 having a too small Cr content. Steels 1 to 3 are inferior in corrosion resistance in general parts and welded parts,
Comparative Example No. 1 in which the Ni content and the Mo content are too large. Four
In the steel of Comparative Example No. 3, the roll formability was poor and the bead weldability was also poor, and the Cr content was too high and the Ni content was too low. The steel of No. 5 is inferior in roll formability, and has a relatively high Cr content. Comparative Example N
o. Steel No. 7 had poor roll formability.
【0026】これに対して、この発明に係わるステンレ
ス鋼成分組成を満足する発明例No.6A,6B,6C
の鋼では、耐食性および加工性の両方が共に優れたもの
であり、アンテナを製造する際のロール成形性や溶接性
に優れていると共に、アンテナとして使用した後の耐食
性に優れていて、錆の発生を長期にわたって防止するこ
とが可能であり、外観品質を良好なものに維持できると
共にアンテナの伸縮性も長期にわたって円滑なものにで
きることが確認された。On the other hand, Invention Example No. Satisfying the compositional composition of stainless steel according to the present invention. 6A, 6B, 6C
Steel has both excellent corrosion resistance and workability, as well as excellent roll formability and weldability when manufacturing an antenna, and excellent corrosion resistance after being used as an antenna. It was confirmed that the occurrence can be prevented for a long period of time, the appearance quality can be maintained to be good, and the elasticity of the antenna can be smoothed for a long period of time.
【0027】[0027]
【発明の効果】この発明による伸縮アンテナ用ステンレ
ス鋼は、重量%で、C:0.05%以下、Si:1.0
%以下、Mn:2.0%以下、P:0.05%以下、
S:0.001%以下、Ni:9〜14%、Cr:22
〜24%、Mo:1〜2%、Cu:0.1〜0.2%、
N:0.1〜0.2%、残部Feおよび不純物よりな
り、Cr−Ni系ステンレス鋼を基本にして、冷間加工
による加工誘起マルテンサイトの生成による耐食性の劣
化を防止する作用のあるNiの含有量を多くし、錆の発
生時期を延長する作用のあるMoの含有量を多目にし、
錆の進行を防ぐ作用のあるCrの含有量を多くし、ロー
ル成形性や溶接性などの加工性や耐食性等に影響する
C,Si,Mn,P,S,Cu,N等の微量元素を調整
ないしは規制する構成としたから、伸縮アンテナを製造
する際のロール成形性や溶接性などの加工性に優れてい
ると共に、素材そのものや溶接部分が冷間加工や表面研
磨加工を受けたときでも加工誘起マルテンサイトが生じ
がたく、加工誘起マルテンサイトの生成による耐食性の
低下が防止されて、素材そのものや溶接部分において錆
が発生しにくい耐食性に優れたものであることから、自
動車用その他用途における伸縮アンテナの素材として使
用した場合に湿潤環境や塩害環境にさらされたときでも
錆の発生を長期にわたって抑制することが可能であり、
全体的な耐食性が向上したものとなるため酸性雨や火山
灰等による腐食環境下においても腐食による被害を防止
ないしは軽減することが可能になり、アンテナの伸縮性
を長期にわたって円滑なものとすることが可能であると
共に、外観品質をも長期にわたって良好に維持すること
が可能になるという著しく優れた効果がもたらされる。INDUSTRIAL APPLICABILITY The stainless steel for a telescopic antenna according to the present invention has a weight percentage of C: 0.05% or less and Si: 1.0.
% Or less, Mn: 2.0% or less, P: 0.05% or less,
S: 0.001% or less, Ni: 9 to 14%, Cr: 22
-24%, Mo: 1-2%, Cu: 0.1-0.2%,
N: 0.1 to 0.2%, balance Fe and impurities, Ni based on Cr-Ni type stainless steel and having a function of preventing deterioration of corrosion resistance due to formation of work-induced martensite by cold working The content of Mo and increase the content of Mo, which has the effect of extending the rust generation time,
Increasing the content of Cr, which has the effect of preventing the progress of rust, and adding trace elements such as C, Si, Mn, P, S, Cu and N, which affect workability such as roll formability and weldability and corrosion resistance. Since it is adjusted or regulated, it has excellent workability such as roll formability and weldability when manufacturing the telescopic antenna, and even when the material itself or the welded part is subjected to cold working or surface polishing processing. It does not easily generate processing-induced martensite, prevents deterioration of corrosion resistance due to the formation of processing-induced martensite, and is excellent in corrosion resistance that does not easily cause rust in the material itself or the welded part. When used as a material for a telescopic antenna, it is possible to suppress rust generation for a long time even when exposed to a humid environment or salt damage environment.
Since the overall corrosion resistance is improved, it is possible to prevent or reduce damage due to corrosion even in a corrosive environment due to acid rain, volcanic ash, etc., and it is possible to make the elasticity of the antenna smooth for a long time. In addition to being possible, the remarkably excellent effect that the appearance quality can be favorably maintained over a long period of time is brought about.
Claims (1)
1.0%以下、Mn:2.0%以下、P:0.05%以
下、S:0.001%以下、Ni:9〜14%、Cr:
22〜24%、Mo:1〜2%、Cu:0.1〜0.2
%、N:0.1〜0.2%、残部Feおよび不純物より
なることを特徴とする伸縮アンテナ用ステンレス鋼。1. By weight%, C: 0.05% or less, Si:
1.0% or less, Mn: 2.0% or less, P: 0.05% or less, S: 0.001% or less, Ni: 9 to 14%, Cr:
22-24%, Mo: 1-2%, Cu: 0.1-0.2
%, N: 0.1 to 0.2%, balance Fe and impurities, stainless steel for telescopic antenna.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP33892891A JPH05171363A (en) | 1991-12-20 | 1991-12-20 | Stainless steel for expansion antenna |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP33892891A JPH05171363A (en) | 1991-12-20 | 1991-12-20 | Stainless steel for expansion antenna |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH05171363A true JPH05171363A (en) | 1993-07-09 |
Family
ID=18322650
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP33892891A Pending JPH05171363A (en) | 1991-12-20 | 1991-12-20 | Stainless steel for expansion antenna |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH05171363A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5638594A (en) * | 1992-12-04 | 1997-06-17 | Harada Kogyo Kabushiki Kaisha | Method for manufacturing a telescopic antenna for vehicles |
JP2012048053A (en) * | 2010-08-27 | 2012-03-08 | Sharp Corp | Developing device and image forming apparatus having the same |
-
1991
- 1991-12-20 JP JP33892891A patent/JPH05171363A/en active Pending
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5638594A (en) * | 1992-12-04 | 1997-06-17 | Harada Kogyo Kabushiki Kaisha | Method for manufacturing a telescopic antenna for vehicles |
JP2012048053A (en) * | 2010-08-27 | 2012-03-08 | Sharp Corp | Developing device and image forming apparatus having the same |
US8699926B2 (en) | 2010-08-27 | 2014-04-15 | Sharp Kabushiki Kaisha | Developing device and image forming apparatus including the developing device |
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