JP4041514B2 - Method for producing release sheet - Google Patents

Description

  The present invention relates to a method for manufacturing a release sheet for peeling a sheet from a fixing member such as a fixing roller or a fixing belt installed in an electrophotographic apparatus such as a copying machine or a laser beam printer.

An electrophotographic apparatus such as a copying machine or a laser beam printer is provided with a heat fixing device for developing an electrostatic latent image formed on a photosensitive drum on a sheet using a developer such as toner and fixing the image thereafter. It has been. The heat fixing device has a fixing member such as a fixing roller and a fixing belt for fixing the toner on the sheet by heating and melting the developer and pressurizing the developer.
2. Description of the Related Art Conventionally, a separation claw is provided on a fixing member and a pressure roller that presses the sheet against the fixing member in order to prevent the sheet from being wound around the roller and hindering smooth operation. This separation claw prevents the paper from being wound around the roller or the like by scooping up the end of the paper while sliding the tip thereof on the outer peripheral surface of the roller or the like.
The width of the contact portion of the separation claw with the roller or the like is about 1 to 10 mm, and 4 to 16 pieces are arranged for one roller or the like. Since the separation claw is locally in contact with the roller or the like, the roller or the like is inevitably partially worn and a good image cannot be obtained. In addition, since the paper is locally contacted with the paper, it is easy to scrape off the developer transferred to the paper, and the paper may be easily soiled due to the scraped developer adhering to the separation claw. There was a problem.
In order to solve such a problem, for example, a paper peeling device capable of making line contact with a roller has been proposed (see Patent Document 1).

  However, the paper peeling device described in the above-mentioned patent document 1 is a plastic plate made of fluororesin or the like having a thickness of 0.05 mm or more fixedly supported on a metal base plate, and a plastic plate slightly protruding from the metal base plate. The tip is in line contact with the fixing roller. For this reason, there is a problem that the tip of the plastic plate is turned up by plastic deformation and the paper peeling performance is lowered.

In particular, developers used in recent electrophotographic apparatuses have improved the color developability, and the binder resin, which is one of the components of the toner, has also moved to a highly transparent polyester system. Since the toner having toner has very high adhesiveness, the paper peeling device described in Patent Document 1 has a problem that the toner adheres to the metal base plate or the joint between the metal base plate and the plastic plate. .
JP 59-188681 A

  The present invention has been made to cope with such a problem, and can sufficiently make line contact with the roller, and does not damage the fixing member such as the roller at the contact portion, and has excellent paper peeling performance for a long time. It aims at providing the manufacturing method of the peeling sheet which can be maintained.

The method for producing a release sheet of the present invention is a method for producing a release sheet comprising a metal plate having a plate thickness of 50 to 300 μm, wherein a sheet is peeled from a fixing member of an electrophotographic apparatus. At least a step of adhering a fluororesin film to an adjacent site via a silicone-based adhesive is provided, and the step of adhering the fluororesin film is performed on the surface of the fluororesin film having a thickness of 10 to 200 μm applied to the metal plate. Then, after applying a silicone adhesive solution and drying by heating, cooling to form a silicone adhesive layer having a thickness of 5 to 50 μm , the fluororesin film is coated on the surface having the silicone adhesive layer. after had laid on a smooth plate and face up, the corner is a roller contact portion of the metal plate is disposed in a central portion of the fluorine resin film, the gold of the corner as a boundary It is characterized by comprising a step of attaching to the surface of the metal plate.
Here, the contact with the fixing member means that one side of the release sheet is in line contact with the axial direction of the fixing member, and the proximity means that the paper can be prevented from being wrapped around the fixing member. It means that one side of the release sheet is disposed close to the fixing member.
The fixing member has various shapes such as a roller shape, a film shape, or a belt shape that can come into contact with the paper in a process of fixing the developer on the unfixed paper on the paper by pressurizing simultaneously with heating. Refers to a member. For example, a fixing roller or a pressure roller.

  A step of applying a surface treatment to the surface of the fluororesin film attached to the metal plate is provided.

The fluororesin film is a polytetrafluoroethylene polymer (hereinafter abbreviated as PTFE), a tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer (hereinafter abbreviated as PFA), a tetrafluoroethylene-hexafluoropropylene copolymer. (Hereinafter abbreviated as FEP) and a tetrafluoroethylene-ethylene copolymer (hereinafter abbreviated as ETFE). In particular, the fluororesin film is PTFE.
In addition, the silicone-based pressure-sensitive adhesive for attaching the fluororesin film and the metal plate contains dimethylpolysiloxane raw rubber.

  By sticking a fluororesin film to a metal plate, particularly a metal thin plate having a thickness of 300 μm or less in contact with or close to the roller, the tip of the metal thin plate is not turned over by plastic deformation. Moreover, since excellent adhesiveness is obtained by using a predetermined silicone-based pressure-sensitive adhesive and performing a surface treatment such as an etching treatment, the durability is excellent.

  The method for producing a release sheet of the present invention includes a step of attaching a fluororesin film via a silicone-based adhesive to at least a portion of a metal plate that is in contact with or close to a fixing member such as a fixing roller or a fixing belt. Thus, a release sheet having excellent paper peelability, high temperature durability and non-toner adhesion can be produced.

  Since the surface of the fluororesin film attached to the metal plate is provided with a surface treatment, the adhesion between the fluororesin film and the silicone-based pressure-sensitive adhesive is improved. As a result, the fluororesin film becomes difficult to peel off from the metal plate.

  Since the thickness of the silicone pressure-sensitive adhesive layer is 5 to 50 μm, the adhesive effect is sufficient and the paper peelability does not deteriorate. If the thickness is less than 5 μm, a sufficient adhesive effect cannot be obtained. If the thickness is more than 50 μm, the peelability of the release sheet decreases due to the relatively thick release sheet.

  Since the fluororesin film is selected from predetermined fluororesins, non-toner adhesion is further improved. Further, since the silicone-based pressure-sensitive adhesive contains dimethylpolysiloxane raw rubber, the fluororesin film can be firmly adhered to the metal thin plate, and the fluororesin film does not peel even when continuously exposed to a high temperature such as a fixing temperature.

An example of a release sheet produced by the production method of the present invention will be described with reference to FIGS. FIG. 1 is a schematic view of a heat roller type fixing device using a release sheet, and FIG. 2 is a partially enlarged perspective view of the release sheet.
The fixing device has a built-in heater 5a, the fixing roller 5 that rotates in the direction of arrow A, the pressure roller 6 that contacts the fixing roller 5 and rotates in the direction of arrow B, and the fixing roller 5 and the pressure roller are in contact with each other. And the release sheet 1 disposed in the vicinity of the nip portion 7 formed in this manner. The release sheet 1 is provided at a position in contact with or close to the fixing roller 5 so that the paper 8 that has passed through the nip portion 7 can be released from the fixing roller 5.
As shown in FIG. 2, the release sheet 1 has a fluororesin film 4 attached to the surface of the metal plate 2 via a metal plate 2 and a silicone-based adhesive 3. The fluororesin film 4 is affixed to a site including a site 1 a where the release sheet 1 is in contact with or close to the fixing roller 5.
Further, the release sheet 1 has a contact width (L) that is substantially the same length as the axial length of the roller. Since the contact width is large, the contact pressure per unit area to the roller is reduced, and local wear on the roller surface can be prevented. Note that the length substantially the same as the axial length of the roller means a length to the extent that the above-mentioned effect is obtained. Specifically, it is at least about half of the axial length of the roller, and the axial length of the roller. Same or slightly longer.

  As a material of the metal plate 2, iron, aluminum, copper, stainless steel or the like can be used. The plate thickness is preferably in the range of 50 to 300 μm. If it is less than 50 μm, it may not be possible to apply a pressure contact force to the roller to secure the peeling force. If it exceeds 300 μm, the paper to be peeled may hit the leading edge of the release sheet, which may cause jamming. There is.

  The thickness of the fluororesin film 4 is preferably in the range of 10 to 200 μm, more preferably 40 to 80 μm. If the thickness is less than 10 μm, the metal sheet may be exposed due to the possibility of tearing due to friction with the developer or slight wear. Moreover, it becomes easy to wrinkle in the sticking process to a metal thin plate, and handling becomes difficult. When the thickness exceeds 200 μm, the paper peelability decreases.

  The material of the fluororesin film 4 is PTFE, PFA, FEP, ETFE, polychlorotrifluoroethylene, chlorotrifluoroethylene-ethylene copolymer, polyvinylidene fluoride, polyvinyl fluoride, tetrafluoroethylene-hexafluoropropylene-per A film made of a known fluororesin of a fluoroalkyl vinyl ether copolymer can be used.

  Among the fluororesin films described above, films made of PTFE, PFA, FEP, and ETFE are excellent in non-adhesiveness to the developer, and also have sufficient heat resistance, so they are suitable for the release sheet according to the present invention. It is. In addition, by forming the fluororesin film from a fluororesin blended with carbon fine powders such as ketjen black and acetylene black, it is possible to prevent a decrease in paper peelability due to static electricity.

  The fluororesin film is preferably subjected to a surface treatment on the surface attached to the metal plate. Here, the surface treatment is a treatment for enhancing the adhesion effect when the fluororesin film is adhered to the metal plate via a silicone-based pressure-sensitive adhesive material described later. For example, corona discharge treatment, sputter etching treatment, plasma etching treatment, metal sodium treatment, ultraviolet irradiation treatment and the like can be mentioned.

Examples of the silicone pressure-sensitive adhesive used in the present invention include a pressure-sensitive adhesive obtained by condensing a copolymer composed of SiO ₂ units and (CH ₃ ) ₃ SiO units and diorganopolysiloxane raw rubber. By using this silicone-based pressure-sensitive adhesive, the fluororesin film can be firmly bonded to the metal plate, and particularly important, the adhesive effect can be maintained even at the fixing temperature. Further, the pressure-sensitive adhesive layer can be thinned, and the pressure-sensitive adhesive layer does not increase the thickness of the release sheet so as to impair the release function. The thickness of the silicone-based pressure-sensitive adhesive layer should be in the range of 5 to 50 μm. If it is thinner than 5 μm, sufficient adhesive effect cannot be obtained, and if it is thicker than 50 μm, the thickness of the release sheet becomes relatively thick. This is not preferable because the paper peelability is lowered.

  The release sheet manufactured by the manufacturing method of the present invention can be used to release a sheet from a fixing member such as a fixing roller or a fixing belt installed in an electrophotographic apparatus.

Example 1
A metal thin plate made of stainless steel (SUS304CSP) having a thickness of 100 μm was cut into a contact width (L) of 300 mm in length and 40 mm in width to prepare a metal thin plate as a release sheet substrate. The burrs generated on the cut surface of the release sheet substrate were carefully removed, and the corners that would be in contact with the roller were rounded to a radius of curvature of about R0.01 mm to R0.03 mm.
A PTFE film having a thickness of 50 μm (Bearly FL3090 manufactured by NTN Precision Resin Co., Ltd.) was prepared as a fluororesin film, and an etching process was performed in which the surface to be attached to the metal thin plate was immersed in an ammonia solution of metal sodium.
A silicone-based pressure-sensitive adhesive solution containing dimethylpolysiloxane raw rubber (KR101 manufactured by Shin-Etsu Chemical Co., Ltd.) was uniformly applied to the etched surface of the fluororesin film and dried by heating at 120 to 200 ° C. Thereafter, it was naturally cooled to room temperature to form a silicone adhesive layer having a thickness of about 30 μm.

Lay the fluororesin film on a smooth plate so that it does not become wrinkled with the surface with the adhesive layer facing up, and then thoroughly degrease the chamfered metal sheet with petroleum benzine, then in the center of the fluororesin film The roller contact part which rounded the corner | angular part of a metal thin plate was arrange | positioned. The film was affixed to the surface of the thin metal plate with this roller contact portion as a boundary.
In this way, a release sheet was formed by adhering the fluororesin film to the roller contact portion and the back surface with a silicone-based adhesive. The total thickness of the release sheet is 230 μm.

This release sheet is set in the fixing section of a heat roller type test copying machine (fixing temperature 190 ° C, A4 copying speed 57 sheets / min), and a line chart with an image ratio of 30% is used as the original and A4 plain paper is used. A copy test with 5,000 continuous paper passes was performed up to 30,000. The test machine was stopped every 5,000 sheets, and the copied paper was visually checked for image degradation. Further, the release sheet was removed from the fixing portion, and the wear of the fluororesin, the presence or absence of toner adhesion, and the wear state of the fixing roller were confirmed.
As a result of the test, the image of the release sheet of Example 1 was not reduced until the end of the 30,000 sheet passing test, and the fluororesin film confirmed after the end of the sheet passing test was not damaged. Further, no toner adhered to the release sheet, and further no wear of the fixing roller was observed.

Comparative Example 1
The same thin metal plate as in Example 1 was prepared, and a PTFE film having a thickness of 50 μm (Bearly FL3090 manufactured by NTN Precision Resin Co., Ltd.) was applied to the thin metal plate from one side of the thin metal plate so that one end thereof was a free end. It was fixed and supported by projecting a length of mm.
This release sheet was set in the test copying machine used in Example 1, and the same copying test by continuous paper passing as in Example 1 was performed.
As a result of the test, it was confirmed that the paper peeling device of Comparative Example 1 was adhered to the metal thin plate after 10,000 sheets were confirmed. However, since no image degradation was observed on the paper after copying, the test was continued. After 15,000 sheets, deformation of the plastic plate and image degradation on the paper after copying were observed. For this reason, subsequent tests were discontinued.

Comparative Example 2
A release sheet identical to that of Example 1 was prepared except that the fluororesin film was replaced with a PTFE film with an acrylic adhesive (Nitoflon adhesive tape manufactured by Nitto Denko Corporation).
This release sheet was set in the test copying machine used in Example 1, and the same copying test by continuous paper passing as in Example 1 was performed.
As a result of the test, the image of the release sheet of Comparative Example 2 was not deteriorated until 5,000 sheets were passed, but jamming occurred until about 9,000 sheets were passed. When the release sheet was confirmed, the fluororesin film was peeled off from the metal thin plate, and the toner entered the gap where the metal thin plate and the film were peeled off.

It is a schematic diagram of a fixing device using a release sheet. It is a partial expansion perspective view of a peeling sheet.

Explanation of symbols

DESCRIPTION OF SYMBOLS 1 Release sheet 2 Metal plate 3 Silicone adhesive 4 Fluororesin film 5 Fixing roller 6 Pressure roller 7 Nip part 8 Paper

Claims (5)

In a method for producing a release sheet made of a metal plate having a thickness of 50 to 300 μm , which peels paper from a fixing member of an electrophotographic apparatus,
At least a step of attaching a fluororesin film via a silicone-based adhesive to at least a portion of the metal plate that is in contact with or close to the fixing member,
The process of attaching the fluororesin film is
A silicone adhesive solution is applied to the surface of the fluororesin film with a thickness of 10 to 200 μm applied to the metal plate, dried by heating, and then cooled to form a silicone adhesive layer with a thickness of 5 to 50 μm. After
After had laid on the fluororesin film to face up to the surface having the silicone adhesive layer smooth on the plate, placing the corner is a roller contact portion of the metal plate in the central portion of the fluororesin film A method for producing a release sheet, comprising the step of adhering to the surface of the metal plate with the corner as a boundary.   The method for producing a release sheet according to claim 1, further comprising a step of performing a surface treatment on a surface of the fluororesin film attached to the metal plate. The fluororesin film is at least one selected from a polytetrafluoroethylene polymer, a tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer, a tetrafluoroethylene-hexafluoropropylene copolymer, and a tetrafluoroethylene-ethylene copolymer. It is a resin film, The manufacturing method of the peeling sheet of Claim 1 or Claim 2 characterized by the above-mentioned. The method for producing a release sheet according to claim 3 , wherein the fluororesin film is a polytetrafluoroethylene polymer. The method for producing a release sheet according to any one of claims 1 to 4 , wherein the silicone-based pressure-sensitive adhesive contains dimethylpolysiloxane raw rubber.

Images